• Title/Summary/Keyword: pea

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Polymerization and Effect of Organic/Organic Core Shell Binder (Organic/organic Core Shell 바인더의 중합과 처리영향)

  • Sim, Dong-Hyun;Ban, Ji-Eun;Kim, Min-Sung;Seul, Soo-Duk
    • Polymer(Korea)
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    • v.32 no.5
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    • pp.470-477
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    • 2008
  • Core shell binder of organic/organic pair that has two different properties within a particle were prepared by a step emulsion polymerization of methacrylate (MMA), styrene (St), ethyl acrylate (EA), butyl acrylate (BA), and 2-HEMA by using an water soluble initiator(APS) in the presence of an anionic surfactant (SDBS). Unwoven tensile strength of the core shell binder after processing and measuring the PSt/PMMA/2-HEM core shell with the binder is a value represents the highest was $10.75\;kg_f$/2.5cm, elongation measurements PEA/PBA core shell binder showed the highest value was 120.00%. In conclusion, using the core shell binders were able to control the mechanical properties such as tensile strength and elongation.

Potential Functional Role of Phenethylamine Derivatives in Inhibiting Dopamine Reuptake: Structure-Activity Relationship

  • Dooti Kundu;Anlin Zhu;Eunae Kim;Suresh Paudel;Choon-Gon Jang;Yong Sup Lee;Kyeong-Man Kim
    • Biomolecules & Therapeutics
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    • v.31 no.1
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    • pp.108-115
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    • 2023
  • Numerous psychotropic and addictive substances possess structural features similar to those of β-phenethylamine (β-PEA). In this study, we selected 29 β-PEA derivatives and determined their structure-activity relationship (SAR) to their ability to inhibit dopamine (DA) reuptake; conducted docking simulation for two selected compounds; and identified their potential functionals. The compounds were subdivided into arylethylamines, 2-(alkyl amino)-1-arylalkan-1-one derivatives and alkyl 2-phenyl-2-(piperidin-2-yl)acetate derivatives. An aromatic group, alkyl group, and alkylamine derivative were attached to the arylethylamine and 2-(alkyl amino)-1-arylalkan-1-one derivatives. The inhibitory effect of the compounds on dopamine reuptake increased in the order of the compounds substituted with phenyl, thiophenyl, and substituted phenyl groups in the aromatic position; compounds with longer alkyl groups and smaller ring-sized compounds at the alkylamine position showed stronger inhibitory activities. Docking simulation conducted for two compounds, 9 and 28, showed that the (S)-form of compound 9 was more stable than the (R)-form, with a good fit into the binding site covered by helices 1, 3, and 6 of human dopamine transporter (hDAT). In contrast, the (R, S)-configuration of compound 28 was more stable than that of other isomers and was firmly placed in the binding pocket of DAT bound to DA. DA-induced endocytosis of dopamine D2 receptors was inhibited when they were co-expressed with DAT, which lowered extracellular DA levels, and uninhibited when they were pretreated with compound 9 or 28. In summary, this study revealed critical structural features responsible for the inhibition of DA reuptake and the functional role of DA reuptake inhibitors in regulating D2 receptor function.

South-South Collaborations: A Policy Recommendation Model for Sustainable Win-Win Infrastructure Partnerships Based on Sino - Ghana and Nigeria Case.

  • Eshun, Bridget Tawiah Badu;Chan, Albert P.C.;Oteng, Daniel;Antwi-Afari, Maxwell Fordjour
    • International conference on construction engineering and project management
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    • 2022.06a
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    • pp.33-41
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    • 2022
  • Infrastructure procurement has been a major engagement route between China and Africa. This contributes immensely to the gradual infrastructure development seen on the continent. However, maturing discourse purports that these infrastructure collaborations lack intentionality in the continuous development of strategic guidelines and policies for effective implementation despite their uniqueness and criticality. This study proposes that an efficient approach to policy recommendations is through the political and economic analysis (PEA) of these partnerships using public-private partnership (PPP) optics. Unquestionably, these partnerships are representative of the concept of diplomatic transnational public-private partnership (DT-PPP) where infrastructure is procured through the collaboration of public (African governments) and private sector (Chinese state-owned corporations) who provide the managerial, financial, and technical resources for the project implementation. Given the quest for sustainable win-win, this study identifies strategies towards the realization of win-win in the implementation (i.e enablers of win-win) such that fairness and co-benefit, as well as interests, will be achieved. Thus, based on the PEA framework, case scenarios from Ghana and Nigeria using expert interviews identify the criticalities and best practices for the realization of these enablers at the development phase. Findings indicate more effort is required of the public sector (African host countries) in terms of people, structure/institutions, and the implementation processes. Recommendations include improvement of environmental management structures, contract administration procedures, external stakeholders/local community engagement mechanisms, knowledge and technology transfer procedures, and sector-based project operation and maintenance culture and systems. Additionally, actors must have emotional intelligence, good problem-solving abilities, and overall ensure cordial relationships for continued bilateral cooperation.

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Space Charge Measurement as a Diagnostic Tool to Monitor Ageing in Polymeric Materials

  • Chen, George
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.5
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    • pp.235-239
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    • 2006
  • Charge dynamics in polymeric materials after aged under ac electric field using the pulsed electroacoustic (PEA) technique is reported. The emphasis is placed on charge decay. The charge dynamics of the ac aged additive free low density polyethylene (LDPE) samples under dc bias differ from the sample without ac ageing, indicating changes brought in by ac ageing. It is believed that a slow decay rate of charge in the ac aged sample is related to the formation of deep traps in the material. However, chemical analysis by infrared spectroscope (FTIR) and Raman microscope reveals no significant chemical changes taken place in the bulk of the material after ac ageing. Further experiments on irradiated LDPE have revealed a similar behaviour, i.e. the charge decay is slower in irradiated samples than that of fresh sample. The findings presented clearly indicate that space charge measurement can be used as a diagnostic tool to monitor ageing in polymeric materials.

Studies on the Nodulation ana its Effects on the Growth of Several Pulse Crops in the Volcanic Soil (화산회토에 있어서 몇가지 두과작물의 근류착생 및 작물생육에 미치는 영향(제주))

  • Yang-Mun Park
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.21 no.2
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    • pp.277-280
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    • 1976
  • In order to obtain the fundamental informations on the nodulation and its effect on growth of pulse crops in volcanic soil, 6 legume crops were planted in the newly reclaimed land of Cheju-do. The attached nodule weight was in the order of senna, pea, soybean (hill), white clover and kidney beans.

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Interfacial Properties and Microfailure Degradation Mechanisms of Bioabsorbable Composites for Implant Materials using Micromechanical Technique and Acoustic Emission (Micromechanical시험법과 Acoustic Emission을 이용한 Implant용 생흡수성 복합재료의 계면물성과 미세파괴 분해메카니즘)

  • Kim, Dae-Sik;Park, Joung-Man;Kim, Sung-Ryong
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.05a
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    • pp.263-267
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    • 2001
  • The changes of interfacial properties and microfailure degradation mechanisms of bioabsorbable composites with hydrolysis were investigated using micromechanical test and acoustic emission (AE). As hydrolysis time increased, the tensile strength, the modulus and the elongation of PEA and bioactive glass fibers decreased, whereas those of chitosan fiber changed little. Interfacial shear strength (IFSS) of bioactive glass fiber/poly-L-lactide (PLLA) composite was significantly higher than that two other systems. The decreasing rate of IFSS was the fastest in bioactive glass fiber/PLLA composite, whereas that of chitosan fiber/PLLA composite was the slowest. With increasing hydrolysis time, distribution of AE amplitude was narrow, and AE energy decreased gradually.

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Charge Accumulation in Glass under Electron Beam Irradiation (전자빔 조사중 유리의 전하축적)

  • Cho, Jae-Chul;Hwang, Jong-Sun
    • Proceedings of the KIEE Conference
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    • 2008.09a
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    • pp.235-236
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    • 2008
  • Charging of spacecraft occurs in plasma and radiation environment. Especially, we focused on an accident caused by internal charging in a glass material that was used as the cover plate of solar panel array, and tried to measure the charge distribution in glass materials under electron beam irradiation by using a PEA (Pulsed Electro-Acoustic method) system. In the case of a quartz glass (pure $SiO_2$), no charge accumulation was observed either during or after the electron beam irradiation. On the contrary, positive charge accumulation was observed in glass samples containing metal-oxide components. It is found that the polarity of the observed charges depends on the contents of the impurities. To identify which impurity dominates the polarity of the accumulated charge, we measured charge distributions in several glass materials containing various metal-oxide components and calculated the trap energy depths from the charge decay characteristics of all glass samples.

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Interfacial Breakdown Characteristics in XLPE/EPDM Laminate as a function of Additives (XLPE/EPDM laminate의 첨가제에 따른 전하분포특성)

  • 남진호;서광석
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2000.11a
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    • pp.77-80
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    • 2000
  • In order to determine what influences the interfacial charge in EPDM/XLPE laminates, We used PEA (pulsed electroacoustic) method. Interfacial properties such as space charge accumulation and breakdown strength in crosslinked polyethylene (XLPE)/ethylene-propylene-diene monomer (EPDM) laminates were investigated. Interfacial charge develops when the EPDM is laminated with XLPE. It showed the positive polarity same as the simulation in case on intercase of EPDM/XLPE. In case of coupling agent added silicone oil, as increasing the content of coupling agent, the interfacial charge decreased. Details of the results are given and their origins discussed.

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Electrical Properties of Polyaniline Blends (폴리아닐린 블랜드의 전기적 특성)

  • Kim, Won-Jung;Kim, Yun-Sang;Kim, Tae-Young;Kim, Jong-Eun;Suh, Kwang-S.
    • Proceedings of the KIEE Conference
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    • 2003.10a
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    • pp.95-97
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    • 2003
  • This paper describes electrical properties such as electrical conduction characteristics and space charge distributions of polyaniline/polystyrene conducting blends. It is interesting to note that the charging current decreased as the temperature was elevated when DC voltage was applied, and also the hopping distance decreased with the increase of temperature for the PANI/HIPS blends, while generally, the hopping distance decreases as the charging current increases. It is exposed that this result is opposed to widely known phenomenon. It could be examined viewing space charge distributions by a pulsed electroacoustic (PEA) method.

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Factors influencing the penetration kinetics of PVAm solution in z-direction of paper (PVAm 용액 종이 두께 방향 침투 kinetics에 영향하는 인자들)

  • Cho, Byoung-Uk;Won, Jong-Myoung;Moon, Eun-Sik;Choi, Do-Chim
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.04a
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    • pp.31-35
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    • 2011
  • Factors influencing penetration kinetics of PVAm solution into paper were investigated with ultrasonic Penetration Evenness Analyzer (PEA). Paper structure was varied by changing basis weight, freeness of pulp, calendering, number of plies and filler addition and hydrophobicity of paper was varied by adding AKD. Important factors affecting liquid penetration are found to be pore structure and hydrophobicity of paper. Pore structure of paper can be designed by controlling refining degree and filler addition. Hydrophobicity of paper can be controlled by internal sizing.

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