• The Journal of Advanced Prosthodontics
• /
• v.5 no.3
• /
• pp.305-311
• /
• 2013

PURPOSE. Over the past years, the adhesion of fiber posts luted with simplified adhesive systems has been a matter of great interest. The aim of this study was to assess the post retentive potential of a self-adhesive resin cement using different adhesive systems to compare the push-out bond strengths of fiber posts. MATERIALS AND METHODS. The post spaces of 56 mandibular premolar roots were prepared and divided into 4 experimental groups and further divided into 2 subgroups according to testing time (n=7). The fiber posts (Rely X Fiber Post) were luted with a self-adhesive resin cement (RelyX Unicem) and one of the following adhesive systems: no adhesive, a total-etch adhesive resin (Single Bond), a two-step self-etch adhesive resin (Clearfil SE Bond) and a one-step self-etch adhesive resin (Clearfil S3 Bond). Each root was cut horizontally, and 1.5 mm thick six root segments were prepared. Push-out tests were performed after one week or three months (0.5 mm/min). Statistical analysis were performed with three-way ANOVA (${\alpha}$=.05). RESULTS. Cervical root segments showed higher bond strength values than middle segments. Adhesive application increased the bond strength. For one week group, the total-etch adhesive resin Single Bond showed higher bond strength than the self-adhesive resin cement RelyX Unicem applied without adhesive resin at middle region. For 3 months group, the two-step self-etch adhesive resin Clearfil SE Bond showed the highest bond strength for both regions. Regarding the time considered, Clearfil SE Bond 3 months group showed higher bond strength values than one week group. CONCLUSION. Using the adhesive resins in combination with the self-adhesive resin cement improves the bond strengths. The bond strength values of two-step self-etch adhesive resin Clearfil SE Bond improved as time passes.

• Steel and Composite Structures
• /
• v.44 no.4
• /
• pp.519-529
• /
• 2022

Sandwich structures with the superior mechanical properties such as high stiffness and strength-to-weight ratio, good thermal insulation, and high energy absorption capacity are used today in aerospace, automotive, marine, and civil engineering industries. These structures are composed of moderately stiff, thin face sheets that withstand the majority of transverse and in-plane loads, separated by a thick, lightweight core that resists shear forces. In this research, the finite element technique is used to simulate a sandwich panel with a truss core under axial compressive stress using ABAQUS software. A review of past experimental studies shows that the bondline between the core and face sheets plays a vital role in the critical failure load. Therefore, this modeling analyzes the damage initiation modes and debonding between face sheet and core by cohesive surface contact with traction-separation model. According to the results obtained from the modeling, it can be observed that the adhesive stiffness has a significant influence on the critical failure load of the specimens. To achieve the full strength of the structure as a continuum, a lower limit is obtained for the adhesive stiffness. By providing this limit stiffness between the core and the panel face sheets, sudden failure of the structure can be prevented.

• Structural Engineering and Mechanics
• /
• v.78 no.3
• /
• pp.319-332
• /
• 2021

The wood-concrete composite is an interesting solution in the field of Civil Engineering to create high performance bending elements for bridges, as well as in the building construction for the design of wood concrete floor systems. The authors of this paper has been working for the past few years on the development of the bonding process as applied to wood-concrete composite structures. Contrary to conventional joining connectors, this assembling technique does ensure an almost perfect connection between wood and concrete. This paper presents a careful theoretical investigation into interfacial stresses at the level of the two interfaces in composite wooden beam- reinforced concrete slab strengthened by external bonding of prestressed composite plate under a uniformly distributed load. The model is based on equilibrium and deformations compatibility requirements in all parts of the strengthened composite beam, i.e., the wooden beam, RC slab, the CFRP plate and the adhesive layer. The theoretical predictions are compared with other existing solutions. This research is helpful for the understanding on mechanical behaviour of the interface and design of the CFRP- wooden-concrete hybrid structures.

• Korean Journal of Heritage: History & Science
• /
• v.54 no.4
• /
• pp.78-89
• /
• 2021

Organic residues analysis is an analysis method that reveals the types of organic material samples by using the characteristic that main components constituting substances are different depending on the species of animals and plants. In this study, scientific analysis of the organic residues attached to wood coffins in the Joseon Dynasty Hoemyo excavated from the site of Singok-dong, Uijeongbu was used to identify the types of remnants and to use them as information to restore the uses of organic materials and the way they lived in the past. As a result of FT-IR analysis of the residue attached to the inside of the wood, it was estimated to be a natural plant resin material. In addition, as a result of analysis by GC-MS to confirm the characteristic factors of natural resins, diterpenoids (abietane) and pimaran (pimarane), such as dehydroabietic acid and pimaric acid (diterpenoid) compounds, and saturated and unsaturated fatty acid components were detected together. Diterpenoid compounds are components mainly found in Pinaceae resins. It is confirmed in the literature that rosin, a representative material of Pinaceae resin, was used as an adhesive material. Considering the situation where an organic material remained at the joint of the wood, the organic material attached to the wood is judged to be an adhesive material made of Pinaceae resin. In addition, the fatty acid component detected together is a component derived from plant oil, and it is presumed to be made by mixing rosin and oil as recorded in previous studies. This study confirms that organic residues remain in the burial environment without losing their characteristics. It is expected that scientific analysis of organic residues will be conducted in the future to accumulate information necessary for the interpretation of past living culture.

• Korean Journal of Heritage: History & Science
• /
• v.55 no.2
• /
• pp.200-211
• /
• 2022

The celadon stools with an openwork ring design which consist of four items as one collection were excavated from Gaeseong, Gyeonggi-do Province. The celadon stools were designated and managed as treasures due to their high arthistorical value in the form of demonstrating the excellence of celadon manufacturing techniques and the fanciful lifestyles during the Goryeo Dynasty. However, one of the items, which appeared to have been repaired and restored in the past, suffered a decline in aesthetic value due to the aging of the treatment materials and the lack of skill on the part of the conservator, raising the need for re-treatment as a result of structural instability. An examination of the conservation condition prior to conservation treatment found structural vulnerabilities because physical damage had been artificially inflicted throughout the area that was rendered defective at the time of manufacturing. The bonded surfaces for the cracked areas and detached fragments did not fit, and these areas and fragments had deteriorated because the adhesive trickled down onto the celadon surface or secondary contaminants, such as dust, were on the adhesive surface. The study identified the position, scope, and conditions of the bonded areas at the cracks UV rays and microscopy in order to investigate the condition of repair and restoration. By conducting Fourier-transform infrared spectroscopy(FT-IR) and portable x-ray fluorescence spectroscopy on the materials used for the former conservation treatment, the study confirmed the use of cellulose resins and epoxy resins as adhesives. Furthermore, the analysis revealed the addition of gypsum(CaSO₄·2H₂O) and bone meal(Ca₁₀ (PO₄)₆(OH)₂) to the adhesive to increase the bonding strength of some of the bonded areas that sustained force. Based on the results of the investigation, the conservation treatment for the artifact would focus on completely dismantling the existing bonded areas and then consolidating vulnerable areas through bonding and restoration. After removing and dismantling the prior adhesive used, the celadon stool was separated into 6 large fragments including the top and bottom, the curved legs, and some of the ring design. After dismantling, the remaining adhesive and contaminants were chemically and physically removed, and a steam cleaner was used to clean the fractured surfaces to increase the bonding efficacy of the re-bonding. The bonding of the artifact involved applying the adhesive differently depending on the bonding area and size. The cyanoacrylate resin Loctite 401 was used on the bonding area that held the positions of the fragments, while the acrylic resin Paraloid B-72 20%(in xylene) was treated on cross sections for reversibility in the areas that provided structural stability before bonding the fragments using the epoxy resin Epo-tek 301-2. For areas that would sustain force, as in the top and bottom, kaolin was added to Epo-tek 301-2 in order to reinforce the bonding strength. For the missing parts of the ring design where a continuous pattern could be assumed, a frame was made using SN-sheets, and the ring design was then modeled and restored by connecting the damaged cross section with Wood epos. Other restoration areas that occurred during bonding were treated by being filled with Wood epos for aesthetic and structural stabilization. Restored and filled areas were color-matched to avoid the feeling of disharmony from differences of texture in case of exhibitions in the future. The investigation and treatment process involving a variety of scientific technology was systematically documented so as to be utilized as basic data for the conservation and maintenance.

• 한국문화재보존과학회:학술대회논문집
• /
• 2005.11a
• /
• pp.179-184
• /
• 2005

Materials used for repairing and restoring both pottery and porcelain are practically organic, which makes the analysis procedure difficult in the course of time. It is, however, important in the field of conservation to analyze the material applied in the past. In consequence, this research will examine the components of the restoration materials collected in the process of ceramic conservation: the fillings using SEM-EDS and FT-IR; retouching materials; the adhesive used between the filling and retouching material.

• Proceedings of the Polymer Society of Korea Conference
• /
• 2006.10a
• /
• pp.346-346
• /
• 2006

Several types of dynamic atomic force microscopy such as tapping-mode, force modulation-mode are commonly cooperated by phase-contrast imaging techniques, which were interpreted as elastic contrast by mistake in the past and are nowadays regarded as the representation of energy dissipative processes. However, as theoretically reported, the situation is not so simple when the strong adhesive interaction is involved. Furthermore, elastic and viscous contributions are not easily divided in the case of polymeric systems. Thus, the interpretation of image contrast for them must be very carefully treated. In this study, we will demonstrate how such contrast mechanisms are complicated, using several miscible and immiscible polymer blend systems as model samples.

• Journal of Mechanical Science and Technology
• /
• v.20 no.12
• /
• pp.2052-2060
• /
• 2006

The wear of engine valve and seat insert is one of the most important factors which affect engine performance. Because of higher demands on performance and the increasing use of alternative fuel, engine valve and seat insert are challenged with greater wear problems than in the past. In order to solve the above problems, a simulator was developed to be able to generate and control high temperatures and various speeds during motion. The wear simulator is considered to be a valid simulation of the engine valve and seat insert wear process with various speeds during engine activity. This work focuses on the different degrees of wear at three different singular test speeds (10 Hz, 25 Hz & multi-Hz). For this study, the temperature of the outer surface of the seat insert was controlled at 350$^{\circ}C$, and the test load was 1960 N. The test cycle number was $6.0{\times}10^6$. The mean ($\pm$standard error) wear depth of the valve at 10 Hz and 25 Hz was 45.1 ($\pm$3.7)$\mu$m and 81.7 ($\pm$2.5)$\mu$m, respectively. The mean wear depth of the seat insert at 10 Hz and 25 Hz was 52.7 ($\pm$3.9)$\mu$m and 91.2 ($\pm$2.7)$\mu$m, respectively. In the case of multi-Hz it was 70.7 ($\pm$2.4)$\mu$m and 77.4 ($\pm$3.8)$\mu$m, respectively. It was found that higher speed (25 Hz) cause a greater degree of wear than lower speed (10 Hz) under identical test condition (temperature, valve displacement, cycle number and test load). In the wear mechanisms of valves, adhesive wear, shear strain and abrasive wear could be observed. Also, in the wear mechanisms of seat inserts, adhesive wear, surface fatigue wear and abrasive wear could be observed.

• Journal of Ocean Engineering and Technology
• /
• v.27 no.2
• /
• pp.33-38
• /
• 2013

In the past, a very popular method for reducing the corrosion on zinc involved the use of chemical conversion layer coatings based on $Cr^{+6}$. However, there is an important problem with using chromium salts as a result of restrictive environmental protection legislation. This study investigated the optimum condition for galvanized steel using an organic/inorganic solution with a Ti composition. In the case of a fixed heat treatment time, the corrosion resistance values of LR-0727(1) and LR-0727(2) were improved as the heat treatment temperature increased, and the optimum minimum temperature decreased with the heat treatment time. At the optimum heat treatment condition of two coating solutions, the heat treatment time of the LR-0727(1) solution was shorter than LR-0727(2) for the same heat treatment temperature. LR-0727(1) coated specimens did not show desquamation, and all of the specimens showed a good adhesive property. In contrast, in the case of the LR-0727(2) coated specimens, desquamation arose. Therefore, the adhesive property of LR-0727(1) was superior to that of LR-0727(2). The pencil hardness had a 3H average for all of the coating solutions and heat treatment conditions. In the case of a corrosion resistance test with boiling water, the coated specimens of LR-0727(1) were discolored, but LR-0727(2) was not. Finally, LR-0727(1) was more moisture proof than LR-0727(2).

• Journal of Adhesion and Interface
• /
• v.11 no.2
• /
• pp.76-83
• /
• 2010

The extensive use of fossil resources over the past century resulted in dwindling supply and surging price of oil and it is strongly suspected that irreversible global climate change might be due to carbon dioxide emitted from combustion of fossil carbons. With this regard, much attention is recently paid to renewable and sustainable resources as alternatives to petroleum. In this review, we considered a range of efforts to replace petroleum-derived chemicals, particularly adhesive materials with renewable and sustainable plant-based biomass feedstock.