• 제목/요약/키워드: particle size effect

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다층도공층의 설계에 의한 인쇄적성 개선(제2보) - 프리코팅층의 안료배합이 탑코팅층의 특성에 미치는 영향 - (Improvement of printability by the new designe of the multi-layered coating structure (II) - The effect of pigment blending in pre-coating layer on characteristics of top-coating layer -)

  • 김선경;원종명;이용규
    • 펄프종이기술
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    • 제48권2호
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    • pp.61-67
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    • 2016
  • This study was carried out in order to investigate the effect of pigment properties in a pre-coating layer on the characteristics of a top-coating layer and the print mottle of the coated paper. Five different pigments were applied for this study as raw materials for the pre-coating layer. The properties and print mottle of the coated paper samples were evaluated according to the coating color formulation. Type of pigments appliied in a pre-coating layer was one of the most important factor to control the properties of pre and top coating layer. Surface properties of pre and top coated paper were improved by blending GCC which had smaller particle size, with clay. Properties of a top-coating layer was affected by the pigment properties used in the pre-coating layer. It was found that print mottle of coated paper can be improved by replacing part of GCC with smaller particle size GCC or clay in pre-coating layer.

Poly-DADMAC과 PSS의 분자량을 달리한 중질탄산칼슘의 개질과 종이 물성에 미치는 영향 (Modification of GCC with Poly-DADMAC and PSS with Different Molecular Weights and its Effect on the Paper Properties)

  • 안정언;이제곤;이혜윤;윤혜정;이학래
    • 펄프종이기술
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    • 제44권5호
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    • pp.21-31
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    • 2012
  • In this study, we modified the surface of ground calcium carbonate (GCC) with polyelectrolytes with different molecular weight using Layer-by-Layer (LbL) multilayering technique and investigated its effect on the paper properties. Polydiallydimethylammonium chloride (poly-DADMAC) and poly sodium 4-styrene sulfonate (PSS) which have different molecular weights were used for LbL multilayering. Zeta potential and particle size of the LbL modified GCC were measured. After preparation of handsheets, their structural and mechanical properties were evaluated. The zeta potential and average particle size of the modified GCC were affected by the molecular weight of anionic polyelectrolyte (PSS). The zeta potential was higher and the particle size was smaller when GCC was treated by PSS with high molecular weight compared to the case with low molecular weight of PSS. The tensile and internal bond strength of the handsheets was increased with an increase in the number of layers on GCC particles, but the molecular weight of polyelectrolyte did not significantly affect the paper strength.

분무건조된 Nd-Fe-B 전구체 입자의 크기조절 및 환원-확산 후 자기 특성에 미치는 영향 (Size Control of Nd-Fe-B Precursor Particles Prepared by Spray Drying and Its Effect on the Magnetic Properties of Nd-Fe-B Alloy Powders after Reduction-Diffusion)

  • 백연경;서영택;이정구;김동수;배동식;최철진
    • 한국분말재료학회지
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    • 제20권5호
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    • pp.359-365
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    • 2013
  • In this study, we fabricated $Nd_2Fe_{14}B$ hard magnetic powders with various sizes via spray drying combined with reduction-diffusion process. Spray drying is widely used to produce nearly spherical particles that are relatively homogeneous. Thus, the precursor particles were prepared by spray drying using the aqueous solution containing Nd salts, Fe salts and boric acid with the target stoichiometric composition of $Nd_2Fe_{14}B$. The mean particle sizes of the spray-dried powders are in the range from one to seven micrometer, which are adjusted by controlling the concentrations of precursor solutions. After debinding the as-prepared precursor particles, ball milling was also conducted to control the particle sizes of Nd-Fe-B oxide powders. The resulting particles with different sizes were subjected to subsequent treatments including hydrogen reduction, Ca reduction and washing for CaO removal. The size effect of Nd-Fe-B oxide particles on the formation of $Nd_2Fe_{14}B$ phase and magnetic properties was investigated.

Fenitrothion과 Tebuconazole의 입상 활성탄 및 차콜에 의한 흡착과 용탈에 관한 연구 (Sorption and Leaching Studies of Fenitrothion and Tebuconazole in Granular Activated Carbon and Charcoal)

  • 이동익;천소을;주영규
    • 아시안잔디학회지
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    • 제20권1호
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    • pp.47-55
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    • 2006
  • 본 실험은 농약 흡착제(adsorbent)로서 입상 활성탄(활성탄 I 및 활성탄 II) 및 차콜의 사용가능성을 알아보기 위하여 흡착질(adsorbate)로 현재 골프장에서 사용하고 있는 살충제인 스미치온(Fenitrothion)과 살균제인 호리쿠어(Tebuconazole)를 대상으로 하였다. 흡착실험에서는 스미치온 및 호리쿠어의 처리 농도별 흡착에 미치는 영향과 흡착제의 입자크기가 흡착에 미치는 영향을 살펴본 결과, 흡착실험에서는 흡착제의 입자 크기가 작을수록 높은 흡착율을 보였으며, 활성탄이 차콜에 비하여 상대적으로 높은 흡착율을 나타내었다. 그러나 스미치온의 탈착(desorption)에 관한 실험에서는 활성탄 및 차콜 모두 1200mm 이상의 강우량에서도 스미치온이 용탈되지 않았으므로, 차콜 또한 활성탄과 함께 골프장 농약 흡착제로서의 이용 가능한 것으로 나타났다.

사질토의 전단거동에 실트 함량이 미치는 영향 (Effect of Silty Soil Content on Shear Behavior of Sandy Soil)

  • 유정석;안광국;강홍식
    • 한국지반환경공학회 논문집
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    • 제21권11호
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    • pp.21-26
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    • 2020
  • 자연상태의 흙은 다양한 크기의 입자로 구성되어 있으며, 이 흙의 역학적 거동 중 전단거동은 입도 분포에 크게 영향을 받는다. 그리고 자연상태의 흙은 조립토와 세립토가 다양하게 혼합되어 존재하기 때문에 그 역학적 성질인 전단특성을 명확히 파악하기 어렵다. 이에 본 연구에서는 흙의 입도 분포가 흙의 전단특성에 미치는 영향을 확인하기 위한 목적으로 조립토는 모래를 세립토는 실트를 이용해 모래에 대한 실트의 함유량을 변화시켜 입도 분포가 다른 사질토를 조성한 후 링 전단시험을 수행하였다. 그리고 물 공급 시 입도 분포가 다른 사질토의 전단특성 변화를 확인하기 위해 링 전단시험 중 물을 공급하여 실험을 수행하였다. 그 결과 실트 함유량이 증가할수록 전단강도는 점차 증가하다 실트 함유량이 모래보다 많아지면 전단강도는 감소하는 것으로 나타났다. 그리고 수분 공급 시 실트 함유량에 따라 잔류전단강도는 완만한 경사를 나타내며 감소하는 것으로 나타났다.

Effect of Unsaturation on the Stability of C18 Polyunsaturated Fatty Acids Vesicles Suspension in Aqueous Solution

  • Teo, Yin Yin;Misran, Misni;Low, Kah Hin;Zain, Sharifuddin Md.
    • Bulletin of the Korean Chemical Society
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    • 제32권1호
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    • pp.59-64
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    • 2011
  • Degree of unsaturation in fatty acid molecules plays an important role in the formation of vesicles. Vesicle formation from C18 fatty acids with different amount of double bonds such as oleic acid, linoleic acid and linolenic acid with the incorporation of 1,2-dipalmitoyl-sn-glycerol-3-phosphoethanolamine-N-[methoxy(polyethylene glycol)-2000] (DPPE-PEG2000) have been examined by TEM. Critical vesicular concentrations (CVC) of the vesicle suspension are determined by turbidity and surface tension methods. The CVC of fatty acids increases when the amount of unsaturation in the alkyl chain increases. On the other hand, stability of vesicle suspension has been examined by using particle size and zeta potential at $30^{\circ}C$. There was a dramatic decrease in particle size measurement from mono-unsaturation to tri-unsaturation which could be due to the effect of fluidity in the membrane bilayer caused by different degree of unsaturation. The values of zeta potential for vesicles that were formed without the incorporation of DPPE-PEG2000 were in the range of -70 mV to -100 mV. It has been observed that the incorporation of DPPEPEG2000 to the vesicle reduces the magnitude of zeta potential. However, this phenomenon does not obviously seen in fatty acid vesicles formed by linoleate-linoleic acid and linolenate-linolenic acid. We therefore conclude that the addition of DPPE-PEG2000 does not effectively improve the stability of the linoleate-linoleic acid and linolenatelinolenic acid vesicle at pH 9.0 after the evaluation of their particle size and zeta potential over a period of 30 days. Although the vesicles formed were not stable for more than 10 days, they have displayed the potential in encapsulating the active ingredients such as vitamin E and calcein. The results show that the loading efficiencies of vitamin E are of encouraging value.

광도가 서울 대기의 오존 생성 및 에어로졸 수 농도에 미치는 영향 (Effect of light intensity on the ozone formation and the aerosol number concentration of ambient air in Seoul)

  • 배귀남;박주연;김민철;이승복;문길주;김용표
    • 한국입자에어로졸학회지
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    • 제4권1호
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    • pp.9-20
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    • 2008
  • The effect of light intensity on the ozone formation and the aerosol number concentration during the photochemical reactions of ambient air was investigated in an indoor smog chamber. The smog chamber consists of a housing, 64 blacklights, and a $2.5-m^3$ reaction bag made of Teflon film. The bag was filled with the unfiltered ambient air in Seoul from January 10 to March 18, 2002. In this work, the photolysis rate of $NO_2$, $k_1$ was used as an index of light intensity. Three levels of light intensity were controlled by changing the number of blacklights turned on among 64 blacklights: $0.29min^{-1}$ (50%), $0.44min^{-1}$ (75%), $0.57min^{-1}$ (100%). The ozone concentration increased rapidly within 10 minutes after irradiation irrespective of light intensity, thereafter it increased linearly during the irradiation. The ozone production rate seems to be dependent on both the light intensity and the quality of ambient air introduced into the reaction bag. The change in aerosol number concentration also depended on both the light intensity and the ambient air quality, especially aerosol size distribution. Based on the initial ambient aerosol size distributions, the photochemical potential for aerosol formation and growth is classified into two cases. One is the case showing aerosol formation and growth processes, and the other is the case showing no apparent change in particle size distribution.

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전동볼밀의 복합재 제조공정에서 각종 실험조건에 따른 입자형상 변화 및 DEM 시뮬레이션을 통한 밀링 효율의 고찰 - 회전속도, 매체크기, 매체재질의 영향 (Particle Morphology Behavior and Milling Efficiency by DEM Simulation during Milling Process for Composites Fabrication by Traditional Ball Mill on Various Experimental Conditions - Effect of Rotation Speed, Ball Size, and Ball Material)

  • 보르 암갈란;바춘흘루 이치커;자갈사이항 바트체첵;이재현;최희규
    • Korean Chemical Engineering Research
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    • 제56권2호
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    • pp.191-203
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    • 2018
  • 이 연구는 각각 크기와 재질이 다른 3 가지 종류의 분쇄 매체를 이용하여 회전속도와 밀링 시간의 따른 구리 (Cu) 분말의 형상변화의 과정에 미치는 영향을 관찰하고, 볼 움직임의 DEM시뮬레이션을 행하였다. 전동볼밀에서 볼 움직임의 3차원 시뮬레이션을 통해 분쇄 메커니즘을 규명하기 위하여 분쇄매체의 힘, 운동에너지, 매체 운동속도 등을 계산하였다. 시뮬레이션에서는 회전속도, 볼 재질, 운동속도, 마찰계수 등을 실제 실험조건과 동일하게 조건을 맞추어 투입되는 에너지의 변화량도 계산하였다. 주사전자현미경 결과를 살펴보면 볼 직경이 작을 때 입자형상이 불규칙한 형태에서 구형 형태로 변화하는 것을 알 수 있었다.

Ammonia gas를 침전제로 이용한 PZT 미분말의 합성 (The Preparation of PZT Fine Powder Using Ammonia Gas as a Precipitator)

  • 현성호;김정환;이한철;허윤행
    • 환경위생공학
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    • 제14권1호
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    • pp.62-69
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    • 1999
  • In this study, the synthesis of PZT powder by bubble column reactor was investigated at various reaction conditions. As a result, the volume % of $NH_3$ gas used as a precipitator had no effect on the synthesis, but the more research is needed to control particle size.As a carrier gas, Ar, $O_2$ and air only increased the stirring effect but had no effect chemically on the synthesis. The calcination temperature of prepared PZT powder was about $500-600^{\circ}C$ and the meanparticle size of synthesized PZT powder was about $0.17{\mu}m$. The grain size of sintered body is about $0.5~3{\mu}m$ and this is similar with the value of commercial products.

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Processing Effects of Feeds in Swine - Review -

  • Chae, B.J.;Han, In K.
    • Asian-Australasian Journal of Animal Sciences
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    • 제11권5호
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    • pp.597-607
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    • 1998
  • Processing is generally employed to alter the physical and chemical properties of feeds used in pig diets, using hammer/roller mills, pellet mills and extruders/expanders. The reported optimum particle sizes of corn are approximately $500{\mu}m$, $500-700{\mu}m$, $400-600{\mu}m$, for nursery, growing-finishing, and breeder pigs respectively. Optimum particle size of grains are affected by diet complexity. There was a trend towards reducing particle size in order to increase ADG in pigs fed a simple diet, though such was not the case for pigs fed a complex diet. Uniformity of particle size also affects the nutritional values of swine feeds. Uniform particle sizes would consistently give greater nutrient digestibilities. In terms of pellet quality, it is reported that a higher incidence of fmes in pelleted feeds has a direct correlation with poorer feed conversion ratio in pigs. Particle and pellet sizes are also very important for pelleting in terms of grinding, digestibility, stomach ulceration and pellet durability. A particle size of $600{\mu}m$, or slightly less, seemed optimal for com in fmishing pigs, and the 5/32 in. diameter pellets supported the best efficiencies of gain during nursery and finishing phases. Extruder and/or expander processes would allow the feed industry an increased flexibility to utilize a wider spectrum of feed ingredients, and improve pellet quality of finished feeds. It would appear that extruded or expanded diets containing highly digestible ingredients have little effect on the growth performance of pigs, and the feeding values of the feeds over pelleted diets were not improved as pigs grew. The extruder or expander is much more effective than a pelletizer in salmonella control. Gastric ulcerations and/or keratinizations were consistently reported in pigs fed mash and processed diets containing finely ground grains, whereas carcass quality was not affected by diet processing methods such as pelleting, extruding or expanding. In corn- or sorghum-based diets, the electrical energy consumption is 4-5 times higher in the expanding than in the pelleting process. But the expander's processing cost was half of that shown by an extruder. Finally, the decision of which feed processing technology to adopt would depend on the processing cost, and any potential improvement in growth performance and digestibilities of nutrients should offset the increased operating and capital costs related to the extruder/expander technology over mash or pelleting processes in pigs.