• 전기화학회지
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• 제11권4호
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• pp.313-318
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• 2008

본 연구에서는 백금의 입자크기가 내구성과 활성에 미치는 영향을 고찰하였다. 상용 Pt/C의 열처리를 통해 백금 입자 크기를 $3.5{\sim}9\;nm$로 조절하였고, XRD와 TEM을 통해 이를 확인하였다. 촉매의 내구성 분석을 위해 가속 실험을 실시하였고, 촉매 활성 측정을 위해 산소환원반응 실험을 하였다. 백금의 입자크기를 증가시킬수록 내구성은 향상되었으나 촉매의 활성이 저하되었다. 즉 촉매의 내구성과 활성은 반비례관계가 성립된다는 것을 확인하였다. 그리고 저하된 촉매 활성과 내구성을 향상시키기 위해, 합금 촉매를 사용하였다.상용 Pt/C의 최대 전력 밀도는 약 $507.6\;mV/cm^2$ 이고, PtCo/C 합금촉매는 $585.8\;mV/cm^2$이었다. 전기화학적 표면적은 상용 Pt/C는 약 60%정도 감소하였고, PtCo/C 합금촉매는 약 24%정도의 감소율을 나타냈다. 따라서 백금의 입자 크기 조절과 합금화를 통해 백금의 내구성과 활성을 동시에 높일 수 있었다.

• 상하수도학회지
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• 제17권4호
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• pp.528-533
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• 2003

Bubble size is one of the most important parameters affecting DAF (Dissolved-Air-Flotation) process. It is generally known that small bubbles are preferred. However, the fact seems to be based on the particle removal efficiency at contact zone only, without considering separation zone. Besides, the effect of bubble size on the overall DAF process has not been fully investigated yet. Therefore, the effect of bubble size on collision efficiency, collision chances, and surface loading rate is calculated using theoretical models, and the results are discussed in this paper.

• 한국산업보건학회지
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• 제6권2호
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• pp.265-271
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• 1996

This study was conducted to investigate distribution of lead particles by operation of industry, to evaluate the effect of particle size on the absorption to workers, and to recommend the Occupational Health Standard for lead. Total lead concentrations in the secondary smelting industry were higher than those in the battery and litharge manufacturing industry. Total lead concentrations in other industries except radiator manufacturing industry exceeded the standard of $50{\mu}g/m^3$. Only radiator manufacturing industry indicated lead concentrations significantly lower than those in other industries(p<0.05). Average blood lead level of workers was $85.1{\mu}g/dl$ in secondary smelting manufacturing, $51.3{\mu}g/dl$ in the battery manufacturing, and below $40{\mu}g/dl$ in the litharge and radiator manufacturing industry. Blood lead levels of workers by industry were significantly different(p<0.05). From relationship between airborne lead concentrations by size and lead in blood, confidence limits of airborne lead concentration equivalent to $40{\mu}g/dl$ of permissible limit in blood, was $147.9-489.8{\mu}g/m^3$ as total lead and $28.8-79.4{\mu}g/m^3$ as ACGIH-RPM. It is recommended that two separate occupational health standards for lead should be established by particle size. Airborne concentration of $150{\mu}g/m^3$ as fatal lead dust and $30{\mu}g/m^3$ as respirable lead dust was recommended.

• 한국해양공학회지
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• 제12권3호통권29호
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• pp.49-59
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• 1998

The damage mechanism of $Cr_2O_3$ plasma coated soda-lime glass and uncoated glass by steel ball particle impact was analyzed in this study. And the shape variation of the cracks was investigated by stereo-microscope according to the impact velocity and steel ball diameter. In order to improve the damage reduction effect by $Cr_2O_3$ coating layer, crack size was measured and surface erosion state was observed for both of two kinds of specimen after impact experiment. And the results were compared with each other. The 4-point bending test was performed according to ASTM D790 testing method to evaluate the effect of coating layer for bending strength variation. As a result, it was found that the crack size of $Cr_2O_3$ coated specimen was smaller than that of uncoated one, because of the impact absorption by interior pores in the coating layer and the load dispersion by the structural characteristic of the coating layer. For the specimens subjected to the steel ball impact, the bending strength of coated specimen was higher than that of uncoated specimen.

• 지질공학
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• 제9권2호
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• pp.135-145
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• 1999

동적 하중을 받는 지반반응 평가시 필요한 가장 중요한 변수 중에 하나가 지반의 전단탄성계수(G)이다. 지반의 동특성은 시간에 따라 변화하게 되는데, 이 점은 흔히 간과되어져 왔다. 이번 연구를 통하여 일정구속압에서 시간에 따라 변하는 토질 최대전단탄성계수($G_{max}$) 및 그 영향요소에 관해 고찰해보고 몇몇 경험식을 제안하고자 한다. 경험식 작성을 위해 고려된 요소는 선행응력과 선행변형율, 입자크기와 지속응력, 소성지수 등이고, 실제로 가장 큰 영향을 미치는 평균입자직경과 소성지수를 이용한 두개의 경험식을 작성하였다. 끝으로 $G_{max}$의 일시적 변화와 그 원인, 그리고 시간에 따라 증가하는 G가 시사하는 점에 대해 서술한다

• 한국가시화정보학회:학술대회논문집
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• 한국가시화정보학회 2006년도 추계학술대회 논문집
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• pp.125-130
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• 2006

The characteristics of boiling heat transfer and critical heat flux (CHF) behavior of nano-fluids were studied by using various sized silver and alumina nanoparticles. The diameter of nanoparticles was from 2 nm to 250 nm for silver and from 20nm to 40nm for alumina. Pool boiling characteristics and CHF enhancement of nano-fluids with different sized nanoparticles were compared with those of pure water and each nano-fluids. The experiment was performed at atmospheric pressure and the temperature of the pool was maintained constantly by using a flat immersed heater. The concentration of nano-fluids was uniform in all experiments as 0.01g/liter. The results showed that the measured boiling curves were shifted to the right. It demonstrated that the occurrence of nucleate boiling regime in nano-fluids retarded, compared with that of pure water. Also, in nano-fluids, the boiling curves showed that CHF of nano-fluids is significantly enhanced and represented the effect of particle size on boiling characteristics.

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 2006년도 High Temperature Superconductivity Vol.XVI
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• pp.86-86
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• 2006

• 한국유변학회:학술대회논문집
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• 한국유변학회 2002년도 추계학술발표회 논문집
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• pp.117-120
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• 2002

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제36회 동계학술대회 초록집
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• pp.225.1-225.1
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• 2009

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2006년도 추계학술대회 논문집
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• pp.158-160
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• 2006