• Title/Summary/Keyword: particle size effect

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The calculation of stress-strain behavior of Ti-10V-2Fe-3Al alloys (Ti-10V-2Fe-3Al 합금의 응력-변형거동 계산)

  • 오택열
    • Journal of the korean Society of Automotive Engineers
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    • v.11 no.6
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    • pp.38-47
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    • 1989
  • The Finite Element Method has been employed to calculate the effect of particle size, matrix, and volume fractions on the stress-strain relations of .alpha.-.betha. titanium alloys. It was found that for a given volume fraction, the calculated stress-strain curve was higher for a finer particle size than for a coarse particle size within the range of the strains considered, and this behavior was seen for all the different volume fraction alloys considered. The calculated stress-strain curves for three vol. pct .alpha. alloys were compared with their corresponding experimental curve, and in general, good agreement was found.

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Particle Size Effect: Ru-Modified Pt Nanoparticles Toward Methanol Oxidation

  • Kim, Se-Chul;Zhang, Ting;Park, Jin-Nam;Rhee, Choong-Kyun;Ryu, Ho-Jin
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3331-3337
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    • 2012
  • Ru-modified Pt nanoparticles of various sizes on platelet carbon nanofiber toward methanol oxidation were investigated in terms of particle size effect. The sizes of Pt nanoparticles, prepared by polyol method, were in the range of 1.5-7.5 nm and Ru was spontaneously deposited by contacting Pt nanoparticles with the Ru precursor solutions of 2 and 5 mM. The Ru-modified Pt nanoparticles were characterized using transmission electron microscopy, X-ray photoelectron spectroscopy and cyclic voltammetry. The methanol oxidation activities of Ru-modified Pt nanoparticles, measured using cyclic voltammetry and chronoamperometry, revealed that when the Pt particle size was less than 4.3 nm, the mass specific activity was fairly constant with an enhancement factor of more than 2 at 0.4 V. However, the surface area specific activity was maximized on Pt nanoparticles of 4.3 nm modified with 5 mM Ru precursor solution. The observations were discussed in terms of the enhancement of poison oxidation by Ru and the population variation of Pt atoms at vertices and edges of Pt nanoparticles due to selective deposition of Ru on the facets of (111) and (100).

The effect of particle size on the determinability of maize composition in reflection mode.

  • MVaradi, Maria;Turza, Sandor
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1129-1129
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    • 2001
  • Maize, in Hungary, is the fodder-plant grown in the biggest quantity. It is not only used as a fodder but other products such as iso-sugar are made from it, too. The quality of the fodder and the produce is largely dependent on the composition of the supplied maize to the processing site. The examination of quality parameters besides conventional methods are investigated and measured by NIR spectroscopy on a routine basis. The investigated parameters are the following: water, total protein, starch and oil content. The accuracy and precision of determining these parameters we, apart from the wet chemical methods, influenced by sample preparation to a great extent. One of the main features of this is the sample particle size and its distribution across the sample. The uneven distribution of particle size negatively influences the measurement accuracy, decreases model robustness and prediction ability. With these in mind the aim of our experiment was to investigate the effect of particle size on the accuracy of maize composition determination using reflection measurement setup. In addition, we tested different spectrum transformations, which are suitable for canceling this effect. In our experiment 47 samples were analyzed with three different mesh sizes (1.5mm, 1.8mm and 2mm). The results of our findings are presented here.

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Analysis of the Effect of Particle Size and Humidity on Reaction Characteristics of $CaCO_3$ Sorbent Particle under Air and $O_2/CO_2$ Atmospheric Conditions (공기연소 분위기와 순산소 연소 분위기에서 입자 크기와 습도가 $CaCO_3$ 흡착제 입자의 반응특성에 미치는 영향 분석)

  • Jeong, Seongha;Lee, Kang Soo;Keel, Sangin;Yun, Jin Han;Kim, Sang Soo
    • Particle and aerosol research
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    • v.10 no.2
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    • pp.75-82
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    • 2014
  • It is necessary to find out the reaction characteristics of $CaCO_3$ sorbent particles in air and $O_2/CO_2$ atmospheric conditions in order that an in-furnace desulfurization technique can be applied to oxy-fuel combustion system. In this study, rate of change of GMD(geometric mean diameter) and specific surface area of $CaCO_3$ sorbent particles reacted in DTF(drop tube furnace) experimental setup were analyzed to investigate the effect of particle size and humidity on the reaction characteristics of them. In air atmospheric condition, calcination process occurs actively within shorter residence times as the particle size increases. On the contrary, in $O_2/CO_2$ atmospheric condition, a calcination process is delayed as particle size increases. The increment of humidity accelerates calcination process in an air atmospheric condition and increase rate of calcination in an $O_2/CO_2$ atmospheric condition.

The Effect of the Acid Precipitate Conditions on the Size Distribution of Molybdenum Trioxide Particle

  • Tang, Jun-Li
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.171-172
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    • 2006
  • The effect of the preparation factors, such as the feeding mode and rate of raw materials, the reaction temperature and the surfactant on the size distribution of molybdenum trioxide particle were investigated by orthogonal test. The optimum conditions for the preparation of $MoO_3$ precursors are as following; opposite feeding fast, reaction temperature of $60^{\circ}C$ and adding dispersant.

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Effect of Particle Size Distribution on the Sensitivity of Combustion Instability for Solid Rocket Motors (입자 크기 분포도를 고려한 고체로켓 모터의 연소 불안정 민감도 예측)

  • Joo, Seongmin;Kim, Junseong;Moon, Heejang;Ohm, Wonsuk;Lee, Dohyung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.5
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    • pp.37-45
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    • 2015
  • Prediction of combustion instability within a solid-propellant rocket motor has been conducted with the classical acoustic analysis. The effect of particle size distribution on the instability has been analyzed by comparing the log-normal distribution to the fixed mono-sized particle followed by a survey of motor length scale effect between the baseline model and small scale model. Particle damping effect was more efficient for the small scale motor which has a relatively high unstable mode frequencies. It was also revealed that the prediction results by considering the particle size distribution show an overall attenuation of fluctuating pressure amplitude with respect to the mono-sized case.

Variation of Cone Crack Shape and Impact Damage According to Impact Velocity in Ceramic Materials (세라믹에서 충격속도에 따른 충격손상 및 콘크랙 형상의 변화)

  • Oh, Sang-Yeob;Shin, Hyung-Seop;Suh, Chang-Min
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.383-388
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    • 2001
  • Effects of particle property variation of cone crack shape according to impact velocity in silicon carbide materials were investigated. The damage induced by spherical impact having different material and size was different according to materials. The size of ring cracks induced on the surface of specimen increased with increase of impact velocity within elastic contact conditions. The impact of steel particle produced larger ring cracks than that of SiC particle. In case of high impact velocity, the impact of SiC particle produced radial cracks by the elastic-plastic deformation at impact regions. Also percussion cone was formed from the back surface of specimen when particle size become large and its impact velocity exceeded a critical value. Increasing impact velocity, zenithal angle of cone cracks in SiC material was linearly decreasing not effect of impact particle size. An empirical equation, $\theta=\theta_{st}-\upsilon_p(180-\theta_{st})(\rho_p/\rho_s)^{1/2}/415$, was obtained from the test data as a function of quasi-static zenithal angle of cone crack($\theta_{st}$), the density of impact particle(${\rho}_p$) and specimen(${\rho}_s$). Applying this equation to the another materials, the variation of zenithal angle of cone crack could be predicted from the particle impact velocity.

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Effects of Particle Size of Alumina on the Behaviors of Tape Casting and Sintering of Alumina-Talc System (알루미나-활석계에서 알루미나의 입자 크기가 테이프 케스팅 및 소결 거동에 미치는 영향)

  • 윤원균;김호양;이정아;김정주
    • Journal of the Korean Ceramic Society
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    • v.34 no.12
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    • pp.1213-1220
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    • 1997
  • Effect of particle size of alumina and amount of talc on tape casting and densification behaviors of alumina-talc system were investigated. The pseudoplastic behaviors of slurries increased with increase in amount of talc addition and decrease in alumina particle size. In case of using coarse alumina powder, densification of specimens were accelerated with increase of sintering temperature and amount of talc addition. On the contrary, fine alumina powder retarded of rearrangement of alumina particle during liquid phase sintering due to premature densification of alumina matrix region before formation of liquid phase and then densification of specimens were suppressed with increase of sintering temperature and amount of talc addition.

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Effect of Particle Size on the Mechanical and Electrical Properties of Epoxy/Spherical Silica Composites

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.1
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    • pp.39-42
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    • 2013
  • The effects of particle size on the mechanical and electrical properties of epoxy/spherical silica composites were studied. The silica particle sizes were varied from 5 to 30 ${\mu}m$ and the filler content was fixed to 60 wt%. Tensile and flexural tests were carried out and the interfacial morphology was observed by scanning electron microscopy (SEM). The electrical insulation breakdown strength was estimated using sphere-sphere electrodes with different insulation thicknesses of 1, 2 and 3 mm. The tensile strength and flexural strength increased with decreasing particle size, while electrical insulation breakdown strength increased with increasing particle size.

The Relationship between Rheology Properties and Particle size distribution in Cement paste (시멘트 페이스트에서 유동성과 입도분포와의 관계)

  • Hwang, Hae-Jeong;Lee, Seung-Heun;Lee, Won-Jun;Kim, Won-Ki
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.721-724
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    • 2006
  • In this study, particle size distribution of cement powder system were adjusted using the blast furnace slag powder, Blaine $2250cm^2/g\;and\;8300cm^2/g$, which easy to adjust particle size distribution to examine how particle size distribution of the binder has an effect on rheological properties of the cement paste. In addition, the relationship between n-value of Rosin-Rammler function and plastic viscosity were discussed. All measured flow curves represented thixotropy behavior and the hysteresis area was smaller for the more added coarse particle. When the combination was based on a ratio of $20{\sim}25vol%$ fine particles, $30{\sim}40vol%$ OPC and $40{\sim}45vol%$ coarse particles of the total volume, a high fluidity and low yield strength was achieved.

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