• Title/Summary/Keyword: particle size effect

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Effect of the Calcination Conditions for the Synthesized $BaTiO_3$ Powder and the Sintered PTC Ceramics by Oxalic Acid Method (Oxalic Acid법으로 합성한 $BaTiO_3$ 분말과 소결한 PTC 세라믹스에 대한 하소조건의 효과)

  • 이미재;황선아;최병현
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1378-1386
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    • 1994
  • The characteristic of calcined BaTiO3 powder and sintered PTC ceramics was investigated varing with calcination temperature and time of BaTiO(C2O4)2.4H2O synthesized from BaCl2.2H2O, TiCl4, oxalic acid and ethanol by oxalic acid method. When the particle size was less than 0.1 ${\mu}{\textrm}{m}$ by controlling calcination temperature and time, the resistance at room temperature was measured very high (above M{{{{ OMEGA }}). However, when the calcined particle sizes ranged from 0.2 to 0.3 ${\mu}{\textrm}{m}$, the resistance was 100 {{{{ OMEGA }} (After sintering, the grain size was 10~30 ${\mu}{\textrm}{m}$ homogeneously with the addition of dopant in sintering, the resistivity, resistance, $\alpha$ value and jumped to were 110{{{{ OMEGA }}.cm, 24$^{\circ}C$/% and 106{{{{ OMEGA }}, respectively.

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An Study on the Spray Structure of Fuel Port Injectors (포트 분사 연료 인젝터의 분무 구조에 관한 연구)

  • Lee, C.S.;Lee, K.H.;Chon, M.S.;Sohn, K.H.;Park, J.S.
    • Journal of ILASS-Korea
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    • v.3 no.3
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    • pp.42-48
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    • 1998
  • This study describes the spray structure of gasoline port injectors by using phase Doppler particle analyzer(PDPA) and particle motion analysis system(PMAS). The characteristics of fuel spray such as the spray penetration, spray angle and breakup processes were obtained by PMAS and the droplet size and mean velocity were measured by PDPA system. Pintle type and two-hole type injectors were used as gasoline port fuel injectors under various injection pressures. The effect of injection pressure on the droplet mean diameter and axial mean velocity of droplet were investigated under the various injection conditions. In addition the comparison of breakup processes for the two types of injectors was also conducted. It Is shown that pintle type injector has smaller droplet size than that of two-hole type injector.

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Effect of particle size on capacity of $LiMn_2O_4$ as cathode materials of lithium ion secondary batteries for HEV application (HEV용 리튬이온 배터리의 양극물질로 사용되는 $LiMn_2O_4$의 용량에 대한 입자크기의 효과)

  • Jee, Mi-Jung;Choi, Byung-Hyun;Lee, Dae-Jin;Wai, Yin-Loo;Bae, Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.169-172
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    • 2007
  • HEV용 리튬이온 전지에 대한 연구는 최근에 많은 연구가 진행되고 있으며 그중 고용량 및 저렴한 가격, 환경에 대한 안정성으로 인해 Li-Mn spinel에 대한 성능향상 연구가 많이 이루어지고 있다. 본 연구에서는 Li-Mn spinel의 입자크기에 대한 기초 물성 과 전기적 특성을 측정하여 입자크기가 용량에 미치는 영향에 대한 고찰을 하였다. Li-Mn spinel의 비표면적, C-V 특성, 전기적 용량, coulomb efficiency 등을 통하여 입자의 크기와 전해액, Li의 구동등과 관련하여 용량특성에 향상을 가져오는 입자크기 조건을 정의하였고 그에 따라 온도별로 합성 한 후 입자사이즈에 대한 특성을 나타내었다.

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A Study on the High-efficient Bioethanol Production Using Barley (보리를 이용한 고효율 바이오에탄올 생산 연구)

  • JEON, HYUNGJIN;GO, KYOUNG-MO;KIM, SHIN;JEONG, JUN-SEONG
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.6
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    • pp.697-703
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    • 2017
  • This study investigated the high-efficient process for bioethanol from barley by various condition. First, higher concentrations of ethanol could be produced without loss of yield by using reducing water consumption. This is because it could prevent to increase viscosity despite reducing water consumption. Second, the ethanol yield could be improved by using reducing particle size of biomass (increase of enzyme reactive surface). Third, The addition of protease could have a considerable effect on yield of fermentation, which provides nutrients to the yeast. This results showed that bioethanol production would provide efficient ethanol production and lower production costs.

Properties of Waterborne Polyurethane/Nanosilica Composite

  • Kim, Byung-Kyu;Seo, Jang-Won;Jeong, Han-Mo
    • Macromolecular Research
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    • v.11 no.3
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    • pp.198-201
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    • 2003
  • Aqueous emulsion of polyurethane (PU) ionomers were reinforced with hydrophobic nanosilica to give composites. The aqueous emulsion was stable and the particle size increased as the content of hydrophobic nanosilica was increased. The reinforcing effect of nanosilica in mechanical properties of these composites were examined by dynamic mechanical and tensile tests, and the Shore A hardness was measured. Enhanced thermal and water resistance and marginal reduction in transparency of these composites were observed compared with pristine polymer. These results were similar with those of our previous studies on waterborne PU/organoclay nanocomposites.

Optimization of Condition of Chemical Additives in Cu CMP Slurry (Cu CMP 슬러리에서 화학첨가제 조건의 최적화)

  • Kim, In-Pyo;Kim, Nam-Hoon;Lim, Jong-Heun;Kim, Sang-Yong;Kim, Chang-Il;Chang, Eui-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.304-307
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    • 2003
  • Replacement of aluminum by copper for interconnections in the semiconductor industry has raised a number of important issues. The integration of copper interconnection can be carried out by CMP(chemical mechanical polishing) is used to planarize the surface topography. In this experiments, we evaluated the optimization of several conditions for chemical additives during Cu CMP process. It was presented that the main cause of grown particle size is tartaric acid. The particle size was in inverse propotion to a quantity of bead and the time of milling process. The slurry stabilizer and oxidizer have been shown to have very good effect by addition in later milling process.

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Reduction of Soot Emitted from a $C_2$$H_4$ Normal Diffusion Flame with Application of DC Corona Discharge (DC 코로나 방전이 적용된 에틸렌 정상 확산 화염의 Soot 배출 저감)

  • Lee, Jae-Bok;Hwang, Jeong-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.4
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    • pp.496-506
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    • 2001
  • The effect of corona discharge on soot emission was experimentally investigated. Size and number concentrations of soot aggregates were measured and compared for various voltages. Regardless of the polarity of the applied voltage, the flame length decreased and the tip of flame spreaded with increasing voltage. For the experimental conditions selected, the flame was blown off toward the ground electrode by corona ionic wind. When the negative applied voltage was greater than 3kV(for electrode spacing = 3.5cm), soot particles in inception or growth region were affected by the corona discharge, resulting in the reduction of number concentration. The results show that the ionic wind favored soot oxidation and increased flame temperature. Number concentration and primary particle size greatly increased, when the corona electrodes were located the region of soot nucleation or growth(close to burner mouth).

Study on the Effect of Particles Injected Into the Head/Disk Interface (헤드-디스크 인터페이스에 주입되는 입자의 영향에 대한 연구)

  • Han Je-Hee;Lee Rae-Jun;Kim Dae-Eun;Kang Tae-Sik;Cho Keung-Youn
    • 정보저장시스템학회:학술대회논문집
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    • 2005.10a
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    • pp.179-183
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    • 2005
  • Particles in the HDD can cause serious damages such as scratches and thermal asperity(TA) at the head/disk interface(HDI). Accordingly, particles cause data loss including physical and electrical damages. To improve the reliability of head-disk interface, understanding the damage characteristics at the HDI due to particle interactions is required. The materials such as $A1_2O_3$, TiC and aluminum were used in this experiment. The size and hardness of particles injected into the HDI are closely relevant to surface damage caused the data loss on the disk and head. In this paper, a variety of scratches were analyzed using scanning electron microscope(SEM) and atomic force microscope(AFM). In order to analyze defects of very small size on the disk, optical surface analyzer(OSA) was also used.

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Preparation and Characterization of CdTe Quantum Dots (CdTe 양자점 합성과 물리적 특성 분석)

  • Kim, Hyun-Suk;Song, Hyun-Woo;Cho, Kyung-Ah;Kim, Sang-Sig
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.195-197
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    • 2002
  • CdTe quantum dots(QDs) were synthesized in aqueous solution by colloidal method. Photoluminescence(PL) spectra of the synthesized CdTe QDs revealed the intensity of PL peaks was stronger as the condensation time was longer. This result was thought because annealing effect by thermal energy transferred during condensation eliminated defects which act as traps and recombination centers in CdTe particle. PL intensity has stron dependence of Te precursor concentration. It confirmed the ratio of Te ion to Cd ion added during synthesis affected the particle size and size distribution of the CdTe QDs. Finally, the synthesized CdTe QDs were identified to be cubic structured CdTe quantum dots by X-ray diffraction(XRD).

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Effect of Catalyst Preparation on the Selective Hydrogenation of Biphenol over Pd/C Catalysts

  • Cho, Hong-Baek;Park, Jai-Hyun;Hong, Bum-Eui;Park, Yeung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.29 no.2
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    • pp.328-334
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    • 2008
  • The effects of catalyst preparation on the reaction route and the mechanism of biphenol (BP) hydrogenation, which consists of a long series-reaction, were studied. Pd/C catalysts were prepared by incipient wetness method and precipitation and deposition method. The reaction behaviors of the prepared catalysts and a commercial catalyst along with the final product distributions were very different. The choice of the catalyst preparation conditions during precipitation and deposition including the temperature, pH, precursor addition rate, and reducing agent also had significant effects. The reaction behaviors of the catalysts were interpreted in terms of catalyst particle size, metal distribution, and support acidities.