• Title/Summary/Keyword: particle size effect

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Effect of Pt Particle Size on the Durability of PEMFC (연료전지 촉매의 입자크기가 내구성에 미치는 영향)

  • Min, Kyoung-Won;Kim, Hyun-Jong;Han, M.K.;U, Yu-Tae;Kim, Mok-Soon;Chu, Young-Hwan
    • Journal of the Korean Electrochemical Society
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    • v.11 no.4
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    • pp.313-318
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    • 2008
  • The influence of the particle size of platinum(Pt) on the stability and activity was studied. The particle size of platinum was controlled in the range of $3.5{\sim}9\;nm$ by heat treatment of commercial Pt/C and confirmed by XRD and TEM. An accelerated degradation test was performed to evaluate the stability of platinum catalysts. Oxygen reduction reaction was monitored for the measurement of activity. As increasing the Pt particle size, the stability of Pt/C electrode was enhanced and the activity was reduced. It was confirmed that the stability of Pt/C electrode was in inverse proportion to the activity. PtCo/C alloy catalyst was used to improve the activity and stability of large-sized platinum particle. The maximum power density of commercial Pt/C was $507.6\;mV/cm^2$ and PtCo/C alloy catalyst was $585.8\;mV/cm^2$. The decrement of electrochemical surface area showed Pt/C(60%) and PtCo/C alloy catalyst(24%). It was possible to enhance both of stability and activity of catalyst by the combination of particle size control and alloying.

Effect of Bubble Size in DAF (DAF에서 기포크기의 영향)

  • Park, Yong-Hyo;Han, Moo-Young
    • Journal of Korean Society of Water and Wastewater
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    • v.17 no.4
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    • pp.528-533
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    • 2003
  • Bubble size is one of the most important parameters affecting DAF (Dissolved-Air-Flotation) process. It is generally known that small bubbles are preferred. However, the fact seems to be based on the particle removal efficiency at contact zone only, without considering separation zone. Besides, the effect of bubble size on the overall DAF process has not been fully investigated yet. Therefore, the effect of bubble size on collision efficiency, collision chances, and surface loading rate is calculated using theoretical models, and the results are discussed in this paper.

Estimation of Occupational Health Standard by Relationship between Airborne Lead Concentration by Particle Size and Lead in Blood (공기중 납입자의 크기 특성과 혈액중 납농도와의 관계에 의한 허용농도 측정)

  • Park, Dong-Wook;Paik, Nam-Won
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.6 no.2
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    • pp.265-271
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    • 1996
  • This study was conducted to investigate distribution of lead particles by operation of industry, to evaluate the effect of particle size on the absorption to workers, and to recommend the Occupational Health Standard for lead. Total lead concentrations in the secondary smelting industry were higher than those in the battery and litharge manufacturing industry. Total lead concentrations in other industries except radiator manufacturing industry exceeded the standard of $50{\mu}g/m^3$. Only radiator manufacturing industry indicated lead concentrations significantly lower than those in other industries(p<0.05). Average blood lead level of workers was $85.1{\mu}g/dl$ in secondary smelting manufacturing, $51.3{\mu}g/dl$ in the battery manufacturing, and below $40{\mu}g/dl$ in the litharge and radiator manufacturing industry. Blood lead levels of workers by industry were significantly different(p<0.05). From relationship between airborne lead concentrations by size and lead in blood, confidence limits of airborne lead concentration equivalent to $40{\mu}g/dl$ of permissible limit in blood, was $147.9-489.8{\mu}g/m^3$ as total lead and $28.8-79.4{\mu}g/m^3$ as ACGIH-RPM. It is recommended that two separate occupational health standards for lead should be established by particle size. Airborne concentration of $150{\mu}g/m^3$ as fatal lead dust and $30{\mu}g/m^3$ as respirable lead dust was recommended.

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Damage Mechanism of Particle Impact in a $Cr_2O_3$ Plasma Coated Soda-lime Glass ($Cr_2O_3$ 플라스마 용사 코팅된 유리의 입자충격에 의한 손상기구)

  • Suh, Chang-Min;Lee, Moon-Whan;Kim, Sung-Ho;Jang, Jong-Yun
    • Journal of Ocean Engineering and Technology
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    • v.12 no.3 s.29
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    • pp.49-59
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    • 1998
  • The damage mechanism of $Cr_2O_3$ plasma coated soda-lime glass and uncoated glass by steel ball particle impact was analyzed in this study. And the shape variation of the cracks was investigated by stereo-microscope according to the impact velocity and steel ball diameter. In order to improve the damage reduction effect by $Cr_2O_3$ coating layer, crack size was measured and surface erosion state was observed for both of two kinds of specimen after impact experiment. And the results were compared with each other. The 4-point bending test was performed according to ASTM D790 testing method to evaluate the effect of coating layer for bending strength variation. As a result, it was found that the crack size of $Cr_2O_3$ coated specimen was smaller than that of uncoated one, because of the impact absorption by interior pores in the coating layer and the load dispersion by the structural characteristic of the coating layer. For the specimens subjected to the steel ball impact, the bending strength of coated specimen was higher than that of uncoated specimen.

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Effect of Duration of Confinement and Its Affecting Factors on the Low-Amplitude Shear Modulus ($G_{max}$) of Soils (토질 최대전단탄성계수($G_{max}$)에 미치는 시간지속효과 및 그 영향요소에 관한 연구)

  • 박덕근
    • The Journal of Engineering Geology
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    • v.9 no.2
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    • pp.135-145
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    • 1999
  • Dynamic Shear modulus (G) is one of the imfortant dynamic soil properties to estimate the response of soil to dynamic loading. Problems in engineering geo1ogy practice the require the knowledge of soil properties subjected to dynamic loadings include soil-structure interaction during earthquakes, bomb blasts, construction operations, and mining. Although the dynamic shear modulus (G) is a time-dependent property, G change with time is often neglected. In this study, the effect of duration of confinement and its affecting factors (previous stress and strain, particle size and sustained pressure, and plasticity index) on the low-amplitude shear modulus ($G_{max}$) of soils are reviewed, and some empirical correlations based on mean particle diameter and plasticity index are proposed.

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Effect of particle sizes on CHF enhancement and boiling characteristics of nano-fluids (나노유체의 임계열유속 및 비등특성에 미치는 나노입자 크기의 영향)

  • Jo, Byeong-Nam;Kang, Jun-One;Yoo, Jai-Suk;Kim, Hyun-Jung
    • 한국가시화정보학회:학술대회논문집
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    • 2006.12a
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    • pp.125-130
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    • 2006
  • The characteristics of boiling heat transfer and critical heat flux (CHF) behavior of nano-fluids were studied by using various sized silver and alumina nanoparticles. The diameter of nanoparticles was from 2 nm to 250 nm for silver and from 20nm to 40nm for alumina. Pool boiling characteristics and CHF enhancement of nano-fluids with different sized nanoparticles were compared with those of pure water and each nano-fluids. The experiment was performed at atmospheric pressure and the temperature of the pool was maintained constantly by using a flat immersed heater. The concentration of nano-fluids was uniform in all experiments as 0.01g/liter. The results showed that the measured boiling curves were shifted to the right. It demonstrated that the occurrence of nucleate boiling regime in nano-fluids retarded, compared with that of pure water. Also, in nano-fluids, the boiling curves showed that CHF of nano-fluids is significantly enhanced and represented the effect of particle size on boiling characteristics.

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