• Title/Summary/Keyword: particle size effect

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La2/3Ca1/3MnO3 Nanoparticles with Novel Magnetoresistance Property

  • Zhang, Jianwu;Jang, Eue-Soon;Chung, Il-Won;Choy, Jin-Ho
    • Bulletin of the Korean Chemical Society
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    • v.25 no.2
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    • pp.182-184
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    • 2004
  • Fine $La_{2/3}Ca_{1/3}MnO_3$ nanocrystalline powders have been successfully prepared by modified citrate pyrolysis process. The obtained LCMO nanoscale grains have a mean particle size of about 30 nm under optimal treatment conditions. The particle size can be controlled by adjusting processing parameters, such as treatment temperature and calcination time. X-ray diffraction, SEM and magnetoresistance effect were employed to study the crystal structure, morphology and magnetic property of these nanosized powders. A novel MR effect (MR > 45% (0 K < T < 340 K)) at room temperature has been found.

Enhanced Protective Effect of Ultrafine Particles of Red-Ginseng against Phenanthrene-induced Cell Damage

  • Seo, Yoo-Na;Lee, Mi-Young
    • Journal of Ginseng Research
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    • v.33 no.4
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    • pp.305-310
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    • 2009
  • Phenanthrene, one of the polycyclic aromatic hydrocarbons, has been known to be toxic to the environment. In this investigation, the protective effect of red ginseng on phenanthrene-induced oxidative DNA damage was evaluated using Comet assay in A549 cells. Red ginseng's cytoprotective effect on phenanthrene-induced hemolysis was also investigated. This study's findings show that oxidative DNA damage and hemolysis were significantly prevented by red ginseng treatment. Notably, it was found that pulverizing red ginseng into ultra-fine particles even enhanced its protective effects against DNA damage and hemolysis. The results suggest that particle size reduction seems to effectively enhance red ginseng's pharmacological efficacies.

h Study on the Preparation of PMMA/PSt Composite Particles by Sequential Emulsion Polymerization (단계중합법에 의한 PMMA/PSt Composite Particle의 제조에 관한 연구)

  • 이선룡;설수덕
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.617-624
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    • 2001
  • The core-shell composite latexes were synthesized by stage emulsion polymerization of methyl methacrylate (MMA) and styrene (St) with ammonium persulfate after preparing monomer pre-emulsion in the presence of anionic surfactant. However, in preparation of core-shell composite latex, several unexpected results are observed, such as, particle coagulation, low degree of polymerization, and formation of new particles during shell polymerization. To solve the disadvantages, We study the effect of initiator concentrations, surfactant concentrations, and reaction temperature on the core-shell structure of polymethyl methacrylate/polystyrene and polystyrene/polymethyl methacrylate. Particle size and particle size distribution were measured using particle size analyzer, and the morphology of the core-shell composite latex was determined using transmission electron microscope. Glass temperature was also measured using differential scanning calorimeter. To identify the core-shell structure, pH of the two composite latex solutions were measured.

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Vertical Change in Extinction and Atmospheric Particle Size in the Boundary Layers over Beijing: Balloon-borne Measurement

  • Chen, Bin;Shi, Guang-Yu;Yamada, Maromu;Zhang, Dai-Zhou;Hayashi, Masahiko;Iwasaka, Yasunobu
    • Asian Journal of Atmospheric Environment
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    • v.4 no.3
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    • pp.141-149
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    • 2010
  • Aerosol size and number concentration were observed in the atmospheric boundary layer over Beijing (from near the ground to 1,200 m) on March 15 (a clear day) and 16 (a dusty day), 2005. The results were further compared with lidar measurements in order to understand the dependency of extinction on the particle size distribution and their vertical changes. The boundary layer atmosphere was composed of several sub-layers, and a dry air layer appeared between 400 and 1,000 m under the influence of dust event. In this dry air layer, the concentration of the fine-mode particles (diameter smaller than $1.0\;{\mu}m$) was slightly lower than the value on the clear day, while the concentration of coarse-mode particles (diameter larger than $1.0\;{\mu}m$) was remarkably higher than that on the clear day. This situation was attributed to the inflow of an air mass containing large amounts of Asian dust particles and a smaller amount of fine-mode particles. The results strongly suggest that the fine-mode particles affect light extinction even in the dusty atmosphere. However, quantitatively the relation between extinction and particle concentration is not satisfied under the dusty atmospheric conditions since laser beam attenuates in the atmosphere with high concentration of particles. Laser beam attenuation effect becomes larger in the relation between extinction and coarse particle content comparing the relation between extinction and fine particle content. To clarify this problem technically, future in situ measurements such as balloon-borne lidar are suggested. Here extinction was measured at 532 nm wavelength. Measurements of extinction at other wavelengths are desired in the future.

Effects of the Block Arrangement on the Collection Efficiency in the Two-Stage Electrostatic Precipitator with Charging Plate (평판형 방전판을 갖는 2단식 전기집진기의 집진판 블록배열이 집진효율에 미치는 영향)

  • 박성호;박청연;김태권
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.6
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    • pp.641-652
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    • 2000
  • The effect of block arrangement has been investigated on the particle deposition in the specified collecting cell of two-stage electrostatic precipitator by numerical analysis. Recirculation zone existed at the downstream of the block in the collecting cell, and the particles entering the recirculation zone were deposited on the collecting plate. Particle trajectory and deposition had considerably different phenomenon according to electrostatic and inertial effect, which depended on inlet mean velocity, electrostatic number, and particle diameter in the collecting cell. The total collection efficiency reached a minimum value through an interaction of electrostatic and inertial effect. In the computational domain, total collection efficiency for the case of two blocks in the computational domain was more than that of one block at the relative small electrostatic number. However as the block distance and inertial effect increased, the difference between the collection efficiency of two cases decreased. In the range of relatively small particle size total collection efficiency was always superior to particle collection efficiency that was predicted by Deutsch equation.

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Effect of particle size of rice flour on popping rice bread (쌀가루 입도가 쌀 식빵의 팽화에 미치는 영향)

  • Park, Mi-Kyung;Kang, Soon-Ah;Lee, Kyung-Hee
    • Korean journal of food and cookery science
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    • v.22 no.4 s.94
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    • pp.419-427
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    • 2006
  • The purpose of this study is to promote the substitution of rice flour for wheat flour in making bread and thus the consumption of rice by examining the effect of particle size of rice flour on leavening rice bread. For this purpose, several experiments were carried out. With regard to particle size distribution, 59.45% of wheat flour had passed 200 mesh and 3 kinds of rice flour milled to penetrate into 20, 35, and 45 mesh (S1, S2 and S3) had passed 21.88%, 33.1% and 36.38% of those for 200 mesh, respectively. To leaven the rice flour dough to bread, 25% of vital gluten was needed. To determine the optimal water quantity for rice bread dough, the hardness of wheat and rice flour dough was measured by rheometer. The appropriate water quantity for S1, S2 and S3 was set at 285 ml , 295 ml and 335${\sim}$340m1, respectively. The loaf volume index of the wheat flour bread was 6.24, while that of and rice flour bread S1, S2 and S3 was 5.38, 5.50 and 5.75, respectively. These results indicated that the loaf volume index of rice flour bread is lower than that of wheat flour bread, but that the volume of rice flour bread was increased with fuel particle size of rice flour. Scanning electron microscopy (SEM), image of the wheat bread tissue at a magnification of 35 times showed long, large, oval-shaped, air cells and thin cell membrane, as well as small air cells, whereas the images of rice flour showed angular, circular, air cells and rough and thick cell membrane. The size and number of air cells in the rice bread were larger in S2 and S3 with fuel particle flours than in S1. In particular, the bread made with S3 contained many air cells that were as large as those in the wheat bread were. In addition, when the inner cell wall was magnified 1500 times, almost no small air cell was observed in C and S3, whereas many fine air cells were observed in the cell wall of S1 and S2.

Glass-alumina Composites Prepared by Melt-infiltration: Ⅰ. Effect of Alumina Particle Size (용융침투법으로 제조한 유리-알루미나 복합체: Ⅰ. 알루미나 입도 효과)

  • Lee, Deuk-Yong;Jang, Ju-Woong;Kim, Dae-Joon;Park, Il-Seok;Lee, Jun-Kwang;Lee, Myung-Hyun;Kim, Bae-Yeon
    • Journal of the Korean Ceramic Society
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    • v.38 no.9
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    • pp.799-805
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    • 2001
  • Two commercial alumina powders having different particle size of $0.5{\mu}m$ and 3${\mu}$m were presintered at 1120$^{\circ}$C for 2h and then lanthanum aluminosilicate glass was infiltrated at 1100$^{\circ}$C for up to 4h to obtain the densified glass-alumina composites. The effect of alumina particle size on packing factor, microstructure, wetting, porosity and pore size, and mechanical properties of the composite was investigated. The optimum mechanical properties and compaction behavior were observed for the 3${\mu}$m alumina particle dispersed composite. The 3${\mu}$m alumina particle size and distribution for he preform were within 0.1 to 48${\mu}$m and bimodal and random orientation. The strength and the fracture toughness of the composite having 3${\mu}$m alumina particles were 519MPa and $4.5MPa{\cdot}m^{1/2}$, respectively.

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An Experimental Investigation of the Effect of Particle Size on the Combustion Characteristics of Pulverized Sub-Bituminous Coal with Low Calorific Value by Using an LFR System (LFR 장치를 이용한 입자 크기 변화에 따른 저열량 아역청 미분탄의 연소특성에 관한 실험적 연구)

  • Jeon, Chung-Hwan;Kim, Yong-Gyun;Kim, Jae-Dong;Kim, Gyu-Bo;Song, Ju-Hun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.3
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    • pp.259-267
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    • 2010
  • In this study, the effect of particle size on the combustion characteristics of pulverized sub-bituminous coal was experimentally investigated. A laminar-flow-entrained reactor was designed and implemented to realize the desired heating ratio and temperature corresponding to the combustion atmosphere of a pulverized-coal-fueled furnace. The flame length and structure of burning particles according to different sizes were investigated. Coal combustion processes were clearly distinguished by direct visual observation of the flame structure. The onset point of volatile ignition is greatly affected by changes in the particle size, and the burning time of the volatiles is least affected by changes in the particle size. The length and instability of char flame also increase with the increase of the particle size. However, the char consumption rate within the residential time remains nearly constant.

Effects of Particle Size and Structure of Fillers on the Friction and Wear Behavior of Filled Elastomer (충전제의 입자크기 및 구조에 따른 고무 배합물의 마찰 마모특성)

  • Kaang, Shin-Young;Ryu, Chang-Seok;Hong, Chang-Kook;Moon, Chae-Woo
    • Elastomers and Composites
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    • v.41 no.3
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    • pp.194-204
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    • 2006
  • The effects of the particle size and the structure of carbon blacks on the friction and the wear behavior of filled natural rubber were investigated in this study. The particle size and the structure of carbon black had a significant effect on the wear rates and the worn surface pattern, and the effect of them on abrasion resistance should be considered for the optimum design of desired wear properties. Ten carbon blacks with various sizes and structures are mixed with natural rubber in order to investigate the effects on the wear rate ($W_R$). The friction and the wear behavior were examined by self-made blade type friction-wear abrader, and the ,elation with characteristic parameter (${\psi}=\sqrt{{N_2^2}+{DBP^2}}$), obtained from the particle size and the structure, was studied. The wear rate ($W_R$) had a Power Law relation with the frictional work ($W_f$) and it was inversely proportional to the characteristic parameter of carbon black. It means that smaller particle size and better structure development of carbon black resulted in improved abrasion resistance.

Effect of Precursor Alumina Particle Size on Pore Structure and Gas Permeation Properties of Tubular α-alumina Support Prepared by Slip Casting Process (초기 알루미나 분체의 입자크기가 주입성형법에 의해 제조된 튜브형 α-알루미나 지지체의 기공구조 및 기체 투과 특성에 미치는 영향)

  • Yang, Eun-Mok;Lee, Hye Ryeon;Cho, Churl-Hee
    • Membrane Journal
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    • v.26 no.5
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    • pp.372-380
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    • 2016
  • The present paper reports the effect of precursor alumina particle size on pore structure and single gas permeation properties of tubular ${\alpha}$-alumina supports, prepared by a combined process of slip casting and sintering. Pore diameter of as-prepared ${\alpha}$-alumina support was highly dependent on precursor ${\alpha}$-alumina particle size. Although, increase in the precursor particle size increases the pore diameter, but the porosity of ${\alpha}$-alumina support mainly control by sintering temperature. Sintering studies reveal that as sintering temperature increased porosity of support decreased. Single gas permeance results indicate that permence is proportional to the square of pore diameter and linearly to porosity. These dependencies revealed that gas permeation trough as-prepared ${\alpha}$-alumina support was governed by viscous flow mechanism. The present announces that precursor ${\alpha}$-alumina particle size and sintering temperature are key parameters to control gas permeantion properties of ${\alpha}$-alumina supports.