• Title/Summary/Keyword: partial stability

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Ab initio Study of the Complexes of Trimethyl Ether of Monodeoxycalix[4]arene with Potassium Ion: Cation-π Interactions

  • Lee, Hyung-Dae;Kim, Kwang-Ho;Lee, Ho-Jun;Lee, Sik;Nanbu, Shinkoh;Choe, Jong-In
    • Bulletin of the Korean Chemical Society
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    • v.27 no.4
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    • pp.508-514
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    • 2006
  • In this study, we have performed ab initio computer simulations to investigate the conformational and complexation characteristics of the trimethyl ether of p-tert-butylmonodeoxycalix[4]arene (6) with a potassium ion. The structures of different conformers of 6 and their potassium complexes were optimized by using ab initio RHF/6-31G and B3LYP/6-31G(d,p) methods. The relative stability of the various conformers of the uncomplexed 6 is in following order: cone (most stable) > 1-partial-cone ~ 2i-partial-cone > 2-partial-cone ~ 1,3-alternate > 3i-partial-cone. However, the relative stability of the conformational complexes of 6 with $K^+$ is in the following order: 2-partial cone ~ 1,3-alternate > cone > 3-partial cone > 1-partial cone (least stable). The highest binding strengths of 2-partial-cone and 1,3-alternate complexes originate from two strong cation-$\pi$ interactions and two strong cation-oxygen interactions in the complex of 6+$K^+$. Due to the cation-$\pi$ interactions, the calculated C-C bond distances in the arenes of the $K^+$-complexes are about 0.0048 $\AA$ longer than the values of their isolated hosts.

Mandibular implant assisted removable partial denture with a small number of implant crowns: two case reports (소수의 임플란트 크라운을 지대치로 이용한 하악 가철성 국소 의치 수복 증례)

  • Kim, Youla;Lee, Suyoung
    • Journal of Dental Rehabilitation and Applied Science
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    • v.38 no.2
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    • pp.110-119
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    • 2022
  • When restoration for partially edentulous patients, abutments are not always in favorable positions for making removable partial dentures. Because of these situations, patients are sometimes unsatisfied with the stability and support of their removable partial prostheses. In this regard, removable partial denture using a few implant surveyed crown prostheses can be a good alternative. It can be expected to increase stability and support of removable partial dentures by strategically placing a small number of implants and restoring with implant-supported surveyed crowns. In these cases, the patients who had unilateral residual teeth on mandible were treated with two implant surveyed crowns in the tactical place to have bilateral distribution. After definitive removable partial prosthesis, the patients showed satisfaction with the masticatory function and comfort of using removable dentures.

Deformation characteristics of brick masonry due to partial unloading

  • Alshebani, Milad M.;Sinha, S.N.
    • Structural Engineering and Mechanics
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    • v.11 no.5
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    • pp.565-574
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    • 2001
  • Experimental investigation into the behaviour of half-scale brick masonry panels were conducted under cyclic loading normal to the bed joint and parallel to the bed joint. For each cycle, full reloading was performed with the cycle peaks coinciding approximately with the envelope curve. Unloading, however, was carried out fully to zero stress level and partially to two different stress levels of 25 percent and 50 percent of peak stress. Stability point limit exhibits a unique stress-strain curve for full unloading but it could not be established for partial unloading. Common point limit was established for all unloading-reloading patterns considered, but its location depends on the stress level at which unloading is carried to. Common point curves were found to follow an exponential formula, while residual strains versus envelope strains can be expressed by a polynomial function of a single term. The relation between residual strain and envelope strain can be used to determine the stress level at which deterioration due to cyclic loading began.

Effects of Partial Beef Fat Replacement with Gelled Emulsion on Functional and Quality Properties of Model System Meat Emulsions

  • Serdaroglu, Meltem;Nacak, Berker;Karabiyikoglu, Merve;Keser, Gokcen
    • Food Science of Animal Resources
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    • v.36 no.6
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    • pp.744-751
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    • 2016
  • The objective of this study was to investigate the effects of partial beef fat replacement (0, 30, 50, 100%) with gelled emulsion (GE) prepared with olive oil on functional and quality properties of model system meat emulsion (MSME). GE consisted of inulin and gelatin as gelling agent and characteristics of gelled and model system meat emulsions were investigated. GE showed good initial stability against centrifugation forces and thermal stability at different temperatures. GE addition decreased the pH with respect to increase in GE concentration. Addition of GE increased lightness and yellowness but reduced redness compared to control samples. The results of the study showed that partial replacement of beef fat with GE could be used for improving cooking yield without negative effects on water holding capacity and emulsion stability compared to C samples when replacement level is up to 50%. The presence of GE significantly affected textural behaviors of samples (p<0.05). In conclusion, our study showed that GE have promising impacts on developing healthier meat product formulations besides improving technological characteristics.

Partial Charge and CMC Characteristics of Hydrophilic and Hydrophobic Group of Surfactants (Cationic and Amphoteric Surfactant) (계면활성제의 친수.소수성 그룹의 부분전하와 CMC특성 (양이온 및 양쪽성 계면활성제))

  • 하윤식
    • Journal of Environmental Science International
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    • v.9 no.5
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    • pp.403-408
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    • 2000
  • On the basis of theory of Bratsch's electronegativity equalization the electronegativity equalization the group electronegativities and the group partial charges for cationic and amphoteric surface and amphoteric surfactants could be calculated using Pauling's electronegativity parameters. From calculated output we have investigated relationships between CMC(critical micelle concentration) and partial charge and group electronegativity of hydrophilic and hydrophobic groups structural stability of micelle for cationic and amphoteric surfactants. As a result CMC depends upon partial charge and electronegativity of hydrophilic group is decreased. With increasing the carbon number of hydrophilic group for cationic surfactant its partial charge is increased but CMC and its electronegativity are decreased. With increasing the carbon number of hydrophobic group for cationic and amphoteric surfactant its partial charge is increased but CMC andits electronegativity are decreased.

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Optimal Design of Rubble Mound Breakwater Used by Partial Safety Factor Method (부분안전계수를 이용한 경사식 방파제의 최적설계기법)

  • 이동훈;민석진;김성득
    • Journal of Ocean Engineering and Technology
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    • v.17 no.6
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    • pp.23-31
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    • 2003
  • As there are so many uncertainties associated with using the determinism analysis method in the design of rubble mound breakwater, it is impossible for a designed construction to provide ultimate stability. First of all, due to the uncertainty of Load and Resistance, a safety level concerning the destruction mode of construction must be given. Then, the optimization design should be processed. After all, we can say that it is a more reasonable design method than the design used by the stability rate. In this study, an established design process is accomplished using Hudson's equation and an economic analysis with the breakwater's section is also conducted. Hudson's equation is compared to Van der Meer's equation. These results are utilized to drop a damage rate, increase the stability of construction, and determine the optimization section of the breakwater.

Evaluation of Design Equation and Stability for Trenchless Pipe Liner System with Boundary Treatment (비굴착 전체보수용 라이너의 두께 설계식 및 말단부 처리에 따른 라이너의 안정성 검토 연구)

  • Park, Jong-Sup;Song, Ho-Myeon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.8 no.5
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    • pp.1166-1172
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    • 2007
  • Drainage pipeline system repaired by trenchless technology using liners can be defined between partial and entire collapse. The liners in the partial collapse pipeline are subjected to only uniform groundwater pressure on the surface. This research evaluates practical and useful cured-in-placed pipe (CIPP) design equations based on experimental results and finite element analysis results. Also, stability evaluation of pipe liner system with edge treatment is performed using finite element analysis. The CIPP equation should be used to design liner pipe system.

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THE STABILITY OF WEAK SOLUTIONS TO AN ANISOTROPIC POLYTROPIC INFILTRATION EQUATION

  • Zhan, Huashui
    • Journal of the Korean Mathematical Society
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    • v.58 no.5
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    • pp.1109-1129
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    • 2021
  • This paper considers an anisotropic polytropic infiltration equation with a source term $$u_t={\sum\limits_{i=1}^{N}}{\frac{{\partial}}{{\partial}x_i}}\(a_1(x){\mid}u{\mid}^{{\alpha}_i}{\mid}u_{x_i}{\mid}^{p_i-2}u_{x_i}\)+f(x,t,u)$$, where pi > 1, αi > 0, ai(x) ≥ 0. The existence of weak solution is proved by parabolically regularized method. Based on local integrability $u_{x_i}{\in}W_{loc}^{1,p_i}(\Omega)$, the stability of weak solutions is proved without boundary value condition by the weak characteristic function method. One of the essential characteristics of an anisotropic equation different from an isotropic equation is found originally.

EXISTENCE AND EXPONENTIAL STABILITY OF NEUTRAL STOCHASTIC PARTIAL INTEGRODIFFERENTIAL EQUATIONS DRIVEN BY FRACTIONAL BROWNIAN MOTION WITH IMPULSIVE EFFECTS

  • CHALISHAJAR, DIMPLEKUMAR;RAMKUMAR, K.;ANGURAJ, A.
    • Journal of Applied and Pure Mathematics
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    • v.4 no.1_2
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    • pp.9-26
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    • 2022
  • The purpose of this work is to study the existence and continuous dependence on neutral stochastic partial integrodifferential equations with impulsive effects, perturbed by a fractional Brownian motion with Hurst parameter $H{\in}({\frac{1}{2}},\;1)$. We use the theory of resolvent operators developed in Grimmer [19] to show the existence of mild solutions. Further, we establish a new impulsive-integral inequality to prove the exponential stability of mild solutions in the mean square moment. Finally, an example is presented to illustrate our obtained results.

A Study of New Technical Standards for Slope Stability in Port Structures (항만구조물의 사면안정 신 설계기준 연구)

  • Yoon, Gil-Lim;Yoon, Yeo-Won;Kim, Hong-Yeon
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.21 no.4
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    • pp.316-325
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    • 2009
  • Technical design codes of slope stability for port structures were studied by comparing local Korean code with international codes; Japanese, EC and China codes. Three international design codes are based on limit state design method. Although Chinese code was based on the modified Fellenius method in slope stability analyses, it is currently changing to the simplified Bishop method. In Eurocode, the Morgenstern & Price method or the Bishop method is recommended. In Japanese code, however, the modified Fellenius method is preferentially recommended, but the simplified Bishop method could be alternatively used in case of thick sandy ground conditions. As for design parameter determination, Eurocode has stipulated comprehensive partial factors and partial material factors, however Japanese code has clarified empirical partial material factors for each port structure. Chinese code, the minimum ranges of the comprehensive partial factors are stipulated, and the use of the strength index by specific tests is concretely clarified with the safety condition. Case study of slope stability analyses showed the safety factors were higher in order of Chinese, Japanese and Eurocode, respectively.