• Title/Summary/Keyword: partial oxidation

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Application of Electronic Nose for Quality Control of The High Quality and Functional Components (고품질 기능성 물질의 품질관리를 위한 전자코 응용)

  • Noh Bong-Soo
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2006.04a
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    • pp.40-54
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    • 2006
  • It's not easy to detect the high quality and functional compounds for control quality of food materials. The electronic nose was an instrument, which comprised of an array of electronic chemical sensors with partial specificity and an appropriate pattern recognition system, capable of recognizing simple or complex odors. It can conduct fast analysis and provide simple and straightforward results and is best suited for quality control and process monitoring in the field of functional foods. Numbers of applications of an electronic nose in the functional food industry include discrimination of habitats for medicinal food materials, monitoring storage process, lipid oxidation, and quality control of food and/or processing with principal component analysis, neural network analysis and the electronic nose based on GC-SAW sensor. The electronic nose would be possibly useful for a wide variety of quality control in the functional food and plant cultivation when correlating traditional analytical instrumental data with sensory evaluation results or electronic nose data.

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Effect of discontinuous mixture gas feeding on effective hydrogen production in a steam reformer frommethane (효율적 수소 생산을 위한 메탄 수증기 개질 반응기에서의 불연속적 가스 유입의 영향)

  • Lee, Shin-Ku;Park, Joon-Guen;Lim, Sung-Kwang;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.25-28
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    • 2008
  • Steam reforming reaction is a matured technology to get hydrogen from hydrocarbon fuels compared with other reforming reactions such as partial oxidation(POX), autothermal reforming(ATR). It is so endothermic that it needs heat source to activate the reaction. Due to the reaction characteristics, heat transfer limitation phenomena generally occur in the steam reformer. As one of new ideas, the effect of discontinuous gas feeding is investigated based on heat transfer characteristics. The new operating method is usually favorable at high GHSV region(i.e. over $10,000h^{-1}$). In order to numerically simulate the physical issues, numerical approach is adopted based on heterogeneous reaction model, two-equation model in energy equation, and other constitutive models in porous media.

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A Study on the Pyrolysis of Waste Tires with Partial Oxidation (부분연소를 통한 폐타이어의 열분해 연구)

  • 이종민;김정래;김상돈
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1993.11a
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    • pp.88-91
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    • 1993
  • 유동층 반응기 (H=0.8 m, ID=0.08 m) 에서 폐타이어의 열분해를 수행함에 있어 열분해에 사용되는 열을 외부에서 공급함과 동시에 일부는 내부에서 자체적으로 연소시켜 열을 얻고자 하였다. 온도 증가에 따라 가스의 수율은 40 %까지 증가하였고, 반면에 오일의 수율은 감소하였다. 또한 가스중에 heavy hydrocarbon 이 감소함과 동시에 H$_2$ 및 light hydrocarbon 이 증가하였고 이로 인해 가스 부피당 발열량은 감소하는 것으로 나타났다. 가스의 체류시간도 가스조성에 상당히 영향을 미치는 것으로 나타났으며, 본 시스템에서 발열량 및 가스생성량은 2 u$_{mf}$ 에서 최소치를 나타내는 것으로 보였다. 또한 $O_2$ 농도의 증가는 결국에는 생성가스의 연소를 일으키며, 적당한 $O_2$ 농도의 설정으로 이의 연소를 최소화하는 작업이 필요하다.

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Changes in Adhesion Interface between Rubber and Steel Cord with Aging Treatment (열화처리에 따른 고무와 강선코드간 접착계면의 변화)

  • Seo, Gon;Sohn, Bongyoung
    • Applied Chemistry for Engineering
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    • v.5 no.4
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    • pp.630-636
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    • 1994
  • The changes in adhesion interface between rubber compound and brass plated steel cord after various aging treatments were studied by using an Auger electron spectrometer and a scanning electron microscope. After thermal aging, partial oxidation and additional growth of adhesion layer were observed. The adhesion layer and brass were partially removed after humid aging. With dynamic aging the adhesion layer was destroyed and the corrosion of steel core was proceeded. The changes in adhesion interface were discussed in terms of the adhesion properties determined from the stress-strain experiments.

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A Study on the Catalytic Oxidation Reaction of Carbon Monoxide with Nickel Oxide (NiO 촉매에 의한 CO 산화반응에 관한 연구)

  • Jae Shi Choi;Keu Hong Kim
    • Journal of the Korean Chemical Society
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    • v.13 no.4
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    • pp.241-247
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    • 1969
  • The catalytic reaction between carbon monoxide and oxygen was investigated with the various nickel oxide catalysts at different partial pressures of carbon monoxide and oxygen and at reaction temperatures in the region of 120$^{circ}$to 250$^{circ}C$. The reaction has the highest rate with the nickel oxide catalyst which is sintered at low temperature. A reaction mechanism to explain the data is derived. From the Arrhenius equation, the activation energies in the region of experimental temperatures are found to be from 5.49 to 9.15 kcal/mole. The concentration of excess oxygen in the nickel oxide seems to vary according to the sintering temperatures and periods and is the controlling factor in determining the type of kinetics followed by the catalytic reaction.

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Analysis of Volatile Compounds using Electronic Nose and its Application in Food Industry (전자코를 이용한 휘발성분의 분석과 식품에의 이용)

  • Noh, Bong-Soo
    • Korean Journal of Food Science and Technology
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    • v.37 no.6
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    • pp.1048-1064
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    • 2005
  • Detection of specific compounds influencing food flavor quality is not easy. Electronic nose, comprised of electronic chemical sensors with partial specificity and appropriate pattern recognition system, is capable of recognizing simple and complex volatiles. It provides fast analysis with simple and straightforward results and is best suited for quality control and process monitoring of flavor in food industry. This review examines application of electronic nose in food analysis with brief explanation of its principle. Characteristics of different sensors and sensor drift. and solutions to related problems are reviewed. Applications of electronic nose in food industry include monitoring of fermentation process and lipid oxidation, prediction of shelf life, identification of irradiated volatile compounds, discrimination of food material origin, and quality control of food and processing by principal component analysis and neural network analysis. Electronic nose could be useful for quality control in food industry when correlating analytical instrumental data with sensory evaluation results.

Antiplatelet and antithrombotic activities of purpurogallin in vitro and in vivo

  • Ku, Sae-Kwang;Bae, Jong-Sup
    • BMB Reports
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    • v.47 no.7
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    • pp.376-381
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    • 2014
  • Enzymatic oxidation of pyrogallol was efficiently transformed to an oxidative product, purpurogallin (PPG). Here, the anticoagulant activities of PPG were examined by monitoring activated partial thromboplastin time (aPTT), prothrombin time (PT), and the activities of thrombin and activated factor X (FXa). And, the effects of PPG on expression of plasminogen activator inhibitor type 1 (PAI-1) and tissue-type plasminogen activator (t-PA) were evaluated in tumor necrosis factor (TNF)-${\alpha}$ activated human umbilical vein endothelial cells (HUVECs). Treatment with PPG resulted in prolonged aPTT and PT and inhibition of the activities of thrombin and FXa, as well as inhibited production of thrombin and FXa in HUVECs. In addition, PPG inhibited thrombin-catalyzed fibrin polymerization and platelet aggregation. PPG also elicited anticoagulant effects in mice. In addition, treatment with PPG resulted in significant reduction of the PAI-1 to t-PA ratio. Collectively, PPG possesses antithrombotic activities and offers a basis for development of a novel anticoagulant.

Experimental Study on the Partial Oxidation Reforming of CH4/O2 Mixture in Two-Section Porous Media at High Pressure Conditions (고압 분위기에서 CH4/O2 혼합기의 2단 다공체 내 부분산화 개질에 관한 실험적 연구)

  • Guahk, Young Tae;Lee, Dae Keun;Kim, Seung Gon;Ko, Chang-Bog;Park, Jong-Ho
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.73-74
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    • 2015
  • Synthesis gas such as hydrogen and carbon monoxide was produced from $CH_4/oxygen$ mixture using insulated pressurized porous media combustor. Experimentally, two cylindrical SiC foams with the different pore density were piled up in a quartz tube and fully premixed mixture was supplied in the axial direction. After stabilizing fuel-rich flame at the interface of the two foams at several pressure conditions, mole fractions of synthesis gases were measured by gas chromatography. Heat recirculation through the inner foam structure could extend the flow velocity of stable region over the laminar burning velocity. As the pressure increased, the rich flammability limit, $H_2/CO$ ratio, and module M increased.

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Hydrogen Production from Methane Reforming Reactions over Ni/MgO Catalyst

  • Wen Sheng Dong;No, Hyeon Seok;Zhong Wen Liu;Jeon, Gi Won;Park, Sang Eon
    • Bulletin of the Korean Chemical Society
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    • v.22 no.12
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    • pp.1323-1327
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    • 2001
  • The catalyst Ni/MgO (Ni : 15 wt%) has been applied to methane reforming reactions, such as steam reforming of methane (SRM), partial oxidation of methane (POM), and oxy-steam reforming of methane (OSRM). It showed high activity and good stability in all the reforming reactions. Especially, it exhibited stable catalytic performance even in stoichiometric SRM (H2O/CH4 = 1). From TPR and H2 pulse chemisorption results, a strong interaction between NiO and MgO results in a high dispersion of Ni crystallite. Pulse reaction results revealed that both CH4 and O2 are activated on the surface of metallic Ni over the catalyst, and then surface carbon species react with adsorbed oxygen to produce CO.

MAGNETISM OF NANOPHASE IRON PARTICLES LASER EVAPORATED IN A CONTROLLED OXYGEN ATMOSPHERE

  • Turkki, T.;Jonsson, B.J.;Strom, V.;Medelius, H.;El-Shall, M.S.;Rao, K.V.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.745-748
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    • 1995
  • Magnetic nanoparticles of iron and iron oxide have been prepared in a modified upward thermal diffusion cloud chamber using pulsed laser evaporation. SEM/TEM studies of these particles reveal a size distribution with a mean diameter of about $60\;{\AA}$. FTIR spectrum measurements are used to investigate the difference in oxidation level between nanoparticles prepared at different partial oxygen pressures. The complex magnetic behaviour of these particles was studied using DC- and AC-susceptibility measurements. All samples exhibit superparamagnetism with blocking temperatures ranging from 50 K to above room temperature. The coercivity fields as well as the dependence of the blocking temperature on measuring frequency have been studied. magnetic anisotropy constants are found to be one order of magnitude higher than is known for the bulk values. The mean particle size estimated from the magnetic data is found to be in perfect agreement with the TEM observations.

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