• Title/Summary/Keyword: parathion

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Distribution characteristics of organophosphorous pesticides in Asan Bay, Korea (아산만 해역의 유기인계농약 분포특성)

  • Choi Jin-Young;Yang Dong-Beom;Ju Hyo-Jung;Kim Kyung-Tae;Hong Gi-Hoon;Shin Kyoung-Hoon
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.9 no.3
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    • pp.176-186
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    • 2006
  • Distribution characteristics of organophosphorous pesticides(OPs) in water and suspended particles were studied in Asan Bay, Korea, from June 2004 to October 2005. 28 organophosphorous pesticides could be detected in Asan Bay during this study. The most commonly and abundantly measured OPs in the surface waters were IBP (max=$6,343.7ng\;l^{-1}$). DDVP, diazionon, ethoprophos and methidathion were also observed at relatively high concentrations. Their maximum concentrations exceeded $100ng\;l^{-1}$ in almost every month. Malathion, mevinphos, ph orate and chlorfenvinphos were also detected at relatively high concentrations. Many OPs more frequently appeared in summer than in winter due to the intensive application of pesticides in summer months. The concentration of OPs generally decreased with increasing distance from the mouth of Asan Bay. This result implies progressive dilution of these pesticides in the marine environment. Measured concentrations of diazinon were well below $20,000ng\;l^{-1}$ which is a limit set by the seawater quality standard of Korea. The concentrations of malathion and parathion in the surface waters of Asan Bay did not exceed the seawater quality standard of Korea($250,000\;and\;60,000ng\;l^{-1}$ respectively). OPs adsorbed on suspended particles were also studied. DDVP, phorate, stirofos, EPN, azinphos-methyl and IBP had higher adsorption capacity onto suspended particles than other pesticides. Calculated pesticide-particle adsorption coefficient($K_d-particle$) for samples collected in Asan Bay were closely related to the reported pesticides-soil adsorption coefficient ($K_d-soil$).

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Organophosphorus Insecticide Residues in Fruits and Vegetables (과실채소중(果實菜蔬中) 유기인계(有機燐系) 농약잔류(農藥殘留)에 관(關)한 연구(硏究))

  • Suh, Y.S;Rhu, H.I.;Kim, I.K.;Kim, H.Y.;Jun, S.H.
    • Korean Journal of Environmental Agriculture
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    • v.3 no.2
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    • pp.30-36
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    • 1984
  • This study was to investigate the organophosphorus insecticide residues in crops including five kinds of vegetables and two kinds of fruits. The pesticides investigated in spring-radish, spring Chinese cabbage, cucumber and tomato were diazinon, DEP and malathion, in unripe pepper EPN and PAP, in peach EPN, parathion and demeton-methyl, and in grape EPN, PAP and MEP. All samples were analysed by gas chromatographic technique with NPD detector. No one sample was found to approach proposed national maximum residue limits in Korea.

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Simultaneous determination of carbaryl & organophosphorous pesticides in water by liquid chromatography-tandem mass spectrometry (LC/MS/MS를 이용한 수중의 카바릴·유기인계 농약 동시분석)

  • Park, Keun-Young;Shin, Jung-Chul;Pyo, Dongjin
    • Analytical Science and Technology
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    • v.31 no.1
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    • pp.39-46
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    • 2018
  • Carbaryl and seven organophosphorous pesticides were analyzed simultaneously using on-line solid phase extraction (on-line SPE) coupled with liquid chromatography tandem mass spectrometry (LC/MS/MS). The target pesticides are Carbaryl, Methyl demeton, Fenitrothion, Malathion, Parathion, Phenthoate, Diazinon, and EPN. This method includes the direct injection of $500{\mu}L$ in the water sample, a 15 min separation period using a rapid resolution liquid chromatography system with on-line SPE, and detection through electrospray ionization (ESI) positive mode. The percentage of recovery of all pesticides ranged from 85.3 % to 100 %. This method showed an accuracy of ${\geq}90.0%$, possessing limits of detection and quantification within 0.05 to $0.28{\mu}g/L$ and 0.16 to $0.89{\mu}g/L$, respectively. The correlation coefficients (r) for the calibration curves within a range of 0.5 to $8.0{\mu}g/L$ were higher than 0.99. The evaluation results showed the efficacy of the method for all contents, and no pesticides were detected in the water quality sample.

Simultaneous Determination of Pesticides in Water Using a GC/MS Coupled with Micro Extraction by Packed Sorbent (MEPS-GC/MS를 이용한 농약류 동시 수질분석)

  • Lee, Ki-chang;Lee, Wontae
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.5
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    • pp.262-268
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    • 2015
  • This study established an analytical method to simultaneously determine six organophosphorous pesticides [methyldemetone-S, diazinon, fenitrothion, parathion, phentoate, and O-ethyl O-(4-nitrophenyl) phenylphosphonothioate (EPN)] and carbaryl in water using a gas chromatography/mass spectrometry (GC/MS) system coupled with on-line micro extraction by packed sorbent (MEPS) and programmed temperature vaporizer (PTV) injector. Polystyrene divinylbenzene (PDVB) was used as a sorbent of MEPS. The effects of elution solvents, pH, elution volume and draw-eject cycles of samples on sample pretreatment process were investigated. Also, quality assurance and quality control (QA/QC) and the recovery of the pesticides in environmental samples were evaluated. The elution was performed using $30{\mu}L$ of a mixed solvent (acetone : dichloromethane = 80 : 20 (v/v)). Sample pretreatment processes were optimized with seven cycles of draw-eject of sample (1 mL) spiking an internal standard and sulfuric acid. At lower pH, the analytical sensitivity of diazinon decreased, but that of carbaryl increased. The method detection limit and the limit of quantification for this method were 0.02~0.18 and $0.08{\sim}0.59{\mu}g/L$, respectively. The method precision and accuracy were 1.5~11.5% and 83.3~129.8%, respectively, at concentrations of $0.5{\sim}5.0{\mu}g/L$. The recovery rates for all the pesticides except carbaryl in various environmental samples ranged 75.7~129.3%. The recovery rate of carbaryl in effluent sample was over 200% whereas carbaryl in drinking water, groundwater, and river water were in the acceptable range.

Management Strategies for Apolygus spinolae(Hemiptera: Miridae) in Grapevine Yards (포도원에서 애무늬고리장님노린재(Apolygus spinolae(Meyer-Dur))방제체계)

  • 김동순;조명래;전흥용;임명순;최용문
    • Korean journal of applied entomology
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    • v.41 no.1
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    • pp.67-73
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    • 2002
  • Studies were conducted to investigate the control effects of several insecticides on Apolygus(=Lygocoris) spinolae(Meyer-Dur) and to develop its management strategies in grapevine yards. Of insecticides which were applied by farmers in commercial grapevine yards, chlorpyrifos, parathion, fenvalerate, and esfenvalerate$.$fenitrothion showed good control effects against A. spinolae. In designed field experiments of fenitrothion and chlorpyrifos for the evaluation of A. spinolae control, both insecticides showed high control efficacy of 94.8 and 91.6%, respectively. The damage of A. spinolae was examined in a grapevine yard, where five different combinations of application timing and number were treated with fenitrothion to assess yield losses (average cluster weight) by A. spinolae. There were no significant differences among average cluster weights of sprayed vines; 466.0 g in sprayed vines on 2 to 3 leaves unfolded stage, 460.7g in sprayed vines on flower separating stage, 465.0 g in sprayed vines each on 2 to 3 leaves unfolded and flowers separating stage, and 487.4 g in sprayed vines each on 2 to 3 leaves unfolded, flowers separating and fruit set stage. Weights of fruit clusters of unsprayed vines was significantly lower than those of sprayed vines. Based on yield and spray cost, chemical control on 2 to 3 leaves unfolded stage produced higher net income than each spray on 2 to 3 leaves unfolded and flower separating stage (i.e., two times of spray), and produced similar net income as each spray on 2 to 3 leaves unfolded, flowers separating and fruit set stage (i.e., three times of spray). Thus, the 2 to 3 leaves unfolded stage was economical spray timing to controlA. spinolae in grapevine yards. Also, management strategies for A. spinolae were discussed.

Study on the Residue Analysis of Organophosphorus and Organochlorine Pesticides with Ion Trap and Quadrupole Mass Spectrometer (Ion Trap Mass Spectrometer와 Quadrupole Mass Spectrometer를 이용한 유기인제 및 유기염소제 농약 분석에 관한 연구)

  • Rhee, Jae-Seong;Park, Hyun-Mee;Er, Yon-Woo
    • Journal of the Korean Chemical Society
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    • v.39 no.12
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    • pp.902-909
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    • 1995
  • Detection limit as well as calibration curves on organophosphorus pesticide(dimethoate, diazinon, parathion-methyl, fenitrothion, malathion) and BHCs were measured for evaluation of utility on qualitative or quantitative analysis of pesticides with ion Trap mass spectrometer and quadrupole mass spectrometer. As ionization source, EI and CI were adopted for qualitative analysis of pesticides by comparison of each fragmentation pattern. At the same time, the utility as trace analysis techniques through scan or selected ion monitoring(SIM) mode was evaluated. With ion trap for all pesticides, detection limit(DL, 1 ${\mu}L$ injection) on scan mode was ranged 0.008∼0.225 ng at signal to noise ratio 3. With quadrupole DL on scan mode was ranged 0.23∼3.1 ng over 0.032∼0.68 ng on SIM mode. The calibration curve with ion trap generated good linearity over 0.99 as correlation coefficient. As clean up procedure, Bio Beads S-X3 was used for the separation of oils from five organophosphorous pesticides in flour extractant showing more than 80% as recovery at most cases. In case of BHCs in jinseng with Florisil column, the recovery of pesticides has been 60% to 90%.

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Studies on Pear Phylloxera (Aphanostigma iakusuiense Kishida) (1) On the Control Methods (콩가루벌레 (Aphanostigma iakusuiense)에 관한 연구 (I) 방제시험을 중심으로)

  • Yoon Ju Kyung;Lee Don Kil
    • Korean journal of applied entomology
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    • v.13 no.4 s.21
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    • pp.209-216
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    • 1974
  • Life history and control methods of Aphanostigma iakusuiense Kishida were studied during April to November, 1974, in the Naju pear orchard area, Cholla Namdo. The results are summarized as follows: 1. More than $60\%$ of wintering eggs were found at the height of 1.5 to 2.0m from the soil surface, with approximately $10\%$ at 0.5 to 1.5m and 1.5 to 2.5m respectively. 2. There was little difference in the size of egg masses and hatching ratio $(12.7-13.7\%)$ between the varieties of host trees, Mansamkil and Kooksoo. 3. Hatching was not observed until April 6, but hatches of $12.8\%$ on April 13 and $90.6\%$ on May 4 were found. 4. During the hatching season in early spring, 8 chemicals were applied to test effectiveness of control. C8514, Metasystox, Acar 338, and Parathion were more effective than either Sevin or Malix for control of this insect. 5. Highest populations of pear phylloxera ocurred from August 20 to September 20 at which time levels of eggs and larvae were simillar in abundance. 6. In tests for control of this insect after in paper bags, DDVP, Loxon, C8514, Sevin, and Binapacryl were more effective than either EPN or Otran. 7. Predacious mite, Protolaelape pygmaeus Miller, and several species of lady beetles (Coccinellidae) preying on this insect as natural enemies were collected. The predation ratio of mites varied according to region: that is 0.77 to $18.6\%$ in Bia Orchard; $7.88-48.7\%$ in Noan Orchard and almost none in Youngsanoo Orchard. 8. The varietal difference in fruit damage by this insect was in the order of Choseng Chuck, Kooksoo, followed by Sin Ko, Mansamkil, Keumchon Choo, and Changsimrang.

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Evaluation of Groundwater Contamination Potential of Pesticides Using Groundwater Ubiquity Score in Jeju Island Soils (Groundwater Ubiquity Score를 이용한 제주도 토양 특성별 농약의 지하수 오염가능성 평가)

  • Hyun, Hae-Nam;Jang, Gong-Man;Oh, Sang-Sil;Chung, Jong-Bae
    • The Korean Journal of Pesticide Science
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    • v.11 no.3
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    • pp.144-153
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    • 2007
  • One of the most recent issues facing the pesticides regulatory process is the assessment of the potential for pesticides to leach through soil and appear in groundwater. Since Jeju island depends on a hydrogeologically vulnerable aquifer system as its principle source of drinking water, it is important to identify which pesticides are the most likely to result in groundwater contamination. The objective of this study was to assess groundwater contamination risk of 21 pesticides (12 insecticides, 6 herbicides and 3 fungicides) in Jeju soils using groundwater ubiquity score (GUS). Considering GUS estimated in 21 representative series of Jeju soils, generally herbicides showed relatively higher leaching potentials and insecticides showed lower leaching potentials. Groundwater contamination risk was higher in the order of bromacil > metolachlor > alachlor > linuron pretilachlor > butachlor for herbicides, carbofuran > ethoprophos > diazinone > dimethoate > penthoate > mecarbam > methidathion > endosulfan > fenitrothion > parathion > chlorpyrifos > terbufos for insecticides, and metalaxyl > chlorothalonil > triadimefon for fungicides. Among the tested pesticides alachlor, metolachlor, bromacil, ethoprophos and carbofuran were classified as the pesticides of very high or high groundwater contamination potential. Although the ranking of the leaching potential was essentially determined on the base of the intrinsic properties of the chemicals and environmental properties, variation of the relative groundwater contamination potentials of each pesticides in different soils were not significant. Therefore, the above ranking of groundwater contamination risk would be applied in most of Jeju soils. To lower the possibility of pesticide contamination of groundwater, the use of those pesticides classified as high or very high leaching potential should be strictly regulated in Jeju Island.

A Survey on the Damage done to the Farmers by Agrochemicals in a Rural Area of Korea (일부(一部) 농촌지역(農村地域)에서의 농약(農藥)에 의한 인체(人體)의 피해상황(被害狀況)에 관(關)한 조사연구(調査硏究))

  • Lim, Hyun-SuI
    • Journal of Preventive Medicine and Public Health
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    • v.15 no.1
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    • pp.205-211
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    • 1982
  • This survey was conducted to find out demage done to the farmers by Agrochemicals in a rural area of Korea from January to October, 1980. Choon Sung Gun, Kang Won Province was the survey area and the 412 males were surveyed among all those that have sprayed agrochemicals during 10 Months in 1980. Obtained results and findings from this survey are summarized as follows; 1. The total spray days of 413 males were 3,114 days and avarage spray days per person were 7.54 days. Also avarage spray hours per person were 4.7 hours. 2. The incidence rate per 100 persons of self-recognized skin manifestation was 12.6 persons and incidence rate per spray day was 2.7 percent. The incidence rate per 100 persons of self-recognized intoxication was 23.0 persons and incidence rate per spray day was 3.6 percent. 3. In cases where mask was not used, when it was syrayed in hot weather, when stronger solution was used, the results were higher percentage in self-recognized intoxication (P<0.01). 4. The symptoms of self-recognized intoxication were headache (55.8%), dizziness (46.9%), nausea (17.7%), fatigue (17.0%), and vomiting (17.0%), 5. Number of intoxication per 100 used standardized unit by agrochemicals was parathion (93.8 spells), sumithion (91.8 spells) and folithion (66.7 spells). 6. Treatment was done by health facility utilization (27 cases), visits to drug store (13 cases) and visits to health center (7 cases).

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Monitoring on Endocrine Disruptors in Commercial Agricultural Products in the Northern Area of Seoul(2007) (서울 강북지역 유통 농산물의 내분비계장애 추정농약의 잔류실태(2007))

  • Ha, Kwang-Tae;Park, Sung-Kyu;Cho, Tae-Hee;Han, Chang-Ho;Kim, Sung-Dan;Lee, Kyeng-A;Kim, Si-Jung;Jang, Jung-Im;Jo, Han-Bin;Choi, Byung-Hyun
    • Journal of Food Hygiene and Safety
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    • v.24 no.2
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    • pp.136-142
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    • 2009
  • This study was carried out to investigate the current status of suspected endocrine disrupting pesticides among the agricultural products in northern area of Seoul in 2007. 3,026 samples was analyzed by multiresidue method. Detected Pesticide in 11 cases were procymidone, endosulfan, chlorothalonil, chlorpyrifos, cyermethrin, fenvalerate, hexaconazole, carbendazim, pendimethalin, permethrin, parathion and exceeded 7 cases of endosulfan, procymidone, carbendazim, chlorothalonil, chlorpyrifos, cypermethrin, fenvalerate in the maximum residue limits(MRLs). Procymidone, endosulfan, chlorothalonil and chlorpyrifos comprised up to 80.5% in detected pesticides. Among the 321 cases of detected agricultural products, 287 cases(89.4%) were vegetables, 25 cases (7.8%) were fruits, Others were 9 cases(2.8%).