• Title/Summary/Keyword: paraffin

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Preparation process of functional particles: II. Particle coating by rapid expansion of supercritical fluid solutions (기능성 미분말의 제조공정에 관한 연구: II. 초임계 분출법에 의한 입자 코팅)

  • 류완원;김영도;신건철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.673-676
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    • 1998
  • The Rapid Expansion of Supercritical fluid Solutions (RESS) process was applied to particles coating. Experiments were conducted in a fluidized bed with an internal nozzle in the center of the reaction tube. Pure glass beads (500~590$\mu$m, 74~149$\mu$m) and glass beads covered with brilliant blue were used as the core particles. Supercritical $CO_2$ solutions of paraffin were expanded through the nozzle into the bed that was fluidized by air. The precipitate coating materials on core surface was analyzed by using SEM, FT-IR. The releasing behavior of brilliant blue was inspected by atomic absorbance spectrophotometer. The release behavior of coated particles superior to noncoated particles.

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Morphological Changes of Radiation-Induced Atretic Follicles in Mouse Ovary

  • Kim Sung-In;Kwon O-Yu;You Kwan-Hee
    • Biomedical Science Letters
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    • v.12 no.2
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    • pp.105-112
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    • 2006
  • This study was undertaken to investigate the morphological changes between normal and atretic follicle after gamma irradiation and treatment of follicle stimulating hormone (FSH). The ovaries of each group of treated immature mice were prepared the paraffin sections after 0, 6, 12, and 24 hours (hrs) of those treatment. Hematoxylin-eosin (HE) stain, reticulin stain, and terminal deoxynucleotidyl transferase (TdT)-mediated dUTP nick end labeling (TUNEL) immunohistochemical stain were performed on the each paraffin sections. As the results of HE staining, the condensed nuclei of oocytes were observed in the atretic primordial follicles, on the other hand the condensations of granulosa cell nuclei were prominent in the atretic primary, preantral, and antral follicles. Only the granulosa cells of atretic follicle were stained specifically with TUNEL staining but not stained in the theca cells, which suggested granulosa cells degenerated through apoptosis. In the reticulin staining, the basement membranes of atretic follicle which was stained weakly showed irregular structure and detachment from the follicles. The ratio of normal to atretic follicle in control and FSH treated group was about 33% but this ratio increased rapidly over 90% in the 6, 12, and 24 hrs group after the irradiation. It could be suggested that the gamma irradiation is the useful tool far the induction of follicle atresia and immunohistochemical staining methods are essential in the study of follicle atresia.

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Tansport Rate of Chromium ion from Waste Water through the Liquid Surfactant Membrane Containing Carrier (운반체 함침 유화액막에 의한 폐수중 크롬(VI)의 이동속도)

  • Woo, In-Sung;Kim, Kyoung-Ho;Lee, Sang-Jin;Kang, An-Soo;Choi, Sei-Young
    • Elastomers and Composites
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    • v.23 no.1
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    • pp.11-17
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    • 1988
  • The transport of chromium(VI) ion from waste water through the liquid surfactant membrane containing tri-n-octylamine as a carrier, was analyzed by a slab model and was investigated through experiments. For the experiment of membrane stability, concentrations of surfactant and liquid paraffin oil were analyzed. Extraction experiments were carried out to observe the effect of system variables, such as concentrations of carrier, and initial chromium(VI) ion in external aqueous phase at $25^{\circ}C$. It is concluded that the most stable formation of liquid membrane emulsion was obtained when surfactant concentration is above 3 wt.% and liquid paraffin oil concentration is 50 vol.%. The theoretical equation on the transport of chromium(VI) ion agreed well with the experimental results.

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Experimental Study on Inward Melting of Phase Change Material in Inclined Circular Tube (경사진 원통형 용기내에서 상변화 물질의 내향 용융에 관한 실험적 연구)

  • Yim, Chang-Soon;Son, Ha-Jin
    • Solar Energy
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    • v.12 no.1
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    • pp.48-58
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    • 1992
  • In the present investigation, experimental analysis was performed to research heat transfer phenomena generated by means of conduction and natural convection at a succession of tube-inclimations relative to the vertical tube during inward melting process of a phase change material. The phase change material used in the experiments is 99 percent pure n-docosane paraffin($C_{22}H_{46}$). When the tube is vertical, the dominant mode of energy transfer between the tube wall and the melting interface is natural convection. On the other hand, when the tube is inclined to the vertical, the melting solid is brought into direct contact with the tube wall by the action of gravity. In the experimental results, direct contact gave rise to substantial enhancements in the amount of melted mass, relative to those for natural-convection-dominated melting.

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Fundamental Study on the Chemical Ignition Delay Time of Diesel Surrogate Components (모사 디젤 화학반응 메커니즘의 각 성분이 화학적 점화 지연 시간에 미치는 영향에 관한 기초 연구)

  • Kim, Gyujin;Lee, Sangyul;Min, Kyoungdoug
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.3
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    • pp.74-81
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    • 2013
  • Due to its accuracy and efficiency, reduced kinetic mechanism of diesel surrogate is widely used as fuel model when applying 3-D diesel engine simulation. But for the well-developed prediction of diesel surrogate reduced kinetic mechanism, it is important to know some meaningful factors which affect to ignition delay time. Meanwhile, ignition delay time consists of two parts. One is the chemical ignition delay time related with the chemical reaction, and the other is the physical ignition delay time which is affected by physical behavior of the fuel droplet. Especially for chemical ignition delay time, chemical properties of each fuel were studied for a long time, but researches on their mixtures have not been done widely. So it is necessary to understand the chemical characteristics of their mixtures for more precise and detailed modeling of surrogate diesel oil. And it shows same ignition trend of paraffin mixture with those of single component, and shorter ignition delay at low/high initial temperature when mixing paraffin and toluene.

Comparison of Two Methods to Extract DNA from Formalin-Fixed, Paraffin-Embedded Tissues and their Impact on EGFR Mutation Detection in Non-small Cell Lung Carcinoma

  • Hu, Yu-Chang;Zhang, Qian;Huang, Yan-Hua;Liu, Yu-Fei;Chen, Hong-Lei
    • Asian Pacific Journal of Cancer Prevention
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    • v.15 no.6
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    • pp.2733-2737
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    • 2014
  • Objective: Molecular pathology tests are often carried for clinicopathological diagnosis and pathologists have established large collections of formalin-fixed, paraffin-embedded tissue (FFPE) banks. However, extraction of DNA from FFPE is a laborious and challenging for researchers in clinical laboratories. The aim of this study was to compare two widely used DNA extraction methods: using a QIAamp DNA FFPE kit from Qiagen and a Cobas Sample Preparation Kit from Roche, and evaluated the effect of the DNA quality on molecular diagnostics. Methods: DNA from FFPE non-small cell lung carcinoma tissues including biopsy and surgical specimens was extracted with both QIAamp DNA FFPE and Cobas Sample Preparation Kits and EGFR mutations of non-small cell lung carcinomas were detected by real-time quantitative PCR using the extracted DNA. Results and Conclusion: Our results showed that DNA extracted by QIAamp and Cobas methods were both suitable to detect downstream EGFR mutation in surgical specimens. Howover, Cobas method could yield more DNA from biopsy specimens, and gain much better EGFR mutation results.

Changes in Facilitated Transport Behavior of Silver Polymer Electrolytes by UV Irradiation

  • Jongok Won;Yosang Yoon;Kang, Yong-Soo
    • Macromolecular Research
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    • v.10 no.2
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    • pp.80-84
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    • 2002
  • Silver species other than the silver ion were formed by UV irradiation on polymer electrolyte membranes containing silver salts and their effect on complexation behavior between the silver and olefin was investigated through the separation performance of olefin/paraffin mixtures. The ideal propylene/propane separation factor reached 350 and the separation coefficient was ca.15 due to the high loading amount of silver ions into poly(2-ethyl-2-oxazoline) (POZ) without UV irradiation. On UV irradiation either in air or under nitrogen, the silver-POZ membranes became yellow-brown initially due to the formation of colloidal silver particles, and finally black and metal-like luster. Even when Ag$^{+}$ was converted, to some extent, to Ag$^{\circ}$ by UV irradiation in air at the early stage, the separation coefficient of olefin/paraffin mixtures was maintained. This suggests that silver species other than the silver ion is active for olefin carrier for facilitated transport. Meanwhile the steady decrease of the separation coefficient was observed in the silver/POZ membranes irradiated under $N_2$. It is suggested that the reduction of silver ions in POZ goes through a different photoreduction mechanism with UV irradiation depending on the environment.t.

Study on Nanocomposite Thermoplastic Elastomer Gels

  • Paglicawan Marissa A.;Balasubramanian Maridass;Kim, Jin-Kuk
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.370-370
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    • 2006
  • Thermoplastic elastomer gels, which has molecular networks composed of a microphase-separated multiblock copolymer swollen to a large extent by a low volatility mid-block selective solvent such as white oil have various applications. In this particular study, the effect of several network-forming nanoscale fillers such as two different graphite particles and carbon nanotube on the properties of TPE gels prepared from a microphaseordered poly[styrene-b-(ethylene-co-butylene)-b-styrene] (SEBS) triblock copolymer with an EB compatible white oil was studied. The linear viscoelastic behavior, sol-gel transition, x-ray diffraction and mechanical properties were discussed. The properties of thermoplastic elastomer gels hybrid with graphite prepared by mixing Poly(styrene-b-ethylene-co-butylene)-b-styrene) with paraffin oil and different amount of expandable graphite were found to increase the mechanical properties at only lower graphite concentration but tends to decrease when paraffin oil/SEBS ratio is lower. The gelation temperature is the same for all TPE gels with different amounts of graphite. Both storage (G') modulus loss (G") modulus of TPE gels slightly increase with addition of graphite.

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Preparation of Polyvinylpyrrolidone/AgBF4/Al(NO3)3 Electrolyte Membranes for Facilitated Gas Transport (기체 촉진수송을 위한 polyvinylpyrrolidone/AgBF4/Al(NO3)3 전해질 분리막 제조)

  • Yoon, Ki Wan;Kang, Sang Wook
    • Membrane Journal
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    • v.26 no.1
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    • pp.38-42
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    • 2016
  • Polyvinylpyrrolidone (PVP), which is glassy polymer to have amide functional group, was induced to fabricate the facilitated olefin transport membranes for olefin/paraffin separation. Separation performance for the mixed gas consisting of propylene and propane (50 : 50 vol%) was measured by gas chromatography and bubble flow meter. The properties of membranes were confirmed by scanning electron microscope and FT-IR. The results of long-term separation tests showed the selectivity of 15 and permeance of 1.3 GPU. The membranes was compared with poly(2-ethyl-2-oxazoline) $(POZ)/AgBF_4/Al(NO_3)_3$ membranes and the characteristics were confirmed as polymer matrix for facilitated transport membranes.

High Resolution Melting Analysis for Epidermal Growth Factor Receptor Mutations in Formalin-fixed Paraffin-embedded Tissue and Plasma Free DNA from Non-small Cell Lung Cancer Patients

  • Jing, Chang-Wen;Wang, Zhuo;Cao, Hai-Xia;Ma, Rong;Wu, Jian-Zhong
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.11
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    • pp.6619-6623
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    • 2013
  • Background:The aim of the research was to explore a cost effective, fast, easy to perform, and sensitive method for epidermal growth factor receptor (EGFR) mutation testing. Methods: High resolution melting analysis (HRM) was introduced to evaluate the efficacy of the analysis for dectecting EGFR mutations in exons 18 to 21 using formalin-fixed paraffin-embedded (FFPE) tissues and plasma free DNA from 120 patients. Results: The total EGFR mutation rate was 37.5% (45/120) detected by direct sequencing. There were 48 mutations in 120 FFPE tissues assessed by HRM. For plasma free DNA, the EGFR mutation rate was 25.8% (31/120). The sensitivity of HRM assays in FFPE samples was 100% by HRM. There was a low false-positive mutation rate but a high false-negative rate in plasma free DNA detected by HRM. Conclusions: Our results show that HRM analysis has the advantage of small tumor sample need. HRM applied with plasma free DNA showed a high false-negative rate but a low false-positive rate. Further research into appropriate methods and analysis needs to be performed before HRM for plasma free DNA could be accepted as an option in diagnostic or screening settings.