• Title/Summary/Keyword: papermaking

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Effect of PVOH or polyDADMAC Addition on Surface Sizing with Oxidized Starch (PVOH와 polyDADMAC 첨가에 의한 산화전분의 표면사이징 효과 변화)

  • Seo, Dongil;Jeong, Young Bin;Jeong, Kwang Ho;Lee, Hak Lae;Youn, Hye Jung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.4
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    • pp.1-8
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    • 2013
  • High loading of printing and writing grades with fillers has many advantageous aspects in papermaking because it allows decreasing fiber use and reducing manufacturing cost. High loading technology, however, has some disadvantageous aspects as well. It decreases physical properties of papers, especially strength properties. The problem associated with high loading can be reduced by applying surface sizing starch solution onto paper surface. It is important to control the penetration of the surface sizing starch solution into paper web to obtain the desired property improvement. In this study, the effect of the addition of two polymers into starch solution on paper properties has been examined. PVOH and polyDADMAC were used as polymeric additives for surface sizing with oxidized starch. Viscosity of starch solutions and surface roughness of dried starch films on glass slides showed that some interactions between polymeric additives and oxidized starch have been occurred and the most extensive interaction with starch solution was obtained with high molecular weight polyDADMAC. Low molecular weight PVOH was most effective in improving folding endurance and internal bond strength. On the other hand, polymer addition showed no effect on surface strength of paper. This indicates that not the level of starch holdout but the bonding strength of starch itself has predominant influence on surface strength of paper.

Investigation of Paper Characteristics on Old Documents Related to the Head Family of Admiral Yi Sun-sin (이충무공 종가 관련 고문서의 지질 특성 조사)

  • Ahn, Ji Yoon;Bae, Su Bin
    • Journal of Conservation Science
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    • v.34 no.5
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    • pp.407-420
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    • 2018
  • Old documents related to the head family of admiral Yi Sun-shin have been preserved by the descendants of Deoksu Yi clan and various kinds of documents have remained even today. Seven documents issued by the king,"Goshin Gyoji", "Jeunggik Gyoji", "Gyochub", "Gyoseo", "Yuseo", "Hongpae", and "Chikmyung", showed the time when they were made. Because they have been kept in their original form, these documents make it possible to identify the characteristics of the paper used to create documents during that time and to compare the records in those documents with other cultural properties based on scientific investigation and analysis of conservation treatment processing. The characteristics of Oebal-tteugi(Heulim-tteugi) in the papermaking process were identified through the shape of the surface fibers, and Dochim processing was found in most of the old documents with the help of density measurement and paper surface analysis. All the papers were found to be made of paper mulberry, and bast fibers of mature mulberry were mainly used for the process.

Study on Preparation of Environmental-Friendly Specialty Paper Using Functional Antibiotic Nano-Particle (II) (기능성 항균 나노입자를 이용한 친환경성 특수지 제조에 관한 연구(II))

  • Cho, Jun-Hyung;Lee, Yong-Won;Kim, Hyoung-Jin
    • Applied Chemistry for Engineering
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    • v.18 no.1
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    • pp.17-23
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    • 2007
  • For the purpose of antibacterial and photocatalystic deodorization functions, the papermaking inorganic fillers and pigments were surface-modified with Ag nano-colloidal solution and $TiO_2$ by using the hybridization technique. The functional specialty sheets and coating papers were produced with the surface-modified fillers and pigments, and evaluated by halo test and inhibition growth test in their antibacterial and photocatalystic characteristics. For the application of specially produced antibacterial handsheet to the wallpaper usages, the photocatalyst efficiency test of benzene in volatile organic compound dissolution experiment of antibacterial and deodorization function wallpaper showed that the efficiency was 45~50% for 80 min of reaction time and 90% of attained resolution was reached at approximately 30 min of response time.

Isolation and Identification of the Origins Causing the Slime Found in Pulp and Paper Making Processes (제재공장내 슬라임 발생원의 분리와 동정)

  • Oh, Jung-Soo;Jo, Byoung-Muk;Kim, Eun-Hee
    • Journal of the Korean Wood Science and Technology
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    • v.25 no.3
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    • pp.50-57
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    • 1997
  • The presence of slime in paper mills is practically universal. Many researches have been performed for many years to resolve the problem caused by the slime in pulp and paper mill. Many papers have been published to show the bacteria is a major cause of paper mill slime. Now that the recycling of the water has been increased and the regulations of a toxic chemical dosage have become more strengthen, the importance of the control of slime in pulp and paper mill recently has been more recognized. Therefore, to produce quality products at the lowest economic and environmental costs, a through study of the microbial ecology and the indentification of troublesome slime-forming bacteria is a quite necessary. The purpose of this paper is to indentify slime~forming bacteria isolated from the papermaking process. The samples were taken from four parts of making fine paper : machine chest, head box, wire part, white water tank. Machine chest showed the most numbers of bacteria, numbering $2.55{\times}10^7$. The different colony types were taken from the 105 dilution plate. Nine bacteria were identified u sing the Biolog system and the vitek system: 6 gram-negative bacteria, 3 gram-positive bacteria. They are Pseudomonas paucimobilis B., Staphylococcus sp., Acinetobacter calcoaceticus., Pseudomonas cepacia, Actinobaci1lus capsulatus, Acidovorax sp., Flavobacterium sp., and Staphylococcus auricularis in addition to one unidentified sp., Among them. Pseudomonas paucimobillis was found in all places where the samples were taken. And, each parts had the different predominant bacteria in it : Pseudomonas paucimobilis B. in machine chest, Acinetobactor calcoaceticus. in Wire Part and Staphylococcus sp. in head box.

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The Role of Charge and Retention in Effective Wet end Management

  • Rantala, T.;Nokelainen J.;Ojala, T;Dr. Taina Sopenlehto
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.06a
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    • pp.1-10
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    • 2000
  • The development of paper machines, increasing machine speeds with new, mostly low basis weight and/or high ash content paper grades, as well as the fact that several trends regarding process items have increased the sensitivity of papermaking. At the same time, papermakers are looking for flexibility in the production line. We can say that with all PMs the biggest benefits with the lowest capital spending can be achieved by focusing on improved wet end management. In order to manage wet end chemistry on a paper machine, our goal is to control sub-process through which we can influence the operation of the entire wet end with maximum effect. Key measurements and controls are-white water consistency control which is the most effective way to control retention - charge demand measurement and control which takes care of concentration of the anionic material entering to PM -ash measurements and controls which are deeply related to retention and paper quality This paper presents and concentrates to two of these key controls ; retention and charge. The purpose of charge control is to give the process control the tools to react to changes caused by amount of dissolved and colloida material incoming to wet end system. It is called coagulation or fixing control. Retention control is then taking care of retention aid flow to the process by responding any changes seen in white water consistency. It is called flocculation control. Each of these solutions separately , and even more effectively all together, stabilize the wet end operations and so greatly improve the produced paper quality and machine runnability. Practical results will be presented and they are referring to the latest mill cases. We have developed the first wet end measuring system in the late 1980s and control solutions based on this modern measuring technology were completely updated in 1990s. This paper introduces the principle, operation , and results of our unique wet end analyzers (retention and charge ) which are at the level of automation solutions as a part of paper machine quality control Especially our newest member of the platform , on-line charge analyzer has reached and set new standards to the on-line charge monitoring.

The Role of Charge and Retention in Effective Wet End Management

  • Rantala, T.;Nokelainen, J.;Ojala, T.;Sopenlehto, Taina
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.5
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    • pp.44-53
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    • 2000
  • The development of paper machines, increasing machine speeds with new, mostly low basis weight and/or high ash content paper grades, as well as the fact that several trends regarding process items have increased the sensitivity of papermaking. At the same time, papermakers are looking for flexibility in the production line. We can say that with all PMs, the biggest benefits with the lowest capital spending can be achieved by focusing on improved wet end management. In order to manage wet end chemistry on a paper machine, our goal is to control subprocesses through which we can influence the operation of the entire wet end with maximum effect. Key measurements and controls are - white water consistency control which is the most effective way to control retention. - charge demand measurement and control which takes care of concentration of the anionic material entering to PM. - ash measurements and controls which are deeply related to retention and paper quality. This paper presents and concentrates to two of these key controls: retention and charge. The purpose of charge control is to give the process control the tools to react to changes caused by amount of dissolved and colloidal material incoming to wet end system. It is called coagulation or fixing control. Retention control is then taking care of retention aid flow to the process by responding any changes seen in white water consistency. It is called flocculation control. Each of these solutions separately, and even more effectively all together, stabilize the wet end operations and so greatly improve the produced paper quality and machine runnability. Practical results will be presented and they are referring to the latest mill cases. We have developed the first wet end measuring system in the late 1980s and control solutions based on this modern measuring technology were completely updated in 1990s. This paper introduces the principle, operation, and results of our unique wet end analyzers (retention and charge) which are at the level of automation solutions as a part of paper machine quality control. Especially our newest member of the platform, on-line charge analyzer has reached and set new standards to the on-line charge monitoring.

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Evaluation of Control Efficiency of Oil Mark Originated from the Recycled Fibers (재활용폐지 유래 기름반점 제어효율 평가)

  • Sung, Yong Joo;Yoon, Do-Hyun;Kim, Dong Sub;Lee, Ji-Young;Heo, Young-Jun;Kim, Young-Hoon;Kim, Yeon-Oh;Lee, Se-Ran
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.5
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    • pp.69-78
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    • 2014
  • The paper recycling becomes more important technology in terms of the reduction of the municipal waste and of saving natural resource such as wood. However the more utilization of recycled fiber would result in the higher contaminants in the papermaking processes and in the deterioration of the paper quality. The oil marks in the paper products becomes one of the major defects of paper products originated from paper recycling. The coagulation of various stickies in recycled fiber stock led to the oil marks. In this work, we applied functional polymer additives such as the dispersing agents, the fixing agents and the hydrophobic talc powder for the control of those stickies in order to remove the oil marks. The addition of the talc powder showed the great reduction in the oil marks of the packaging paper products. The hydrophobic surface of the talc particles collected the individual sticky materials and prevented their aggregation in the recycled fiber stock, which resulted in the great reduction of the oil marks on the paper products.

Application of In-situ CaCO3 Formation Method for Better Utilization of Recycled Fibers (2) - Comparison with CaCO3 Addition Method and Effects of Temperature - (고지의 효과적인 활용을 위한 in-situ 탄산칼슘 부착방식의 연구(2) - 탄산칼슘 첨가방식과 비교 및 반응온도에 따른 변화 -)

  • Lee, Min Woo;Lee, Young Ho;Jung, Jae Kwon;Seo, Yung Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.5
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    • pp.27-34
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    • 2014
  • In-situ $CaCO_3$ formation onto recycled wood pulp was studied to improve optical properties and ash attachment to the fiber furnish in papermaking. We controlled initial reaction temperature of in-situ $CaCO_3$ formation method from $30^{\circ}C$ to $50^{\circ}C$. It was found that the attachment of newly formed $CaCO_3$ to recycled fibers, old newspaper (ONP) in this case, was stronger than that of ground calcium carbonate (GCC, mean dia. $2.4{\mu}m$) addition case, but was not much different among those formed at different temperature. Morphologies of newly formed $CaCO_3$ were changed according to the reaction temperature. More aragonite shape was seen at higher temperature. In-situ $CaCO_3$ formation increased brightness and lowered ERIC value of ONP sheet greatly at the same level of ash contents when compared to GCC addition method, but gave equivalent ERIC and brightness when compared to those of the precipitated calcium carbonate (PCC) addition method. However, tensile strength of the handsheets of the in-situ $CaCO_3$ formation method were much greater than those of the PCC addition method.

Application of In-situ CaCO3 Formation Method for Better Utilization of Recycled Fibers (1) - Enhancing Attachment of CaCO3 to Fibers by Polymer Pre-Treatment - (고지의 효과적인 활용을 위한 in-situ 탄산칼슘 부착방식의 연구 (1) - 탄산칼슘의 부착 효과 증대를 위한 고분자 전처리 -)

  • Seo, Yung Bum;Lee, Min Woo;Lee, Young Ho;Jung, Jae Kwon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.5
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    • pp.19-26
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    • 2014
  • In-situ $CaCO_3$ formation on recycled wood pulp was studied to improve optical property and filler attachment to the fiber furnish in papermaking. We tried to attach calcium oxide (CaO) to the recycled fibers, old newspaper (ONP) in this case, by using selected polymers before in-situ $CaCO_3$ formation reaction on fibers, and then, $CO_2$ was injected to the furnish until all the CaO on fiber surfaces was consumed. It was found that the attachment of newly formed $CaCO_3$ to recycled fibers became stronger by attaching CaO to the fibers before in-situ $CaCO_3$ formation reaction. It was expected that the polymers used for the attachment of calcium source to the fiber furnishes helped to keep the newly formed $CaCO_3$ strongly attached to the fiber surface as well as to retain the impurities associated with calcium source and recycled fibers, if any. In-situ $CaCO_3$ formation gave higher brightness and much less ERIC value in ONP sheet than the case when the equivalent amount of GCC was added to the furnish.

Manufacture of Specialty Paper with Hemp Bast Fiber Cultivated in Korea (Part 1) - Characteristics of Hemp-Wood Paper by Soda Pulping - (삼섬유를 이용한 특수기능지 개발 (제 1보) - 소다펄프화 삼 섬유의 수초지 특성 -)

  • Lee, Dah-Hee;Lee, Myoung-Ku
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.6
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    • pp.30-35
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    • 2013
  • To conserve wood resources for papermaking, chemical compositions of the hemp (Cannabis sativa L.) bast fiber cultivated in Korea such as holocellulose, ${\alpha}$-cellulose, lignin, alcohol-benzene extractives, hot and cold water extractives, and ash contents were investigated to manufacture the specialty packaging paper effectively. Significantly very low klason lignin content of 3.3% was accomplished by removing of the outer shell of bark. Laboratory soda pulping method which is very useful for the nonwood fiber was adapted, and it was found that there was no significant difference in both kappa number and H-factor between 25% and 30% NaOH charge. Hemp pulp cooked with the laboratory digester in 25% NaOH at $170^{\circ}C$ were mixed together with the wood pulp(NBKP:LBKP=1:1) in order to find the optimum mixture ratio which exhibited acceptable paper strength properties such as tensile index, burst index, and tear strength. When 10% of hemp soda pulps was mixed with 90% of wood pulps comprised of SwBKP and HwBKP (1:1), all physical strength increased significantly. The physical strength decreased as the amount of hemp pulp increased because the cell wall of bast fiber is very thick which causes low conformability and low fiber-fiber bonding. These results showed that paper made of hemp-wood pulp can be used for the specialty packaging paper which requires both the characteristic surface properties and the high physical strength of hemp fiber.