• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.11a
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• pp.332-334
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• 2000

The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. Supercapacitor cell of CP composite electrode with 1M LiClO$_4$/ PC bring out good capacitor performance below 4V. The radius of semicircle of CP composite cell with PAn composite electrode adding 30wt% acetylene black was absolutely small. The total resistance of supercapacitor cell mainly depended on internal resistance of the electrode. The discharge capacitance of supercapacitor cell with PAn composite electrode adding 30wt% acetylene black in 1st and 50th cycles was 27F/g and 31F/g at current density of 1mA/$\textrm{cm}^2$. Supercapacitor cell with PAn composite electrode adding 30wt% acetylene black performed a good cycliability.

• Textile Coloration and Finishing
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• v.7 no.2
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• pp.55-62
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• 1995

Plasma polymerization of Perfiuoropropene(PFP) and n-Hexane was carried out in a tubular type reactor by means of 13.56MHz radio frequency generator at the fixed RF discharge power of 25W and at the pressures of 100mTorr, 140mTorr and 200mTorr. The thin films were deposited on PAN fabrics in order to improve the dimemsional stability of woven states in hot water laundry. IR spectroscopy was used for the analysis of the structures of the thin films deposited and SEM for examination of surfaces of the fabrics. the PAN fabrics, which were coated by thin films at several experimental conditions, were immersed in boiling water for 2 hours and then the dimension stability of woven states were evaluated. In spite of very thin films, the results of surface modification were satisfactory. In general the performace of thin films by PFP was superior to that of n-Hexane.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2007.05a
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• pp.350-352
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• 2007

This paper describes the discharge and ozone generation characteristics with variation of the applied voltage, the number of ozonizer, the quantity of flowing material gas. The important conclusions are as follows. The discharge voltage and current values are proportional to the applied voltage. The ozone concentration and generation are proportional to the applied voltage and the number of ozonizer. As the maximum value of ozone concentration and generation of silent discharge type ozonizer using discharge lamp can be obtained 890[ppm] and 59.7[mg/h] respectively.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.11a
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• pp.308-311
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• 2004

In this paper, we investigated $\phi-q-n$ distribution to inquire discharge characteristic according to variation of electrode. Also, we investigated Weible distribution of discharge number using Weible analysis to search the relationship between a part discharge and shape of electrode. We increased voltage 1[kV] AC 60[Hz] of impressed voltage, data is acquired a generating discharge for 10 seconds after impressing voltage. Also, as we repeated the experiment 10 times at same condition, analyzed foible using data except for maximum and minimum. As the result, we confirmed that discharge generating and discharge quantity were significantly increased narrowing radius of electrode, also discharge frequency was close to shape of a standard distribution.

• Journal of the Korean Chemical Society
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• v.43 no.2
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• pp.199-205
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• 1999

The electrochemical properties of PAN-PVDF-PEGME blend polymer electrolyte system are investigated and the physical properties are also measured with varying the content of PEGME. This PEGME partially reduces the crystallinity of PVDF. The ionic conductivities of the polymer electrolytes are about $10^{-3}S/cm$, which may be applicable to a constituent of lithium secondary battery. From the temperature dependence of ionic conductivity, it is suggested that the ionic conductivity increases with the PEGME content due to the fomation of effective ion-conducting path. The cation transference number reaches its maximum value for the electrolytes (SPE 2) with 10 wt% PEGME and then decreases for further increase of PEGME contnet. The electrochemically stable range of SPE 1 (without PEGME) is about 4.3 V, but SPE 2-4 (PAN-PVDF-PEGME system) is about 4.6 V. When these polymer electrolyte are used as electrolyte in rechargeable battery and the cell performances are tested, the discharge capacity increses with the amount of PEGME. Therefore, PEGME increases the ionic conductivity, extends the electrochemical stable range, and finally improves the discharge capacity of cell adopting the electrolyte system.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.4
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• pp.323-327
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• 2001

The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. The radius of semicircle of CP composite cell with polyaniline(PAn) composite electrode adding 30wt% acetylene black was small. The total resistance of supercapacitor cell mainly depended on internal resistance of he electrode. The discharge capacitance of supercapacitor cell with PAn composite electrode adding 30wt% acetylene black in 1st and 50th cycles was 27F/g and 31F/g at current density of 1mA/$\textrm{cm}^2$, respectively. Supercapacitor cell with PAn composite electrode adding 30wt% acetylene black showed a good cycliability. Supercapacitor cell of CP composite electrode with 1M LiClO$_4$/PC brings out god capacitor performance below 4V.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.18 no.2
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• pp.180-185
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• 2006

This study has been conducted in order to develop a temperature-controlled round pan diffuser with variable-openings. Flow visualization was performed to investigate the airflow patterns according to gap openings. The velocity profiles were measured using an omni-directional anemometer for two cases, i.e. a horizontal and a vertical discharge conditions. Numerical simulation also confirms there is a narrow range of gap openings where a horizontal discharge shifts to a vertical discharge. The air distribution performance index increases abruptly when the air discharge shifts from vertical to horizontal direction.

• Journal of the Korean Electrochemical Society
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• v.5 no.3
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• pp.106-110
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• 2002

Gel-type polyacrylonitrile(PAN) polymer electrolytes have been prepared using ethylene carbonate(EC), propylene carbonate(PC) and dimethyl carbonate(DMC) plasticizer, $LiPF_6$ salt and $TiO_2$ ceramic filler. Electrochemical properties, such as electrochemical stability, ionic conductivity and compatibility with lithium metal and mechanical properly of polymer electrolytes were investigated. Charge/discharge performance of lithium secondary battery using these polymer electrolytes were investigated. The maximum load that the polymer electrolyte resists increased about two times as a result of adding $TiO_2$ in the polymer electrolyte containing EC and PC. Polymer electrolyte containing EC, PC and $TiO_2$ also showed ionic conductivity of $2\times10^{-3} S/cm$ at room temperature and electrochemical stability window up to 와 4.5V. Polymer electrolyte containing EC, PC, and $TiO_2$ showed the most stable interfacial resistance of $130\Omega$ during 20 days in the impedance spectra of the cells which were constructed by lithium metals as electrodes. Lithium metal secondary battery which employed $LiCoO_2$ cathode, lithium metal anode and $TiO_2$-dispersed polymer electrolyte showed $90\%$ of charge/discharge efficiency at the 1C rate of discharge.

• Carbon letters
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• v.12 no.1
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• pp.16-20
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• 2011

Commercial PAN fibers were thermally stabilized at 220 or $240^{\circ}C$ for 30 min. Those fibers were further stabilized using radio-frequency (RF) capacitive plasma discharge during 5 or 15 min. From Fourier transform infrared spectroscopy results, it was observed that an additional plasma treatment led to further stabilization of PAN fibers. After stabilization, carbonization was performed to investigate the final tensile properties of the fabricated carbon fibers (CFs). The results revealed that a combination of thermal and plasma treatment is a possible stabilization process for manufacturing CFs. Morphology of CFs was investigated using scanning electron microscopy. The morphology shows that the plasma stabilization performed by the RF large gap plasma discharge may damage the surface of the CF, so it is necessary to select a proper process condition to minimize the damage.

• Journal of Electrochemical Science and Technology
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• v.8 no.2
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• pp.107-114
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• 2017

Pseudo capacitors belong to one group of super capacitors which are consisted with non carbon based electrodes. As such, conducting polymers and metal oxide materials have been employed for pseudo capacitors. Conducting polymer based pseudo capacitors have received a great attention due to their interesting features such as flexibility, low cost and ease of synthesis. Much work has been done using liquid electrolytes for those pseudo capacitors but has undergone various drawbacks. It has now been realized the use of solid polymer electrolytes as an alternative. Among them gel polymer electrolytes (GPEs) are in a key place due to their high ambient temperature conductivities as well as suitable mechanical properties. In this study, composition of a polyacrylonitrile (PAN) based GPE was optimized and it was employed as the electrolyte in a pseudo capacitor having polypyrrole (PPy) electrodes. GPE was prepared using ethylene carbonate (EC), propylene carbonate (PC), sodium thiocyanate (NaSCN) and PAN as starting materials. The maximum room temperature conductivity of the GPE was $1.92{\times}10^{-3}Scm^{-1}$ for the composition 202.5 PAN : 500 EC : 500 PC : 35 NaSCN (by weight). Performance of the pseudo capacitor was investigated using Cyclic Voltammetry technique, Electrochemical Impedance Spectroscopy (EIS) technique and Continuous Charge Discharge (GCD) test. The single electrode specific capacity (Cs) was found out to be 174.31 F/g using Cyclic Voltammetry technique at the scan rate of 10 mV/s and within the potential window -1.2 V to 1.2 V. The same value obtained using EIS was about 84 F/g. The discharge capacity ($C_d$) was 69.8 F/g. The capacity fade over 1000 cycles was rather a low value of 4%. The results proved the suitability of the pseudo capacitor for improving the performance further.