• Title/Summary/Keyword: pH values

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Development of Low-fat Meat Processing Technology Using Interactions between Meat Proteins and Hydrocolloids- I Optimization of Interactions between Meat Proteins and Hydrocolloids by Model Study (식육단백질과 친수성 콜로이드의 상호결합 특성을 이용한 저지방 육제품 제조기술 개발 - I 모델연구를 이용한 상호반응의 최적화)

  • Chin, Koo-Bok;Chung, Bo-Kyung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.31 no.3
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    • pp.438-444
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    • 2002
  • Interactions between meat proteins and hydrocolloids in a model system may play an important role for the improvement of textural properties in low-fat sausage mixtures. The objective of this study was to determine gel properties as affected by the type and level of hydrocolloid, various pH values of meat protein-hydrocolloid mixture before cooking, and internal cooking temperatures. The desirable heat-induced gels (HIGs) were formed at least pH values above 6.0. The addition of konjac flour (KF), kappa-carrageenan (CN) and locust bean gum (LBG) to extracted salt soluble proteins (2%) improved the gel strength with increased levels (0.5∼1.5%) and HIGs containing CN had the highest (p<0.05) gel strength. The increase of cooking temperature increased gel strength, depending on pH and type of hydrocolloid. However, the minimun internal cooking temperature to make viscoelastic HIGs was 70$^{\circ}C$. These results indicated that desirable HIGs were manufactured with each hydrocolloid concentration of 1% and minimum cooking temperature of 70$^{\circ}C$ with pH values higher than 6.0.

Comparison of Pork Quality by Different Berkshire Line (버크셔 계통조성돈의 육질 특성비교)

  • Park, Beom-Young;Cho, Soo-Hyun;Kim, Jin-Hyoung;Seong, Pil-Nam;Kang, Geun-Ho;Jeong, Da-Woon;Kim, Chul-Wook;Park, Hwa-Chun;Jeong, Jong-Hyun;Choi, Jong-Soon;Kim, Dong-Hun
    • Food Science of Animal Resources
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    • v.30 no.5
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    • pp.867-871
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    • 2010
  • Objective of this study was to develop a Korean Berkshire line produced using organized management techniques. A total of 448 pigs divided into five line groups were slaughtered and analyzed for their meat quality. $pH_{45}$ values were significantly higher in lines 1~4 (pH 6.08). However, $pH_{24}$ values were lower in line 1 (pH 5.69) and line 3 (pH 5.65) (p<0.05) than in the other lines. Moisture contents were significantly higher in line 5, and the intramuscular fat contents (3.07%) were significantly higher in the other four lines. Water holding capacity (WHC) was higher for line 3 (58.36%) while Warner-Bratzler shear force (WBS) values were significantly higher for line 4 (2.84 kg/$0.5inch^2$) than in the other lines (p<0.05). For meat color properties, L values (CIE L) were 51.59 for line 5, and this value was higher than the other lines. There were no significant differences in $a^*$ values and $b^*$ values among the five lines (p>0.05). Therefore, line 5 was selected as the growth type, whereas line 4 was selected as the Korean Berkshire line that produced pork significantly higher in pH and significantly lower in meat color (lightness), drip loss, and WBS.

Transfer properties of nif-plasmid pEA 9 by pEA 9::Tn5-Mob (pEA 9::Tn5-Mob에 의한 nif-plasmid pEA 9의 transfer 성질)

  • 민병환;이호자
    • Korean Journal of Microbiology
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    • v.26 no.3
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    • pp.181-187
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    • 1988
  • Using a Tn5-Mob system, pEA9 was characterized as a self-transmissible plasmid carrying a kanamycin resistance marker. The self-transfer frequencies of pEA9 varied greatly depending on pH values. The transfer frequency was about $4\times 10^{-5}$ at pH 5, that was 10 times higher than one at pH 6.5. With a helper plasmid, transfer frequencies were increased about $10^{4}$ times than the frequencies obtained without it.

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A Kinetic Study on the Solvolysis of Benzyl Chloride under High Pressure (고압하에서 염화벤질의 가용매분해반응에 대한 속도론적 연구)

  • Kwon, Oh-Cheun;Kyong, Jin-Burm
    • Journal of the Korean Chemical Society
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    • v.31 no.3
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    • pp.207-214
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    • 1987
  • Rates of solvblysis of benzyl chloride in ethanol-water mixtures have been measured at 30 and $40^{\circ}C$ under various pressures up 1.6 kbar. The plots of 1n k as a function of pressure are fitted to a second order function in p, and values of ${\Delta}V^{\neq}$and ${\Delta}{\beta}^{\neq}$ are obtained from the results. Also the values of various pseudo thermodynamic quantities were evaluated from the rate constants. The relationships of the 1n k to $Q_w$ or 1n $C_w$ indicate that the reaction proceeds through $S_N1$ mechanism. A comparison between the present and the previous results gives that the increasing order of ${\mid}{{\Delta}V_0}^{\neq}{\mid}$ and n-values are $p-Cl>p-H>p-CH_3$ and $p-CH_3>p-H.p-Cl$, respectively. From these results, it is believed substituent such as the $p-CH_3$group favors the $S_N1(1)$ character, while the p-Cl group leads to the $S_N1(2)$ character.

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Removal of Sulfamethoxazole using Ozonation or UV Radiation; Kinetic Study and Effect of pH (오존 처리 및 UV 조사를 이용한 Sulfamethoxazole 제거; 동역학적 고찰 및 pH 영향)

  • Jung, Yeonjung;Kim, Wangi;Jang, Hayoung;Choi, Yanghwun;Oh, Byungsoo;Kang, Joonwun
    • Journal of Korean Society on Water Environment
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    • v.24 no.1
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    • pp.63-68
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    • 2008
  • This study was performed to assess the potential use of ozone or UV radiation for the treatment of water contaminated with sulfamethoxazole (SMX), which is frequently used antibiotic in human and veterinary medicines, especially focusing on the kinetic study and effect of pH. In a study using ozone alone, kinetic study was performed to determine second-order rate constant ($k_{O3,SMX}$) for the reactions of SMX with ozone, which was found to be $1.9{\times}10^6M^{-1}s^{-1}$ at pH 7. The removal efficiencies of SMX by ozone were decreased with increase of pH due to rapid decomposition of ozone under the condition of various pH (2.5, 5.3, 7, 8, 10). In a UV irradiation study at 254 nm, a kinetic model for direct photolysis of SMX was developed with determination of quantum yield ($0.08mol\;Einstein^{-1}$) and molar extinction coefficient ($15,872M^{-1}cm^{-1}$) values under the condition of quantum shielding due to the presence of reaction by-products formed during photolysis. For effect of pH on photolysis of SMX, SMX in the anionic state ($S^-$, pH > 5.6), most prevalent form at environmentally relevant pH values, degraded more slowly than in the neutral state (SH, 1.85 < pH < 5.6) by UV radiation at 254 nm.

Changes of multi-purpose solutions for soft contact lens depending on using period or keeping temperature (사용기간 및 온도에 따른 소프트콘택트렌즈 다목적용액의 변화)

  • Park, Mi-Jung;Ha, Ju-Ryung;Lee, Young-Min;Han, Hyeun-Woo;Kim, Seung-Tae
    • Journal of Korean Ophthalmic Optics Society
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    • v.9 no.2
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    • pp.381-389
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    • 2004
  • To investigate changes of multi-purpose solutions for soft contact lens(MPS) depending on using period or keeping temperature, we evaluate four brands of MPS. No significant difference was seen in protein deposit removing efficacy after samples had used for 24 weeks and kept at $4^{\circ}C$, $20^{\circ}C$ or $30^{\circ}C$. The pH values of the samples of 4 brands measured weekly over the 24 week testing period. The initial average pH value of samples were 7.0, 7.5, 7.6 or 8.2. One brand of MPS was in the range of the threshold for ocular awareness, which is outside the zone of 6.6 ~ 7.8. During the testing period, the pH value were decreased in using period-dependent manner. At the 24th week, the average pH values of samples turned to 6.6, 7.2, 7.2 or 7.7. However, the difference of keeping temperature was not associated with decreased levels of pH values. After 24 weeks, one of total 36 samples was contaminated by bacteria. Furthermore, the change of components was shown after 24 weeks in the analysis using thin layer chromatography and the analysis of UV absorption pattern. The results of our study provides that the keeping temperature of MPS is not the important factor of changes of MPS, but the using period of MPS can cause contact lens wearers discomfort.

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pH Measurement Using Isosbestic Point of Indicator (지시약의 등흡광점을 이용한 용액의 pH 측정)

  • Won-Hyung Choi;Ho-Jang Hur
    • Journal of the Korean Chemical Society
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    • v.33 no.2
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    • pp.203-207
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    • 1989
  • The methyl red stock solution was added to sample solution and the absorbance values of this solution were measured at the maximum absorption wavelengths of the acidic form, the basic form, and the isosbestic point of the indicator. From the measurements of absorbance, the pH of this solution was calculated. The range of absorbance at the isosbestic point was maintained within 0.1 ${\sim}$ 0.3. The error of pH measurement was within ${\pm}0.08$ pH unit in the pH range of sample solution of $pK_I{\pm}1$.

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Effect of pH on the Extraction Characteristics of Succinic and Formic Acids with Tri-n-octylamine Dissolved in 1-Octanol

  • Hong, Yeon-Ki;Hong, Won-Hi;Chang, Yong-Keun
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.6 no.5
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    • pp.347-351
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    • 2001
  • A study was made on the extraction equilibria of succinic and formic acids from aqueous solutions using tri-n-octylamine (TOA) in 1-octanol. It was shown that the loading values of TOA decreased with increasing pH values. The apparent equilibrium constants for each acidamine complex were determined by an equilibrium model. In the case succinic acid, the formation of a bisuccinate anion played an important role in the stoichiometry of the acid-amine complex.

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Effect of pH in Irrigation Water on the Growth, Yield, and Grain Quality of Rice (관개용수 pH가 벼 생육, 수량, 미질에 미치는 영향(I))

  • Choi, Sun-Hwa;Kim, Ho-Il;An, Yeul;Huh, Yoo-Man
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2003.10a
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    • pp.551-554
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    • 2003
  • This study was carried out to investigate the effects of the pH of irrigation water on the growth, yield, and grain quality of rice. It acquire fundamental knowledges to set up irrigation water quality standards. The pot experiment was conducted with 5 treatments using irrigation waters with various pH values(control, 4, 6, 8, 10) and replicated four times with randomized block design. The results of this study showed that the uptake of N, P, and K, Ripened grain ratio and yield of rice tended to be reduced at the irrigation water of pH 4 and pH 10. P uptake, Ripened grain ratio and yield of rice at pH 4 water were significantly lower than the control. K uptake at pH 10 water was significantly lower than the control. Plant height, SPAD value and protein content of rice were not affected by the pH of irrigation water.

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Electrochemical Oxidation of Benzidine and Hydrazobenzene

  • Won Mi-Sook;Shim Yoon-Bo;Park Su-Moon
    • Bulletin of the Korean Chemical Society
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    • v.13 no.6
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    • pp.680-683
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    • 1992
  • The electrochemistry of benzidine and hydrazobenzene was studied in water-acetonitrile mixed solutions at various pHs and the results are reported. The cyclic voltammetric peak for the oxidation of benzidine shows a pH dependency of -62 mV/pH in the pH range of 0-3.5, no pH dependency between pH values of 3.5 and about 10.5, and of about -50 mV/pH between pH=10.50 and 14.0, indicating that oxidation mechanisms differ depending on the pH of the medium. However, the CV peak for the hydrazobenzene oxidation is shown to be independent of pH of the medium, suggesting that the proton is not involved in the rate limiting step of the electrochemical oxidation of hydrazobenzene to azobenzene. Results of in situ spectroelectrochemical experiments indicate that the oxidation products obtained during the oxidation of benzidine and hydrazobenzene depend on the result of dynamic equilibria taking place at various pHs.