• 제목/요약/키워드: pH threshold

검색결과 163건 처리시간 0.025초

2단계 반응에 의한 마그네타이트 나노입자의 제조 (Preparation of Magnetite Nanoparticles by Two Step Reaction)

  • 신대규;류도형
    • 한국분말재료학회지
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    • 제15권2호
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    • pp.148-155
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    • 2008
  • Nano magnetite particles have been prepared by two step reaction consisting of urea hydrolysis and ammonia addition at certain ranges of pH. Three different concentrations of aqueous solution of ferric ($Fe^{3+}$) and ferrous ($Fe^{2+}$) chloride (0.3 M-0.6 M, and 0.9 M) were mixed with 4 M urea solution and heated to induce the urea hydrolysis. Upon reaching at a certain pre-determined pH (around 4.7), 1 M ammonia solution were poured into the heated reaction vessels. In order to understand the relationship between the concentration of the starting solution and the final size of magnetite, in-situ pH measurements and quenching experiments were simultaneous conducted. The changes in the concentration of starting solution resulted in the difference of the threshold time for pH uprise, from I hour to 3 hours, during which the akaganeite (${\beta}$-FeOOH) particles nucleated and grew. Through the quenching experiment, it was confirmed that controlling the size of ${\beta}$-FeOOH and the attaining a proper driving force for the reaction of ${\beta}$-FeOOH and $Fe^{2+}$ ion to give $Fe_3O_4$ are important process variables for the synthesis of uniform magnetite nanoparticles.

A high response to controlled ovarian stimulation induces premature luteinization with a negative impact on pregnancy outcomes in a gonadotropin-releasing hormone antagonist cycle

  • Koo, Hwa Seon;Cha, Sun Hwa;Kim, Hye Ok;Song, In Ok;Min, Eung Gi;Yang, Kwang Moon;Park, Chan Woo
    • Clinical and Experimental Reproductive Medicine
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    • 제42권4호
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    • pp.149-155
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    • 2015
  • Objective: The goal of this study was to investigate the relationship between serum progesterone (P4) levels on the day of human chorionic gonadotropin (hCG) administration and the pregnancy rate among women undergoing controlled ovarian stimulation for in vitro fertilization (IVF) or intracytoplasmic sperm injection-embryo transfer (ICSI-ET) using a flexible antagonist protocol. Methods: This prospective study included 200 IVF and ICSI-ET cycles in which a flexible antagonist protocol was used. The patients were divided into five distinct groups according to their serum P4 levels at the time of hCG administration (0.80, 0.85, 0.90, 0.95, and 1.00 ng/mL). The clinical pregnancy rate (CPR) was calculated for each P4 interval. Statistically significant differences were observed at a serum P4 level of 0.9 ng/mL. These data suggest that a serum P4 concentration of 0.9 ng/mL may represent the optimal threshold level for defining premature luteinization (PL) based on the presence of a significant negative impact on the CPR. Results: The CPR for each round of ET was significantly lower in the PL group defined using this threshold (25.8% vs. 41.8%; p=0.019), and the number of oocytes retrieved was significantly higher than in the non-PL group ($17.3{\pm}7.2$ vs. $11.0{\pm}7.2$; p=0.001). Elevated serum P4 levels on the day of hCG administration were associated with a reduced CPR, despite the retrieval of many oocytes. Conclusion: Measuring serum P4 values at the time of hCG administration is necessary in order to determine the optimal strategy for embryo transfer.

Study of the Resonance Structures of the Preionizing Spectrum of Molecular Hydrogen by Phase-Shifted Multichannel Quantum Defect Theory II

  • Lee, Chun-Woo
    • Bulletin of the Korean Chemical Society
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    • 제33권8호
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    • pp.2657-2668
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    • 2012
  • We obtain the general formulation which can handle the rotational preionization spectrum of $H_2$ in the region above its ${H_2}^+$ ionization threshold, ($^2{\sum}_g^+$, ${\nu}^+=0$, $N^+=0$) converging toward its rotationally excited (${\nu}^+=0$, $N^+=2$) limit and perturbed by the vibrationally excited levels $7p{\pi}$ ${\nu}=1$ and $5p{\pi}$ ${\nu}^=2$. The formulation is based on phase-shifted multichannel quantum-defect theory. With this formulation, resonance structures are analyzed in detail.

Glycosylsucrose의 이화학적 특성 (Physical and Chemical Properties of Glycosylsucrose)

  • 설혜미;지옥화;김미리
    • 한국식품조리과학회지
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    • 제7권4호
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    • pp.51-61
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    • 1991
  • Physical and chemical properties of glycosylsucrose were characterized as follows: 1. The moisture content of glycosylsucrose syrup (35% , w/w) was 63.6% and total sugar in solid was 35.9%. 2. Main sugar compositions of glycosylsucrose syrup were maltotetraose 54.5%, sucrose 18.0%, glycosylsucrose 15.3%, maltosylsucrose 11.3% and the content of glucose, maltose, maltotriose and fructose were very little. 3. Perceived sweetness threshold of glycosylsucrose was 0.71%, relative sweetness was 0.53, and sweetness intensity expressed as power function was S=$0.78^{\circ}$C^{1.5}$$. 4. Viscosity of glycosylsucrose was higher than that of sucrose and Japanese product at 10, 25, 35 and $65^{\circ}C$. 5. The content of water absorption of gylcosylsucrose at Aw 0.80 was 0.48 g $H_2$O/g dry weight while that of sucrose was 0.17g $H_2$O/g dryweight at Aw 0.86. 6. The stability of glycosylsucrose was decreased by acidic pH, high temperature and long heating time. 7. The glycosylsucrose showed very little browning when heated with pepton, but alkaline pH (pH8), high temperature and long heating time increased browning reaction.

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움직임 벡터의 변화량을 이용한 인터 예측 모드 결정에 관한 연구 (A Study on Inter Prediction Mode Determination using the Variance in the Motion Vectors)

  • 김준;김영섭
    • 반도체디스플레이기술학회지
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    • 제13권1호
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    • pp.109-112
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    • 2014
  • H.264/AVC is an international video coding standard that is established in cooperation with ITU-T VCEG and ISO/IEC MPEG, which shows improved code and efficiency than the previous video standards. Motion estimation using various macroblock from 44 to 1616 among the compression techniques of H.264/AVC contributes much to high compression efficiency. Generally, in the case of small motion vector or low complexity about P slice is decided $P16{\times}16$ mode encoding method. But according to circumstances, macroblock is decided $P16{\times}16$ mode despite large motion vector. If the motion vector variance is more than threshold and final select mode is $P16{\times}16$ mode, it is switched to $P8{\times}8$ mode, so this paper shows that the storage capacity is reduced. The results of experiment show that the proposed algorithm increases the compression efficiency of the H.264/AVC algorithm to 0.4%, even reducing the time and without increasing complexity.

공기희석관능법과 기기분석법에 기초한 악취감지기술의 연계성 비교: 산단지역 및 음식물 부패시료를 중심으로 (A Comparative Study of Odors between Air Dilution Sensory Test and Instrumental Detection Method Using Industrial and Food Waste Samples)

  • 박신영;김기현
    • 한국대기환경학회지
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    • 제23권4호
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    • pp.420-429
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    • 2007
  • In this study, we attempted to evaluate the relationship between air dilution sensory test and instrumental detection method for individual odorous compound. For the purpose of our comparative study, we conducted the analysis of malodor on total of 46 samples collected from both industrial and food waste sectors using the two independent approaches. The results of instrumental analyses were explained after modification to several parameters such as: the sum of odor concentration (SOC), sum of odor quotient (SOQ) and sum of odor intensity (SOI). When we compared dilution ratio values (DRV) of threshold limit (TL) with the modified instrumental data sets, pearson coefficient of SOC, SOQ, and SOI were 0.556 (p=5.83E-05), 0.911 (p=9.64E-19) and 0.847 (p=8.93E-14), respectively. The results of this study thus suggest that the DRV of TL sensitively reflects odor strength measured intuitive.

The Dependence of Mechanical Strain on a-Si:H TFTs and Metal Connection Fabricated on Flexible Substrate

  • Lee, M.H.;Ho, K.Y.;Chen, P.C.;Cheng, C.C;Yeh, Y.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.439-442
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    • 2006
  • We evaluated a-Si:H TFTs fabricated on polyimide substrate (PI) at the highest temperature of $160^{\circ}C$ with uniaxial and tensile strain to imitate flexible display. With tensile strain, the threshold voltage of a-Si:H TFTs have positive shift due to extra dangling bond formation in a-Si:H layer. However, no significant degradation of the subthreshold swing and effective mobility with tensile strain of a-Si:H TFTs indicates the similar level of band tail state. The metal wire with the width of $10\;{\mu}m$ for connection on flexible substrate can sustain with curvature radius 2.5 cm.

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사용기간 및 온도에 따른 소프트콘택트렌즈 다목적용액의 변화 (Changes of multi-purpose solutions for soft contact lens depending on using period or keeping temperature)

  • 박미정;하주령;이영민;한현우;김성태
    • 한국안광학회지
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    • 제9권2호
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    • pp.381-389
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    • 2004
  • 사용기간과 보관 온도에 따른 소프트콘택트렌즈 다목적용액의 변화를 알아보기 위해 4개 회사의 제품을 조사하였다. 실험에 사용한 다목적용액들을 각각 $4^{\circ}C$, $20^{\circ}C$$30^{\circ}C$로 보관하면서 24주간동안 단백질 제거 효능을 측정한 결과, 사용기간이나 보관용도에 따라 통계적으로 의미있는 변화가 나타나지 않았다. 다목적 용액들의 pH를 24주 동안 매주 측정한 결과, 개봉 직후 pH는 각기 7.0, 7.5, 7.6 및 8.2로 제품마다 큰 차이가 났으며 한 제품은 안자극을 유발시키지 않는 pH인 6.6~78 범위를 벗어났다. 24주간의 시험기간 동안 pH는 점점 산성화되어 24주에 이르러서는 제품들의 평균 pH는 6.6, 7.2, 7.2 및 7.7로 되어 제품에 따라서는 사용기간에 따라 역시 자극감을 느끼는 pH가 될 수 있음을 알 수 있었다. 그러나, 이러한 pH 변화는 보관온도와는 관계가 없었다. 또한 24주 동안 사용한 한 개의 다목적용액에서 세균의 오염이 관찰되었으며, 박층크로마토그라피와 UV 흡광 양상비교를 통한 성분의 변화여부 분석에서 성분의 변화가 나타남을 확인하였다. 본 연구로 다목적 용액의 변화가 보관온도와는 상관이 없었지만, 보관기간과는 큰 연관성이 있어 착용자에게 불편감을 초래할 수 있는 것으로 확인되었다.

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304 스테인레스鋼 熔接部의 응력부식구열에 관한 硏究 (A study on stress corrosion cracking of weld zone in 304-stainless steel)

  • 김경일;강인찬
    • Journal of Welding and Joining
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    • 제5권2호
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    • pp.35-43
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    • 1987
  • The effect of post weld heat treatment (P.W.H.T) on the propagation rate of stress corrosion cracking(S.C.C) and threshold stress intensity factor ($K_{IC}.c.c$) for stress corrosion cracking of 304 stainless steel has been investigated in boiling 45% $MgCl_2$ solutions with W.O.L specimens. Specimens were precracked by turning a pair of Cr-Mo steel bolts into a machined slot at the end of the specimen. The fracture surface was examined fractographically by Scanning Electron Microscope(S.E.M.)

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Electrooptic Response of Reflective Liquid Crystal Cell

  • Lee, Geon-Joon;C. H. Oh;Lee, Y. P.;T. K. Lim
    • 한국진공학회지
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    • 제12권S1호
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    • pp.33-35
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    • 2003
  • The electrooptic properties of the reflected light in a reflective mode, $45^{\circ}C$twisted nematic liquid crystal (TNLC) cell were investigated in the voltage regions near and away from the Freedericksz transition threshold. The measured reflectivity away from the threshold voltage ($V_th$) could not be described by the model which assurnes a constant tilt angle as well as a linearized distribution of twist angle across the cell, although the data are well fitted near $V_th$. We found that in the voltage region away from $V_th$, the model considering the distributions of the tilt angle and the twist angle should be applied for the calculation of the reflectivity. The director-axis distributions were obtained from the numerical integration of the Euler-Lagrange equation.