• Title/Summary/Keyword: pH threshold

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Preparation of Magnetite Nanoparticles by Two Step Reaction (2단계 반응에 의한 마그네타이트 나노입자의 제조)

  • Shin, Dae-Kyu;Riu, Doh-Hyung
    • Journal of Powder Materials
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    • v.15 no.2
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    • pp.148-155
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    • 2008
  • Nano magnetite particles have been prepared by two step reaction consisting of urea hydrolysis and ammonia addition at certain ranges of pH. Three different concentrations of aqueous solution of ferric ($Fe^{3+}$) and ferrous ($Fe^{2+}$) chloride (0.3 M-0.6 M, and 0.9 M) were mixed with 4 M urea solution and heated to induce the urea hydrolysis. Upon reaching at a certain pre-determined pH (around 4.7), 1 M ammonia solution were poured into the heated reaction vessels. In order to understand the relationship between the concentration of the starting solution and the final size of magnetite, in-situ pH measurements and quenching experiments were simultaneous conducted. The changes in the concentration of starting solution resulted in the difference of the threshold time for pH uprise, from I hour to 3 hours, during which the akaganeite (${\beta}$-FeOOH) particles nucleated and grew. Through the quenching experiment, it was confirmed that controlling the size of ${\beta}$-FeOOH and the attaining a proper driving force for the reaction of ${\beta}$-FeOOH and $Fe^{2+}$ ion to give $Fe_3O_4$ are important process variables for the synthesis of uniform magnetite nanoparticles.

A high response to controlled ovarian stimulation induces premature luteinization with a negative impact on pregnancy outcomes in a gonadotropin-releasing hormone antagonist cycle

  • Koo, Hwa Seon;Cha, Sun Hwa;Kim, Hye Ok;Song, In Ok;Min, Eung Gi;Yang, Kwang Moon;Park, Chan Woo
    • Clinical and Experimental Reproductive Medicine
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    • v.42 no.4
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    • pp.149-155
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    • 2015
  • Objective: The goal of this study was to investigate the relationship between serum progesterone (P4) levels on the day of human chorionic gonadotropin (hCG) administration and the pregnancy rate among women undergoing controlled ovarian stimulation for in vitro fertilization (IVF) or intracytoplasmic sperm injection-embryo transfer (ICSI-ET) using a flexible antagonist protocol. Methods: This prospective study included 200 IVF and ICSI-ET cycles in which a flexible antagonist protocol was used. The patients were divided into five distinct groups according to their serum P4 levels at the time of hCG administration (0.80, 0.85, 0.90, 0.95, and 1.00 ng/mL). The clinical pregnancy rate (CPR) was calculated for each P4 interval. Statistically significant differences were observed at a serum P4 level of 0.9 ng/mL. These data suggest that a serum P4 concentration of 0.9 ng/mL may represent the optimal threshold level for defining premature luteinization (PL) based on the presence of a significant negative impact on the CPR. Results: The CPR for each round of ET was significantly lower in the PL group defined using this threshold (25.8% vs. 41.8%; p=0.019), and the number of oocytes retrieved was significantly higher than in the non-PL group ($17.3{\pm}7.2$ vs. $11.0{\pm}7.2$; p=0.001). Elevated serum P4 levels on the day of hCG administration were associated with a reduced CPR, despite the retrieval of many oocytes. Conclusion: Measuring serum P4 values at the time of hCG administration is necessary in order to determine the optimal strategy for embryo transfer.

Study of the Resonance Structures of the Preionizing Spectrum of Molecular Hydrogen by Phase-Shifted Multichannel Quantum Defect Theory II

  • Lee, Chun-Woo
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2657-2668
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    • 2012
  • We obtain the general formulation which can handle the rotational preionization spectrum of $H_2$ in the region above its ${H_2}^+$ ionization threshold, ($^2{\sum}_g^+$, ${\nu}^+=0$, $N^+=0$) converging toward its rotationally excited (${\nu}^+=0$, $N^+=2$) limit and perturbed by the vibrationally excited levels $7p{\pi}$ ${\nu}=1$ and $5p{\pi}$ ${\nu}^=2$. The formulation is based on phase-shifted multichannel quantum-defect theory. With this formulation, resonance structures are analyzed in detail.

Physical and Chemical Properties of Glycosylsucrose (Glycosylsucrose의 이화학적 특성)

  • 설혜미;지옥화;김미리
    • Korean journal of food and cookery science
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    • v.7 no.4
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    • pp.51-61
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    • 1991
  • Physical and chemical properties of glycosylsucrose were characterized as follows: 1. The moisture content of glycosylsucrose syrup (35% , w/w) was 63.6% and total sugar in solid was 35.9%. 2. Main sugar compositions of glycosylsucrose syrup were maltotetraose 54.5%, sucrose 18.0%, glycosylsucrose 15.3%, maltosylsucrose 11.3% and the content of glucose, maltose, maltotriose and fructose were very little. 3. Perceived sweetness threshold of glycosylsucrose was 0.71%, relative sweetness was 0.53, and sweetness intensity expressed as power function was S=$0.78^{\circ}$C^{1.5}$$. 4. Viscosity of glycosylsucrose was higher than that of sucrose and Japanese product at 10, 25, 35 and $65^{\circ}C$. 5. The content of water absorption of gylcosylsucrose at Aw 0.80 was 0.48 g $H_2$O/g dry weight while that of sucrose was 0.17g $H_2$O/g dryweight at Aw 0.86. 6. The stability of glycosylsucrose was decreased by acidic pH, high temperature and long heating time. 7. The glycosylsucrose showed very little browning when heated with pepton, but alkaline pH (pH8), high temperature and long heating time increased browning reaction.

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A Study on Inter Prediction Mode Determination using the Variance in the Motion Vectors (움직임 벡터의 변화량을 이용한 인터 예측 모드 결정에 관한 연구)

  • Kim, June;Kim, Youngseop
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.1
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    • pp.109-112
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    • 2014
  • H.264/AVC is an international video coding standard that is established in cooperation with ITU-T VCEG and ISO/IEC MPEG, which shows improved code and efficiency than the previous video standards. Motion estimation using various macroblock from 44 to 1616 among the compression techniques of H.264/AVC contributes much to high compression efficiency. Generally, in the case of small motion vector or low complexity about P slice is decided $P16{\times}16$ mode encoding method. But according to circumstances, macroblock is decided $P16{\times}16$ mode despite large motion vector. If the motion vector variance is more than threshold and final select mode is $P16{\times}16$ mode, it is switched to $P8{\times}8$ mode, so this paper shows that the storage capacity is reduced. The results of experiment show that the proposed algorithm increases the compression efficiency of the H.264/AVC algorithm to 0.4%, even reducing the time and without increasing complexity.

A Comparative Study of Odors between Air Dilution Sensory Test and Instrumental Detection Method Using Industrial and Food Waste Samples (공기희석관능법과 기기분석법에 기초한 악취감지기술의 연계성 비교: 산단지역 및 음식물 부패시료를 중심으로)

  • Park, S.Y.;Kim, K.H.
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.4
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    • pp.420-429
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    • 2007
  • In this study, we attempted to evaluate the relationship between air dilution sensory test and instrumental detection method for individual odorous compound. For the purpose of our comparative study, we conducted the analysis of malodor on total of 46 samples collected from both industrial and food waste sectors using the two independent approaches. The results of instrumental analyses were explained after modification to several parameters such as: the sum of odor concentration (SOC), sum of odor quotient (SOQ) and sum of odor intensity (SOI). When we compared dilution ratio values (DRV) of threshold limit (TL) with the modified instrumental data sets, pearson coefficient of SOC, SOQ, and SOI were 0.556 (p=5.83E-05), 0.911 (p=9.64E-19) and 0.847 (p=8.93E-14), respectively. The results of this study thus suggest that the DRV of TL sensitively reflects odor strength measured intuitive.

The Dependence of Mechanical Strain on a-Si:H TFTs and Metal Connection Fabricated on Flexible Substrate

  • Lee, M.H.;Ho, K.Y.;Chen, P.C.;Cheng, C.C;Yeh, Y.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.439-442
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    • 2006
  • We evaluated a-Si:H TFTs fabricated on polyimide substrate (PI) at the highest temperature of $160^{\circ}C$ with uniaxial and tensile strain to imitate flexible display. With tensile strain, the threshold voltage of a-Si:H TFTs have positive shift due to extra dangling bond formation in a-Si:H layer. However, no significant degradation of the subthreshold swing and effective mobility with tensile strain of a-Si:H TFTs indicates the similar level of band tail state. The metal wire with the width of $10\;{\mu}m$ for connection on flexible substrate can sustain with curvature radius 2.5 cm.

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Changes of multi-purpose solutions for soft contact lens depending on using period or keeping temperature (사용기간 및 온도에 따른 소프트콘택트렌즈 다목적용액의 변화)

  • Park, Mi-Jung;Ha, Ju-Ryung;Lee, Young-Min;Han, Hyeun-Woo;Kim, Seung-Tae
    • Journal of Korean Ophthalmic Optics Society
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    • v.9 no.2
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    • pp.381-389
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    • 2004
  • To investigate changes of multi-purpose solutions for soft contact lens(MPS) depending on using period or keeping temperature, we evaluate four brands of MPS. No significant difference was seen in protein deposit removing efficacy after samples had used for 24 weeks and kept at $4^{\circ}C$, $20^{\circ}C$ or $30^{\circ}C$. The pH values of the samples of 4 brands measured weekly over the 24 week testing period. The initial average pH value of samples were 7.0, 7.5, 7.6 or 8.2. One brand of MPS was in the range of the threshold for ocular awareness, which is outside the zone of 6.6 ~ 7.8. During the testing period, the pH value were decreased in using period-dependent manner. At the 24th week, the average pH values of samples turned to 6.6, 7.2, 7.2 or 7.7. However, the difference of keeping temperature was not associated with decreased levels of pH values. After 24 weeks, one of total 36 samples was contaminated by bacteria. Furthermore, the change of components was shown after 24 weeks in the analysis using thin layer chromatography and the analysis of UV absorption pattern. The results of our study provides that the keeping temperature of MPS is not the important factor of changes of MPS, but the using period of MPS can cause contact lens wearers discomfort.

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A study on stress corrosion cracking of weld zone in 304-stainless steel (304 스테인레스鋼 熔接部의 응력부식구열에 관한 硏究)

  • 김경일;강인찬
    • Journal of Welding and Joining
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    • v.5 no.2
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    • pp.35-43
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    • 1987
  • The effect of post weld heat treatment (P.W.H.T) on the propagation rate of stress corrosion cracking(S.C.C) and threshold stress intensity factor ($K_{IC}.c.c$) for stress corrosion cracking of 304 stainless steel has been investigated in boiling 45% $MgCl_2$ solutions with W.O.L specimens. Specimens were precracked by turning a pair of Cr-Mo steel bolts into a machined slot at the end of the specimen. The fracture surface was examined fractographically by Scanning Electron Microscope(S.E.M.)

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Electrooptic Response of Reflective Liquid Crystal Cell

  • Lee, Geon-Joon;C. H. Oh;Lee, Y. P.;T. K. Lim
    • Journal of the Korean Vacuum Society
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    • v.12 no.S1
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    • pp.33-35
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    • 2003
  • The electrooptic properties of the reflected light in a reflective mode, $45^{\circ}C$twisted nematic liquid crystal (TNLC) cell were investigated in the voltage regions near and away from the Freedericksz transition threshold. The measured reflectivity away from the threshold voltage ($V_th$) could not be described by the model which assurnes a constant tilt angle as well as a linearized distribution of twist angle across the cell, although the data are well fitted near $V_th$. We found that in the voltage region away from $V_th$, the model considering the distributions of the tilt angle and the twist angle should be applied for the calculation of the reflectivity. The director-axis distributions were obtained from the numerical integration of the Euler-Lagrange equation.