• Title/Summary/Keyword: pH ranges

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Solubility, Emulsion Capacity, and Emulsion Stability of Protein Recovered from Red Crab Processing Water (홍게 가공회수 단백질의 용해도, 유화력 및 안정성)

  • Kim, Yong-Jin;Sin, Tae-Seon;O, Hun-Il
    • The Korean Journal of Food And Nutrition
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    • v.9 no.3
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    • pp.319-324
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    • 1996
  • The functional properties of protein recovered from red crab (Chitinonecetes opiiie) processing in water (RCP) were examined and compared with those of soybean protein isolate at pH 2~10 in water and NaCl solu5ion. The solubilities of RCP and SPI were miniumu at pH 4, the isoelectric point and increased significantly at lower or higher than pH 4. Solubilities in NaCl solution for both proteins decreased with incr NaCl concentration increase at all pH ranges. Emulsion capacity for both proteins was also minimum at pH 4 and increased as protein concentration increased from 2 to 6%. Emulsion capacity of RCP was higher than these of SPI at pH 6∼10 and all protein concentrations. Emulsion stability showed a similar trend to that of emulsion capacity. RCP had higher oft absorption capacity and lower water absorption capacity than SPI.

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Self-assembled Micelle-based Fluorescence Sensor for Extremely Acidic pH Range (강산성 용액의 pH를 측정할 수 있는 미셀기반의 형광센서 개발)

  • Lee, Jeongmoo;Lee, Seoung Ho
    • Journal of Environmental Science International
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    • v.29 no.8
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    • pp.801-808
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    • 2020
  • In this study, an effective fluorescence pH sensor based on conjugated polyelectrolyte micelles (CPMs) was devised for detecting extremely acidic conditions. An amphiphilic coumarin derivative (CC12-N), a building block, was prepared, into which an ionizable amino group, aryl amine, was incorporated as a potential hydrophilic moiety. This monomer displays self-assembled micelle formation in extremely acidic pH ranges, giving a hydrophobic π-extended conjugated system at the inner part and hydrophilic functionality at the periphery, resulting in efficient fluorescence intensity enhancement. This new micelle-based fluorescence provides an efficient sensing platform for detecting very low pH values in the presence of competing substances.

Effect of Salts and Temperature upon the Rate and Extent of Aggregation of Casein during Acidification of Milk (산에 의한 우유단백질의 응고속도에 염과 온도가 미치는 영향)

  • Kim, Byung-Yong;Kim, Myung-Hwan;Kinsella, John E.
    • Korean Journal of Food Science and Technology
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    • v.24 no.1
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    • pp.42-48
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    • 1992
  • The rate and extent of coagulation of milk using fast acidification with 0.1 N HCl were monitored by changes in viscosity and turbidity at various temperatures and pH. Also the gelation rate of milk using slow acidification with D-glucono-${\delta}$-lactone was measured in a small strain rheological scanner. Coagulation of milk casein occurred in a specific pH range and was accompanied by an abrupt increase in viscosity at pH 5.0. Acid coagulation rate was enhanced by increasing temperature from $20^{\circ}C{\sim}50^{\circ}C$, and the maximum rate was shown around pH 5.0. The addition of salt ($CaCl_{2}$) reduced the maximum coagulation rate at all temperature ranges and shifted the pH ranges for maximum coagulation rate and the onset pH of coagulation. The onset of gelation and the rate of network formation during slow acidification were facilitated by Cl ion, but suppressed by SCN-ion, as indicated by the rate of rigidity development. The susceptibility to syneresis was greater in the gel made at lower temperature and around pH 4.6, while preheated milk at $90^{\circ}C$ for 5 min prior to acidification showed the same syneresis profile at all heating temperatures ($60{\sim}90^{\circ}C$).

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Effects of pH Change by CO2 Induction and Salinity on the Hatching Rate of Artemia franciscana

  • Salma, Umme;Uddowla, Md. Hasan;Lee, Gi-Hun;Yeo, Young-Min;Kim, Hyun-Woo
    • Fisheries and Aquatic Sciences
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    • v.15 no.2
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    • pp.177-181
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    • 2012
  • To understand the effects of lower pH levels due to elevated $CO_2$ and salinity, we designed and constructed a pH-control system that included automatic $CO_2$ infusion and measured the hatching rate of a crustacean model species, Artemia franciscana. The pH-control system was cost-effective and capable of performing animal tests in which pH fluctuated around $8.0{\pm}0.1$, with the temperature around $27{\pm}0.5^{\circ}C$. Hatching rate was observed under four different pH levels (7.0, 7.3, 7.6, and untreated control) combined with three salinity ranges (15, 25, and 35 ppt). The results demonstrated that lower pH levels led to decreased hatching rates regardless of salinity, and the minimum hatching rate was detected at pH 7.0 compared to the control (pH $8.0{\pm}0.1$), supporting the idea that OA has adverse effects on hatching rates and increases the risk of juveniles being introduced in the ecosystem. In contrast, salinity changes exhibited no synergistic effects with pH and had independent effects.

A study on the synthesis of amorphous aluminium phosphate powders by hydrothermal precipitation method (수열침전법에 의한 비정질 인산알루미늄 분말의 합성에 관한 연구)

  • 김판채;최종건;황완인;이충효
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.5
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    • pp.185-189
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    • 2001
  • Amorphous aluminium phosphate powders were synthesized as a single phase by neutralization reaction of a stoichiometric mixture of $Al_2(SO_4)_3$ and $H_3PO_4$ using the NaOH or KOH solution and subsequently by the hydrothermal precipitation method. The synthesis conditions were as follows : starting materials; $Al_2(SO_4)_3$ and $H_3PO_4$,pH ranges of neutralization reaction; between 5.6 and 6.0, temperature ranges of hydrothermal reaction; between 170 and $180^{\circ}C$,time ranges of hydrothermal reaction; between 4 and 5hs. Under such synthesis conditions, the products are obtained as amorphous aluminium phosphate powders of 0.1~0.3$\mu\textrm{m}$ in size and are Eitted to USP (United Standard Pharmacopoeia) test.

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Development of a New Synthetic Medium Composition for the Submerged Culture of Phellinus linteus (Phellinus linteus의 액체배양을 위한 새로운 합성배지의 개발)

    • KSBB Journal
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    • v.14 no.2
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    • pp.167-173
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    • 1999
  • A new synthetic medium was developed for the submerged mycelial cultures of Phellinus linteus. The medium for maximum mycelial growth of Phellinus linteus (3 days incubation, 28$^{\circ}C$, pH 5) consisted of (per 1 L): glucose, 90 g peptone, 10 g soluble starch, 10 g yeast extract, 3 g KH2PO4, 1 g MgSO4.7H2O, 1 g and CaCl2, 0.1 g. The concentrations of glucose, peptone, yeast extract, KH2PO4, MgSO4.7H2O, and CaCl2 were examined in the ranges of 10~90 g/L, 0~10 g/L, 0~15 g/L, 0~2 g/L, 0~1 g/L, and 0~0.5 g/L, respectively. The dry weight of mycelium in 3 days increased to 16.79 mg/mL using the new synthetic medium. The optimum temperature for mycelial growth of Phellinus linteus was 28$^{\circ}C$. The concentrations of KH2OP4, CaCl2, and yeast extract, which gave the maximum mycelial growth of Phellinus linteus, existed in the concentration ranges examined in this study. But, in the cases of other compositions (MgSO4.7H2O, peptone, and glucose), the mycelial growth of Phellinus linteus increased with the concentration in the ranges.

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Rheological Properties of Biopolymer Produced by Bacillus coagulans CE-74 (Bacillus coagulans CE-74가 생산하는 Biopolymer의 물성)

  • Lee, Seon-Ho;Son, Gyu-Mok;Choi, Cheong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.2
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    • pp.198-203
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    • 2000
  • A highly viscous biopolymer from Bacillus coagulans CE-74 was purified and its rheological properties were studied The rheological properties of biopolymers produced by Bacillus coagulans CE-74 were studied at the temperature ranges with 20~8$0^{\circ}C$, at the concentration of 0.5~4.0%, at the pH ranges from 3 to 1 and at the shear rate fo 7.34~73.38 sec-1. The apparent viscosity of biopolymer was decreased with increasing shear rate, and thereby biopolymer showed pseudoplastic characteristics. Biopolymer solution showed a characteristic of non-Newtonian fluid properties. At the concentration of 1%, the consistency index and the flow behavior index were shown at 2.64 poise. sec11 and 0.8571, respectively. All dispersions were pseudoplastic fluids described accurately by Herschel-Bulkley model. The change of the biopolymer viscosity on pH showed the highest value at the pH 7.0 and it showed lower at acidic conditon that at alkaline condition comparatively.

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Fabrication of Disposable pH Sensor with Micro-volume Type (Micro-volume형 일회용 pH 센서 제작)

  • Jung, Ho;Kim, Heung-Rak;Kim, Young-Duk;Jung, Woo-Chul;Kim, Dong-Su;Nam, Hyo-Duk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.950-952
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    • 2003
  • This paper have been studied fabrication and characteristics of disposable pH sensor using MEMS technology. The sensor has two open-well structure, the container for the internal electrolyte and electrode were formed by anisotropically etching a silicon substrate. unlike currently used KCI saturated solution, the structure was introduced hydrogel which take an advantage of miniaturization, bulk product, a low price. PU and CA/TP used to measurement ion detection, one is reference membrane and the other is pH. fabricated sensor is encapsulated entirely with epoxy, finally sensor was estimated various ion sorts and pH ranges.

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Mechanism of the Hydrolysis of 2-Phenyl-4H,5H,6H-3-methyl-3-thiazinium Perchlorate Derivatives

  • 김태린;이소영;변상용;김주창;한만소
    • Bulletin of the Korean Chemical Society
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    • v.20 no.10
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    • pp.1213-1217
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    • 1999
  • Hydrolysis reactions of 2-phenyl-4H,5H,6H-3-methyl-3-thiazinium perchlorate (PTP) and its derivatives at various pH have been investigated kinetically. The hydrolysis is quantitative, producing N-3-mercaptopropyl-N-methylbenzamide as the only product in the all pH ranges. The observed rate of hydrolysis of PTP was always of the first-order. For hydrolysis from PTP, Hammett ρvalues were 0.53, 0.84 and 1.13 for pH 5.0, 8.0, and 10.0, respectively. Bronsted βvalue was 0.53 for general base catalysis. This reaction is catalyzed by general w acetate concentration. However, as the amount of base becomes larger, the rate of hydrolysis reaction approaches the limiting values. The plot of log k vs. pH shows that the rate constants (kt) are two different regions in the profile; one part is directly proportional to hydroxide ion concentration and the other is not. On the bases of these result, the plausible hydrolysis mechanism and a reaction equation were proposed: Below pH 4.5, the hydrolysis was initiated by the addition of water to α-carbon. Above pH 9.0, the hydrolysis was proceeded by the addition of hydroxide ion to α-carbon. However, in the range of pH 4.5-8.0, these two reactions occured competitively.

Effect of pH, nutrient and light on the early stage of Microcystis bloom (pH, 영양염류 농도 및 빛이 Microcystis bloom의 초기단계에 미치는 영향)

  • Ha, Kyong;Jang, Min-Ho;Jeong, Kwang-Seuk;Park, Jae-Rim;Joo, Gea-Jae
    • Journal of Environmental Science International
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    • v.11 no.7
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    • pp.705-711
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    • 2002
  • In order to determine the factors causing Microcystis spp. bloom in the lower Nakdong River (Mulgum), we prepared wide ranges of pH, nutrient(N, P) concentration and the light through an enclosure experiment far 10days (pH gradient. 6.5, 7.5, 8.5, 9.5; gradient of N, P: ${\frac{1}{2}}DW+{\frac{1}{2}}River$ Water (RW), RW only; four different levels of nutrient addition/day; light: 100, 85, 60, 30, 15% of full sun light). From three days, the difference of Microcystis density in each enclosures was observed. The high density of Microcystis was maintained in the treatments over pH 9.5 and 85% of full sun light. However, in all nutrient treatments, relatively lower cell density than that of pH and light treatments was observed. These results suggested that pH and light input may play more important roles than nutrients in the early development of Microcystis bloom in the eutrophic lower Nakdong River.