• Title/Summary/Keyword: pH neutralization process

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EA-Based Tuning of the PID Controller for a CSTR (CSTR용 PID 제어기의 EA 기반 동조)

  • Jin, Gang-Gyoo
    • Journal of the Korean Institute of Intelligent Systems
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    • v.24 no.3
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    • pp.330-336
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    • 2014
  • Many industrial processes such as continuous stirred tank reactors(CSTRs), desalination plant, distillation columns, pH neutralization processes and so on exhibit highly nonlinear characteristic and time-varying behavior during operation. The control of such processes has been challenging to control engineers. Hence, a variety of forms of PID controllers and their tuning rules for industrial processes have been developed to guarantee the best performance. In this paper, a scheme that designs the practical PID controller with an anti-windup strategy incorporating with an evolutionary algorithm(EA) is presented for the concentration control of a nonisothermal CSTR. EA is used to tune the parameters of the overall PID control process with anti-windup by minimizing the integral of absolute error(IAE). Simulation works for reference tracking and disturbance rejecting performances and robustness to parameter changes show the feasibility of using the proposed method.

Recovery of Potassium and Flux Component in the Production Process of K2Ti6O13 Whisker (K2Ti6O13 whisker의 제조 공정에서 Potassium 및 Flux 성분의 회수)

  • Lee, Chul-Tae;Lee, Jin-Sik;Oh, Chi-Hoon;Kim, Young-Myoung
    • Applied Chemistry for Engineering
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    • v.7 no.6
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    • pp.1174-1180
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    • 1996
  • Potassium hexatitanate whisker was effectively prepared with calcination and flux method by using industrial $TiO_2$, $K_2CO_3$ and $K_2MoO_4$ as the starting materials. When it was synthesized by the calcination method, the filtrate after boiling water treatment was required a neutralization, as the pH of filtrate was higher than 9. Because K component was very small, recovery of K component was not economically suitable. In case of flux method, flux was recovered 96.1% of Mo component and 91.8% of K component at $K_2MoO_4$, for 10th treatment in boiling water of 100ml to 10g.

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Self-Organizing Polynomial Neural Networks Based on Genetically Optimized Multi-Layer Perceptron Architecture

  • Park, Ho-Sung;Park, Byoung-Jun;Kim, Hyun-Ki;Oh, Sung-Kwun
    • International Journal of Control, Automation, and Systems
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    • v.2 no.4
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    • pp.423-434
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    • 2004
  • In this paper, we introduce a new topology of Self-Organizing Polynomial Neural Networks (SOPNN) based on genetically optimized Multi-Layer Perceptron (MLP) and discuss its comprehensive design methodology involving mechanisms of genetic optimization. Let us recall that the design of the 'conventional' SOPNN uses the extended Group Method of Data Handling (GMDH) technique to exploit polynomials as well as to consider a fixed number of input nodes at polynomial neurons (or nodes) located in each layer. However, this design process does not guarantee that the conventional SOPNN generated through learning results in optimal network architecture. The design procedure applied in the construction of each layer of the SOPNN deals with its structural optimization involving the selection of preferred nodes (or PNs) with specific local characteristics (such as the number of input variables, the order of the polynomials, and input variables) and addresses specific aspects of parametric optimization. An aggregate performance index with a weighting factor is proposed in order to achieve a sound balance between the approximation and generalization (predictive) abilities of the model. To evaluate the performance of the GA-based SOPNN, the model is experimented using pH neutralization process data as well as sewage treatment process data. A comparative analysis indicates that the proposed SOPNN is the model having higher accuracy as well as more superb predictive capability than other intelligent models presented previously.reviously.

Design of Particle Swarm Optimization-based Polynomial Neural Networks (입자 군집 최적화 알고리즘 기반 다항식 신경회로망의 설계)

  • Park, Ho-Sung;Kim, Ki-Sang;Oh, Sung-Kwun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.2
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    • pp.398-406
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    • 2011
  • In this paper, we introduce a new architecture of PSO-based Polynomial Neural Networks (PNN) and discuss its comprehensive design methodology. The conventional PNN is based on a extended Group Method of Data Handling (GMDH) method, and utilized the polynomial order (viz. linear, quadratic, and modified quadratic) as well as the number of node inputs fixed (selected in advance by designer) at Polynomial Neurons located in each layer through a growth process of the network. Moreover it does not guarantee that the conventional PNN generated through learning results in the optimal network architecture. The PSO-based PNN results in a structurally optimized structure and comes with a higher level of flexibility that the one encountered in the conventional PNN. The PSO-based design procedure being applied at each layer of PNN leads to the selection of preferred PNs with specific local characteristics (such as the number of input variables, input variables, and the order of the polynomial) available within the PNN. In the sequel, two general optimization mechanisms of the PSO-based PNN are explored: the structural optimization is realized via PSO whereas in case of the parametric optimization we proceed with a standard least square method-based learning. To evaluate the performance of the PSO-based PNN, the model is experimented with using Gas furnace process data, and pH neutralization process data. For the characteristic analysis of the given entire data with non-linearity and the construction of efficient model, the given entire system data is partitioned into two type such as Division I(Training dataset and Testing dataset) and Division II(Training dataset, Validation dataset, and Testing dataset). A comparative analysis shows that the proposed PSO-based PNN is model with higher accuracy as well as more superb predictive capability than other intelligent models presented previously.

A Study on the Optimal Design of Polynomial Neural Networks Structure (다항식 뉴럴네트워크 구조의 최적 설계에 관한 연구)

  • O, Seong-Gwon;Kim, Dong-Won;Park, Byeong-Jun
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.49 no.3
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    • pp.145-156
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    • 2000
  • In this paper, we propose a new methodology which includes the optimal design procedure of Polynomial Neural Networks(PNN) structure for model identification of complex and nonlinear system. The proposed PNN algorithm is based on GMDA(Group Method of Data handling) method and its structure is similar to Neural Networks. But the structure of PNN is not fixed like in conventional Neural Networks and can be generated. The each node of PNN structure uses several types of high-order polynomial such as linear, quadratic and cubic, and is connected as various kinds of multi-variable inputs. In other words, the PNN uses high-order polynomial as extended type besides quadratic polynomial used in GMDH, and the number of input of its node in each layer depends on that of variables used in the polynomial. The design procedure to obtain an optimal model structure utilizing PNN algorithm is shown in each stage. The study is illustrated with the aid of pH neutralization process data besides representative time series data for gas furnace process used widely for performance comparison, and shows that the proposed PNN algorithm can produce the model with higher accuracy than previous other works. And performance index related to approximation and prediction capabilities of model is evaluated and also discussed.

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The Soil and Water Pollution caused by the Weathering of Pyrophyllite Deposits: Upstream Part of Hoidong Water Reservoir in Pusan (납석광산에서 발생하는 토양 및 수질오염 실태 : 부산광역시 회동수원지 상류 지역)

  • 박맹언;김근수
    • Journal of Environmental Science International
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    • v.7 no.2
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    • pp.149-156
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    • 1998
  • Enoronmental problems caused by certain geologic conditions Include pollution of soil by heavy metal, acidization of souls , acid mine drainage, Pound-water pollution, and natural radioactivity, as well as zoo-logical hazards such as landslide and subsidence. The acrid mine drainage contains large amount of heavy metals nO, therefore. cause serious pollution onto the nearby drainage systems and soils. In spite of this prospective environmental danger, few studies have been done on the acid mine drainage derived from non-metallic ore deposits such as pyrophyllitefNapseok) deposits. The sudo-bearing pyrophyllite ores, alteration zones, and mine talllngs of pyrophylllte deposits produce acrid mine drainage by the okidation of weathering. Compared to the fresh host rocks, the ores and altered rocks of pyrophyllite deposits produce acidic solution which contain higher amount of heavy metals because of OeP lower buffering capacity to acrid solution. The pus of urine water and nearby stream water of pyrophyllite deposits are 2.1~3.7, which are strong- ly acidic and much lower than that (6.2~7.2) of upstream water and than that (6.8~7.6) of the stream water derived from the non-mineralized area. This study reveals that this acrid mine drainage can affect the downstream area which is 8km far from the pyrophyllite deposits, even though the drain Is diluted with abundant non-contaminated river water This suggmists that not only acid mine drainage but also the sulfide-bearing sediments originated from the pyrophyllite deposits move downstream and form acidic water through continuous oxidation reaction. The heavy metals such as Pb, Zn, Cu, Cd, Nl, Mn and Fe are enriched In the mine water of low pH, and their contents decrease as the pH of mine water Increases because of the Influx of fresh stream wainer. SoUs of the Pyrophyulte deposits are characterized by high contents of heavy metals. The stream sediments containing the yellowish brown precipitates formed by neutralization of acid mine drainage occur in all parts of the stream derived from the pyrophyllite deposits, and the sediments also contain high amounts of heavy metals. In summary, the acid mine drainage of the pyrophyllite deposits is located in the upstream part of Hoidong water reservoir in Pusan contains large amounts of heavy metals and flows into the Holdong water reservoir without any purification process. To protect the water of Holdong reservoir, the acid mine drainage should be treated with a proper purification process.

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Removal Efficiency of Ammonia and Toluene using Mobile Scrubber (이동형 스크러버를 이용한 암모니아 및 톨루엔의 제거 효율)

  • Kim, Jae-Young;Kim, Jang-Yoon;Lee, Yeon Hee;Kim, Min Sun;Kim, Min-Su;Kim, Hyun Ji;Ryu, Tae In;Jeong, Jae Hyeong;Hwang, Seung-Ryul;Kim, Kyun;Lee, Jin Hwan
    • Korean Journal of Environmental Agriculture
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    • v.37 no.1
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    • pp.49-56
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    • 2018
  • BACKGROUND: The mobile vortex wet scrubber was developed to remove the harmful chemicals from accidental releases. However, there was a disadvantage that it was limitedly used for volatile organic compounds (VOCs) such as toluene according to the physicochemical properties. This study compared the removal efficiencies of an improved mobile scrubber on toluene and ammonia by applying diverse adsorption and absorption methods. METHODS AND RESULTS: The removal efficiencies on harmful chemicals were examined using various adsorption and absorption methods of water vortex process (C), phosphoric acid-impregnated activated carbon adsorption (PCA), pH-controlled water (pH 2.5) vortex process absorption with sulfuric acid (SWA) after ammonia exposure, granular activated carbon adsorption (GCA), and activated carbon mat adsorption (CMA) after toluene exposure. As a result, the best removal efficiency was shown in the SWA for ammonia and GCA for toluene. Also, the SWA and GCA methods were compared with different concentration levels. In the case of ammonia exposure (5, 10 and 25%), there was no difference by concentration levels, and the concentration in the outlet gradually increased, with pH change from acid to base. In the case of toluene exposure (50, 75 and 100%), the outlet concentration was higher relative to the exposure concentration in the initial 10 min, but the outlet concentration was remained steady after 10 min. CONCLUSION: The newly improved mobile scrubber was also effective in removing VOCs through adsorption techniques (activated carbon, activated carbon fiber, carbon mat filter etc.), as well as removing acid-base harmful chemicals by neutralization reaction.

Nitrate Removal and Recycling Technique (질산 제거 및 재이용 기술)

  • Lee, Kyoung Hee;Sim, Sang Jun;Choi, Guang Jin;Kim, Young Dae;Woo, Kyoung ja;Cho, Young Sang;Choi, Eui-So
    • Clean Technology
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    • v.3 no.2
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    • pp.87-93
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    • 1997
  • A new process has been developed for nitrate and other salts removals from polluted waters. Alumina cement and calcium oxide served as precipitating agents to remove nitrate with stirring at basic pH. Low content of alumina in the commercialized alumina cements resulted in a increasing in nitrate removal yield. It is found that the compositions of aluminium and calcium are the most important factors in successful nitrate insolubilization. In order to remove high concentration of nitrate in polluted water, multi-stage precipitation was found to be very effective. Sulfate, chloride, and phosphate ions as well as nitrate were also removed by the precipitated reaction. After precipitation, post-treatments including Na2CO3 addition and neutralization with acid alleviated the level of aluminium and calcium in the treated water.

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Thromboelastographic Analysis of the Coagulation System During Cardiopulmonary Bypass -Analysis of the Effect of Low-Dose Aprotinin (심폐바이패스시 혈액응고체계 변화의 혈전탄성검사 분석 - 단일 저용량 아프로티닌 투여 효과 분석 -)

  • 김관민;박계현
    • Journal of Chest Surgery
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    • v.30 no.7
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    • pp.677-685
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    • 1997
  • Thromboelastography(TEG) is the unique measure that gives rapid information about the whole clotting process. Simplifying the diagnosis of coagulopathy during operations, TEG can provide an adequate therapy for postoperative bleeding. Remarkable improvement in hemostasis after cardiopulmonary bypass(CPB) has been achieved by the treatment with proteinase inhibitor aprotinin, but the hemostatic mechanism of aprotinin during CPB is still unclear. This study was designed to evaluate the effects of aprotinin on coagulation system during CPB by using TEG. Forty patients who underwent CPB were divided into two groups: aprotinin(2u 106 kallikrein inhibition units, as a single dose into the cardiopulmonary bypass priming solution) treatment group(male 14, female 8, mean age=50.Byears) and no aprotinin treatment(control) group(male 10, female 8, mean age=53.4 years). TEG, activated clotting time, prothrombin time, activated partial thromboplastin time, platelet counts, fibrinogen an (ibrinogen degradation product(FDP) concentrations were checked before and after CPB(30 minutes after neutralization of heparin effect by protamine sulfate). There was no significant difference in other conventional coagulation tests of two groups except postcardiopulmonary bypass FDP concentration in control group, which was significantly increased compared to that in aprotinin group(p<0.05). In TEG variables of both groups, clot formation time(K) and alpha $angle(\alpha^{\circ})$ were significantly increased and decreased, respectively, after CPB(p<0.05), but fibrinolytic index(LYS60) was not changed during CPB. In aprotinin group, reaction time(R) was decreased significantly after CPB(p<0.05) but maximum amplitude(MA) was not changed(p>0.05). On the contrary, R was not changed markedly but MA was decreased significantly in control group after CPB(p<0.05). This result shows that main change in coagulation system during CPB is not hyperfibrinolysis but cecrease in clot strength by platelet dys unction, and the main effect of aprotinin during cardiopulmonary bypass is the maintenance of clot strength to the pre-CPB level by the preservation of platelet function.

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Toxin Produced by Pathogenic Vibrios Isolated from Sea Food (수산물에서 분리된 병원성 비브리오균의 용혈성독소)

  • CHANG Dong-Suck;SHINODA Sumio
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.27 no.2
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    • pp.107-113
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    • 1994
  • Among the currently recognized pathogenic vibrios, V. vulnificus and V. cholerae non O1 are the most serious bacteria from the point of view of sea food hygiene in Korea. In this paper, the authors compared the hemolytic activities of the crude hemolysin produced by V. vulnificus and V. cholerae non O1 isolated from shellfish collected in Chungmoo, Korea. The authors also attempted to improve the purification method of V. vulnificus hemolysin(VVH) and tried to make antiserum with the purified hemolysin. VVH was produced in abundance in heart infusion broth containing $2\%$ NaCl in a shaking cultivation process(140rpm) at $37^{\circ}C$ for 15 hours. While hemolysin production patterns of V. cholerae non O1 were quite different by the strain during the culture times compared with the V. vulnificus. Hemolytic activity of the VVH on sheep erythrocytes was stronger than those of rabbit, but hemolytic activities of the hemolysin produced by V. cholerae non O1 on rabbit erythrocytes were as much as twice as strong as on those of sheep and horse. VVH was purified by two steps of hydrophobic column chromatography on Phenyl-Sepharose HP with Fast Protein Liquid Chromatography(FPLC). Purification fold and yield of VVH was much improved by changing the elution buffer's pH from 6.0 to 9.8 and adding $1\%$ CHAPS(a zwitter ionic detergent) and $50\%$ ethylene glycol to the 10mM glycine buffer during the repeated hydrophobic column chromatography. Homogeneity of the purified hemolysin was shown by polyacrylamide gel electrophoresis. According to the five times repeated purification results, the specific activity was increased 27500 times and the yield was improved by $23.4\%$ on average. About $250{\mu}g$ of purified hemolysin was harvested from the 2400ml of culture supernatant of V. vulnificus. Molecular weight of VVH was estimated to be 50KDa by the SDS-PAGE and the neutralization scores of the obtained antiserum acting against VVH were $2000{\sim}8500$.

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