• Title/Summary/Keyword: pH effect

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Effect of pH Level on the Characteristics of a Landfill Clay Liner Material (pH에 따른 점토차수재의 특성)

  • Jung, Soo-Jung;Lee, Yong-Su;Kim, Tae-Hyung
    • Journal of the Korean Geotechnical Society
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    • v.23 no.8
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    • pp.97-106
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    • 2007
  • In this study, experiments are conducted to find out the effect of waste leachate on landfill clay liner system. Tensile test, hydrometer analysis and crack pattern test were conducted on sand-bentonite mixtures with different pH values of water. The tensile strength of specimen compacted with pH 9 of water is smaller than that of specimen compacted with for pH 3 and 6 of water. That is, the higher the pH value, the smaller the tensile strength, because a higher pH solution decreases flocculation phenomenon. The percent finer also increased with high pH value in particle size distribution of fine grained soil (<0.075 mm), because the velocity of particles settling decreases. This trend becomes the clearer as the content of bentonite, becomes the larger, because the higher pH value decreases flocculation structure of fine soils. The results of the crack pattern tests also showed the effect of pH values of water.

The Structural Effects of Acidic Comonomers in pH/Thermal Sensitive Copolymer Based on N-Isopropylacrylamide on Their LCST Behavior (pH/온도 민감성 N-Isopropylacrylamide계 공중합체의 LCST거동에 대한 산성 공단량체의 구조적 영향)

  • 조항규;김병수;노시태
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.186-198
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    • 2001
  • pH/Thermal sensitive copolymers with the various acidic comonomer compositions composed of N-isopropylacrylamide (NIPAAm) with acrylic acid (AAc), 2-acrylamido glycolic acid (AAmGAc), and 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) were synthesized by free radial polymerization. In this study, to characterize the effect of different acidic comonomer composition and pH on the lower critical solution temperature (LCST) behaviors of their copolymers. phase transition experiments were performed with a thermo-optical analyzer (TOA). The phase transition temperature (T$^{p}$ ) of aqueous poly(NIPAAm-co-AAc) solution was lowered with increasing the ionization of the acid group in AAc, that is, the ionized state induced the electrostatic repulsion of ionized groups. In contrast, when AAmGAc was introduced into PNIPAAm, T$^{p}$ was little changed at pH 1-3, whereas climbed up significantly from pH 1 to pH 3. In the range of pH 6-10, Tp was lower than that of pH 3-5. This result was considered to be \"Ionic Screen Effect\" and this effect had been also observed in the case of poly(NIPAAm-co-AMPS).-co-AMPS).

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Antifungal Effect of Chitosan against Malassezia pachydermatis Isolated from the Dog with Otitis Externa (개 외이도에서 분리된 Malassezia pachydermatis에 대한 키토산의 항진균 효과)

  • Oh, Hyun-Ho;Kim, Young-In;Seo, Jeong-A;Choe, Seong-Won;Bae, Seul-Gi;Oh, Tae-Ho
    • Journal of Veterinary Clinics
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    • v.29 no.4
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    • pp.323-327
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    • 2012
  • The effect of pH of chitosan solution (w/v) on antifungal activity against Malassezia pachydermatis isolated from a dog with otitis externa was evaluated. This study was investigated to find out the optimal pH of chitosan solution that could be able to eliminate yeast cells. For comparison of antifungal activity of chitosan solution 2% chlorhexidine that have been already proved the antifungal effect against M. pachydermatis was used as positive control. The chitosan solution at different pH (2.5, 3.0, 3.5, 4.0, 4.5, 5.0) were involved this experiment. The chitosan solutions at each pH could eliminate a number of yeast cells when they were compared to other antifungal agents. In chitosan solution's antifungal effect of varying degrees according to the pH M. pachydermatis was inhibited at pH of < 5.0. Especially it has been proved an effective antifungal effect at pH 3.5. Therefore, the pH of chitosan solution had a effect on antifungal activity and the optimal pH was 3.5 in vitro. The possibility of topical therapy with acidific solution of chitosan has a potential in skin infection against M. pachydermatis.

Effect of Polyamine on Auxin Polar Transport in Corn Coleoptile Segments (Polyamine이 옥수수 자엽초 절편에서 오옥신 이동에 미치는 영향)

  • 허윤정
    • Journal of Plant Biology
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    • v.34 no.4
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    • pp.297-302
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    • 1991
  • The effects of polyamines on auxin polar transport were studied in corn coleoptile segments. Among putresine, spermidine and spermine tested in labelled auxin transport, spermidine inhibited auxin polar transport most strongly. Its inhibitory effect appeared after 1 h of transport period. Spermidine inhibited labelled auxin and 14C-benzoic acid accumulation into the tissue in the various pH range tested (pH 4.0-8.0). These results suggest that the inhibition of auxin transport may not be due to decrease in pH by spermine the effect of decreased pH in the extracellular space.

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On the action of Ca in pollen growth as influenced by interaction of the different Ca concentration, acidity and temperature (화분생장에 미치는 석탄이온의 작용과 그 농도, 산성도 및 온도의 상호관계에 대하여)

  • 곽병화
    • Journal of Plant Biology
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    • v.8 no.1_2
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    • pp.19-23
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    • 1965
  • Interaction occuring among the different Ca concentrations, pH and temperatures in the promotive effect of Ca in pollen growth was studied by using pollen from Crinum asiaticum and Cryptostegia grandiflora. Data for pollen tube elongation were found to be more indicative of representing the promotive action of Ca ion in pollen growth than those for pollen germination, and were served to evaluate the experimental results. The pollen growth increased as the concentration of Ca increase. The optimal pH range for pollen growth shifted from the lower pH to the higher as the concentration of Ca increase. The characteristic Ca effect was disappeared, and no pH effect at various ranges was observed when pollen grains were grown at the low temperature(8$^{\circ}C$). The Ca effect became quite pronounced if temperature were raised. The Ca effect became even mroe striking if the condition was in higher pH ranges (weak alkaline). Higher pH ranges were found to be more favorable for the Ca action, whereas higher temperature was required to bring about more pronounced Ca effect. Thus, the longest pollen tube was obtained with the highest pH, temperature adopted for the medium supplemented with Ca in the present experiment, and the shortest tube with the lowest temperature applied at the highest pH. Pectin synthesis in pollen tube was considered as a metabolic process, whereas Ca binding in pectin of the pollen tube wall as non-metabolic in nature. Disappearance of Ca effect at the low temperature was probably brought about by blocking the metabolic synthesis of pectin, and nonmetabolic Ca binding seems to take place more extensively with higher concentrations of Ca and at higher pH levels than the lower.

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Effect of pH and Temperature on the Adsorption of Heavy Metals in Acid Mine Drainage (AMD) Onto Coal Mine Drainage Sludge (CMDS) (탄광슬러지를 이용한 금속광산 산성배수 처리 시 pH및 온도의 영향)

  • Cui, Ming-Can;Lim, Jung-Hyun;Kweon, Bo-Youn;Jang, Min;Shim, Yon-Sik;Khim, Jee-Hyeong
    • Journal of Soil and Groundwater Environment
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    • v.14 no.1
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    • pp.29-35
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    • 2009
  • In this study, the effect of pH and temperature on the adsorption behavior of acid mine drainage (AMD) on coal mine drainage sludge (CMDS) has been investigated during the treatment of coal mine drainage (CMD) by electrical purification method. The pH$_{zero\;point\;charge}$ (pH$_{zpc}$) of CMDS was 5. The removal ratio of copper, zinc, cadmium, iron were increased according to the increase of pH value. The adsorption amount of copper showed 0.64 mg g$^{-1}$ sludge. It was independent of pH value. The adsorption amount of the other metals showed l.l times when pH was 3. The adsorption amount of chromium was a little bit increased at the pH value higher than 7 due to a small amount of the chromium was eluted as $Cr(OH)_6^{3-}$. The amount of metals' absorption were decreased according to temperature was increase at pH value was 3. The selectivity order was Cd>Fe > Zn > Cu. The amount of absorption showed q$_{max}$ Cu 2.747 mg g$^{-1}$ andZn 2.525 mg g$^{-1}$ when pH value higher than 5. It was independent of temperature.

Proton Effect on the Degradation of Phenolic Compound by Activated Sludge and Nocardia asteroides (활성슬러지 혼합미생물과 Nocardia asteroides에 의한 페놀화합물 분해시 양성자이온의 영향)

  • 조관형;조영태;우달식
    • Journal of Environmental Science International
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    • v.11 no.6
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    • pp.561-567
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    • 2002
  • This study was investigated to evaluate the effect of the sodium ion and pH on toxicity of dinitrophenol at high concentrations (0.41 to 0.54 mM), over a sodium concentration range of 0.1 mM to 107 mM and over a pH range of 5 to 9. The concentration of sodium ions in the activated sludge mixed liquor seemed to have very little effect on dinitrophenol toxicity. However, lack of sodium in the growth media resulted in a reduction of the dinitrophenol degradation rate by bacterial isolate from the activated sludge culture, which has been identified as Nocardia asteroides. Dinitrophenol inhibition was found to be strongly dependent on mixed liquor pH. The dinitrophenol degradation rate was highest in the pH range of 6.95 to 7.84; at pH 5.94 degradation of 75 mg/L dinitrophenol was significantly inhibited; at pH < 5.77, dinitrophenol degradation was completely inhibited after approximately 30% of the dinitrophenol was degraded.

Effect of Particle Size of Sediment on Adsorption of Fluoride (하천 퇴적물의 입자크기에 따른 불소의 흡착 특성)

  • Kim, Chae-Lim;Oh, Jong-Min
    • Korean Journal of Ecology and Environment
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    • v.49 no.4
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    • pp.289-295
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    • 2016
  • The purpose of this study is to find out the effect of particle size of sediment on adsorption of fluoride. Particle size is classified as sand, silt and clay. Adsorption equilibrium time, adsorption isotherms and the effect of pH were investigated through batch tests. The $pH_{pzc}$ of sand, silt, clay was respectively 6, 8, 4.5 and AEC (anion exchange capacity) was highest in silt, respectively 0.0095, 0.0224, $0.014meq\;g^{-1}$. Adsorption of fluoride on the sediment was in equilibrium within 300 minutes from all particle size. The experimental data of isotherms at various pH were well explained by Freundlich equation. As the experimental results of the effect of pH, the adsorption efficiency of sand and silt were reduced after the $pH_{pzc}$. However, the adsorption efficiency of clay was maintained after the $pH_{pzc}$, and decreased rapidly higher than pH 12.

Effect of the N-nitrosodimethylamine Formation in Ascorbate and Phenolic Portions from Citrus Juice (감귤류의 Ascorbate 및 Phenolic 획분이 N-nitrosodimethylamine의 생성에 미치는 영향)

  • 성낙주;송미향;이수정;신정혜;최선영
    • The Korean Journal of Food And Nutrition
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    • v.15 no.2
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    • pp.97-103
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    • 2002
  • Five citrus juices were separated into a ascorbate and phenolic portion using rep-pak C$\_$18/ cartridge, respectively, in order to elucidate the nitrite scavenging effect and N-nitrosodimethylamine(NDMA) formation in model system. The nitrite scavenging effect of ascorbate portion from citrus juices, in the different pH, when added with 5ml were 79.9 ∼98.6% under the condition of pH 2.5. 48.5∼86.3% at pH 4.2 and lower than 35.2% at pH 6.0. The nitrite scavenging effect was excellent phenolic portion rather than ascorbate portion. Particularly, the effect was more 2 times than ascorbate portion under the reaction condition of pH 6.0. When added the phenolic portion in the reaction mixture, NDMA formation was inhibited 92.8% or more in kum quat, mandarin orange and sweet orange juices. But the ascorbate portion was a negative response of the inhibition of NDMA formation. The inhibition on NDMA formation in citrus juice may be due to phenolic compounds were reacted.

Effect of pH Stimulation on Acrosome Reaction of Bovine Spermatozoa (pH 자극이 소 정자의 첨모반응에 미치는 영향)

  • 박영식;임경순
    • Korean Journal of Animal Reproduction
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    • v.15 no.3
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    • pp.195-199
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    • 1991
  • This study was carried out ot investigate effect of pH stimulation on acrosome reaction of bovine spermatozoa. The results obtained were as follows : 1. When sperm was sequentially washed with SHP solution of pH 7.4, 7.7 and 7.4 and incubated in mTALP solution of pH 7.4 for 120min, 15, 30, 60 and 120min incubations showed significantly(p<0.05) higher sperm acrosome reaction rate than 0 min. 2. When sperm was sequentially washed with SHP solution of pH 7.4, 8.0 and 7.4 and incubated in mTALP solution of pH 7.4 for 15 minutes, sperm acrosome reaction rate was significantly(p<0.01) increased until 9 min. Incubation, but not increased thereafter. 3. When sperm were separately washed with SHP solutions of pH 7.0, 7.4 and 8.0 and incubated in mTALP solution of pH 7.4 for 9min, sperm acrosome reaction rate was 74.8, 71.8 and 93.4%. pH 8.0 showed signifciantly(p<0.01) higher sperm acrosome reaction rate than pH 7.0 and 7.4. The results suggest that stimulation of sperm with high pH induces sperm crosome reaction.

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