• Proceedings of the Korean Geotechical Society Conference
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• 2001.03a
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• pp.585-590
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• 2001

Physicochemical phenomena in soils are dependent upon pH when using electrokinetic extraction for the contaminants removal especially for heavy metals. pH variation in soils is affected on H$\^$+/ and OH￣ ions produced by electrolysis reaction and buffer capacity of soil. High amount of heavy metals are retained in the soils if the soil buffer capacity remains high enough to resist a change in pH. Therefore, accurate pH estimation of soil is important in the application of electrokinetic mechanism for decontamination and understanding of subsurface physicochemical characteristics is also required as well as considering buffer capacity for the enhanced methods application. For these, buffer capacity and pH distribution were measured for the four soils, and also compared with modeling results. The results of buffer modeling were good agreement with experimental data. It is showed that four soils were effected by buffer capacity

• KSBB Journal
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• v.13 no.4
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• pp.461-467
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• 1998

A fermentation system was supplemented with a device for the measurement of the durations of alkali pump feeding for automatic pH control and an A/D convertor for precise monitoring of pH value by computer. A software program was developed to measure buffer capacities from the pH signal and the pH control signal during fermentation. By measuring the buffer capacity on-line, levels of acetic acid were estimated by a software sensor using pH signal in a fermentation process of E.coli growing in a minimal medium. The measured values of acetic acid showed correlation to those of estimated by the software sensor. Lacitic acid production was also successfully estimated by the values of buffer capacities measured on-line.

• Korean Journal of Soil Science and Fertilizer
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• v.32 no.1
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• pp.1-6
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• 1999

To find the latent effect of paper mill sludges (PMS) with and without alum, and alum paper mill sludge compost(PMSC) on aluminum toxicity of crops, the pH buffer capacity and the acidification resistance index (ARI) for PMSs and PMSC were investigated, comparing to upland soil. Buffer capacities of PMS with and without alum, and PMSC were significantly higher than $2.5cmol^+kg^{-1}$ of check soil as 137, 250, and $147cmol^+kg^{-1}$, respectively. Owing to such high buffer capacity of PMS and PMSC, they showed to be well-resisted to acidification.

• Biotechnology and Bioprocess Engineering:BBE
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• v.10 no.4
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• pp.304-308
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• 2005

The response of IPTG induction was investigated through the monitoring of the alkali consumption rate and buffer capacity during the cultivation of recombinant E. coli BL21 (DE3) harboring the plasmid pRSET-LacZ under the control of lac promoter. The rate of alkali consumption increased along with cell growth, but declined suddenly after approximately 0.2 h of IPTG induction. The buffer capacity also declined after 0.9 h of IPTG induction. The profile of buffer capacity seems to correlate with the level of acetate production. The IPTG response was monitored only when introduced into the mid-exponential phase of bacterial cell growth. The minimum concentration of IPTG for induction, which was found out to be 0.1 mM, can also be monitored on-line and in-situ. Therefore, the on-line monitoring of alkali consumption rate and buffer capacity can be an indicator of the metabolic shift initiated by IPTG supplement, as well as for the physiological state of cell growth.

• The korean journal of orthodontics
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• v.40 no.2
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• pp.95-105
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• 2010

Objective: To identify clinical, salivary, and bacterial changes during orthodontic treatment with follow-up to 24 months. Methods: In 30 patients, clinical (decayed, missing, and filled surfaces [DMFS], O'Leary's plaque index, and plaque pH), salivary (unstimulated and stimulated saliva, buffer capacity, pH, and occult blood), and bacterial (Streptococcus mutans and Lactobacillus) markers were evaluated. A questionnaire was employed to evaluate their hygienic-dietary habits. Data were analyzed by ANOVA, logistic regression and Spearman's correlation. Results: DMFS increased significantly, whereas the plaque index diminished, plaque pH was more acidic (p = 0.23), and unstimulated salivary flow showed significant differences during the treatment (p = 0.013). Stimulated saliva flow increased in females after the placement of appliances; buffer capacity was diminished in males during the therapy; salivary pH remained at basal values. Bacterial levels and occult blood increased to high-risk levels and were not statistically significant different between genders (p > 0.05). Two major relationships were confirmed: initial plaque with use of dental aids (r = 0.429; p = 0.018) and final DMFS with unstimulated salivary flow (r = -0.372; p = 0.043). Conclusions: The increase in retentive surfaces increased the bacterial levels, plaque pH became acidified, and gingival damage was greater. Buffer capacity was altered but maintained a healthy salivary pH during the treatment.

• Korean Journal of Soil Science and Fertilizer
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• v.37 no.6
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• pp.378-382
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• 2004

Soil pH is an important indicator for soil reactions and crop growth. pH buffer capacity and lime requirements are necessary to comprehend and manage soils well. The characteristics related with soil pH were analyzed and 5 field trials were conducted to elucidate pH buffer capacity of soil and lime requirements and liming factor for Korean acid soils. Soil minerals were analyzed for the soil of 2 years after treating $CaCO_3$ using X-ray diffraction. The amount of neutralized $H^+$ was regarded as the exchangeable aluminium overcoming ${\Delta}pH$, because pH buffer capacity of soil depended on exchangeable aluminium. Lime requirement was somewhat similar to the KCl exchangeable aluminium and it was also affected by the exchangeable cation by added lime. X-ray diffraction analyses revealed that an aluminium dissociation from Korean acid soils was equilibrated with kaolin minerals and changed into anorthite ($CaAl_2Si_2O_8$) by neutralizing with $CaCO_3$. Neutralizing process was composed of changing process of $Al^{3+}$ into $H^+$ and $Al(OH)_4{^-}$ ionic species and of neutralizing $H^+$ by, the amount of which was lime requirement. The fact that anorthite dissociates an aluminium ion higher than kaolinite does enabled to consider a liming factor (LF) the content of exchangeable cation and ${\Delta}pH$, $LF=1.5+0.2{\times}{\sum} Cations{\times}{\Delta}pH$.

• Journal of Korea Soil Environment Society
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• v.3 no.3
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• pp.3-10
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• 1998

Acid/Base buffer capacity of soil is very important in prediction of contaminant transport for its direct impact on pH change of the system composed of soil-contaminant-water, In this research, diffuse double layer theory as well as two layer electrostatic adsorption model are applied to develop a theoretical model of buffer capacity of soil. Model application procedures are presented as well. Buffer capacity of Georgia kaolinite and Milwhite kaolinite was measured by acid-base titration. Model prediction and experimental results are compared.

• Journal of Korean Society of Forest Science
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• v.87 no.2
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• pp.188-193
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• 1998

Soil pH change is an important factor which determines soil chemical properties. It is an indicator of the effect of urban environmental pollution on soils and plant growth. The objective of this study was to assess the effect of air pollution on the soil of Seoul urban forests during the course of the air pollution being dipersed toward suburb area. Study sites were divided into four sections of concentric circles with 5km interval. Soil samples were collected from A and B horizons in the urban forests, and analyzed for soil pH, soil buffer capacity, cation exchange capacity, and base saturation. Soil pH ranged from 3.96 to 5.08 for A horizon and from 4.10 to 5.25 for B horizon, which were not significantly different among the sections. However, there was a trend of soil pH lowered at the sections close to the urban center. Soil buffer capacity was lower at 0-5km and 5-10km sections compared to that at the outer sections. Cation exchange capacity and base saturation were not different significantly among the sections. Following the pattern of air pollutants being dispersed from urban center to suburb, soil acidification was observed at the urban forests in Seoul area. Low level of soil buffer capacity toward the urban center was an indicator of soil acidification at the urban forests.

• Culinary science and hospitality research
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• v.13 no.2
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• pp.254-259
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• 2007

The control of enzymic browning in potato slices by the use of citrate and phosphate buffer at different pH values and concentration was investigated. Minimally processed potatoes were stored at $5^{\circ}C$ and $20^{\circ}C$ followed by dipping in distilled water, citrate buffer (pH $3.0{\sim}5.0$) and phosphate buffer (pH $5.0{\sim}7.0$). The color characteristic was measured after storage at $5^{\circ}C$ and $20^{\circ}C$ for 24 hours. Treatment effectiveness was greatly improved by reducing pH and temperature. The citrate buffer was more effective than phosphate buffer in the browning inhibitory capacity. The citrate buffer (pH 3.0) showed the most anti-browning effect in this condition and more effective inhibition of browning by increasing concentration of treatment solution. The phosphate buffer (pH 5.0) treatment showed more effectiveness than concentration of 0.5 M of citrate buffer treatment.

• Journal of Korean Society of Forest Science
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• v.79 no.4
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• pp.376-387
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• 1990

A research effort has been made to determine soil buffer capacity in forest soils nearby urban and industrialized regions. Buffer capacities of soils from four regions were measured by different pH levels of artificial acid precipitation. The following conclusions have been drawn in response to the overall research objectives. Soil Suffer capacity was the highest in Kangwondo followed by Uisan, Yeochon and Seoul when simulated acid precipitation were treated at the level of pH 3.0-5.7. With the acid precipitation treatment below pH 2.0 level, however, the capacity dropped seriously with no significant differences between the regions. In Kangwondo region soils weathered from granite and limestone showed significant differences in the buffer capacities. Soil collected in Seoul and Ulsean revealed that the capacities tended to increase with the distance from the pollution sources when treated at pH 3.0, 4.5 and 5.7 level of acid precipitation. The major mechanism of soil buffer observed during simulated acid precipitation experiment was canon exchange for Kangwondo forest soils. In Seoul region canon exchange also played an important role in soil buffering under artificial acid precipitation between 3.0 and 5.7 pH levels, yet under pH 2.0 level aluminum and silicate hydrolysis. In Ulsan canon exchange was a msjor determinant for the buffer capacity above pH 4.5 level, between pH 3.0-4.5 aluminum hydrolysis and below pH 3.0 aluminum and silicate hydrolysis. In Yeochon silicate hydrolysis led buffer capacity above pH 4.5 and below pH 4.5 aluminum hydrolysis.