• Title/Summary/Keyword: pH and alkalinity

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Study on Performance of pH Reducing Agent Applied for Wet Process of Recycled Aggregate (습식 순환골재의 생산공정에 적용 가능한 pH 저감제의 성능 검토)

  • Choi, Jung-Gu;Lee, Gun-Cheol
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.4
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    • pp.366-373
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    • 2015
  • Construction waste is recycled and used for the efficient and eco-friendly disposal of construction waste increasing due to reconstruction and redevelopment project and so on. There is recycled aggregate as a typical case. And this recycled aggregate shows strong alkalinity due to calcium hydroxide, and causes many environmental problems. Therefore, this is a study on reduction in the strong alkalinity of recycled aggregate by using sodium phosphate based ammonium in order to reduce the pH of recycled aggregate. Besides, a possibility that a pH reducing agent of recycled aggregate could be applied to a site was evaluated. As a result, it was possible to verify that pH decreased as the percentage of pH reducing agent increased. It is thought that the pH reducing agent can be applied to a site by methods such as immersion and spray using the pH reducing agent in the process of producing recycled aggregates.

The Effect of Temperature on the Stable Region of Magnesium Ion in Aqueous System (수중 마그네슘이온의 안정영역 변화에 대한 온도효과)

  • Kim, Hee-Jin;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.27 no.4
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    • pp.438-444
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    • 2011
  • Magnesium is one of the abundant natural resources in the earth crust and seawater, which is directly related to various organisms activities interconnecting with water-rock system. In aqueous system, magnesium is known to predominantly exist in the form of $Mg^{2+}$ ion which is verified in its $E_h-pH$ diagram. When it is at equilibrium in aqueous system, temperature takes an essential role to complete equilibrium states. This study represents the change of the stable region of magnesium ion according to temperature, and how the consequences would affect aquatic organisms. It was revealed that there is a noticeable tendency shrinking the stable region of magnesium ion in a diagram as temperature increases, and as a result, aquatic bio-species presumably have difficulties to absorb the nutrient. Also, it was considered that the water system would be acidified by decreasing alkalinity.

Studies on the Water Purification Using Glycine max Merr Seedling (콩(Glycine max Merr)유묘를 이용한 수질정화에 관한 연구)

  • 김순진;나규환
    • Journal of Environmental Health Sciences
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    • v.23 no.1
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    • pp.50-54
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    • 1997
  • The removal efficiency of nutrient was investicated by using Glycine max Meer seedling. After budding, Glycine max Merr was raised at darkness for 4 days. During cultivation, the removal efficiency of $NO_2-N+NO_3-N$ was up to 90% with initial concentration of 20-100 ppm. The removal efficiency of PO$_4$-P was up to 80% with initial concentration at 30 ppm, but it was down to 22% and 27% at 40 ppm and 50 ppm. When the removal efficiency of nutrient was compared with alternating 12 hours' light and darkness, the removal efficiency of NO$_2$-N + NO$_3$-N was up to 90% at below 60 ppm. It was not different from each other. But it was particularly low about 62% and 34% at 80 ppm and 100 ppm in alternating 12 hours' light. The removal efficiency of PO$_4$-P was low at alternating 12 hours' light between 10-50 ppm on the whole range. The neutralizing capacity of pH was shown in acidity and alkalinity except strong acidity(below pH 3). The initial pH was neutralized at 6.0-7.7 of pH after 4 days. Particularly, Glycine max Meer seedling that was difference from other water plants, was shown the neutralizing capacity in strong alkalinity.

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Corrosion Control in Water Distribution System using Lime and Carbon Dioxide(I) - Determination of Optimum Operational Conditions in Lime Adding Process (소석회와 CO2를 이용한 상수관로의 부식제어(I) - 소석회 주입공정의 최적 운전인자 도출)

  • Sohn, Byung-Young;Byun, Kyu-Sik;Kim, Young-Il;Lee, Doo-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.3
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    • pp.373-378
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    • 2008
  • The pH & alkalinity adjustment method by lime and carbon dioxide($CO_2$) for corrosion control in water distribution system was investigated to determine the optimum operational condition in lime adding process in water treatment plant(WTP). The mixing time at dissolution tank and sedimentation time at saturator for maintaining optimal turbidity condition of lime supernatant were 60~75 minutes and 75~95 minutes, respectively. There was no difference according to $CO_2$ adding methods such as $CO_2$ saturated water or $CO_2$ gas. But, $CO_2$ saturated water could be convenience at WTP in terms of pH control and quantitative dosing. To minimize generation of calcium carbonate products, the short time interval between adding of lime and $CO_2$ is most important. The lime should be added below 32 mg/l for preventing pH rising and generation of calcium carbonate products at the heating condition.

Effect of Phosphate-based Inhibitors on Pipe Corrosion of Drinking Water Supply (상수도 배급수관망의 부식방지를 위한 인산염계 방청제 적용에 관한 연구)

  • 이윤진;남상호
    • Journal of Environmental Health Sciences
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    • v.29 no.3
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    • pp.65-71
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    • 2003
  • The injection concentration of corrosion inhibitor increases under the pH 7, temperature of 2$0^{\circ}C$, and alkalinity of 35 mg/l (as CaCO$_3$), the corrosion rate gradually decreased. When the corrosion inhibitor of 10 mg/l is injected, the corrosion rate for carbon steel pipe, galvanized steel pipe, and copper pipe reduces for 37, 66 and 61 % respectively that it is more efficient on galvanized steel pipe and copper pipe. As a result of examination of corrosion rate at pH 6, 7, and 8 when injecting 10 mg/l of corrosion inhibitor under the conditions of 2$0^{\circ}C$ in water temperature and 35 mg/l (as CaCO$_3$) in alkalinity, the efficiency of the corrosion inhibitor increases as the pH increases. For carbon steel pipe, it does not show much a difference with the change of the pH condition, but galvanized steel pipe and copper pipe clearly show the corrosion rate depending on the change of the pH condition. The efficiency of corrosion inhibitor is low as the concentration of residual chlorine is high, but it does not show a great influence at 0.4 mg/l or less. For each pipe type, in the case of carbon steel pipe, the range of increase of corrosion speed following the residual chloride is higher than the other pipe types. In the meantime, the effect following the residual chlorine in copper pipe is low.

Analysis of Construction Condition and Environmental Effect of Deep Soil Mixing (심층혼합처리 공법의 시공조건 및 환경적 영향 분석)

  • Cho, Jin-Woo;Lee, Yong-Soo;Yu, Jun;Shin, Won-Jae
    • Proceedings of the Korean Geotechical Society Conference
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    • 2006.03a
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    • pp.1155-1158
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    • 2006
  • This paper presents a study on the construction condition and environmental effect of deep soil mixing. Construction condition means the difference in unconfined compressive strength with respect to the depth and location of samples. Environmental effect means alkalinity diffused from soil stabilizer. The experimental results indicate that the unconfined compressive strength vary with respect to the depth, and doesn't show consistency pattern. So, in field application we must decide a mixing ratio enough to satisfy the least unconfined compressive strength. The difference in unconfined compressive strength with respect to the location of samples is negligible. The generation of alkalinity from soil stabilizer is reduced by permeating in non-improved soil and it is expected that the diffusion of alkalinity has no environmental effect on soil and ground water.

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Application of Accelerated Carbonation Reaction for Low Alkalinity of Recycled Aggregate

  • Lee, Jong-Chan;Lee, Sae-Hyun;Yoon, Sang-Hyuck;Song, Tae-Hyeob
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.5
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    • pp.515-522
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    • 2011
  • As Construction and Demolition (C&D) debris increases every year, systems have been adopted to compel the use of recycled aggregate made from C&D debris, and the use of recycled aggregate in the construction field has increased. But environmental problems linked to the alkalinity of recycled aggregate have occurred, and a study on approaches to lower the alkalinity of recycled aggregate is needed. It was certified by this study that a large amount of recycled aggregate could be carbonated in the C&D debris midterm-treatment field. As a result, the density and the water absorption of recycled aggregate after carbonation reaction was improved, and pH of recycled aggregate was lowered from over 11 to 9.4. X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), Energy Dispersive Spectroscopy (EDS), and Thermogravimetry/Differential Thermal Analysis (TG/DTA) methods also indicated the carbonation of recycled aggregate.

Examination of the Characteristics of Mortar Mixed with Boron Compounds Presenting Various Levels of Alkalinity (다양한 알칼리도를 가진 붕소화합물이 혼입된 모르타르의 특성 검토)

  • Lee, Binna;Lee, Jong-Suk;Min, Jiyoung;Lee, Jang Hwa
    • Journal of the Korea Concrete Institute
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    • v.29 no.1
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    • pp.85-92
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    • 2017
  • This study examines the characteristics of mortar mixed with various boron compounds. The adapted boron compounds, classified into acid, slightly alkaline and strongly alkaline with respect to the value of the pH are acid-based boron (AA), low-alkaline-based boron (AB), and high-alkaline-based boron (HB). The pH test, setting test and compressive strength test are performed to evaluate the physical and chemical properties of mortar, and SEM imaging is conducted to analyze the microstructure of mortar. The measured pH shows that the specimens mixed with boron compounds have lower pH than the basic mortar without boron and that loss of pH occurs according to time. The setting test reveals that the initial and final setting times of the specimens mixed with boron compounds occur later than the basic mortar, which disagrees slightly with the previous literature stating that the setting time can be shortened according to the alkalinity. From the compressive strength test and SEM imaging results, it is recommended to determine the optimal content of boron considering type and composition of the boron compounds.

Relation between Leaching Characteristics of the positive Ions and Phosphate Removal by granular Converter Slag for the different Conditions and Concentrations of Phosphate (인산염 농도와 폐수조건 변화에 따른 입상 전로슬래그의 양이온 용출 특성과 인산염 제거의 관계에 관한 연구)

  • Lee, In-Gu;Lee, Sang-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.8 no.2
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    • pp.372-379
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    • 2007
  • The converter slag can be used to remove phosphate ion into the form of solid state from the wastewater. This research aims to evaluate the change of pH, alkalinity, leaching of positive ion in the wastewater and the removal of phosphate from the initial condition of wastewater. The change of pH was abruptly increased upto pH 11 for the initial condition of pH from 7.0 to 8.5 fer 0.5 unit of pH. The alkalinity was steadily increased from 10 hours of reaction time not same as pH increase. The removal of phosphate was very effective till 10 hours of reaction then it was slow after that time. The positive ion, magnesium ion was leached from the concentration of 2.0 mg/L to 4.3mg/L at the reaction time of 27 hours and 36 hours. Therefore, converter slag can be used to remove the phosphate in the form of Struvite from the wastewater.

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To Experimental Study of Alkalinity Recovery Agent application in field (알칼리회복제의 현장 적용성에 관한 실험적 연구)

  • 김광기;박선길;김우재;이영도;송병창;정상진
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2002.11a
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    • pp.7-10
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    • 2002
  • Concrete used up to date semipermanent architecture material but now day concrete early deterioration emboss social issue because of construction structure and environmental factor. so, many study of deterioration concrete construction improve durability used impregnation alkalization agent. In These to Study of derelop reoairmeat material in reduce carbonation. xoncrete Building use Alkalinity Recovery Agent which is Realkalinity and strength surface. Alkalinity Recovery Agent undisposed application volume and cure the concrete period. To study Alkalinity Recovery Ahent spray and cure the concrete propriery in field.

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