• 제목/요약/키워드: pH agent

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복합아민 적용에 따른 원전 2차 계통 부식생성물 거동평가 (Evaluation of Corrosion Product Behavior in NPP Secondary System with Complex Amine)

  • 정현준;이인형;김영인
    • 한국압력기기공학회 논문집
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    • 제10권1호
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    • pp.96-99
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    • 2014
  • The aim of the study was to evaluate the water treatment of pressurized water reactor secondary side by the mixed amine of ammonia and ethanolamine, from the standpoint of corrosion control, as compared with all volatile treatment of ammonia. The pressurized water reactor systems have switched a secondary side pH control agent to minimize the corrosion in the moisture separator/reheater and feedwater heater systems and the transport of corrosion products into steam generator. As results of field test, pH was increased in the steam generator and the wet steam area of moisture separator/reheater and the concentration of Fe were decreased by more than 50% as compared with water treatment of ammonia.

Streptomyces kasugaensis의 Kasugamycin 생산배지조성 및 배양조건의 검토 (Studies on the Optimization of Media Composition and Cultural Conditions for Kasugamycin Production, by Streptomyces kasugaensis)

  • 오영준
    • 한국미생물·생명공학회지
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    • 제20권5호
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    • pp.583-587
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    • 1992
  • 본 연구는 농용항생제인 kasugamycin의 생산을 위하여 S.kasugaensis의 배양조건 및 배지조성을 고찰하였다. Kasugamycin 발효시 최적 탄소원 및 질소원은 각각 soybean oil과 soybean flour였다. 배지 최적온도는 28'C, 최적 pH는 6.6이었다. 본 배양의 최적 접종 상태는 64-68시간 배양한 전배양액으로 접종하였으며, 발효중 물의 첨가는 생산성의 증가를 나타냈으나 소포제로서 silicone coil 첨가는 별 영향을 관찰할 수가 없었다.

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8-Hydroxyquinoline 誘導體에 關한 硏究 (第2報) Fe (II)-7-Nitroso-8-Hydroxyquinoline-5-Sulfonate 에 關하여 (Studies of 8-Hydroxyquinoline Derivatives (Part II) Fe (II)-7-Nitroso-8-Hydroxyquinoline-5-Sulfonate)

  • 이동형
    • 대한화학회지
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    • 제9권1호
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    • pp.41-44
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    • 1965
  • 7-Nitroso-8-hydroxyquinoline-5-sulfonate의 Fe(II)錯鹽의 性質을 700$m{\mu}$, $26^{\circ}C$에서 分光光度法으로 調査하였다. 이 錯鹽은 pH6.0에서 가장 큰 吸光度를 나타내며 熱安定度도 대단히 좋다. Ligand나 Fe(III)의 還元에 使用한 hydroxylamine이 過剩으로 存在할때 에도 錯鹽의 生成에 影響을 주지 않는다. 錯鹽의 組成을 몰比法과 連續變化法으로 調査한 結果, 金屬과 ligand의 몰比는 1:3이였다. 檢量線은 實驗한 濃度範圍內에서 Beer의 法則에 따른다.

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폐 AC용액으로부터 제조된 AUC분말의 특성에 대한 연구 (A Study on characteristics of AUC Powder Prepared with the Waste AC Solution)

  • 정경채;김태준;최종현;박진호
    • 한국세라믹학회지
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    • 제33권3호
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    • pp.332-338
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    • 1996
  • This study was investigated on the recycle feasibility of the waste AC(Ammonium Carbonate) solution produ-ced in a commercial AUC(Ammonium Uranyl Carbonate) conversion plant. AUC particles were produced with the AC solution which was prepared with AC solid-agent instead of ammonia and carbon-dioxide gases. As the results particles of monoclinic shapes has been obtained regardless of the pH change if the carbonate concentration is sufficient in the mother liquore. Also a lot of twinned or aggregated particles were formed in case of the increase of pH in the reaction system but not affected in the change of temperature. Consequen-tly the characteristics of the particles which converted for AUC were produced withAC solution to UO2, particles specific surface area shape sintered density and others were similar to that of the particles which were produced with gases only when the pellets are fabricated in the nuclear fuel manufacturing process So the waste AC solution which is produced in the commercial AUC conversion plant is possible to recycle.

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Determination of Trace Metals in Waters by FAAS after Enrichment as Metal-HMDTC Complexes Using Solid Phase Extraction

  • Tokalioglu, Serife;Kartal, Senol;Elci, Latif
    • Bulletin of the Korean Chemical Society
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    • 제23권5호
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    • pp.693-698
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    • 2002
  • A method has been described for the determination of Cu(Ⅱ), Pb(Ⅱ), Ni(Ⅱ), Cd(Ⅱ), Mn(Ⅱ) and Fe(Ⅲ) by flame atomic absorption spectrometry (FAAS) after preconcentration on Amberlite XAD-16 resin, using hexamethyleneammonium-hexamethylenedithiocarbamate (HMA-HMDTC) as a chelating agent, and NH3/NH4Cl buffer solution (pH 9). Influences of various analytical parameters such as pH, concentration of nitric acid, amount of analytes, diverse ions and sample volume were investigated. The relative standard deviation (RSD) and the detection limit (LOD) were found in the range of 0.8-2.9% and 0.006-0.277 ㎍/mL,respectively. Recoveries obtained by the column method were quantitative ( >95%) at optimum conditions.The method was applied to the determination of some metal ions in seawater and wastewater samples. A high preconcentration factor (about 150 for seawater and 75 for wastewater samples) and simplicity are the main advantages of this suggested method.

자가치료용 마이크로캡슐 특성에 영향을 미치는 제작공정 연구 (Study on Manufacturing Process Variables affecting on Characteristics of Autonomic Microcapsules)

  • 윤성호;박희원;소진호;홍순지;이종근
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2003년도 춘계학술발표대회 논문집
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    • pp.169-172
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    • 2003
  • Manufacturing process for autonomic microcapsules was introduced and autonomic microcapsules were manufactured by varying with various manufacturing process variables. Urea-formaldehyde resin was used for the wall of microcapsules and DCPD (dicyclopentadiene) was used for the self-healing agent. The characteristics of these microcapsules was evaluated through a particle size analyaer, an optical microscope, and a TGA. The various manufacturing process variables, such as pH and agitation speed of the emulsified solution, were considered to focus in this study. According to the results, the particle size distributions were affected on the agitation speed of the emulsified solution, and the thermal stability was influenced by pH of the emulsified solution.

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모나자이트 중의 납 정량을 위한 신속한 EDTA 적정법 (A Simple EDTA Titration Method for the Determination of Lead in Monazite)

  • 이철;조원지
    • 대한화학회지
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    • 제13권4호
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    • pp.313-316
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    • 1969
  • 모나자이트 중의 납함량을 신속하고 간편하게 결정하는 방법을 기술하였다. 즉 모나자이트 시료를 황산에 녹여 200ml가 되겠끔 희석하였다. 스트론튬으로 납을 정량적으로 분리한 후 3N 수산화나트륨에 녹였다. 여분의 Zn-EDTA를 가한 다음 남은 아연 이온을 0.01M EDTA표준용액으로 적정하였으며 이때 가리움제 (masking agent)러서 시안화칼륨 및 아세틸 아세톤을 가하였고 pH 5에서 자이렌을 오렌지(Xylenol orange)를 지시약으로 사용하였다.

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산조인 알카로이드의 가용화 및 물성에 관한 연구 (A Study on the Solubilization and Physical Properties of Sanjoinine-A)

  • 서광교;이치호
    • Journal of Pharmaceutical Investigation
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    • 제26권4호
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    • pp.257-261
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    • 1996
  • The seeds of Zizyphus Jujuba have been used as an antianxiety agent for the treatment of insomnia from the earliest times. Sanjoinine-A, isolated from the seeds of Zizyphus Jujuba, have been found to have a minor tranquilizer activity. However this drug is poorly soluble in water. In order to increase the dissolution rate of sanjoinine-A, solid dispersions with PVP-MC and inclusion complex with ${\beta}-cyclodextrin$ were prepared and evaluated. All of these systems increased the dissolution rate of sanjoinine A comparing with sanjoinine-A free base. From pH-rate profile of sanjoinine-A at $60^{\circ}C$, it was found that sanjoinine A was relatively stable in acidic solution, but unstable in basic solution.

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양모직물의 방축가공에 관한 연구(I) - 염소화/MONAMIN BTN 방축가공 양모직물의 역학특성에 미치는 처리조건의 영향 - (A Study on the Shrink Resist Finish of Wool Fabric(I) - Effect of Treating Condition on Mechanical Properties of Wool Fabric with Chlorination and MONAMIN BTN Resin -)

  • 황백순;이재호;김덕리
    • 한국염색가공학회지
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    • 제13권4호
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    • pp.272-281
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    • 2001
  • Shrink resist finishing of wool fabric was carried out with MONAMIN BTN shrink resist agent after chlorination with D.C.C.A.(dichloro isocyanuric acid). The purpose of this study is to investigate the effect of treating conditions, such as concentrations of D.C.C.A and MONAMIN BTN, pH of treating bath, dying times, curing times and temperatures, on shrink resist finishing. Mechanical properties of the treated fabric were measured by KES-FB system. The optimum chlorination of wool corresponds to 2∼3%(o.w.f.) of D.C.C.A. without rendering the damage on surface of wool fiber. Also it seems likely that the shirink resist finishing carried out at 2 ∼3%(o.w.f.) of MONAMIN BTN and pH 7∼8 of treating bath is effective in increasing a softness of hand.

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항곰팡이성 항생물질의 생산하는 균주의 분리 및 동정 (Isolation and Identification of a Bacterium Producing Antifungal Antibiotic)

  • 신영준
    • 한국식품영양과학회지
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    • 제29권5호
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    • pp.832-836
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    • 2000
  • A bactirium prohibiting the growth of fungus Botrytis cineria KT 433 was isolate and identified from soil. The isolated strain was gram positive, aerobic bacteria with cream color, round and mucoid. It showed ord form of 0.45$\times$1.1 ${\mu}{\textrm}{m}$ at the cultivated for 24 hrs and the ellipsoided endospore wer observed after culting for 72 hrs. The optimum growth temperature and pH wer 35$^{\circ}C$ and pH 5.0~8.0, respectively. It could assimilate daxtrin, maltose, glucose, mannose, ribose and collobiose as a sole carbon source. The isolated was confirmed to be a Bacillus sp. strain from the findings. The antibiotic from the isolated strain was stable up to 121$^{\circ}C$. The strain, especially, showed specific activity for mold and yeast. However, there was not significant antibacterial activity.

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