• Title/Summary/Keyword: pH Sensors

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The Optimization of the Number and Positions of Foot Pressure Sensors to Develop Smart Shoes

  • Yoo, Sihyun;Gil, Hojong;Kim, Jongbin;Ryu, Jiseon;Yoon, Sukhoon;Park, Sang Kyoon
    • Journal of the Ergonomics Society of Korea
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    • v.36 no.5
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    • pp.395-409
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    • 2017
  • Objective: The purpose of this study was to optimize the number and positions of foot pressure sensors using the reliability analysis of the center of pressure (COP) in smart shoes. Background: Foot pressure can be different according to foot region, and it is important which region of the foot pressure needs to be measured. Method: Thirty adults (age: $20.5{\pm}1.8years$, body weight: $71.4{\pm}6.5kg$, height: $1.76{\pm}0.04m$) participated in this study. The foot pressure data were collected using the insole of Pedar-X system (Novel GmbH, USA) with a sampling frequency of 100Hz during 1.3m/s speed walking on the treadmill (Instrumented treadmill, Bertec, USA). The intraclass correlation coefficients (ICC) were calculated between the COP positions using 4, 5, 6, 7, 8, and 99 sensors, while one-way repeated measure ANOVA was performed between the standard deviation (SD) of the COP positions. Results: The medio-lateral (M/L) COP position using 99 sensors was positively correlated with the M/L COP positions using 6, 7, and 8 sensors; however, it was not correlated with the M/L COP positions using 4 and 5 sensors during landing phase (1~4%) (p<.05). The antero-posterior (A/P) COP position using 99 sensors was positively correlated with the A/P COP positions using 4, 5, 6, 7, and 8 sensors (p<.05). The SD of the COP position using 99 sensors was smaller than the SD of the M/L COP positions using 4, 5, 6, 7, and 8 sensors (p<.05). Conclusion: Based on our findings, it is desirable to arrange at least 6 sensors in smart shoes. Application: The study of optimizing the number and positions of foot pressure sensors would contribute to developing more effective smart shoes using foot pressure technology.

Preparation and characterization of polymeric membrane pH Sensors (고분자막 pH 센서 제작 및 특성)

  • Cho, Dong-Hoe;Jeong, Seong-Suk;Chung, Koo-Chun;Lee, Kyung-Ho;Park, Myon-Yong;Kim, Byung-Soo
    • Journal of Sensor Science and Technology
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    • v.5 no.4
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    • pp.35-40
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    • 1996
  • The polymeric membrane pH sensor based on HDBA(hexyldibenzylamine) or HDPA(hexyldiphenylamine) as hydrogen ion carrier was prepared and electrochemical characterization for the variation of a temperature and membrane thickness were studied on. The sensor based on HDPA was not responded selectively to hydrogen ion. The sensor based on HDBA was responded linearly to hydrogen ion in the range of pH 2 - pH 10, it showed the fast response time of 30 - 50sec. and Nernstian slope of 53.6mV/pH. The interfering effect on alkali and alkaline earth metal ions of pH sensor were lower than glass pH sensor. There was shown a good reproducibility and stability with the precision of 2 - 4mV (${\pm}0.1mV$).

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Development of a pH/dissolved- oxygen Monitoring System Using HPTS and Rudpp (HPTS, Rudpp를 활용한 pH 및 용존산소 모니터링 시스템 연구)

  • Dong Hyuk Jeong;Daewoong Jung
    • Journal of Sensor Science and Technology
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    • v.32 no.2
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    • pp.82-87
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    • 2023
  • This study proposes a pH-dissolved-oxygen monitoring system using 8-HydroxyPyrene-1,3,6-trisulfonic acid Trisodium Salt (HPTS) and tris(4,7-diphenyl-1,10-phenanthroline)Ruthenium(II) chloride (Rudpp). Commercial water-quality sensors are electrochemical devices that require frequent calibration and cleaning, are subject to high maintenance costs, and have difficulties conducting measurements in real-time. The proposed pH-dissolved-oxygen monitoring system selects a thin-film sensing layer to measure the change in fluorescence intensity. This change in fluorescence intensity is based on reactions with hydrogen ions in an aqueous solution at a given pH and specific amount of dissolved oxygen. The change in fluorescence intensity is then measured using light-emitting diodes and photodiodes in response to HPTS and Rudpp. This method enables the development of a relatively small, inexpensive, and real-time measureable water-quality measurement system.

Nitrogen Monoxide Gas Sensing Properties of CuO Nanorods Synthesized by a Hydrothermal Method (수열합성법으로 합성된 산화구리 나노막대의 일산화질소 가스 감지 특성)

  • Park, Soo-Jeong;Kim, Hyojin;Kim, Dojin
    • Korean Journal of Materials Research
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    • v.24 no.1
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    • pp.19-24
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    • 2014
  • We report the nitrogen monoxide (NO) gas sensing properties of p-type CuO-nanorod-based gas sensors. We synthesized the p-type CuO nanorods with breadth of about 30 nm and length of about 330 nm by a hydrothermal method using an as-deposited CuO seed layer prepared on a $Si/SiO_2$ substrate by the sputtering method. We fabricated polycrystalline CuO nanorod arrays at $80^{\circ}C$ under the hydrothermal condition of 1:1 morality ratio between copper nitrate trihydrate [$Cu(NO_2)_2{\cdot}3H_2O$] and hexamethylenetetramine ($C_6H_{12}N_4$). Structural characterizations revealed that we prepared the pure CuO nanorod array of a monoclinic crystalline structure without any obvious formation of secondary phase. It was found from the gas sensing measurements that the p-type CuO nanorod gas sensors exhibited a maximum sensitivity to NO gas in dry air at an operating temperature as low as $200^{\circ}C$. We also found that these CuO nanorod gas sensors showed reversible and reliable electrical response to NO gas at a range of operating temperatures. These results would indicate some potential applications of the p-type semiconductor CuO nanorods as promising sensing materials for gas sensors, including various types of p-n junction gas sensors.

Cost-effective structural health monitoring of FRPC parts for automotive applications

  • Mitschang, P.;Molnar, P.;Ogale, A.;Ishii, M.
    • Advanced Composite Materials
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    • v.16 no.2
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    • pp.135-149
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    • 2007
  • In the automobile industry, structural health monitoring of fiber reinforced polymer composite parts is a widespread need for maintenance before breakdown of the functional elements or a complete vehicle. High performance sensors are generally used in many of the structural health monitoring operations. Within this study, a carbon fiber sewing thread has been used as a low cost laminate failure sensing element. The experimentation plan was set up according to the electrical conductance and flexibility of carbon fiber threads, advantages of preforming operations, and sewing mechanisms. The influence of the single thread damages by changing the electrical resistance and monitoring the impact location by using carbon thread sensors has been performed. Innovative utilization of relatively cost-effective carbon threads for monitoring the delamination of metallic inserts from the basic composite laminate structure is a highlighting feature of this study.

Hydrogen and Ethanol Gas Sensing Properties of Mesoporous P-Type CuO

  • Choi, Yun-Hyuk;Han, Hyun-Soo;Shin, Sun;Shin, Seong-Sik;Hong, Kug-Sun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.222-222
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    • 2012
  • Metal oxide gas sensors based on semiconductor type have attracted a great deal of attention due to their low cost, flexible production and simple usability. However, most works have been focused on n-type oxides, while the characteristics of p-type oxide gas sensors have been barely studied. An investigation on p-type oxides is very important in that the use of them makes possible the novel sensors such as p-n diode and tandem devices. Monoclinic cupric oxide (CuO) is p-type semiconductor with narrow band gap (~1.2 eV). This is composed of abundant, nontoxic elements on earth, and thus low-cost, environment-friendly devices can be realized. However, gas sensing properties of neat CuO were rarely explored and the mechanism still remains unclear. In this work, the neat CuO layers with highly ordered mesoporous structures were prepared by a template-free, one-pot solution-based method using novel ink solutions, formulated with copper formate tetrahydrate, hexylamine and ethyl cellulose. The shear viscosity of the formulated solutions was 5.79 Pa s at a shear rate of 1 s-1. The solutions were coated on SiO2/Si substrates by spin-coating (ink) and calcined for 1 h at the temperature of $200{\sim}600^{\circ}C$ in air. The surface and cross-sectional morphologies of the formed CuO layers were observed by a focused ion beam scanning electron microscopy (FIB-SEM) and porosity was determined by image analysis using simple computer-programming. XRD analysis showed phase evolutions of the layers, depending on the calcination temperature, and thermal decompositions of the neat precursor and the formulated ink were investigated by TGA and DSC. As a result, the formation of the porous structures was attributed to the vaporization of ethyl cellulose contained in the solutions. Mesoporous CuO, formed with the ink solution, consisted of grains and pores with nano-meter size. All of them were strongly dependent on calcination temperature. Sensing properties toward H2 and C2H5OH gases were examined as a function of operating temperature. High and fast responses toward H2 and C2H5OH gases were discussed in terms of crystallinity, nonstoichiometry and morphological factors such as porosity, grain size and surface-to-volume ratio. To our knowledge, the responses toward H2 and C2H5OH gases of these CuO gas sensors are comparable to previously reported values.

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Fabrication and Evaluation of a New High-Temperature pH Sensor for Use in PWR Nuclear Power Plants

  • Jung, Yong-Ju;Yeon, Jei-Won
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2939-2942
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    • 2010
  • A new high-temperature pH sensor has been successfully developed by reforming the internal reference systems of the pH sensors based on oxygen-ion conducting ceramic membrane. The conventional internal reference system, a mixture of Ni and NiO, has been replaced with partially oxidized Ni powders, where Ni and NiO coexist on the surface of particles, in order to avoid the cumbersome mixing step of Ni and NiO particles. The partially oxidized Ni particles were made by oxidizing Ni under air atmosphere at $600^{\circ}C$ and characterized by X-ray diffraction (XRD) and FTIR spectroscopy. The viability of the pH sensor developed was assessed in boric acid (1000 ppm-B)/ lithium hydroxide (1 to 3 ppm-Li) buffer solutions at $280^{\circ}C$. The pH sensor showed excellent accuracy with a small error less than ${\pm}0.2$ pH units.

Study on Optical Characteristics of pH Indicators in the Immobilized Film for Fiber-Optic pH Sensor (광학적 pH 센서를 위한 지시염료가 고정된 필름의 광학적 특성 연구)

  • Kim, Beom Kyu;Park, Byung Gi
    • Journal of Sensor Science and Technology
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    • v.26 no.6
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    • pp.414-419
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    • 2017
  • The optical characteristics of cresol red, phenol red, and neutral red immobilized in the thin film were investigated with absorbance measurement in order to find a sensing part of a fiber-optic pH sensor. Sol-Gel method with tetramethyl orthosilicate as a precursor was used to immobilize the pH indicators in the thin film. The absorbance spectra were measured when pH indicators were immobilized in the film and were dissolved in the buffer solution. Experimental results showed that the absorbance spectra could be changed when the pH indicator is immobilized in the thin film. As compared with other pH indicators, the neutral red exhibited similar absorbance spectra regardless of physical conditions and was sensitive over whole pH range between 4 and 11. In addition, the absorbance ratio of base peak to acid peak tended to increase in proportion to the increase in pH. Experimental results indicate that the neutral red is a good pH indicator for fabrication of a sensing part of the fiber-optic pH sensor.

Capacitive Humidity Sensors using lodine-doped Polyphenylacetylene Thin Films (요오드가 도우핑된 폴리페닐아세틸렌 박막을 이용한 정전용량형 습도센서)

  • Min, Nam-Ki;Jin, Joon-Hyung;Kim, Tae-Yoon;Hong, Suk-In
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.6
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    • pp.335-340
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    • 2000
  • We report the results of a preliminary investigation on capacitive humidity sensors using iodine-doped polyphenylacetylene(PPA) thin films. PPA was prepared from phenylacetylene(PA), chemically doped with iodine, and characterized by DSC, $^1H$-NMR and FTIR spectra. The iodine-doped PPA sensors showed a sensitivity of 0.20pF/%RH, a linearity of 3.8%FS, a negligible hysteresis, and a low temperature coefficients of $0.043~0.067pF/^{\circ}C$ over a wide range of relative humidity. These results are expected to open up the possibility of iodine-doped PPA thin films as relative humidity sensors.

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A comparative investigation of pH-sensing properties of LPCVD $Si_3N_4$ sensors configured in three different structures (세 가지 다른 구조로 제작된 LPCVD $Si_3N_4$ 센서 소자의 pH 감지특성의 비교분석)

  • Shin, Paik-Kyun;Lee, Neung-Heon;Im, Heon-Chan;Kim, Jin-Sik;Park, Kang-Sik;Cho, Ki-Seon;Lee, Duck-Chool
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1694-1696
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    • 2004
  • $Si_3N_4$ 박막을 동일한 공정 파라메터로 저압 화학기상증착법(LPCVD)으로 증착하고, IS, LOCOS- IS 및 ISFET의 세 가지 각각 다른 구조로 하여 용약 중 pH 농도 감지용 센서소자를 제작하였다. 이 세 가지 다른 센서소자에 대하여 pH 농도변화에 따른 감지도, 감지특성곡선의 선형성, 히스테리시스 등 주요 특성을 각각 조사한 후 비교 분석하였다. LOCOS-IS 구조의 pH 센서는 ISFET 구조의 pH 센서와 유사한 우수한 제반 pH 감지특성을 보였으나, 간단한 IS 구조의 pH 센서는 이들에 비해 상대적으로 열악한 pH 감지특성을 보였다. 동일공정으로 제작된 Si3N4 박막으로 제작되었음에도 불구하고 간단한 IS 구조의 pH 센서의 비교적 열악한 특성을 보이는 원인을 규명하기 위하여, pH 농도 변화에 따른 C-V특성 변화에 의한 pH 감지특성 조사시의 IS 및 LOCOS-IS 구조의 정전용량의 변화를 비교하고 고찰하였다.

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