• Title/Summary/Keyword: pH 미터

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Characteristics Modeling of Junction Barrier Schottky Diodes for ultra high breakdown voltage with 4H-SiC substrate (탄화규소(4H) 기판의 초고내압용 접합 장벽 쇼트키 다이오드의 특성 모델링)

  • Song, Jae-Yeol;Bang, Uk;Kang, In-Ho;Lee, Yong-Jae
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2007.10a
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    • pp.200-203
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    • 2007
  • Devices of junction barrier schottky(JBS) structure using 4H-SiC substrates with wide energy band gaps was designed and fabricated. As a measurement results, the device of reverse I-V characteristics was shown as more than 1000 V, its design optimum length of p-grid was $3{\mu}m$ space. In this paper, I-V characteristics was modeled by using of device fabricated process conditions parameters and it was extracted that the I-V property parameters, and it was compared and analyzed with between device parameters and model parameters.

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Battery Pack Electric Equivalent Circuit Model Based Parameter Extraction and Simulation Verification (배터리 팩 전기적 등가회로 모델 기반 파라미터 추출 및 시뮬레이션 검증)

  • Park, J.H.;Lee, P.Y.;Yoon, C.O.;Kim, J.H.;Jang, S.S.
    • Proceedings of the KIPE Conference
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    • 2017.11a
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    • pp.155-156
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    • 2017
  • 본 논문에서는 단일 셀과 배터리 팩의 전기적 특성 실험 기반 내부 파라미터를 추출하고 등가회로 모델에 적용하여 시뮬레이션 및 검증을 진행하였다. 본 논문에서는 임의로 선정한 단일 셀에 대한 파라미터를 추출하여 스크리닝이 이상적으로 되었다는 가정 하에 팩 단위로 확장한다. 단일 셀에서 확장된 파라미터와 배터리 팩 자체의 파라미터를 구하여 시뮬레이션 결과를 실제 전압과 비교하여 검증한다.

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Equilibrium, Kinetic and Thermodynamic Parameter Studies on Adsorption of Acid Black 1 Using Coconut Shell-Based Granular Activated Carbon (야자각계 입상 활성탄의 Acid Black 1 염료 흡착에 대한 평형, 동역학 및 열역학 파라미터의 연구)

  • Lee, Dong-Chang;Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.590-598
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    • 2016
  • In this study, the adsorption behavior from aqueous solution as well as kinetic and thermodynamic parameters of Acid Black 1 were investigated through batch reaction using coconut shell based granular steam activated carbon. The effects of various adsorption parameters such as pH, initial concentration, contact time, temperature were studied. To confirm the effect of pH, pHpzc measurements were analyzed followed by measuring removal efficiencies of Acid Black 1 at the pH range from 3 to 11. Experimental equilibrium adsorption data were fitted using Langmuir, Freundlich, Temkin and Dubinin-Radushkevich adsorption isotherm. The conformity of adsorption reaction for pseudo first and second order model were evaluated through kinetic analysis. Values of enthalpy change and activation energy were also investigated through thermodynamic analysis and it was confirmed that the adsorption process was endothermic. The spontaneity of adsorption process was evaluated using the values of entropy and Gibbs free energy changes.

Construction of Feed-back Type Flux-gate Magnetometer (피드백형 플럭스게이트 마그네토미터 제작)

  • Son, De-Rac
    • Journal of the Korean Magnetics Society
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    • v.22 no.2
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    • pp.45-48
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    • 2012
  • Feed-back type 3-axis flux-gate magnetometer using Co-based amorphous ribbon (Metglass$^{(R)}$2714A) was constructed in this work. Measuring range of magnetic field and frequency were ${\pm}100\;{\mu}T$ and dc~10 Hz respectively. For the interface to computer, microcontroller and 24 bit ADC (Analog to Digital Converter) were employed and resolution of digital output was 0.1 nT. Magnetometer noise of analog output was 5 pT/$\sqrt{Hz}$ at 1 Hz. Digital output of the magnetometer showed linearity of $1{\times}10^{-4}$ and the offset drift was smaller than 0.2 nT during 1 h.

Studies on the Standardization of pH Measurement System (pH 측정 시스템의 표준화에 관한 연구)

  • Lee, Hwa Shim;Kim, Myung Soo;Kim, Jin Bok;Oh, Sang Hyup
    • Journal of the Korean Chemical Society
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    • v.42 no.4
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    • pp.432-442
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    • 1998
  • Since the definition of pH, $pH=-Ioga_H$ is based on a single ion activity, pH values can not be determined with measurement itself, but require an approximation method. They are derived from EMF measurement of a liquid junction free cell using hydrogen and Ag/AgCl electrodes. Primary standard materials with certified pH values can be obtained with this approximation method. Standard buffer solutions are used to calibrate pH meters. Thus the accuracy of the pH values of standard buffer solutions limits the reliability of measured pH values can be obtained with this approximation method. Standard buffer solution are used to calibrate pH meters. Thus the accuracy of the pH values of standard buffer solutions limits the reliability of measured pH values of sample solutions. To certify the pH values, we have established the system for the primary standard measurement and certified the pH of buffer solutions in the range of 1.6∼12.5 pH unit within uncertainty of ${\pm}0.005$ pH unit.

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Determination of Optimum pH of Enzyme by Electrochemical Method (전기화학적 방법에 의한 효소의 최적 pH 결정)

  • Yoon, Kil-Joong;Lee, Beom-Gyu;Kwon, Hyo-Shik
    • Analytical Science and Technology
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    • v.13 no.1
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    • pp.41-48
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    • 2000
  • A biosensor for the determination of hydrogen peroxide was constructed by immobilizing of porcine small instestinal tissue in a plain carbon paste, and the effect of varying the $H_2O_2$ concentration and pH on the rate of catalytic reaction was evaluated. For the mathematical simplicity, no mediator was added. Electrochemical properties and the maximal rate could be derived from the quantitative analysis of the observed phenomena related to the electrode reaction. Also, pH dependence of the Michaelis constant enabled to calculate various thermodynamic parameters and subsequently to design a electrochemical method to determine the optimum pH of enzyme.

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The Assessment of pH Variation for Neutralized Acidic Areas using Lysimeters by Seasons (라이시미터를 이용한 중화처리된 산성화경사지의 계절별 pH 용탈특성 평가)

  • Oh, Seungjin;Oh, Minah;Park, Chan-O;Jung, Munho;Lee, Jai-Young
    • Journal of the Korean Geosynthetics Society
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    • v.14 no.4
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    • pp.79-86
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    • 2015
  • Korean territories has formed about 70% of mountainous areas that have acidified serious level to average pH 4-5. There are a number of abandoned metal mines about 1,000 in Korea. However, mine tailings and waste rock included heavy metals are exposed to long-term environment without prevention facility or treatment system. Thus, ongoing management and monitoring of soil environment are required. Most of abandoned mine scattered in forest areas of slopes. Soil erosion due to continuous rainfall in the slopy areas can cause the secondary pollution by the influence eutrophication of water system and the productivity loss of the plant. Therefore, this study would like to estimate pH leaching rate by artificial rainfall using waste neutralization-agent in lysimeter. Moreover, the potentially of secondary pollution related to precipitation is figured out through the experiments, and the optimal planting methods would examinate after neutralizing treatment in soil. Experiments composed three kinds of lysimeter; lysimeter 1 had filled only acidic soil, lysimeter 2 had neutralized soil, and lysimeter 3 had planting plants after neutralized soil. In the results, lysimeter 2 showed the lowest pH leaching, and there is not specific relativity with pH leaching of the seasonal characteristics.

Hydrolysis Mechanism of N-(benzoyl)-C-(N-methylanilino)imidoylchloride Derivatives (N-(benzoyl)-C-(N-methylanilino)imidoylchloride 유도체의 가수분해 반응메카니즘)

  • Kwon Ki-Sung;Lee Yong-Gu;Sung Nack-Do;Kim Chon-Suk
    • Journal of the Korean Chemical Society
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    • v.37 no.6
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    • pp.618-625
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    • 1993
  • Rate constants of hydrolysis of N-(benzoyl)-C-(N-methylanilino)imidoylchlorides were determined by UV spectrophotometry in 50% (v/v) aqueous methanol at 25$^{\circ}C$. On the basis of rate equation, substituent effect, solvent effect, salt effect, thermodynamic parameters and hydrolysis product analysis, it may be concluded that the hydrolysis of N-(benzoyl)-C-(N-methylanilino)imidoylchlorides proceed through $S_N$1 mechanism via azocarbonium ion intermediate in the range of from pH 3.0 to pH 10.0, while above pH 10.0 and below pH 3.0 the hydrolysis proceeds through nucleophilic addition-elimination (A$d_{N-E}$) mechanism.

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Construction of Differential Type Search Coil Magnetometer (차동형 탐지코일 마그네토미터 제작)

  • Kim, J.H.;Son, De-Rac
    • Journal of the Korean Magnetics Society
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    • v.20 no.5
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    • pp.178-181
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    • 2010
  • Search coil magnetometer has been used for detection of ac magnetic field with high sensitivity. To reduce demagnetizing factor of core and increase S/N ratio of search coil magnetometer, the core was divided by two parts and coil was wound on each cores. Two coils were connected serially and put into amplifier as differential mode. Constructed 120 mm length search coil magnetometer shows linearity of 0.03%, sensitivity of 9.3 mV/nT, and resolution of 20 pT at 1 Hz.

Self Compensating Flux-gate Magnetometer Using Microcomputer (마이크로컴퓨터를 이용한 자체 보상형 flux-gate 마그네토미터제작)

  • Ga, E.M.;Son, D.;Son, D.H.
    • Journal of the Korean Magnetics Society
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    • v.12 no.4
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    • pp.149-153
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    • 2002
  • Flux-gate magnetometer has been still used for low field magnetic field measurement with portability, low power consumption, and high reliability. In many applications, flux-gate magnetometer measures not absolute values but changes of the earth magnetic field. For the eia magnetic field change measurements, we have constructed a high sensitive 3-axis flux-gate magnetometer of which measuring ranges is ${\pm}$1000 nT and noise level is 5pT/√㎐ at 1 ㎐. Using this magnetometer, we can compensate the earth magnetic field of ${\pm}$50,000 nT with successive approximation methods using microcomputer. After earth magnetic field compensation, we could measure earth magnetic field changes with ${\pm}$100 nT measuring ranges.