• Textile Coloration and Finishing
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• v.27 no.4
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• pp.281-287
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• 2015

The aim of this study was to investigate the possibility utilizing Metasequoia(Metasequoia glyptostroboides) cone as a new natural dye resource. In previous study, dyeing onto cotton fiber was carried out and Metasequoia cone colorant showed low affinity to cotton fiber and maximum dye uptake was obtained at pH 3.5 showing YR Munsell color. For further evaluation of its efficacy as a new natural dye resource, effects of dyeing conditions and mordanting on dye uptake, color change, and colorfastness were investigated for silk fiber. Metasequoia cone colorant showed good affinity toward silk fiber showing YR Munsell color and maximum dye uptake was shown at pH 3.5. Post-mordanting with Cu and Fe improved dye uptake, especially Fe($C_5H_{10}FeO_6$) mordant was effective as much as 2 times higher dye uptake comparing with un-mordanted sample. The color of dyed fabrics with mordanting showed YR Munsell color. Fe mordanted fabrics appeared dark gray~black color. Colorfastness to washing was relatively good, whereas lightfastness of the dyed fabrics showed grade 2. It was confirmed that Metasequoia cone colorant can be used as a new dye resource for silk fiber getting brownish yellow to dark gray/black color depending on mordant type. In addition, it showed antimicrobial functionality.

• Magazine of the Korean Society of Agricultural Engineers
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• v.39 no.3
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• pp.96-107
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• 1997

This study was carried out to examine the physicochemical characteristics of dredged soils in reservoirs. Surveys and analyses of basic materials were made on 241 of 2,328 reservoirs in Chonbuk province through 2 years from December 1994 to November 1996. The results of this study are summarized as follows : 1. Soils were classified as 15 types according to physical properties, and some soils contain comparatively high percentage of sand and gravel. Considering only soil textures, useful and economical soils as aggregate are approximately 25% in all, and the other soils are arable for farm planting. 2. The results of chemical analyses of soils showed on the average 5.9 in pH, 1.lmmhos/cm in ECe, 14.6me/l00g in CEC, 460.0ppm in T-N, 119.0ppm in T-P, 264.9ppm in K, 134.2ppm in Na, l,335.0ppm in Ca, 575.9ppm in Mg, 486.Sppm in Fe, 57.7ppm in Mn, 3.3ppm in Cu, 21.9ppm in Zn, 0.49ppm in As, 0.34ppm in Cd, 0.O3ppm in Hg, 1.7% in OM, respectively. 3. General chemical components, heavy metals, organic matter contents were analyzed as similar to tlie mean values of common soils, therefore it was considered to be no significant effects on crop growth in the chemical properties. 4. Accodingly, the physicochemical characteristics of soils ought to be analyzed accurately before dredging for effective using of dredged soils. And it will be more effective, if the dredged soils are used with proper balance among each content of components with considering to the physicochemical properties of common soils.

• Journal of Electrochemical Science and Technology
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• v.7 no.4
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• pp.298-305
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• 2016

The development of non-precious metal based electrocatalysts is highly desired for the oxygen reduction reaction (ORR) as alternates to noble metal based ORR electrocatalysts. Herein, we report mononulcear copper(II) complex $[CuLbpy]ClO_4$ (L=4-[(2-hydroxyphenylimino)methyl]benzoic acid) containing poly(allylamine.HCl) polymer (PAlACuLbpy) as an electrocatalyst for oxygen reduction reaction (ORR). PAlACuLbpy was mixed with poly(acrylic acid) and tetraethylortho silicate to prepare a composite and then deposited on the screen printed electrode surface. The modified electrode (PAlACuLbpy/PCE) is highly stable and showed a quasi-reversible redox behavior with $E_{1/2}=-0.2V$ vs. Ag/AgCl(3 M KCl) in 0.1 M phosphate buffer at pH 7 under argon atmosphere. PAlACuLbpy/PCE exhibited a remarkable ORR activity with an onset potential of -0.1 V vs Ag/AgCl in 0.1 M PB (pH 7) in the presence of oxygen. The kinetics for ORR was studied by rotating disk voltammetry in neutral aqueous medium and the results indicated that the number of electrons involving in the ORR is four and the conversion products are water and hydrogen peroxide.

• Culinary science and hospitality research
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• v.17 no.1
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• pp.208-217
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• 2011

This study explores the antioxidant activity of solvent extracts from Vitis coignetiea skins, and the result is as follows. Total phenolic compound and flavonoids contents were the highest in ethyl acetate extract, $53.4{\pm}1.2\;mg$/100 g and $644.7{\pm}3.7\;mg$/100 g, respectively. Electron donating abilities of solvent extracts from Vitis coignetiea skin were proportionally increased with concentration and ethyl acetate extract ($80.93{\pm}0.58%$) showed the higher activity than BHT($63.21{\pm}0.72%$) at concentration of $50\;{\mu}l$/mL. Reducing power of solvent extracts from Vitis coignetiea skin was the highest in ethyl acetate extract(1.769) at concentration of $1,000\;{\mu}l$/mL. TBARS of ethyl acetate extract was higher than ascorbic acid. Nitrite scavenging ability of solvent extracts from Vitis coignetiea skin(pH 1.2, $1,000\;{\mu}l$/mL) was the highest in ethyl acetate extract($92.5{\pm}2.4%$).

• Resources Recycling
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• v.9 no.4
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• pp.16-27
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• 2000

In order to produce raw material powder of advanced magnetic material by spray roasting process, newly modified spray roasting system was developed in this work. In this spray roasting system, raw material solution was effectively atomized and sprayed into the reaction furnace. Also, uniform temperature distribution inside reaction furnace made thermal decomposition process fully completed, and produced powder was effectively collected in cyclone and bag filter. This system equipped with apparatus which can purify hazard produced gas. In this study complex acid solution was prepared by dissolution of mill scale and ferro-Mn into the acid solution, and the pH of this complex acid solution was controlled about to 4. It was conformed that mill scale and ferro-Mn containing a lot of impurities such as $SiO_2$, P and Al could be used as raw material by reducing the impurities content of complex acid solution below 20 ppm. Complex oxide powder of Fe-Mn system was produced by spraying purified complex acid solution into the spray roaster through nozzle, and the variations of produced powder characters were studied by changing he reaction conditions such as reaction temperature, the injection velocity of solution and air, nozzle tip size and concentration of solution. The morphology of produced powder had spherical shape under the most experimental conditions, and concentration of solution. The morphology of produced powder has spherical shape under the most experimental conditions, and the composition and the particle size distribution were almost uniform, which tells the excellence of this spray roasting system. The grain size of most produced powder was below 100 nm. From the above results, it will be possible to produce ultra fine oxide powder from the chloride of Fe, Mn, Ni, Cu and rare earth by using this spray roasting system, and also to produce ultra fine pure metal powder by changing reaction atmosphere.

• Conservation Science in Museum
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• v.30
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• pp.23-46
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• 2023

The Jija Chongtong Gun, owned by Seokdang Museum of Dong-A University, is a tubedstyle heavy weapon of the battlefield in the mid-Joseon Dynasty and is the second largest firearm after Cheonja Chongtong. The original surface color of the Jija Chongtong Gun was obscured by foreign substances and therefore it was judged that its condition requires the conservation treatment. For stable conservation treatment, gamma ray and X-ray non-destructive transmission surveys was conducted to determine the internal structure and conservation condition. And the component analysis on the material components and surface contaminants of Jija Chongtong Gun was conducted by utilizing the p-XRF component analysis, SEM-EDS component analysis, and XRD analysis. As a result of the gamma-ray and X-ray non-destructive transmission investigation, a large amount of air bubbles was observed inside Jija Chongtong Gun, and the part that appeared to be a chaplet by visual observation was not identified. As a result of gamma-ray and p-XRF component analysis, it was confirmed that Jija Chongtong Gun was bronze made of copper (Cu), tin (Sn), and lead (Pb) alloy. As a result of surface analysis of foreign substances using SEM-EDS, it was confirmed that the main components of white foreign substances were calcium (Ca), sulfur (S), and titanium (Ti). Titanium was presumed to be titanium dioxide (TiO₂), the main component of white correction fluid. The red foreign substance was confirmed to contain barium (Ba) as its main ingredient, and was presumed to be barium sulfate (BaSO₄), an extender pigment in paint. White and red contaminants, mainly composed of titanium and barium, are presumed to have been deposited on the surface in recent years. The yellow foreign substances were confirmed to be aluminum (Al) and silicon (Si), and were presumed to have originated from soil components. As a result of SEM-EDS and XRD component analysis, the white foreign substance was confirmed to be gypsum (CaS). Based on the results of component analysis, surface impurities were removed, stabilization treatment, and strengthening treatment were performed. During the conservation process, unknown inscriptions Woo (右), Byeong (兵), Sang (上), and Yi (二) were discovered through a portable microscope and precise 3D scanning. In addition, the carving method, depth, and width of the inscription were measured. Woo Byeong Sang is located above Happo Fortress in Changwon, and Yi can be identified as the second hill.

• Microbiology and Biotechnology Letters
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• v.15 no.2
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• pp.129-134
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• 1987

Aspergillus sp. (MK-24) producing a biological active substance that inhibited the venom proteinase activity was isolated from soil. The substance also inhibited the activity of trypsin and coagulation of blood, but did not inhibit papain, $\alpha$-chymotrypsin and pepsin. The substance was partially purified from culture filtrate by precipitaion with acetone, and by chromatography of DEAE-Sepadex A-50 column and Amberlite IRC-50 ion exchange. The inhibitory substance was stable in the wide pH range from 2.0 to 12.0 at 37$^{\circ}C$, but not stable at $65^{\circ}C$ in the alkaline pH. Only 12% of the activity was decreased by the heat treatment at 10$0^{\circ}C$ for two hours. The inhibition on venom proteinase (Agkistrodon bromohoffi brevicaudus) was a mixed type. The inhibitory activity depended on the preincubation time and completely depressed by cupric, zinc and cobalt ions. The inhibition on the venom proteinase was appeared strongly on casein but not on ovalbumin or hemoglobin as a substrate.

• Korean Journal of Heritage: History & Science
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• v.45 no.3
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• pp.212-223
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• 2012

Pigments used paintings, ornaments, weapons and various objects have been recognised as important elements to ascertain the history, manufacturing technique and cultural migration. Since the understanding of composition of pigments by analysis began in 1963, its technique and methodology has much advanced in recent years; recent study used the portable X-ray Fluorescence as non-destructive analysis has been practiced in particular. However the study on pigments necessitates overall and systematic research because it is difficult to understand periodical and regional use of pigments. by fractional studies. Therefore this research investigates the coloring materials and painting techniques of the scroll painting depicting preaching scene of Sakyamuni Buddha in Daeungjeon Hall, a main hall of Bulguk temple, through scientific analysis and comparison of various pigments which had been applied to the buddhist paintings of Joseon Dynasty. Consequently, it is confirmed that the scroll painting used pigments of white lead[$2PbCO_3{\cdot}Pb(OH)_2$] for ground layer and used mixture of different pigments such as cinnabar (HgS) minium($Pb_3O_4$) malachite($2CuO{\cdot}CO_2{\cdot}H_2O$) hematite($Fe_2O_3$) gold(Ag) for presenting various colors on the painting layer. It has been also believed that mineral pigments were applied to the scroll painting, yet it is difficult to confirm whether it is natural or synthetic pigments because the crystal structures of pigments were not analyzed. The results of this study, however, provide useful reference data for the understanding of the components of pigments and manufacturing techniques of buddhist scroll paintings, in particular, of Joseon Dynasty.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.3
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• pp.393-398
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• 2012

We investigated the changes in chemical properties of paddy field soils at 300 different sampling sites containing 4 topography in Jeonbuk province, Korea. The soil samples were collected 43.0% from local valley and fans, 39.3% from fluvio-marine deposits, 15.0% from alluvial plains, and 2.7% from diluvium sites. The optimal values of soil properties in the total soil samples were as follows: 65.3% of total samples in soil pH value, 48.3% of total samples in cation exchange capacity (CEC) value, and 22.3% of total samples in available phosphorus content, whereas the deficient values of soil properties were 63.3% of total samples in soil organic matter (SOM) content, 75.7% of total samples in available silicate content, and 61.3%, 51.0%, and 59.3% of total samples in exchangeable $K^+$, $Ca^{2+}$, and $Mg^{2+}$ concentrations, respectively. There were different soil types in the paddy fields: that is, 34.4% immature paddy and 33.6% sandy paddy in the local valley and fans, 57.8% sandy paddy in the alluvial plains, 47.4% normal paddy in the fluvio-marine deposits, and 75.7% immature paddy in the diluvium. Soil textures were also different: 53.5% loam in the local valley and fans, 37.8% sandy loam in the alluvial plains, and 55.1% silty loam in the fluvio-marine deposits. Soil pH and SOM contents were not different among the different topographical sampling sites. However, the mean value of available phosphorus content, 224 mg $kg^{-1}$, was exceeded optimal values in the diluvium. The contents of exchangeable cations were optimal in all the sites, except exchangeable $Ca^{2+}$ contents in the local valley and fans. The contents of available silicate ranged between 112 and 127 mg $kg^{-1}$ in all the sites, which were lower than optimal value. In addition, soil pH values were proportionally correlated to the order of available silicate, exchangeable $Ca^{2+}$, $Mg^{2+}$, $Na^+$, CEC, and exchangeable $K^+$. The contents of SOM were proportionally correlated to the order of CEC, available $P_2O_5$, exchangeable $Ca^{2+}$, and available silicate. The contents of heavy metals, Cd, Cr, Cu, Ni, Pb, and Zn, were only 10% of the threshold levels of the metals, and As content was about 20 to 30% of the threshold level.

• Korean Journal of Soil Science and Fertilizer
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• v.32 no.2
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• pp.123-131
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• 1999

To get the basic information for the improvement of the optimum levels of upland soil fertility and fertilizer application, the soil samples in two hundred fifteen site were collected from the major condiment vegetable cultivation areas such as red pepper, garlic and onion fields. Physico-chemical properties of the soil samples were investigated. Soil texture distribution of soil samples in red pepper, garlic and onion cultivation areas was in order of loam (L), sandy loam (SL), silt loam (SiL) and clay loam (CL) (35.4, 31.6, 14.9 and 7.0%, respectively). The average pH of soil in garlic and onion cultivation areas were over pH 6.0, whereas in red pepper was under pH 5.5. The frequency distribution of soil pH in total sampling sites were 58.7% in under pH 6.0 and 21.4% in below pH 5.0, in contrast to 10.3% in over pH 7.0. The organic matter contents were in the range of $20{\sim}30g\;kg^{-1}$, and the onion field soils was a little higher than those in red pepper or garlic. The available phosphate contents were in the range of $719{\sim}746mg\;kg^{-1}$ and were not different among in red pepper, garlic and onion. The frequency distribution of available phosphate in total sampling sites were found 62.8% of above $600mg\;kg^{-1}$, which was over the standard level for upland soil improvement, and then 22.3% was exceeded $1,000mg\;kg^{-1}$, especially. In the exchangeable cations, the K and Ca contents in garlic (1.27 and $9.11cmol\;kg^{-1}$) and onion (1.20 and $8.39cmol\;kg^{-1}$) were higher than in red pepper (0.96 and $5.87cmol\;kg^{-1}$), respectively. The Mg contents in garlic field soils ($2.17cmol\;kg^{-1}$) were higher than those in red pepper and onion (1.51 and $1.80cmol\;kg^{-1}$). This exchangeable K, Ca and Mg contents were higher than the standard level for upland soil improvement. The contents of microelement were ranged in $54.3{\sim}60.1mg\;kg^{-1}$ for Fe, $31.3{\sim}42.3mg\;kg^{-1}$ for Mn, $1.7{\sim}2.3mg\;kg^{-1}$ for Cu and $4.8{\sim}5.5mg\;kg^{-1}$ for Zn, respectively.