• Korean Journal of Materials Research
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• v.33 no.11
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• pp.475-481
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• 2023

Recently, the electron transport layer (ETL) has become one of the key components for high-performance perovskite solar cell (PSC). This study is motivated by the nonreproducible performance of ETL made of spin coated SnO₂ applied to a PSC. We made a comparative study between tin oxide deposited by atomic layer deposition (ALD) or spin coating to be used as an ETL in N-I-P PSC. 15 nm-thick Tin oxide thin films were deposited by ALD using tetrakisdimethylanmiotin (TDMASn) and using reactant ozone at 120 ℃. PSC using ALD SnO₂ as ETL showed a maximum efficiency of 18.97 %, and PSC using spin coated SnO₂ showed a maximum efficiency of 18.46 %. This is because the short circuit current (Jsc) of PSC using the ALD SnO₂ layer was 0.75 mA/cm² higher than that of the spin coated SnO₂. This result can be attributed to the fact that the electron transfer distance from the perovskite is constant due to the thickness uniformity of ALD SnO₂. Therefore ALD SnO₂ is a candidate as a ETL for use in PSC vacuum deposition.

• Current Photovoltaic Research
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• v.12 no.1
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• pp.1-5
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• 2024

Perovskite solar cells have exhibited a remarkable increase in efficiency from an initial 3.8% to 26.1%, marking a significant advancement. However, challenges persist in the commercialization of perovskite solar cells due to their low stability with respect to humidity, light exposure, and temperature. Moreover, the instability of the organic charge transport layer underscores the need for exploring inorganic alternatives. In the manufacturing process of the perovskite solar cells' oxide charge transport layer, ultraviolet-ozone (UVO) treatment is commonly applied to enhance the wettability of the perovskite solution. The UVO treatment on metal oxides has proven effective in suppressing surface oxygen vacancies and removing surface organic contaminants. This study focused on the characterization of nickel oxide as the hole transport material in perovskite solar cells, specifically investigating the impact of UVO treatment on film properties. Through this analysis, changes induced by the UVO treatment were observed, and consequent alterations in the device characteristics were identified.

• Journal of the korean society of oceanography
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• v.33 no.3
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• pp.123-135
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• 1998

Cooperative scientific research in Antarctic has been successful since the International Geophysical Year 1957/1958. Presently, 43 nations have joined the Antarctic Treaty as consultative parties or acceding states, and other treaties and agreements have evolved to conserve the integrity and to manage the resources of the Antarctic ecosystem. Although yet to be designated, tourism areas in Antarctica are under consideration. Due to its remoteness and vast magnitude, Antarctica's science is slowly emerging. Satellite technology has enabled observation of the progression of the ozone hole above Antarctica. Mineral exploitation has yet to take place, as has the transport of Antarctic icebergs to some arid nations. On the other hand, both seal and whale exploitations have occurred, devastating these populations. The lessons learned from past human greed are used to design krill and squid fisheries, though the life histories of these organisms are yet to be adequately understood. An ecosystem approach to managing Antarctic resource exploitation is essential. Procuring the needed logistics to do so is daunting, requiring the highest degree of international cooperation and educational outreach to nurture the needed effective scientific and engineering talent, both natural and social.

• Proceedings of the KSME Conference
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• 2001.06e
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• pp.524-529
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• 2001

Because of the ozone layer depletion and global wanning, new alternative refrigerants are being developed. Among them, HFC refrigerants are thought promising, but some European countries are arguing that these refrigerants are also harmful to the global wanning. Therefore, natural refrigerants should be considered as an eventual alternative in refrigerators and heat pumps. In the present study, the supercritical gas cooling process are computationally analysed by employing various turbulence models of carbon dioxide in a trans critical refrigeration cycle. The gas cooling process near the critical point experiences a drastic change in thermodynamic and transport properties, thus the heat transfer characteristics would be different from those of two or single phases. Based on the computational results, the correlations to estimate the near-critical heat transfer characteristics will are obtained.

• Bulletin of the Korean Space Science Society
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• 2011.04a
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• pp.28.1-28.1
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• 2011

Radiation-induced displacement damage which has caused the increase of the dark current in the focal plane adopted in the Ozone Monitoring Instrument (OMI) was studied in regards of the primary protons and the secondaries generated by the protons in the orbit. By using the Monte Carlo N-Particle Transport Code System (MCNPX) version 2.4.0 along with the Stopping and Range of Ions in Matter version 2010 (SRIM2010), effects of the primary protons as well as secondary particles including neutron, electron, and photon were investigated. After their doses and fluxes that reached onto the charge-coupled device (CCD) were examined, displacement damage induced by major sources was presented.

• Journal of the Korean Society of Safety
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• v.23 no.5
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• pp.49-53
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• 2008

Glow discharge has lots of attractive properties, such as lower discharge sustaining voltage, no generation of ozone, and so on. And more, ionizer was developed recently using an atmospheric pressure glow discharge. On the other hand, ionizer needs a compressed or blown air to transport ion for charged objects. This air is very useful in explosive hazardous area to prevent the explosion of flammable gas and/or vapor by ignition sources, e.g. electrical spark. In this paper, we investigated the ionizing characteristic of atmospheric pressure glow discharge by controlled air flow rate from 5 liters to 60 liters a minute, and compared with decay time between the corona discharge and glow discharge as a function of some direction and distance from discharge ion source. We confirmed that an air flow rate needs 25 liters a minute to sustain the most suitable atmospheric pressure glow discharge and to increase an ionizing efficiency.

• Journal of Korean Society for Atmospheric Environment
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• v.28 no.3
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• pp.249-260
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• 2012

Monitoring of climate change and atmospheric environment by satellite measurements has been increased in recent years. In this study, nitrogen dioxide ($NO_2$) measurements from Ozone Monitoring Instrument (OMI) were compared with surface measurements over the Korean peninsula. $NO_2$ from OMI measurements showed high values and also showed seasonal variations such as high concentration in winter and low in summer over metropolitan areas while $NO_2$ concentration at national background station was low and did not clearly show seasonal variations. Surface measurements showed similar temporal and spatial variations to those of satellite measurement. The comparison between satellite measurements and surface measurements showed that the correlation between them was higher in urban area (r=0.64 at Seoul and r=0.63 at Daegu) than in national background stations (r=0.37 at Jeju) because the concentration in urban area was relatively high so that the variation of $NO_2$ concentration could be detected better than at national background stations by satellite. Satellite can effectively measure the emission and transport of pollutants with no limitations in spatial coverage.

• Advances in aircraft and spacecraft science
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• v.1 no.3
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• pp.311-330
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• 2014

Environmental impact of aircraft emissions can be addressed in two ways. Air quality impact occurs during landings and takeoffs while in-flight impact during climbs and cruises influences climate change, ozone and UV-radiation. The aim of this paper is to investigate airports related local emissions and fuel consumption (FC). It gives flight path optimization model linked to a dispersion model as well as numerical methods. Operational factors are considered and the cost function integrates objectives taking into account FC and induced pollutant concentrations. We have compared pollutants emitted and their reduction during LTO cycles, optimized flight path and with analysis by Dopelheuer. Pollutants appearing from incomplete and complete combustion processes have been discussed. Because of calculation difficulties, no assessment has been made for the soot, $H_2O$ and $PM_{2.5}$. In addition, because of the low reliability of models quantifying pollutant emissions of the APU, an empirical evaluation has been done. This is based on Benson's fuel flow method. A new model, giving FC and predicting the in-flight emissions, has been developed. It fits with the Boeing FC model. We confirm that FC can be reduced by 3% for takeoffs and 27% for landings. This contributes to analyze the intelligent fuel gauge computing the in-flight fuel flow. Further research is needed to define the role of $NO_x$ which is emitted during the combustion process derived from the ambient air, not the fuel. Models are needed for analyzing the effects of fleet composition and engine combinations on emission factors and fuel flow assessment.

• Asian Journal of Atmospheric Environment
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• v.4 no.3
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• pp.150-156
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• 2010

Inter-comparison of chemical transport models (CTMs) was conducted among four modeling research groups. Model performance of the ensemble approach to $O_3$ and $PM_{2.5}$ simulation was evaluated by using observational data with a time resolution of 1 or 6 hours at four sites in the Kanto area, Japan, in summer 2007. All groups applied the Community Multiscale Air Quality model. The ensemble average of the four CTMs reproduced well the temporal variation of $O_3$ (r=0.65-0.85) and the daily maximum $O_3$ concentration within a factor of 1.3. By contrast, it underestimated $PM_{2.5}$ concentrations by a factor of 1.4-2, and did not reproduce the $PM_{2.5}$ temporal variation at two suburban sites (r=~0.2). The ensemble average improved the simulation of ${SO_4}^{2-}$, ${NO_3}^-$, and ${NH_4}^+$, whose production pathways are well known. In particular, the ensemble approach effectively simulated ${NO_3}^-$, despite the large variability among CTMs (up to a factor of 10). However, the ensemble average did not improve the simulation of organic aerosols (OAs), underestimating their concentrations by a factor of 5. The contribution of OAs to $PM_{2.5}$ (36-39%) was large, so improvement of the OA simulation model is essential to improve the $PM_{2.5}$ simulation.

• Fire Science and Engineering
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• v.19 no.2 s.58
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• pp.29-36
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• 2005

We carried out discharge and fire extinguishing tests of new inert gas clean agent, which consists of $92\%$ nitrogen and $8\%$ carbon dioxide, as an alternative of Halon that is banned by Montreal Protocol to protect the ozone layer of the earth. Discharge and fire extinguishing tests were performed in $27m^3$ and $190m^3$ rooms with piping which allows gaseous agent to transport from storage to test rooms. We confirmed that it took less than regulation time, 60 seconds for the discharge of over $95\%$ initial charged amounts. Discharge test variables were piping length and orifice size. Fire extinguishing tests verified that this new inert gas clean agent is suitable for both n-Heptane fire and deep seated fire of wood crib.