• Title/Summary/Keyword: ozone transport

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The Detection of Yellow Sand with Satellite Infrared bands

  • Ha, Jong-Sung;Kim, Jae-Hwan;Lee, Hyun-Jin
    • Korean Journal of Remote Sensing
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    • v.22 no.5
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    • pp.403-406
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    • 2006
  • An algorithm for detection of yellow sand aerosols has been developed with infrared bands. This algorithm is a hybrid algorithm that has used two methods combined. The first method used the differential absorption in brightness temperature difference between $11{\mu}m\;and\;12{\mu}m\;(BTD1)$. The radiation at $11{\mu}m$ is absorbed more than at $12{\mu}m$ when yellow sand is loaded in the atmosphere, whereas it will be the other way around when cloud is present. The second method uses the brightness temperature difference between $3.7{\mu}m\;and\;11{\mu}m(BTD2)$. This technique is sensitive to dust loading, which the BTD2 is enhanced by reflection of $3.7{\mu}m$ solar radiation. First the Principle Component Analysis (PCA), a form of eigenvector statistical analysis from the two methods, is performed and the aerosol pixel with the lowest 10% of the eigenvalue is eliminated. Then the aerosol index (AI) from the combination of BTD 1 and 2 is derived. We applied this method to Multi-functional Transport Satellite-l Replacement (MTSAT-1R) data and obtained that the derived AI showed remarkably good agreements with Ozone Mapping Instrument (OMI) AI and Moderate Resolution Imaging Spectroradiometer (MODIS) aerosol optical depth.

Long-Range Transported SO2 Inflow fromAsian Continent to Korea Peninsula Using OMI SO2 Data and HYSPLIT Backward Trajectory Calculations (OMI 이산화황자료와 HYSPLIT 역궤적 계산을 이용한 동북아지역의 장거리 수송되는 이산화황 유입량 산출)

  • Park, Junsung;Hong, Hyunkee;Choi, Wonei;Lee, Hanlim
    • Korean Journal of Remote Sensing
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    • v.30 no.6
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    • pp.743-754
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    • 2014
  • In this present paper, we, for the first time, calculated $SO_2$ inflow from China to Korea peninsula based on OMI $SO_2$ products and HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory Model) backward trajectory calculations. The major factors used to estimate $SO_2$ flux are long range transported $SO_2$ concentration, transport speed of air mass, and thickness of transported air mass layer. The mean and maximum $SO_2$ fluxes are estimated to be 0.81 and $2.11g{\cdot}m^{-2}{\cdot}h^{-1}$, respectively based on OMI products while, those of $SO_2$ fluxes are 0.50 and $1.18g{\cdot}m^{-2}{\cdot}h^{-1}$ respectively using insitu data obtained at the surface. For most cases, larger $SO_2$ inflow values were found at the surface than those estimated for the air mass layer which extends from surface up to 1.5 km. However, increased transport speed of air mass leads to the enhanced $SO_2$ flux at the altitude up to 1.5 km at the receptor sites. Additionally, we calculate uncertainties of $SO_2$ flux using error propagation method.

OXIDES OF NITROGEN SPECIES MEASUREMENTS AND ANALYSIS IN THE CENTRAL PIEDMONT OF NORTH CAROLINA, U.S.A.

  • Kim, Deug-Soo;Viney P. Aneja
    • Journal of Korean Society for Atmospheric Environment
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    • v.10 no.E
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    • pp.311-324
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    • 1994
  • The quantitative knowledge of N $O_{\gamma}$ (=N $O_{x}$ +HN $O_3$+/PAN+N $O_3$$N_2$ $O_{5}$ +HN $O_2$+N $O_3$$^{-10}$ +organic nitrates+......)distribution is essential in tropospheric chemistry, especially, especially that related to understanding the processes leading to ozone production. Ambient concentrations of NO, N $O_2$, HN $O_3$ and PAN as well as total N $O_{\gamma}$ were measured during June and early July 1992 at a rural site(Candor, NC), in the central Piedmont region of NC. The measurements of N $O_{\gamma}$ species were made in an effort to provide a comprehensive understanding of nitrogen chemistry and to investigate the total nitrogen budget at the site. N $O_{\gamma}$, N $O_2$, and NO showed diurnal variations with maxima in the morning. The maximum N $O_{\gamma}$ concentration reached was 14.5 ppbv, and the maximum concentrations of NO and N $O_2$ were 5.4 and 7.8 PPbv, respectively. The mean N $O_{\gamma}$ concentration as found to be 2.88$\pm$1.58 ppbv(n=743). The mean concentrations of NO and N $O_2$, were found to be 0.15 $\pm$ 0.29 ppbv(n=785) and 1.31 $\pm$ 0.99 ppbv(n=769). Products of photochemical oxidants, (N <$O_{\gamma}$-N $O_{x}$ ), such as HN $O_3$ and PAN, as well as ozone showed diurnal variation with maxima in the afternoon and minima at night The fractions of individual reactive nitrogen species to total N $O_{\gamma}$ were investigated and contrasted to the results from remote marine site and rural continental sites. N $O_{x}$ was the major species to total N $O_{\gamma}$(45%). NO concentrations appeared to be nearly constant whether the Prevailing winds were from continental areas or from oceanic areas. Linear regression of $O_3$ with (N $O_{\gamma}$- N $O_{x}$ )/N $O_{\gamma}$ (i.e. percent N $O_{x}$ converted to the photochemical products of N $O_{\gamma}$) yielded ( $O_3$) =25.8 〔 N $O_{\gamma}$-N $O_{x}$ 〕/(N $O_{\gamma}$) +27, ( $r^{2}$=0.58). The regression intercept is interpreted as the ozone back ground (intercept=27ppbv) and the slope suggests that 8.6 molecules of ozone are formed per molecule of N $O_{x}$ oxidized products (when the average N $O_{\gamma}$ concentration, about 3 ppbv at the site, is used). The N $O_{x}$ N $O_{\gamma}$ ratio was used as an indicator of the chemical age of airmasses and the ratio showed strong positive correlations with HN $O_3$( $r^{2}$=0.58), PAN ( $r^{2}$=0.46) and $O_3$( $r^{2}$=0.62). Larger N $O_{\gamma}$ and N $O_{x}$ N $O_{\gamma}$ ratio were found when winds came from continental sides. It may suggest that synoptic meteorological conditions and transport of N $O_{x}$ are important in the distribution of N $O_{\gamma}$ and its relationship with photochemical oxidants at the site.

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Characteristics of Atmospheric Speciated Gaseous Mercury in Chuncheon, Korea (춘천시 대기 중 가스상 수은 종 농도 특성에 관한 연구)

  • Gan, Sun-Yeong;Yi, Seung-Muk;Han, Young-Ji
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.5
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    • pp.382-391
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    • 2009
  • Atmospheric speciated mercury concentrations including total gaseous mercury (TGM) and reactive gaseous mercury (RGM) were measured in Chuncheon from March 2006 to November 2008. Average concentrations were 2.10 ${\pm}$ 1.50 ng/$m^3$ and 3.00 ${\pm}$ 3.14 pg/$m^3$ for TGM and RGM, respectively. RGM concentrations were higher during daytime than nighttime probably because of high photochemical activities. We found that RGM concentration considerably increased as ozone increased when fog occurred, indicating that ozone was the important oxidant for $Hg^0$ in aqueous phase. TGM concentration showed positive correlations with CO and $PM_{10}$ which can transport in long-range, but there was no correlation with $NO_2$. Considering that major source of mercury is combustion process, this result showed that local sources did not significantly impact on TGM concentration in Chuncheon. Five-day backward trajectories were calculated for the samples representing high and low concentrations of TGM, and determined that industrialized area of China including Shenyang and Beijing influenced TGM concentrations in Chuncheon.

Atmospheric Pollutant Concentrations under the Influences of Internal Gravity Wave and Sea-Land Breeze Circulations in the Mountainous Coastal Regions (산악연안지역에서 내부중력파와 해륙풍순환 영향하의 대기오염농도)

  • Hyo Choi;Joon Choi
    • International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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    • v.23 no.1
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    • pp.18-33
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    • 1995
  • Under the synoptic scale strong westerly winds flowing over the large steep mountains in the eastern coastal region, the strong downslope wind storms such as internal gravity waves should be generated in the lee-side of mountain. Int he daytime as sea breeze circulation induced by meso-scale thermal forcing from sea toward inland confines to the offshore side of coastal sites due to the eastward internal gravity waves. Thus, surface winds near the coastal seas were relatively weaker than those in the open sea or the inland sites. Evidently, two different kinds of atmospheric circulations such as an internal gravity wave circulation with westerly wind and a sea breeze circulation with both easterly wind near the sea surface and westerly in the upper level were apparently produced. Under this situation the atmospheric pollutants at Kangnung city should be trapped by two different circulations in the opposite directions and resulted in the high concentrations of Total Suspended Particles (TSP) and ozone (O3). At night a meso-scale land breeze from land toward the more intensification of westerly winds in the coastal regions. The concentrations of TSP controled by the strong surface winds blowing from the mountain side toward the coastal sea were relatively higher at night than those in the daytime case and the concentrations of O3 due to the downward transport of ozone from the upper atmosphere toward the surface were also much higher at night than during the day. Consequently, the atmospheric pollutant concentrations in the mountainous coastal region under the downslope wind storms were higher than those after and before the occurrences of wind storms.

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Exposure and Risk Assessment of Nitrogen Dioxide and Ozone for Sub-population Groups using Monte-Carlo Simulations (Monte-Carlo 모의실험을 통한 부분 인구집단별 이산화질소와 오존의 노출 및 위해성 평가)

  • Park, Jinhyeon;Ryu, Hyeonsu;Yang, So Young;Park, Yunkyung;Heo, Jung;Kim, Eunchae;Choe, Youngtae;Cho, Mansu;Yang, Wonho
    • Journal of Environmental Health Sciences
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    • v.45 no.2
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    • pp.113-125
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    • 2019
  • Objectives: Although the risk assessments for nitrogen dioxide ($NO_2$) and ozone ($O_3$) have been extensively studied, most of the existing risk assessments were limited mainly to indoor environments such as workplaces, schools, and multi-use facilities. Therefore, integrated risk assessment is needed to consider exposure in all microenvironments, including outdoors. The purpose of this study was to assess the differences in risk among sub-population groups according to time-activity patterns and reported concentrations, as well as the lifetime risk of Koreans. Methods: In this study, we estimated time-weighted average exposure concentrations of $NO_2$ and $O_3$ for preschool children, students, housewives, workers, and seniors using residential time and indoor concentrations (house, school or workplace, other), outdoors, and transport by meta-analysis method. The risk for $NO_2$ and $O_3$ were assessed by hazard quotient using reference concentrations 30 and 60 ppb, respectively. The risk assessments were conducted through 1,000,000 Monte-Carlo simulations for probabilistic analysis. Results: Preschool children, students, housewives, workers, and seniors spent 91.9, 86.0, 79.8, 82.2, and 77.3% of their day in a house, school, or workplace, respectively. The risk assessment for the lifetime of a housewife and a worker showed that 33.8 and 28.4% of hazard quotients of $NO_2$ exceed 1, respectively, and more than 99% of hazard quotient of $O_3$ were less than 1. Conclusions: The risk of $NO_2$ and $O_3$ by sub-population group and for the lifetime of housewives and workers were assessed. The risk for $NO_2$ was higher than for $O_3$ and showed a different risk by sub-population group. Both $NO_2$ and $O_3$ showed a higher risk for housewives than for workers. This study can be used as a basis for lifetime exposure and risk assessment for $NO_2$ and $O_3$.

Ozone Pollution Patterns and the Relation to Meteorological Conditions in the Greater Seoul Area (수도권지역 오존오염 패턴과 기상학적 특성)

  • Oh In-Bo;Kim Yoo-Keun;Hwang Mi-Kyoung
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.3
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    • pp.357-365
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    • 2005
  • The typical patterns of surface $O_3$ pollution and their dependence on meteorology were studied in the Greater Seoul Area (GSA) during warm season (April-September) from 1998 to 2002. In order to classify the $O_3$ pollution patterns, two-stage (average linkage then k-means) clustering technique was employed based on daily maximum $O_3$ concentrations obtained from 53 monitoring sites during high $O_3$ events (118 days). The clustering technique identified four statistically distinct $O_3$ pollution patterns representing the different horizontal distributions and levels of $O_3$ in GSA. The prevailed pattern (93 days, $49.5\%$) distinctly showed the gradient of $49.5\%$ concentrations going from west to east in GSA. Very high $49.5\%$ concentrations throughout GSA (24 days, $12.8\%$) were also found as a significant pattern of severe $O_3$ pollution. In order to understand the characteristics of $O_3$ pollution patterns, the relationship between $O_3$ pollution patterns and meteorological conditions were analyzed using both synoptic charts and surface/upper air data. Each pattern was closely associated with surface wind interacted with synoptic background flow allowing to transport and accumulate $O_3$ and its precursor. In particular, the timing and inland penetration of sea-breeze were apparently found to play very important role in determining $O_3$ distributions.

Understanding Interfacial Charge Transfer Nonlinearly Boosted by Localized States Coupling in Organic Transistors (유기트랜지스터 내부 편재화 준위간 커플링에 의한 계면 전하이동의 비선형적 가속화 현상의 이해)

  • Han, Songyeon;Kim, Soojin;Choi, Hyun Ho
    • Journal of Adhesion and Interface
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    • v.22 no.4
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    • pp.144-152
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    • 2021
  • Understanding charge transfer across the interface between organic semiconductor and gate insulator gives insight into the development of high-performance organic memory as well as highly stable organic field-effect transistors (OFETs). In this work, we firstly unveil a novel interfacial charge transfer mechanism, in which hole transfer from organic semiconductor to polymer insulator was nonlinearly boosted by localized states coupling. For this, OFETs based on rubrene single crystal semiconductor and Mylar gate insulator were fabricated via vacuum lamination, which allows stable repetition of lamination and delamination between semiconductor and gate insulator. The surfaces of rubrene single crystal and Mylar film were selectively degraded by photo-induced oxygen diffusion and UV-ozone treatment, respectively. Consequently, we found that the interfacial charge transfer and resultant bias-stress effect were nonlinearly boosted by coupling between localized states in rubrene and Mylar. In particular, the small number of localized states in rubrene single crystal provided fluent pathway for interfacial charge transport.

Research on the emission of electromagnetic waves in ambulance (구급차량 내 전자파 방출에 관한 조사)

  • Yun, Jong-Geun
    • The Korean Journal of Emergency Medical Services
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    • v.23 no.1
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    • pp.61-69
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    • 2019
  • Purpose: The study aims to provide basic data to enhance the health of paramedics responsible for patient transport and treatment by analyzing the exposure level of paramedics to electromagnetic waves generated by electric devices used in ambulances. Methods: The study measured electromagnetic waves in ambulances in N region from July to December 2018. ME3030B produced by German Gigahertz Solutions was used to measure these waves and the maximum value was selected by moving it slowly in various directions. Each measurement part was selected and the mean value was calculated by repeatedly measuring at 10-minute intervals three times in total: $1^{st}$, $2^{nd}$, and $3^{rd}$ phase. Results: Among the electrical devices installed in the patient room of the ambulance measured at distances of 1 cm or 30 cm, results showed a high level of electric waves at the inverter ($26.25{\pm}39V/m$) and high level of electromagnetic waves ($564.00{\pm}31.75nT$) at the ozone sterilizer. According to measurements toward the front near the driver's seat, results indicated high levels of electric waves ($3.67{\pm}1.15V/m$) and electromagnetic waves ($450.00{\pm}19.52nT$) at the black box hard drive. Conclusion: Electromagnetic waves within the ambulance were stable and not beyond the range that might impact human health. However, in the case of the black box hard drive ($3.67{\pm}1.15V/m$, $450.00{\pm}19.52nT$) located under the passenger seat, it may have a direct effect on the human body and, thus it is necessary to move it to a storage area further away from the paramedics to minimized the impact.

Development of a Returnable Folding Plastic Box RFID Module for Agricultural Logistics using Energy Harvesting Technology (에너지 하베스팅 기술을 활용한 농산물 물류용 리턴어블 접이식 플라스틱 상자 RFID 모듈 개발)

  • Jong-Min Park;Hyun-Mo Jung
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.29 no.3
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    • pp.223-228
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    • 2023
  • Sustainable energy supplies without the recharging and replacement of the charge storage device have become increasingly important. Among various energy harvesters, the triboelectric nanogenerator (TENG) has attracted considerable attention due to its high instantaneous output power, broad selection of available materials, eco-friendly and inexpensive fabrication process, and various working modes customized for target applications. In this study, the amount of voltage and current generated was measured by applying the PSD profile random vibration test of the electronic vibration tester and ISTA 3A according to the time of Anodized Aluminum Oxide (AAO) pore widening of the manufactured TENG device Teflon and AAO. The discharge and charging tests of the integrated module during the random simulated transport environment and the recognition distance of RFID were measured while agricultural products (onion) were loaded into the returnable folding plastic box. As a result, it was found that AAO alumina etching processing time to maximize TENG performance was optimal at 31 min in terms of voltage and current generation, and the integrated module applied with the TENG module showed a charging effect even during the continuous use of RFID, so the voltage was kept constant without discharge. In addition, the RFID recognition distance of the integrated module was measured as a maximum of 1.4 m. Therefore, it was found that the surface condition of AAO, a TENG element, has a great influence on the power generation of the integrated module, and due to the characteristics of TENG, the power generation increases as the surface dries, so it is judged that the power generation can be increased if the surface drying treatment (ozone treatment, etc.) of AAO is applied in the future.