• Title/Summary/Keyword: ozone oxidation

Search Result 305, Processing Time 0.027 seconds

A Study on the Static mixer and Microbubble of the Sidestream Ozone Contact System to Improve Water Treatment Efficiency (사이드스트림 오존 접촉조에서 수처리 효율 향상을 위한 정적혼합기와 미세기포에 관한 연구)

  • Kim, Jin-Hoon;Park, Jong-Ho
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.23 no.6
    • /
    • pp.763-768
    • /
    • 2009
  • Ozone is a strong oxidant and a powerful disinfectant. In general, it has been used in drinking water treatment during last 100years. Ozone dissolution features are defined by the two categories of ozone contactors, bubble-diffuser and sidestream ozone contactor. Currently, sidestream-injection systems are gaining in popularity but operating cost might be slightly higher. Sidestream ozone system dissolve ozone into a sidestream flow via an injection setup or in the main process flow stream in some sidestream arrangements. The sidestream flow is subsequently mixed with the main process flow stream, which is directed to a reation tank or pipeline for oxidation and disinfection reactions. The purpose of this study is to suggest optimal operating pressure, to figure out the static-mixer effect and to understand the microbubble characteristics of ozone to improve dissolution efficiency.

Evaluation of Ozone for Metal Oxide Thin Film Fabrication

  • Lim, Jung-Kwan;Park, Yong-Pil;Jang, Kyung-Uk;Lee, Hee-Kab
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2004.11a
    • /
    • pp.675-678
    • /
    • 2004
  • Ozone is usually generated from oxygen gas using a silent discharge apparatus and its concentration is less then 10 mol%. An ozone condensation system is constructed for metal oxide thin film fabrication. Ozone is condensed by the adsorption method, which is widely used for the growth of oxidation thin films such as superconductor. Highly condensed ozone is analyzed by three methods; ultraviolet absorption, thermal decomposition and Q-mass analyzing methods. Thermal decomposition method is most effective in the highly condensed ozone region and its method is superior to Q-mass analyzer for determining ozone concentration because of the simplicity of the method.

  • PDF

불포화 토양내에서 가스상 오존 이동특성에 대한 Multiphase liquids의 영향

  • 정해룡;최희철
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2003.04a
    • /
    • pp.124-127
    • /
    • 2003
  • Laboratory scale experiments on in-situ ozonation were carried out to delineate the effects of liquid phases, such as soil water and nonaqeous phase liquid (NAPL) on the transport of gaseous ozone in unsaturated soil. Soil water enhanced the transport of ozone due to water film effect, which prevent direct reaction between soil particles and gaseous ozone, and increased water content reduced the breakthrough time of ozone because of increased average linear velocity of ozone and decreased air-water interface area. Diesel fuel as NAPL also played a similar role with water film, so the breakthrough time of ozone in diesel-contaminated soil was significantly reduced compared with uncontaminated soil. However, ozone breakthrough time was retarded with increased diesel concentration, because of high reactivity of diesel fuel with ozone. In multiphase liquid system of unsaturated soil, the ozone transport was mainly Influenced by nonwetting fluid, diesel fuel in this study.

  • PDF

A Study on the Microbubble Characteristics of Ozone to Improve Dissolution Efficiency (오존 용해효율 향상을 위한 미세기포 특성 연구)

  • Kim, Jin-Hoon;Park, Jong-Ho
    • The KSFM Journal of Fluid Machinery
    • /
    • v.12 no.6
    • /
    • pp.47-53
    • /
    • 2009
  • Ozone is a strong oxidant and a powerful disinfectant. In general, it has been used in drinking water treatment during last 100years. Ozone dissolution features are defined by the two categories of ozone contactors, bubble-diffuser and sidestream ozone contactor. Currently, sidestream-injection systems are gaining in popularity but operating cost might be slightly higher. Sidestream ozone system dissolve ozone into a sidestream flow via an injection setup or in the main process flow stream in some sidestream arrangements. The sidestream flow is subsequently mixed with the main process flow stream, which is directed to a reation tank or pipeline for oxidation and disinfection reactions. The purpose of this study is to suggest optimal operating pressure, to figure out the static-mixer effect and to understand the microbubble characteristics of ozone to improve dissolution efficiency.

Photodegradation of Gaseous Toluene Using Short-Wavelength UV/TiO2 and Treatment of Decomposition Products by Wet Scrubber (단파장자외선/TiO2 공정에 의한 가스상 톨루엔의 분해 및 습식세정장치에 의한 분해생성물의 제거)

  • Jeong, Ju-Young;Jurng, Jong-Soo
    • Journal of Environmental Science International
    • /
    • v.16 no.4
    • /
    • pp.433-440
    • /
    • 2007
  • The photodegradation and by-products of the gaseous toluene with $TiO_2$ (P25) and short-wavelength UV ($UV_{254+185nm}$) radiation were studied. The toluene was decomposed and mineralized efficiently owed to the synergistic effect of photochemical oxidation in the gas phase and photocatalytic oxidation on the $TiO_2$ surface. The toluene by the $UV_{254+185nm}$ photoirradiated $TiO_2$ were mainly mineralized $CO_2$ and CO, but some water-soluble organic intermediates were also formed under severe reaction conditions. The ozone and secondary organic aerosol were produced as undesirable by-products. It was found that wet scrubber was useful as post-treatment to remove water-soluble organic intermediates. Excess ozone could be easily removed by means of a $MnO_2$ ozone-decomposition catalyst. It was also observed that the $MnO_2$ catalyst could decompose organic compounds by using oxygen reactive species formed in process of ozone decomposition.

Application of Ozone Microbubbles in the Field of Water and Wastewater Treatment (용수 및 폐수 처리를 위한 오존 마이크로버블 적용)

  • Nam, Gwiwoong;Jung, Jinho
    • Ecology and Resilient Infrastructure
    • /
    • v.3 no.4
    • /
    • pp.256-262
    • /
    • 2016
  • Rapid industrialization and a significant population growth has led to an increased use of chemicals, which has limited the biological processes that account for most of the existing water and wastewater treatment methods. Ozone microbubble technology, which is one of advanced oxidation processes, has recently attracted attention as a method to solve these issues. In this paper, we reviewed both the physical and the chemical characteristics of microbubbles, and evaluated microbubble-based ozone oxidation processes focusing on the removal of various toxic contaminants. In addition, we discussed the potential of an ozone microbubble process as water and wastewater treatment processes by combining it with other treatment technologies.

Numerical and Experimental Analyses Examining Ozone and Limonene Distributions in Test Chamber with Various Turbulent Flow Fields

  • ITO, Kazuhide
    • International Journal of Air-Conditioning and Refrigeration
    • /
    • v.16 no.3
    • /
    • pp.89-99
    • /
    • 2008
  • Indoor ozone has received attention because of its well-documented adverse effects on health. In addition to the inherently harmful effects of ozone, it can also initiate a series of reactions that generate potentially irritating oxidation products, including free radicals, aldehydes, organic acids and secondary organic aerosols (SOA). Especially, ozone reacts actively with terpene. The overarching goal of this work was to better understand ozone and terpene distributions within rooms. Towards this end, the paper has two parts. The first describes the development of a cylindrical test chamber that can be used to obtain the second order rate constant $(k_b)$ for the bi-molecular chemical reaction of ozone and terpene in the air phase. The second consists of model room experiments coupled with Computational Fluid Dynamics (CFD) analysis of the experimental scenarios to obtain ozone and terpene distributions in various turbulent flow fields. The results of CFD predictions were in reasonable agreement with the experimental measurements.

A study on improvement of ozone process by Granular Activated Carbon (입상 활성탄을 이용한 오존공정의 개선에 관한 연구)

  • Lee, Yu-Mi;Rhee, Dong Seok
    • Journal of Industrial Technology
    • /
    • v.28 no.A
    • /
    • pp.23-26
    • /
    • 2008
  • Ozone/GAC and ozone-GAC processes were introduced for treatment of humic acid, which is representative refractory organic compound. The treatment efficiencies of humic acid in each process were analyzed in pH variation, DOC removal, and $UV_{254}$ decrease. $UV_{254}$ decrease in all processes was comparatively high with efficiency over 92%. $UV_{254}$ decrease in ozone alone process was 85%. DOC removal in Ozone-GAC process was the highest with 75%. Removal by Ozone/GAC, Ozone alone processes were 71% and 33% respectively.

  • PDF

Basic Design Work of Ozone-Contactor for Advanced Oxidation Treatment (오존산화분해를 위한 오존접촉조의 기본설계 연구)

  • 박영규;이동훈
    • Journal of environmental and Sanitary engineering
    • /
    • v.15 no.1
    • /
    • pp.14-24
    • /
    • 2000
  • The water treatment by ozone was performed to remove VOC and organic substances in the multistage ozone contactor. This paper is secondary paper about the theme of ozone treatment since the first paper (Kor. Sanitary J., 15, 1(2000)) publicized, it was compared experimental results with theoretical those which were derived from the mathematical model associated with chemical reactions and mass transfer. Basic designing factors were determined as an optimal conditions for the removal rate of VOCs as follows: ozone input concentration in the contactor was 2mg/L, ozone contact time was 7 min and number of contactor was three-layered.

  • PDF

Characteristics of Oxidation System for Superconductor Thin Film( I ) (초전도 박막 제작을 위한 산화 시스템의 특성( I ))

  • Lim, J.K.;Park, Y.P.;Yang, D.B.;Kim, J.H.;Lee, H.K.;Park, N.B.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2002.11a
    • /
    • pp.272-275
    • /
    • 2002
  • An ozone condensation system is evaluated in the viewpoint of an ozone supplier for oxide thin film growth. Ozone is condensed by the adsorption and distillation method. Then their concentrations are analyzed by three methods; ultraviolet absorption, thermal decomposition and Q-mass analyzing methods. Thermal decomposition method is found to be available to the concentration evaluation from dilution to highly condensed ozone. The highest ozone concentration condensed by the adsorption method is evaluated to be 96 mol%. The ozone is supplied for a sufficiently long time to grow oxide thin films.

  • PDF