• Title/Summary/Keyword: ozone in Korea

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Investigation of Lichen Species as a Biomonitor of Atmospheric Ozone in 'Backwoon' Mountain, Korea (백운산(白雲山) 서식(棲息) 지의류(地衣類)를 이용(利用)한 오존 민감성(敏感性) 지표종(地表種) 선발(選拔))

  • Hur, Jae-Seoun;Kim, Pan-Gi
    • Journal of Korean Society of Forest Science
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    • v.89 no.1
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    • pp.65-76
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    • 2000
  • Lichen flora of 'Backwoon' mountain, Korea, was investigated during the summer of 1998 and 1999 to screen out lichen species which can be used as a biomonitor for atmospheric ozone. The identified foliose or fructicose lichens in the area were classified into 9 families, 20 genera and 34 species. The dominant lichen species in the area were found to be Leptogium sp., Parmelia sp., Parmotrema sp., Phaeophyscia sp. and Cladonia sp. It was also found that lichen species showing a wide range of sensitiveness to air pollution were distributed in 'Backwoon' mountain. The Parmotrema austrosinense, P. tinctorum, Certrelia braunsiana and Ramalina yasudae collected in the area were exposed to ozone at the level of 200ppb, 8hr/day in controlled growth chamber for 2 weeks. Malondialdehyde(MDA), hydroperoxy conjugated dienes(HPCD), soluble protein content and OD435nm/OD415nm ratio for phaeophytinization of chlorophyll were measured and a pollution index(PI) was calculated for each lichen. Ozone exposure severely damaged to the lichens in the order of P. austrosinense>P. tinctorum>C. braunsiana>R. yasudae. P. austrosinens easily identified and widely distributed in Korea is likely to be a very useful biomonitor of air pollution, especially for ozone. These results indicate that Korean lichen species can be used as a biomonitor for air pollution to evaluate air quality contaminated with ozone.

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Covulcanization and Ozone resistance for Unsaturated and Saturated Rubbers (불포화 고무와 포화 고무의 공가류 및 내오존성)

  • Lim, Won-Woo;Jung, Il-Taek;Han, Min-Hyun
    • Journal of Adhesion and Interface
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    • v.2 no.4
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    • pp.32-38
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    • 2001
  • Effects of the ratio of rubber composition on covulcanization and ozone resistance were studied in this study. Specimens used in this study were rubber compounds(specimen-A) blended with various ratio of NR, SBR, BR, IIR, and EPDM, unsaturated rubber compounds(specimen-B) with NR/BR/SBR, and saturated rubber compounds(specimen-C) with NR/IIR/EPDM. PAD adhesion specimen was prepared from vulcanizing specimen-A and B, and specimen-A and C, respectively. Using same adhesion specimen, peel strength was measured and tested ozone resistance. In specimen-A, peel strength was higher with increasing NR ratio for NR and BR contained blends. In other specimen-A containing NR and SBR, the peel strength was also increased with increasing SBR ratio. NR/BR/IIR/EPDM rubber compounds had also better adhesion property than NR/SBR/IIR/EPDM compounds. As more unsaturated rubber was blended, the peel strength was higher but ozone resistance was worse. Optimum ratio of unsaturated and saturated rubbers for the peel strength and ozone resistance was 60/40.

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Determination of Ozone Tolerance on Environmental Tree Species Using Standard Index (표준화 지수를 이용한 환경수목의 오존 내성 결정)

  • Han, Sim-Hee;Kim, Du-Hyun
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.11 no.1
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    • pp.3-12
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    • 2009
  • Ozone tolerance of tree species was determined by standard index of physiological damages and biochemical defense responses under short-term ozone exposure. At the end of 150ppb $O_3$ fumigation, photosynthetic characteristics and antioxidative enzyme activities were analyzed in the leaves of five species(Koelreuteria paniculata, Firmiana simplex, Styrax japonica, Fraxinus rhynchophylla, Viburnum sargentii). Injury index was determined by the effect of ozone on photosynthetic parameters and malondialdehyde(MDA) content, and tolerance index was calculated using the rate of increase in superoxide dismutase(SOD), ascorbate-peroxidase(APX), glutathione reductase(GR) and catalase(CAT) activities. Apparent quantum yield(AQY), carboxylation efficiency(Ce) and photo-respiration rate(PR) decreased in the leaves of five species with increasing ozone exposure time. These parameters were considered as an appropriate indicator for stress evaluation. Antioxidative enzyme activities showed various results depending on the tree species, exposure time, and enzyme types. SOD activity of K. paniculata increased with ozone exposure time, and that of F. rhynchophylla increased only after 6 hours of ozone exposure. CAT activity of $O_3$-exposed F. simplex was lower than the control. Based on standard index, ozone tolerance ability of five species was determined as two tolerant species(F. rhynchophylla > K. paniculata) and three sensitive species(S. japonica > F. simplex > V. sargentii).

Evaluation of Ozone Resistance and Anti-Corrosion Performance of Water Treatment Concrete according to Types of Metal Spray Coating (수처리시설용 콘크리트의 금속용사 피막 종류에 따른 내오존성 및 전기화학적 방식 성능 평가)

  • Park, Jin-Ho;Choi, Hyun-Jun;Lee, Han-Seung;Kim, Sang-yeol;Jang, Hyun-O
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.61-68
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    • 2019
  • As the pollution of water resources deteriorates due to industrialization and urbanization, it is difficult to supply clean water through a water treatment method using chlorine. Therefore, the introduction of advanced water treatment facilities using ozone is on the increase. However, epoxy which is used as waterproofing and anticorrosives and stainless steel used in conventional waterproofing and anti-corrosive methods have deteriorated because of the strong oxidizing power of ozone, causing problems such as leaking. Moreover, it even causes the durability degradation of a concrete. Therefore, in this study, metal spraying system was used as the means of constructing a metal panel with excellent ozone resistance and chemical resistance which is an easier method than an existing construction method. Ozone resistance was evaluated in accordance with the type of metal sprayed coatings to develop a finishing method which can prevent the concrete structure of water treatment facilities from deterioration. Furthermore, electrochemical stability in actual sewage treatment plant environment was evaluated. Experimental results showed that Ti has superior ozone resistance after spraying and the electrochemical stability in the sewage treatment plant environment showed that Ti has the highest polarization resistance of $403.83k{\cdot}{\Omega}{\cdot}cm^2$, which ensures high levels of durability.

A Study of Ecotoxicity Test for Byproducts of Ozone in the Ballast Water Treatment System with Ozonation

  • Park, Sung-Jin;Ha, Shin-Young;Kim, In-Soo
    • Journal of Navigation and Port Research
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    • v.35 no.9
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    • pp.741-747
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    • 2011
  • Ecological toxicity testing of the whole-effluent from the ozone ballast water treatment system was conducted as specified in the quality assurance project plans (QAPP). The growth inhibition test with microalgae, acute aquatic toxicity test with the Rotifer reproduction, toxicity test (or population growth) with the Rotifer, survival and growth toxicity test with larval fish and sediment toxicity test with amphipod were carried out to evaluate ecological toxicity on the movile test barge.

A Study on the Surface Deterioration Evaluation of Epoxy Resin Coating as Anticorrosive Material of Concrete Water Tank Using Ozone($O_3$) (오존 정수처리 음용수조 구조물에 사용하는 에폭시 수지 방수.방식재의 표면특성 평가)

  • 오상근;강효진;곽규성
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.513-518
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    • 2003
  • Recently, advanced systems for water treatment are introduced for water quality improvement. One of those systems is water treatment method using ozone($O_3$). For it has strong oxidizing energy, it is necessary to have materisl stability against $O_3$. In this paper, epoxy resin specimens using as anticorrosive material of concrete structure for drink water are used to serve as a material of deterioration evaluation. It is to be studied weight loss, surface corrosion of specimens, ingredient analysis of floating particle, a solute of chemical ingredient by way of accelerated ozone testing. As the results of experiment, specimen weight is decreased. The surface of specimen is eroded heavily and showed a loss of gloss and floating particle, and in the stability for drinking water, harmful ingredient is not detected in the water.

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Ozone Measurments in the Stratosphere from KSR420S-1 and -2 : the Preliminary Results

  • Lee, Ki-Yiung-;Lee, Dong-Hun-;Kim, Jhoon-;Park, Chang-joon-
    • Bulletin of the Korean Space Science Society
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    • 1993.10a
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    • pp.11-11
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    • 1993
  • The Korean sounding rockets(KSR) 1, 2 equigped with the UV optical detectors have been launched at An-heung, Chungchongnam-do, of June 4 and September 1, 1993,respectively. The UV detector is used to measure the attenuation of solar UV radiation for various frequency bards in the stratospgere. We obtained the profile of the ozone number density within the altitulde of 15 - 30 km by applying the Beer-Lambert law. It is found that the maHimum of the ozone distribution occurs near 2sht which is quite consistent with the mean value in the mid-latituderegions. We will also compare our results froiu KSR 1,2 with the other observational data from the Dobson speceo meter at Yonsei Univ. and the LIDAa which were performed simultaneously with the sounding rocket experiments.

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Numerical Simulation and Process Analysis Using the MM5-CMAQ in Yangsan on High Ozone Days during Spring and Summer (MM5-CMAQ 모델 시스템을 이용한 양산지역 봄, 여름 고농도 오존일의 발생과정별 기여도 평가)

  • Kim, Yoo-Keun;Park, Sang-Hyun;Kang, Jae-Eun;Song, Sang-Keun
    • Journal of Environmental Science International
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    • v.19 no.3
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    • pp.269-279
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    • 2010
  • The relative contributions of physical and chemical processes to the production of ozone ($O_3$) were evaluated based on an integrated process rate (IPR) analysis using the MM5/CMAQ in a downtown (i.e., Yangsan_U) and suburban area (i.e., Ungsang) on high ozone days during spring and summer in 2006 (28 April and 8 August 2006). The IPR includes a horizontal advection (HADV) and diffusion (HDIF), a vertical advection (ZADV) and diffusion (VDlF), a dry deposition (DDEP), and a chemistry (CHEM). The VDIF in Yangsan_U was found to be the most dominant contributor (29.5% in spring and 32.1% in summer) to high $O_3$ concentrations, followed by the HADV and ZADV. In contrast, the contributions of the HADV (40.3% in spring and 32.3% in summer) in Ungsang were significantly higher than those of VDIF and ZADV. Moreover, $O_3$ production due to the chemical effect in the two areas (especially in Ungsang) during summer was found to be moderately higher than that during spring.

Domestic Ozone Sensitivity to Chinese Emissions Inventories: A Comparison between MICS-Asia 2010 and INTEX-B 2006 (중국 배출량 목록에 대한 국내 오존 민감도 분석: MICS-Asia 2010와 INTEX-B 2006 비교사례)

  • Kim, Soontae;Bae, Changhan;Kim, Eunhye;You, Seunghee;Bae, Minah;Lee, Jae-bum;Seo, Inseok;Lim, Yongjae;Kim, Byeong-Uk;Kim, Hyun Cheol;Woo, Jung-Hun
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.5
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    • pp.480-496
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    • 2017
  • CMAQ (Community Multiscale Air Quality)-HDDM (High-order Direct Decoupled Method) simulations with MICS-Asia 2010 and INTEX-B 2006 emissions inventories were performed to investigate the impact of Chinese $NO_x$ and VOC emissions on 1-hr ozone concentrations over South Korea during May to July in 2014. Chinese $NO_x$ and VOC emissions in MICS-Asia 2010 were 60% higher and 100% lower than those in INTEX-B 2006 during the simulation period. It makes the ratio of Chinese VOC to $NO_x$ emissions in INTEX-B 2006 (Case 1) is 3.2 times higher than that in MICS-Asia 2010 (Case 2). When the observed period mean 1-hr ozone concentration averaged across 106 air monitoring sites in the SMA (Seoul Metropolitan Area) was 37.6 ppb, the modeled values were similar to each other; 37.3 ppb for Case 1, and 40.4 ppb for Case 2. Both cases show that daily maximum 1-hr ZOC (Zero-Out Contribution) of Chinese $NO_x$ and VOC emissions were as high as 55 ppb and 35 ppb for the episode respectively. Correlation coefficients between ZOC of Chinese $NO_x$ and VOC emissions and the SMA daily maximum 1-hr ozone were 0.49~0.69. It indicates that Chinese emissions occasionally affect the SMA daily ozone peaks. On the other hand, Case 2 predicted 7 ppb and 1 ppb higher ZOC of Chinese $NO_x$ and VOC emissions than Case 1, when simulated ozone in the SMA is over 80 ppb. It implies that upwind $NO_x$ emissions would be more important than upwind VOC emissions for the long-range transport of ozone in Northeast Asia.

Evaluation of Water Treament System for Phenol Removal in the Nakdong River Basin (낙동강 수계 페놀처리를 위한 정수처리시스템 평가)

  • Kang, Byung-Jae;Chae, Seon-Ha;Lee, Kyung-Hyuk;Jeon, Hang-Bae
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.5
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    • pp.609-618
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    • 2009
  • Repeated phenol spill in the Nakdong River has been a big issue in Korea since 1991. In this study, treatment of phenol in each water treatment process and total water treatment system is evaluated. Phenol was highly volatile, easily oxidized by ozone, and readily absorbed onto GAC. When there was phenol of 0.3mg/L in water, by ozonation of 1mg/L or by GAC adsorption with EBCT of 10minutes or longer, it could be treated to lower than 0.005mg/L, the national drinking water standard of phenol. Even when a sufficient contact time(70minutes) was allowed, only 35 to 40% of phenol could be removed by powdered activated carbon(PAC). Based on the test results, it can be concluded that 1.0mg/L or less concentration of phenol can be treated at the plants adopting the combination process of ozone and GAC down to the safe level. In this study, removal characteristics for phenol were evaluated with the existing pilot plant and demo plant in different advanced water treatment processes(AWTPs). In the future, studies on changes in oxidation and adsorption characteristics caused by competitive matters such as DOC and removal characteristics by other various AWTPs including ozone/filter adsorber need to be performed.