• Journal of Soil and Groundwater Environment
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• v.17 no.4
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• pp.44-50
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• 2012

A new type of chemical oxidation technology utilizing micro bubble ozone oxidizer and a pneumatic fracturing equipment was developed to enhance field applicability of a traditional chemical oxidation technology using hydrogen peroxide as an oxidizer for in-situ soil remediation. To find an efficient way to dissolve gaseous ozone into hydrogen peroxide, ozone was injected into water as micro bubble form then dissolved ozone concentration and its duration time were measured compared to those of simple aeration of gaseous ozone. As a result, dissolved ozone concentration in water increased by 31% (1.6 ppm ${\rightarrow}$ 2.1 ppm) and elapsed time for which maximum ozone concentration decreased by half lengthened from 9 min to 33 min. When the developed pneumatic fracturing technology was applied in sandy loam, cracks were developed and grown in soil for 5~30 seconds so that the radius of influence got longer by 71% from 392 cm to 671 cm. The remediation system using the micro bubble ozone oxidizer and the pneumatic fracturing equipment for field application was made and demonstrated its remediation efficiency at petroleum contaminated site. The system showed enhanced remediation capacity than the traditional chemical oxidation technology using hydrogen peroxide with reduced remediation time by about 33%.

• Atmosphere
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• v.19 no.3
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• pp.227-235
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• 2009

Global climate warming induced by long-lived greenhouse gases is expected to cause increases in wildfire frequencies and intensity in boreal forest regions of mid- and high-latitudes in the future. Siberian forest fires are one of important sources for air pollutants such as ozone and aerosols over East Asia. Thus an accurate quantification of forest fire influences on air quality is crucial, in particular considering its higher occurrences expected under the future warming climate conditions. We here use the 3-D global chemical transport model (GEOS-Chem) with the satellite constrained fire emissions to quantify Siberian fire effects on ozone concentrations in East Asia. Our focus is mainly on spring 2003 when the largest fires occurred over Siberia in the past decade. We first evaluated the model by comparing to the EANET observations. The model reproduced observed ozone concentrations in spring 2003 with the high $R^2$ of 0.77 but slightly underestimated by 20%. Enhancements in seasonal mean ozone concentrations were estimated from the difference in simulations with and without Siberian fires and amounted up to 24 ppbv over Siberia. Effects of Siberian fires also resulted in 3-10 ppbv incresases in Korea and Japan. These increases account for about 5-15% of the ozone air quality standard of 60 ppbv in Korea, indicating a significant effect of Siberian fires on ozone concentrations. We found however that possible changes in regional meteorology due to Siberian fires may also affect air quality. Further study on the interaction between regional air quality and meteorology is necessary in the future.

• Asian Journal of Atmospheric Environment
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• v.6 no.2
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• pp.111-117
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• 2012

To establish area specific control strategy for ambient ozone in the Seoul Metropolitan Area (SMA), the maximum ozone concentration in each local government district in the SMA were estimated by using the OZone Isopleth Plotting Package for Research (OZIPR) model. The modeling period was June 2000 and the emission inventory data used were from National Institute of Environmental Research (NIER). Except the islands of Incheon, whole Seoul and Incheon areas were volatile organic compounds (VOCs) limited, i.e., decreasing the oxides of nitrogen ($NO_X$) emission alone may increase the maximum ozone concentration upto certain point. In Gyeonggi, 12 areas were VOCs limited while 12 areas were in between VOCs limited and $NO_X$ limited, i.e., decreasing both $NO_X$ and VOCs emission may decrease the maximum ozone concentration. Majority of the estimated ozone values were lower than the measured values. The reason could be inaccuracy in emission inventories and/or transport from other areas. The same calculation was carried out for June 2004 and it was found that Seoul was still in the VOCs limited condition.

• Journal of Environmental Science International
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• v.5 no.3
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• pp.265-275
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• 1996

Air pollution characteristics and the influence of sea breeze on surface ozone concentration were studied using the data measured at 7 air quality continuous monitoring stations from June to September using 3 years (1990, 1993, 1994) in Pusan coastal area. Among the 246 sea breeze days for research Period, there were approximately 89 sea breeze days (36%) from lune to September, And there were 120 the episode days (68%) of ozone greater than or equal to 60 ppb in summer season. In 89 sea breeze days, the episode day was highly marked as 56 days (63%). So, we knew that the sea breeze greatly affects the occurence of ozone episode day. the ozone concentration under the condition of the sea breeze increase about 40% in the daytime. Frequencies distribution of $O_3$ concentration for sea breeze moved toward high concentration class. The characteristics of ozone concentration in relation to meteorological conditions of sea breeze is significant because we can discover major weather factors for eastablishing an air pollution- weather forecast system. For further. study about meterological approach method for photochemical air pollution, it is necessary to explain the characteristics of atmosphere below 1, 000 m, especially concerning the formation mechanism of inversion layers. And finally, we will study the relationships to synoptic weather conditions and vertical structure and diurnal variation of local wind systems including sea breeze, and the vertical movements of atmosphere in the city.

• Journal of Climate Change Research
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• v.7 no.4
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• pp.451-463
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• 2016

We explore the impact of Chinese future air pollutant emissions on ozone air quality in Northeast Asia (NEA) and health in South-Korea using an assessment framework including ICAMS (The Integrated Climate and Air Quality Modeling System) and BenMAP (The Environmental Benefits Mapping and Analysis Program). The emissions data sets from the climate change scenarios, the Representative Concentration Pathways (RCPs) (emission scenarios, EMSO), are used to simulate ozone air quality in NEA in the current (1996~2005, 2000s), the near future (2016~2025, 2020s) and the distant future (2046~2055, 2050s). Furthermore, the simulated ozone changes in the 2050s are used to analyze ozone-related premature mortality and economic cost in South-Korea. While different EMSOs are applied to the China region, fixed EMSO are used for other country regions to isolate the impacts of the Chinese emissions. Predicted ozone changes in NEA are distinctively affected by large changes in NOx emission over most of China region. Comparing the 2020s with the 2000s situation, the largest increase in mean ozone concentrations in NEA is simulated under RCP 8.5 and similarly small increases are under other RCPs. In the 2050s in NEA, the largest increase in mean ozone concentrations is simulated under RCP 6.0 and leads to the occurrence of the highest premature mortalities and economic costs in South-Korea. Whereas, the largest decrease is simulated under RCP 4.5 leads to the highest avoided premature mortality numbers and economic costs. Our results suggest that continuous reduction of NOx emissions across the China region under an assertive climate change mitigation scenario like RCP 4.5 leads to improved future ozone air quality and health benefits in the NEA countries including South-Korea.

• The Korean Journal of Ecology
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• v.22 no.2
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• pp.79-83
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• 1999

Phytotoxic effects of ozone and ethylenediurea (EDU) on soybean (Glycine max) and spinach (Spinacia oleracea) were observed by using open-top field chamber system (OTC). Gas exchange rates (photosynthesis. stomatal conductance and transpiration rates) of soybean plants were decreased by 20% to 30% by ambient ozone and resulted in 30% reduction of seed yields. In OTC. ambient ozone and 0.12 $\mu$l/l $O_3$ decreased gas exchange rates of spinach by 25% to 40% and by 50%. respectively. The protective effect of EDU against ozone induced injury was obtained at 100 mg/l on soybean. and at 250 mg/l on spinach, respectively. The excessive application of EDU. however. inhibited photosynthesis. transpiration. and stomatal conductance without any specific visible damage.

• Journal of Korean Society for Atmospheric Environment
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• v.29 no.4
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• pp.390-406
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• 2013

In Korea, photochemical air pollution has drawn public attention as one of the major environmental issues since 1990s. To abate ozone and air pollution, new legislation was enacted and regulation was reinforced in conjunction with basic researches. As a result, the air quality has been much improved in terms of primary pollutant such as CO and the occurrence of extremely high ozone concentration. In Seoul, on the other hand, concentrations of ozone and exeedance hours of its national standard have increased since 2005, which is intimately coupled with $NO_2$ variations. It indicates the need for further research at long-term bases to improve our understanding on complex processes determining ozone concentrations. In this paper, the characteristics of ozone variation was analyzed with 13-year measurement data obtained in Seoul. In addition, the previous studies and their main results were summarized that have been performed in association with photochemical air pollution in Korea over the last three decades.

• Elastomers and Composites
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• v.54 no.2
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• pp.110-117
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• 2019

The characterization of the ozone oxidation for raw natural rubber (NR) was investigated under controlled conditions through image and fourier transform infrared (FT-IR) analysis. The ozone oxidation was performed on a transparent thin film of raw NR coated on a KBr window in a dark chamber at $40^{\circ}C$ under low humidity conditions to completely exclude thermal, moisture, or light oxidation. The ozone concentration was set at 40 parts per hundred million (pphm). Before or after exposure to ozone, the image of the thin film for raw NR was observed at a right or tilted angle. FT-IR absorption spectra were measured in the transmission mode according to ozone exposure time. The ozone oxidation of NR was determined by the changes in the absorption peaks at 1736, 1715, 1697, and $833cm^{-1}$, which were assigned to an aldehyde group (-CHO), a ketone group (-COR), an inter-hydrogen bond between carbonyl group (-C=O) from an aldehyde or a ketone and an amide group (-CONH-) of protein, and a cis-methine group ($is-CCH_3=CH-$, respectively. During ozone exposure period, the results indicated that the formation of the carbonyl group of aldehyde or ketone was directly related to the decrement of the double bond of cis-1,4-polyisoprene. Only carbonyl compounds such as aldehydes or ketones seemed to be formed through chain scission by ozone. Long thin cracks with one orientation at regular intervals, which resulted in consecutive chain scission, were observed by image analysis. Therefore, one possible two-step mechanism for the formation of aldehyde and ketone was suggested.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.32 no.4
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• pp.320-326
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• 2019

Recently, the application of atmospheric plasma technology in air filtration is increasing. Sterilization by an atmospheric plasma device is very effective. However, ozone gas, which is generated during atmospheric plasma formation, poses a hazard to human health. To reduce the ozone gas during plasma discharge, we fabricated a one-plate hybrid plasma discharge device with a heating element, which can decompose ozone gas effectively by a simple heating action. In this study, we evaluated the plasma discharge characteristics and ozone concentrations with various Ar flow rates and temperatures. With increasing Ar gas flow rate, the ozone concentration and spectrum intensity increased till an Ar gas flow rate of 60 sccm, and decreased thereafter. When discharged in high temperature, the ozone concentration and spectrum intensity decreased. Further, to evaluate the state of the treated surface under various plasma discharge and heating conditions, we measured the variation in the contact angles on the surface. Regardless of the temperature, the contact angle increased with increasing discharge voltage. However, the contact angle increased when discharged at high temperature.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.29 no.2
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• pp.36-45
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• 1997

Newly bleaching sequence using oxygen, ozone and hydrogen peroxide has introduced to avoid pollution hazards from chlorinated organic compounds, because chlorine dioxide substitution bleaching was produced a little chlorinated organic substance. Oxygen-type chemicals replaced for chlorine has attracted much research attention. Bleachability of ozone was improved at low temperature and high pulp consistency. In third bleaching followed OZ bleaching, addition of O2 and NaBH4 in alkali extraction was effective than only alkali extraction. Bleachability of pulps in ozone bleaching(Z) was improved at higher consistency and lower temperature The addition O2 and NaBH4 in alkali extraction after OZ bleaching sequence improved brightness, when compared to those obtained by only alkaline extraction. Pulps bleached by ECF bleaching sequences such as OZEoD and OZEopD was obtained by 90% ISO brightness. The brightness of pulp bleached by TCF sequences with the ozone dosage of 1.6% was approached to target brightness (88~90%ISO). Pulps bleached Z stage combined bleaching sequence was reduced the viscosity to a little greater extent. However, physical properties of pulps was not great different compared to those bleached by conventional bleaching sequences. A pollution index of bleaching effluente by ozone combined bleaching sequences was lower than by conventional bleaching sequence, but somewhat higher than multistage bleaching sequences combined C/D stage.