• 자원리싸이클링
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• 제32권2호
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• pp.43-51
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• 2023

본 연구에서는 자동차엔진의 신품제조시와 재제조시 발생하는 환경영향을 전과정 관점에서 산정하고 이를 기반으로 온실가스 저감효과를 산정하였다. 자동차엔진 원부자재 원료취득 및 제조공정에서 배출되는 온실가스량은 신품제조시 약 3,473 kg, 재제조시 약 872 kg으로 재제조를 통해 저감되는 온실가스량은 약 2,601kg으로 나타나 폐기 단계를 제외한 전과정 측면에서 저감효과가 있는 것으로 분석되었다. LCA 가중화 분석 결과 신품 제조시 환경영향은 1.07E+03 Eco-point, 재제조시 2.67E+02 Eco-point로 나타났으며, 주요 6대 영향 범주 중 지구온난화 점유비율이 99.72%, 99.68%로 높게 나타났다.

• 한국환경과학회지
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• 제16권12호
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• pp.1463-1468
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• 2007

Emission of methyl bromide(MeBr) of soil fumigant was implicated in stratospheric ozone depletion. To determine the environmental fate for 1,3-dichloropene(1,3-D) of alternatives fumigants for MeBr, this paper researched the transformation for 1,3-D in water and soil. Half lives of cis-1,3-D in water with first-order kinetics are 9.9day and 1.7day at $25^{\circ}C\;and\;40^{\circ}C$, half lives of trans-1,3-D are 8.6day and 1.5day at $25^{\circ}C\;and\;40^{\circ}C$, respectively. Transformation for 1,3-D in water at high temperature faster then at low temperature. Hydrolysis for 1,3-D in water are unaffected at $pH\;2.5{\sim}pH\;10.0$, but hydrolysis for 1,3-D at pH 11.5 higher then at $pH\;2.5{\sim}pH\;10.0$. Half lives of cis-1,3-D in soil are 11.5day and 7.7day at 3% and 10% of soil moisture, half lives of trans-1,3-D are 9.9day and 6.9day at 3% and 10% of soil moisture, respectively. Transformation for 1,3-D in water increased with increasing soil moisture. Transformation for trans-1,3-D isomer are more rapid then cis-1,3-D isomer in water and soil. This research has identified that transformation for 1,3-dichloropropene are affected by temperature, pH, soil moisture, and isomer of cis and trans in water and soil.

• 설비공학논문집
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• 제6권4호
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• pp.439-452
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• 1994

One of the chlorofluorocarbon compounds. R-12 deplete atmospheric ozone. It leads to international agreement to reduce CFC production. R-134a has similar thermodynamic properties to CFC-12. It has zero ODP(Ozone Depletion Potential). This Paper focuses on the lubricating oils for using with R-134a PAGs(Polyalkylene Glycol's) and esters are primary lubricants that are now being tested for use with R-134a Because of extreme polarity of R-134a. there are many problems in the selection of lubricating oil. This investigation analyzes compressor working conditions and calculates wear parts friction for simulation testing. Miscibility and material compatibility is proved by sealed glass tests. Friction was tested on the closed type pin on disk wear tester. This equipment simulates actual refrigerating compressor. Environment controlled test made more reliable result than field test Conventional oils(mineral oils, Alkylbenzene, PAO(Polyalpha Olefin) are immiscible with R-134a. PAGs and ester oils are miscible with R-134a. Friction coefficient is similar to conventional system(mineral oil/R-12 systems) at operating condition. At start & stop condition, PAGs/R-134a system has high friction coefficient. It provide reliable result on the lubricity, miscibility, material compatibility of R-134a with these new lubricants. It suggests proper selection of refrigeration oil that may improve compressor durability of performance.

• 설비공학논문집
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• 제19권5호
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• pp.403-410
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• 2007

In this study, natural refrigerants and their mixtures that can supplement and replace R12 and R134a in automobile air-conditioners are studied. R134a is currently used as the refrigerant in new motor vehicle air conditioners, replacing the ozone depleting refrigerant R12. Although R134a has no ozone depletion potential, it has a relatively large global warming potential, approximately 1300 times that of $CO_2$ over a 100 year time horizon. For this reason, performance of natural refrigerants and their mixtures containing R152a, RE170 (Dimethylether, DME) and R600a (Isobutane) are measured under 2 different temperature conditions. They were tested in a refrigerating bench tester with an open type compressor. The test bench provided about 4 kW capacity and water and water/glycol mixture were employed as the secondary heat transfer fluids. Test results show that the coefficient of performance (COP) of these refrigerants is up to 21.55% higher than that of R12 in all temperature conditions. Overall, these fluids provide good performance with reasonable energy savings without any environmental problem and thus can be used as long term alternatives for automobile air-conditioners.

• 대한화장품학회지
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• 제26권1호
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• pp.41-58
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• 2000

최근 환경오염으로 인한 지구오존층의 파괴로 자외선의 지표면의 도달 량이 증가하고 그로 인한 인간에 대한 피해가 증가하고 있다 . 과도한 자외선의 피부에 대한 직접적인 노출은 피부에 많은 문제점을 야기하므로 일차적으로 자외선차단제를 이용하여 인체에 대한 직접적인 피해를 최소화 해야한다 . 현재 자외선 차단제는 유기자외선흡수제와 무기자외선산란제가 많이 사용이 되는데 적은량으로도 효과가 높은 유기자외선차단제는 사용 시 주의를 요하므로 국가별로 사용량과 사용여부에 대하여 규제를 하고 있다. 본 연구에서는 플라보노이드류 ,알카로이드류 같은 자외선 흡수 성분을 함유한 식물중 UV/vis spectrophotometer 에서 자외선 흡수 peak을 나타내는 금은화 , 포공영, 녹차 , 황금추출물을 이용하여 화장품의 자외선 흡수제로서의 사용가능성여부를 조사하였다. 또한 식물추출물이 가진 자극성 성분과 오염성, 그들이 가진 유효성분들을 보호하고자 실리콘을 이용한 겔화를 시도하였다 . 자연친화적인 천연물로써 식물추출성분을 이용 유기자외선흡수제의 사용량을 줄이는 자외선홉수보조제로서 가능성을 보여주었다.

• 한국태양에너지학회 논문집
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• 제26권2호
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• pp.9-18
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• 2006

In this paper, the thermodynamic performance of OTEC cycle was examined. Computer simulation programs were developed for simple Rankine cycle, regenerative Rankine cycle, Kalina cycle, open cycle and hybrid cycle. For the simple Rankine cycle, the results show that newly developed fluids such as R410A and R32 that do not cause stratospheric ozone layer depletion perform as well as R22 and ammonia. Also, simple Rankine cycle OTEC power plant can practically generate electricity when the difference in warm and cold sea water inlet temperatures are greater than $14^{\circ}C$. The regenerative Rankine cycle showed a 1.5 to 2% increase in energy efficiency compared to the simple Rankine cycle while the Kalina cycle employing ammonia/water mixture showed a 2-to-3% increase in energy efficiency, and the overall cycle efficiencies of hybrid cycle and open cycle were 3.35% and 4.86%, respectively.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.2217-2221
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• 2007

Because of the ozone layer depletion and global warming, new alternative refrigerants are being developed. In this study, evaporation heat transfer characteristics of carbon dioxide flowing upward in a vertical tube have been investigated by experiment. Before the test section, a pre-heater is installed to adjust the inlet quality of the refrigerant to a desired value. A smooth tube with outer diameter of 5 mm and length of 1.44 m was selected as a test tube. The test was conducted at mass fluxes of 212 to 530 kg/$m^2s$, saturation temperature of -5 to 20$^{\circ}C$, and heat fluxes of 20 to 45 kW/$m^2$. As the vapor quality and mass fluxes increase, the heat transfer coefficients of carbon dioxide are decreased, and the heat transfer coefficients increase when the heat fluxes and saturation temperatures increase.

• 한국태양에너지학회 논문집
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• 제30권3호
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• pp.124-130
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• 2010

Ocean Thermal Energy Conversion(OTEC) power plants have been examined as a viable option for supplying clean energy. This paper evaluated the thermodynamic performance of the OTEC Power system for the production of electric power and desalinated water. The results show that newly developed fluids such as R32, R125, R143a, and R410A that do not cause stratospheric ozone layer depletion perform as well as R22 and ammonia. Overall cycle efficiency of open cycle is the lowest value of 3.01% because about 10% of the gross power is used for pumping out non-condensable gas. Also, the hybrid cycle is an attempt to combine the best features and avoid the worst features of the open and closed cycles. The overall cycle efficiency of hybrid cycle is 3.44% and the amount of desalinated water is 0.0619 kg/s.

• 농업과학연구
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• 제41권4호
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• pp.275-281
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• 2014

The ozone depletion has caused plants to be exposed to an increased penetration of solar ultraviolet-B (UV-B) radiation. Enhanced UV-B radiation may have influence on biological functions of plant in many aspects including inhibition of photosynthesis. It is evident that UV-B can potentially impair the performance of all three main component processes of photosynthesis, the photophosphorylation reactions of the thylakoid membrane, the $CO_2$-fixation reactions of the Calvin cycle and stomatal control of $CO_2$ supply. Owing to these depressed reactions, the production and allocation of carbohydrates might be markedly affected, and therefore, the growth and development of plant are distinctly reduced. In this review paper, we provide basic theory and further researches in terms of photosynthesis and carbohydrate synthesis in response to elevated UV-B radiation.

• 설비공학논문집
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• 제19권8호
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• pp.555-562
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• 2007

In this study, condensation heat transfer coefficients (HTCs) of R22, R134a, R245fa and R123 are measured on a horizontal plain tube. All data are taken at the vapor temperature of $39^{\circ}C$ with a wall subcooling temperature $3-8^{\circ}C$. Test results show the HTCs of newly developed alternative low vapor pressure refrigerant, R245fa, on a plain tube are 9.5% higher than those of R123 while they are 3.3% and 5.6% lower than those of R134a and R22 respectively. Nusselt's prediction equation for a plain tube underpredicts the data by 13.7% for all refrigerants while a modified equation yielded 5.9% deviation against all data. From the view point of environmental safety and condensation heat transfer, R245fa is a long term good candidate to replace R123 used in centrifugal chillers.