• Applied Chemistry for Engineering
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• v.33 no.3
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• pp.328-334
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• 2022

For the study of environmental application of natural zeolites (NZ) and red mud (RM), which are discharged from various industrial fields, the catalytic ozonation of 2-butaone (methyl ethyl ketone, MEK) was performed using the Mn-loaded NZ prepared according to the Mn content of 1, 3, 5, 7, and 10 wt%. By the addition of Mn to NZ, the BET (Brunaure-Emmett-Teller) specific surface area of Mn/NZ catalysts decreased while the ratio of Mn³⁺/[Mn³⁺+Mn⁴⁺] intensively increased. Besides, the addition of Mn component to NZ increased the ratio of adsorbed oxygen (O_adsorbed) toward lattice oxygen (O_lattice), O_adsorbed/O_lattice from 0.076 of NZ to 0.465 of 10 wt% Mn/NZ according to the amount of Mn. It is known that the proportion of two species, Mn³⁺ and O_adsorbed, would greatly affect the catalytic activity. However, the balancing between the paired species, Mn³⁺ vs. Mn⁴⁺ and O_adsorbed vs. O_lattice might be more essential for the catalytic ozonation of MEK at room temperature. Among the Mn-loaded NZ catalysts, the 3 wt% Mn/NZ showed the best activity for the removal of MEK and ozone. The 5, 7, and 10 wt% Mn/NZ catalysts are slightly inferior to the 3 wt% Mn/NZ. Compared to the pristine NZ, the Mn/NZ catalysts showed better activity for the catalytic ozonation of MEK. In addition, the 3 wt% Mn/NZ was confirmed to have the most available acid sites among them by the analysis of NH₃-TPD (temperature programmed desorption). This might be the major reason for the best catalytic activity of 3 wt% Mn/NZ together with the adjusted distribution ratios of Mn³⁺/Mn⁴⁺ and O_adsorbed/O_lattice. Considering the result of 3 wt% Mn/NZ, the 3 wt% Mn/RM was prepared to perform the catalytic activity for the removal of MEK and ozone, but the efficiency of 3 wt% Mn/RM was significantly lower than that of the 3 wt% Mn/NZ.

• Proceedings of the KSRS Conference
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• 2008.10a
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• pp.305-308
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• 2008

The goal of this study is to retrieve ASTER thermal radiometry using a radiative transfer model. The MODTRAN is used for the model because it is easy to use with high spatial resolution and it is possible to specify input parameters such as profiles of temperature, water vapor density, ozone, aerosols and any of the other gasses. Most of parameters such as temperature and water vapor profiles were obtained from the Terra MODIS. The selected ASTER scene images land and coastal area. The surface radiance of ASTER TIR bands were retrieved by MODTRAN and extracted atmospheric profiles from MOD07 and US standard 76 models. Radiance estimated using MOD07 data was systematically lower by about 0.5-1.0 $W/m^2$ sr ${\mu}m$ than that by US standard 76 model between the two cases.

• Journal of the Korean Society of Safety
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• v.15 no.4
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• pp.41-46
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• 2000

Silicone rubbers are elastomeric materials and organic copolymers, of which backbone is siloxane with high bonding strength. Silicone rubbers have been used as an power insulator because they are well weather proof, ozone proof and have excellent electric characteristics, thermal stability, cold resistance and low surface energy. Especially, it is known that they have very excellent characteristics at 200[$^{\circ}C$]. For this study, we made silicone rubbers as specimens and measured volume resistivity due to applied voltage and a variation of temperature 25[$^{\circ}C$] to 180[$^{\circ}C$]. Also we measured dielectric loss tangent due to applied voltage at temperature range 25[$^{\circ}C$] to 180[$^{\circ}C$] and frequency range 20[Hz] to 1${\times}10^6$[Hz].

• Journal of the Korean institute of surface engineering
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• v.33 no.2
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• pp.87-92
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• 2000

Transparent and electrical conducting tin oxide thin films were fabricated on soda lime silicate glass by thermal chemical vapour deposition technique. Thin films were deposition from mixtures of tetramethyltin (TMT) as a precursor, oxygen or oxygen containing ozone as an oxidant and 1,1,1,2-tetrafluoroethane as a doping material. Electrical properties of fabricated tin oxide films were changed depending on substrate temperature, and the amount of dopant. Resistivity of tin oxide films was reduced by doping fluorine or heat treatment. Thin films can be optimized at TMT flow rate of 8sccm, oxygen flow rate of 150sccm, 1,1,1,2-tetrafluoroethane floe rate of 300sccm and substrate temperature $380^{\circ}C$. In this conditions, the lowest resistivity of tin oxide films were $9$\times$10^{-4}$ $\Omega$cm.

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.258-263
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• 2000

River water is higher in temperature than the surrounding environment during the winter. It is highly suitable a heat source for heat pump system. Despite its suitability, however, it is not widely used, due to its fouling and corrosive nature in heat exchanger tubes of evaporator. It is designed prior-treatment system which come into direct contact with the river water, such as auto-seamer, ozone generator for bactericidal test and auto-cleaning system. And it is analyzed treatment effects for its operation. It is designed two-stage compression heat pump system using R-134a with heating load 35.16kW, ad analyzed its performance. As a result it is obtained 3.08 COP when mid-point pressure is 1,200kPa, and bypass ratio of flowing refreigerant to high-stage compressor is 25.1%

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.10
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• pp.1347-1354
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• 1999

Recently, the markets of the air conditioner are enlarging. The market size will reach 2.0 billion won in 2000. Electric heat pumps have been utilized as main residential air conditioners. especially in Korea. They cause a surge up electric power demand during summer. Moreover, the use of HCFCs and HFCs causes serious problem to the global environment such as global warming and ozone layer destruction. Absorption chiller and heater could solve such problems. It was built and tested for analyzing the performance of the generator for absorption chiller and heater. Experiment was done with a high temperature generator, a low temperature generator, heat exchangers, a condenser and a solution tank. It was tested that the double effect series flow cycle with two kinds of solution cycle. Solution cycle B showed better than solution cycle A. Two kinds of heat exchanger were used, where one's heat transfer area is bigger than the other. Bigger one increased a little performance of absorption chiller and heater. But it was not economical. From this study, we got that the coefficient of performance(COP) is 0.82 and the capacity is 7.24 kW for an absorption chiller and heater.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.1
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• pp.125-132
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• 1999

Studies are being done to replace conventional refrigerants with alternatives that have low or no ozone depletion and greenhouse warming Potentials, yet possess appropriate pro perties for a refrigeration cycle. To achieve this goal, a consistent set of thermodynamic properties of the working fluid is required. A common problem with the possible alternative refrigerants is that sufficient experimental data do not exist, thus making it difficult to develp complete equations of state that can predict properties in all regions including the vapor-liquid equilibrium. One solution is the use of the generalized equation of state correlations that can predict thermodynamic properties with a minimum number of characteristic parameters. Characteristic parameters required for the generalized equation of state are, in general, critical temperature, critical pressure, critical volume and normal boiling temperature. In this study, estimation of these characteristic parameters of refrigerants by group contribution method is developed.

• Journal of Power System Engineering
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• v.19 no.6
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• pp.68-74
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• 2015

NOx emission has been controlled because it is a major cause of the acid rain and effects considerably on formation and destruction of ozone. A SCR system on diesel engine is necessary to clear TierIII, because IMO(International Maritime Organization) plans on tightening regulations to TierIII at $1^{st}$ January 2016. In this study, flow analysis was accomplished with ANSYS Fluent program so that the SCR system would be retrofitted in training ship KAYA and the temperature distributions of exhaust gas in SCR sytem were investigated after it was installed. As a result, it was confirmed that pressure and velocity distributions in SCR system were depended on pipe line shapes, then it was designed as the pressure was lower. The temperature differential between 1 and 3 point was $15^{\circ}C$ because of evaporative latent heat of urea and the temperature of 4 point after catalyst was increased by $5^{\circ}C$ than 3 point because of exothermic reaction.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.7 no.4
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• pp.654-666
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• 1995

R502 has been extensively used as a working fluid in transport refrigerating vehicles and low temperature refrigerating machines but is to be phased out by the end of 1995 due to ozone layer depletion problem. In this study, both theoretical cycle analysis and experiments were carried out to examine the best substitutes for R502. Theoretical results indicate that the alternatives available in the market today may replace R502 without significant changes in the system without suction line heat exchanger(SLHX). When the system contains a SLHX, however, COPs of the alternatives increase up to approximately 15~20% than those without the SLHX. But simultaneously, the discharge temperatures of the compressor also increrease significantly with the SLHX. Actual test results obtained from the experiment with a transport vehicle's refrigerator indicate the similar trend as those of the theoretical results. Especially, HFCs and their mixtures show lower discharge temperature than those of R502, which is one of the desirable features. Further research is needed to study the effect of the SLHX on the performance of the real machine as well as on the oil return for reliability of the system.

• Journal of Environmental Science International
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• v.28 no.10
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• pp.831-840
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• 2019

Recently, summer high temperature events caused by climate change and urban heat island phenomenon have become a serious social problem around the world. Urban areas have low albedo and huge heat storage, resulting in higher temperatures and longer lasting characteristics. To effectively consider the urban heat island measures, it is important to quantitatively grasp the impact of urban high temperatures on the society. Until now, the study of urban heat island phenomenon had been carried out focusing only on the effects of urban high temperature on human health (such as heat stroke and sleep disturbance). In this study, we focus on the effect of urban heat island phenomenon on air pollution. In particular, the relationship between high temperature phenomena in urban areas during summer and the concentration of photochemical oxidant is investigated. High concentrations of ozone during summer are confirmed to coincide with a day when the causative substances (NO2,VOCs) are high in urban areas during the early morning hours. Further, it is noted that the night urban heat island intensity is large.. Finally, although the concentration of other air pollutants has been decreasing in the long term, the concentration of photochemical oxidant gradually increases in Daegu.