• Title/Summary/Keyword: oxygen flux density

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Characteristic analysis of The Catalyst Layer and Gas Diffusion Layer Model for FEMFC optimal design (FEMFC 최적설계를 위한 촉매층모델과 기체확산층 특성해석)

  • Kwon, Kee-Hong
    • Journal of IKEEE
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    • v.21 no.2
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    • pp.123-129
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    • 2017
  • Proton Exchange Membrane Fuel Cell (FEMFC) is a strong candidate for future automobile and power generation because of its high power density, low emission and low operation temperature. The major concerns of the gas diffusion layer (GDL) inside a FEMFC is water management. The GDL is typically comprised of carbon for electrical conductivity and PTFE for Hydrophobicity. In this simulation, GDL flooding was investigated using a simplified approach method of an established equation models(Fick' Law, Darcy, Law, Stefan-Maxwell diffusion). The performance of GDL was shown using result of the inner heat, water density and oxygen density of the cell using model equations. The catalyst layer mode in FEMFC showed results of effectiveness factor, Butler-volmer and hydrogen flux density. These results are interesting because the influence of several factors has been shown and the information will be helpful for fuel cell design.

Development of Virtual Integrated Prototyping Simulation Environment for Plasma Chamber Analysis and Design (VIP-SEPCAD) (플라즈마 챔버의 특성 분석 및 최적 설계를 위한 가상의 시뮬레이션 환경 개발)

  • 김헌창;설용태
    • Journal of the Semiconductor & Display Technology
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    • v.2 no.4
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    • pp.9-12
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    • 2003
  • This paper describes a newly developed simulation environment for analysis and design of a plasma processing chamber based on first principles including complicated physical and chemical interactions of plasma, fluid dynamics of neutrals, and transport phenomena of particles. Capabilities of our simulator, named VIP-SEPCAD (Virtual Integrated Prototyping Simulation Environment for Plasma Chamber Analysis and Design), are demonstrated through a two dimensional simulation of an oxygen plasma chamber. VIP-SEPCAD can provide plasma properties such as spatiotemporal profiles of plasma density and potential, electron temperature, ion flux and energy, etc. By coupling neutral and particle transport models with a three moment plasma model, VIP-SEPCAD can also predict spatiotemporal profiles of chemically reactive species and particles exist in plasma.

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Spatio-temporal Water Quality Characteristics of Major Streams in Pal-dang Watershed (팔당수계 주요하천 수질의 시·공간적 특성)

  • Han, Mideok;Lee, Eunju;Oh, Jogyo;Kim, Woongsoo;Lee, Changhee;Namkung, Eun;Chung, Wookjin
    • Journal of Korean Society on Water Environment
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    • v.25 no.3
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    • pp.394-403
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    • 2009
  • A total of 52 sampling sites were selected in the stream network of the upper Paldang watershed (e.g. Kyonan, Gapyeong, Jojong, Chengmi, Bockha, Yanghwa and Heuk streams). Over the time period of April 2007-February 2008, 1820 samples were collected and analyzed for physico-chemical variables of the upper watershed in order to investigate spatio-temporal water quality variation in particular the relationship with land use. Although temporal variations of water quality in each stream were similar and were significantly influenced by flow, spatial variations in each stream varied as physico-chemical characteristics of upper watershed. As a result of regression analysis, Biological Oxygen Demand (BOD), Chemical Oxygen Demand (COD), Total Nitrogen (T-N), and Total phosphorus (T-P) concentration were the most significantly and positively associated with people population density. It is necessary to manage not only water quality but also land use of upper watershed and flow flux.

DISTRIBUTIONS OF DENSITY, TEMPERATURE AND ABUNDANCES IN THE ORION NEBULA

  • Kim, Dong-Woo;Hong, Seung-Soo
    • Journal of The Korean Astronomical Society
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    • v.15 no.1
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    • pp.9-18
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    • 1982
  • To derive the distributions of electron density, temperature and gas-phase metal abundances within the Orion Nebula, we have performed a non-LTE analysis to the radio observations of hydrogen recombination lines and continuum flux over the frequency range from 0.1GHz to 100GHz. We have explicitly included the thermal balance condition in our analysis, hence our derived distributions have their internal consistencies. This enables us to derive the radial distribution of Oxygen and Nitrogen. The gas-phase concentrations of these cooling agents show about the solar values at the very central part of the nebula, then, decrease slowly outward, and finally become about one quarter of the solar values in the outer extended envelope. Such an outward decrease is interpreted as an outward increase of dust concentrations in the Orion.

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Oxygen Permeation and Mechanical Properties of La0.6Sr0.4Co0.2Fe0.8O3-δ Membrane with Different Microstructures (미세구조에 따른 La0.6Sr0.4Co0.2Fe0.8O3-δ 분리막의 산소투과 및 기계적 특성)

  • Lee, Shi-Woo;Lee, Seung-Young;Lee, Kee-Sung;Woo, Sang-Kuk;Kim, Do-Kyung
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.994-1000
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    • 2002
  • Oxygen permeability and the mechanical properties of mixed ionic-electronic conductive $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ perovskite-type membrane, fabricated by solid state reaction, were investigated with regard to microstructure. The microstructure of the membrane was controlled by changing the sintering temperature and holding time. The average grain size and relative density were evaluated as a function of sintering conditions. As the fraction of grain boundary decreased, oxygen permeability showed a tendency to increase. Especially the maximum oxygen flux of 0.37 ml/$cm^2$${\cdot}$min was measured for the specimen sintered at 1300${\circ}C$ for 10 h, which has high density and relatively large grain size. Fracture strength was dependent on the relative density of sintered body, while fracture toughness increased with average grain size.

Fabrication and Oxygen Permeation Properties of ${La_{1-x}Sr_{x}B_{1-{\gamma}}Fe_{\gamma}O_{3-{\delta}}$(B=Co, Ga) Perovskite-Type Ceramic Membranes (${La_{1-x}Sr_{x}B_{1-{\gamma}}Fe_{\gamma}O_{3-{\delta}}$(B=Co, Ga) 페롭스카이트 세라믹 분리막의 제조 및 산소투과특성)

  • 임경태;조통래;이기성;한인섭;서두원
    • Membrane Journal
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    • v.11 no.4
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    • pp.143-151
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    • 2001
  • We have fabricated mixed-ionic conducting membranes, L $a_{0.6}$S $r_{0.4}$ $Co_{0.2}$F $e_{0.8}$ $O_{3-}$$\delta$/ and L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ by the solid state method. Ceramic membranes consisted of perovskite-type structures and exhibited high relative density, >95%. Especially, dense L $a_{0.6}$S $r_{0.4}$Co $O_{3-}$$\delta$/ layer was coated on the L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ membranes by using screen printing technique in order to improve oxygen ion flux. We measured oxygen ion flux on uncoated L $a_{0.6}$S $r_{0.4}$ $Co_{0.2}$F $e_{0.8}$ $O_{3-}$$\delta$/, uncoated L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/, and coated L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ membranes. The L $a_{0.6}$S $r_{0.4}$ $Co_{0.2}$F $e_{0.8}$ $O_{3-}$$\delta$/ membranes showed the highest flux, 0.26 mL/min.$\textrm{cm}^2$ at 90$0^{\circ}C$, after steady state had been reached. The oxygen flux of coated L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ membranes showed higher value, 0.19 mL/min.$\textrm{cm}^2$ at 95$0^{\circ}C$. This flux was as much as 2 or 3 times higher than those of uncoated L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ membranes. 3-$\delta$/ membranes.X> 3-$\delta$/ membranes.membranes.

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$MgB_2$ Superconducting Properties under Different Annealing Condition (열처리 분위기에 따른 $MgB_2$ 초전도의 특성 변화)

  • Chung, K.C.;Kim, Y.K.;Zhou, S.;Dou, S.X.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.362-362
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    • 2009
  • $MgB_2$ bulk samples were sintered at different ambient. In this work, high purity Ar gas was added with oxygen and hydrogen gas, which can be regarded as impurity in a sense, as a possible dopant in the $MgB_2$. It was found that oxygen in the sintering ambient leads to a decrease in the critical current density $J_c$ at self field and lower fields. However, we can obtained higher $J_c$ at higher fields. It was also noted that $MgB_2$ samples sintered with 5% hydrogen in Ar revealed the increased $J_c$ at all fields compared to those processed in pure Ar ambient. From the XRD and FESEM analysis, the impurity gas in Ar can refine the $MgB_2$ grain size and result in increased grain. boundary, which can act as a strong flux pinning sites in $MgB_2$ samples. Also discussed are the effects of sintering ambient on irreversibility field, $H_{irr}$ and the upper critical field, $H_{C2}$.

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Sap Temperature Distribution of the Xylem and Leaf Water Status of Apple Trees in Relation to Soil Oxygen Diffusion Rates

  • Ro, Hee-Myong
    • Journal of Applied Biological Chemistry
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    • v.43 no.3
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    • pp.170-175
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    • 2000
  • A pot-lysimeter experiment was conducted with 3-year-old 'Tsugaru' apple (Malus domestica Borkh) trees to examine the changes in oxygen diffusion rate (ODR) with lateral flow velocity of water through soil. The influence of lateral water flow velocity on water relations and elemental content in leaf, and sap temperature distribution patterns of the xylem of trees were also determined. Trees were grown under four soil water regimes: (1) fast laterally flowing (FWT, $2.50{\times}10^{-4}cm\;s^{-1}$), (2) slow laterally flowing (SWT, $0.25{\times}10^{-4}cm\;s^{-1}$), and (3) stagnant water table (WLT) at 60-cm, and (4) drip-irrigation at -40 kPa of soil matric potential as a control. The rate of $O_2$ diffusion converged near $2{\times}10^{-3}g\;m^{-2}\;min^{-1}$ for FWT and control soils, but decreased below $1{\times}10^{-3}g\;m^{-2}\;min^{-1}$ 40 days after treatment (DAT) for WLT soils. For SWT soils, however, the ODR at 15 cm below the soil surface was similar to that of control, but at 45 cm below the soil surface, ODR was similar to that of the WLT treatment. Leaf water potential of FWT and SWT plants was similar to that of control plants, but the values for SWT plants declined by 98 DAT. Leaf water potential of WLT plants decreased from -1.86 MPa (9 DAT) to -2.41 MPa (59 DAT) and finally down to -2.70 MPa. The sap temperature measured at 1100-hr was lowest at top and highest at bottom for FWT and control plants, but this pattern of SWT and WLT plants was disturbed from 29 DAT. However, for SWT plants, such thermal disturbance of sap temperature disappeared from 63 DAT.

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A Study on the Fire Risk Comparison of Building Flooring Materials by External Heat Flux (건축용 바닥재의 외부복사열에 의한 화재위험성 비교 연구)

  • Park, Youngju;Kim, Youngtak
    • Journal of the Korean Society of Safety
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    • v.32 no.5
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    • pp.20-24
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    • 2017
  • In this study, we have performed the Cone Calorimeter test in accordance with ISO 5660-1 to check the combustion characteristics of building flooring materials. The fire risk of these materials were evaluated by construction code, KFI criteria and standards of flame retardant performance. When samples exposed to external heat flux, all samples consumed a lot of Oxygen for a long time. So heat release from sample burning continued so long. And also all samples produced so much smoke. Even though a few samples were satisfied with only peak heat release rate criteria, all 8 samples were not satisfied with criteria of peak heat release rate and total heat released together. The results of 5 min total heat released were $15.9MJ/m^2{\sim}5.9MJ/m^2$. It menas the results are more than 2~6 times higher than the criteria. The results of 10 min total heat released were $30.1MJ/m^2{\sim}100.8MJ/m^2$. It means the results are more than 3~12 times higher than the criteria. 6 of 8 samples were not satisfied with Dm.corr.(corrected maximum smoke density) criteria. The building flooring materials which we used for this test ignited very fast and the burning continued so long. It means these samples are susceptible to fire.

Development of Program for Ignition Temperature and Its Applications (발화온도 산출 프로그램 개발 및 적용)

  • Park, Won-Hee;Cho, Youngmim;Kwon, Tae-Soom
    • Asia-pacific Journal of Multimedia Services Convergent with Art, Humanities, and Sociology
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    • v.7 no.4
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    • pp.243-250
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    • 2017
  • A fire phenomenon of a solid such as wood involves a phenomenon in which solid is heated from the outside and the gas generated through the thermal pyrolysis process of the material is burnt. The thermal pyrolysis phenomenon of the solid is a phenomenon in which the amount of energy incident from the outside, the amount of heat dissipation of the solid material, the heat transfer between the solid material and the surroundings including the amount of heat transfer to the air adjacent to the solid surface, and the fraction of oxygen in the air. In this paper, we calculate the required ignition temperature to simulate the fire phenomenon as simple as possible. By using cone calorimeter, the ignition time was measured by variously controlling the heat flux flowing into the wood specimen by using various wood specimens. The user friendly program is developed for calculation of the ignition temperature. Five different woods such as low density MDF, high density MDF, plywood, douglas fir and PB with various thickness are considered. The ignition temperatures suggested in this paper can be used for fire propagation analysis for woods.