• Title/Summary/Keyword: oxygen concentration

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Ellipsometric study of Mn-doped $Bi_4Ti_3O_{12}$ thin films

  • Yoon, Jae-Jin;Ghong, Tae-Ho;Jung, Yong-Woo;Kim, Young-Dong;Seong, Tae-Geun;Kang, Lee-Seung;Nahm, Sahn
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.173-173
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    • 2010
  • $Bi_4Ti_3O_{12}$ ($B_4T_3$) is a unique ferroelectric material that has a relatively high dielectric constant, high Curie temperature, high breakdown strength, and large spontaneous polarization. As a result this material has been widely studied for many applications, including nonvolatile ferroelectric random memories, microelectronic mechanical systems, and nonlinear-optical devices. Several reports have appeared on the use of Mn dopants to improve the electrical properties of $B_4T_3$ thin films. Mn ions have frequently been used for this purpose in thin films and multilayer capacitors in situations where intrinsic oxygen vacancies are the major defects. However, no systematic study of the optical properties of $B_4T_3$ films has appeared to date. Here, we report optical data for these films, determined by spectroscopic ellipsometry (SE). We also report the effects of thermal annealing and Mn doping on the optical properties. The SE data were analyzed using a multilayer model that is consistent with the original sample structure, specifically surface roughness/$B_4T_3$ film/Pt/Ti/$SiO_2$/c-Si). The data are well described by the Tauc-Lorentz dispersion function, which can therefore be used to model the optical properties of these materials. Parameters for reconstructing the dielectric functions of these films are also reported. The SE data show that thermal annealing crystallizes $B_4T_3$ films, as confirmed by the appearance of $B_4T_3$ peaks in X-ray diffraction patterns. The bandgap of $B_4T_3$ red-shifts with increasing Mn concentration. We interpret this as evidence of the existence deep levels generated by the Mn transition-metal d states. These results will be useful in a number of contexts, including more detailed studies of the optical properties of these materials for engineering high-speed devices.

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The Concentrations and Loads of Pollutant in Wet Deposition in Cheongju (습성강하물 중의 오염물질의 농도와 부하 - 충북 청주시를 중심으로-)

  • Kim, Jin-Soo;Oh, Seung-Young;Oh, Kwang-Young;Lee, Jong-Jin;Kim, Sun-Jong;Cho, Jae-Won;Khan, Jong-Bum;Jeong, Gu-Young
    • Journal of Korea Water Resources Association
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    • v.37 no.11
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    • pp.959-967
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    • 2004
  • The concentrations and loads of total nitrogen (TN), total phosphorus (TP), and chemical oxygen demand (COD) in wet deposition were investigated at Chungbuk National University in Cheongju, Chungbuk. Event based precipitation samples were collected during 1998 to 2003. The precipitation-weighted mean concentrations of pollutants were 0.60 mg/L for TN, 0.014 mg/L for TP, and 4.8 mg/L for COD, which were smaller than its arithmetic mean concentrations by 26% for TN, 18% for TP, and 14% for COD. The concentrations of TN, TP, and COD significantly decreased with precipitation. Mean concentrations of pollutants in spring (March-May) were higher than in other seasons likely due to dust caused by wind erosion and sand-dust storms, pollen etc. Significant relationships were determined between TN and TP, and TN and COD. Annual loads of wet deposition averaged 7.9 kg/ha$\cdot$yr for TN, 0.19 kg/ha$\cdot$yr for TP, and 63.9 kg/ha$\cdot$yr for COD, which are almost identical to the values of TN and TP but slightly higher than COD value reported in Japan.

Analysis of RCSTP And MWTP Pollutants Treatment Efficiency in Bong-Hwa Gun (봉화군 마을하수도 및 하수처리장의 오염물질 처리 효율 분석)

  • Park, Minsoo;Im, Jiyeol;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.19 no.1
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    • pp.69-79
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    • 2017
  • Protected area of water for supply source is located mostly of rural area in Korea. Normally, sewage treatment system is poor to manage in rural, because low population and density. Rural area need sewage treatment system to supervise supply source of water. In this study, analysis on operation result of 4 RCSTP and MWTP is located at the rural area. Higher concentration of pollutant were inflows to MWTP than RCSTP, and effluent quality standard is satisfaction. However, RCSTP effluent pollutant concentrations was researched higher than MWTP. The organic matter(BOD, COD) were about 5% of a high treatment efficiency to a median. The nutrient(T-N, T-P) were detected Up to high 30%. Also, we analyzed to effect reactor operational parameters on the pollutant treatment efficiency like mixed liquer suspended solid(MLSS), dissolved oxygen(DO) and sludge retention time(SRT). As a result, pollutant treatment efficiency showed fluctuation in accordance with operating condition. Thus, it is necessary to manage the reactor operation condition for management of rural area sewage treatment.

Study on Feasibility of Fluidized Bed Membrane Reactor with Granular Activated Carbon Particles as Fluidized Media to Treat Metal-plating Wastewater (도금폐수처리를 위한 입상활성탄 유동 메디아 적용 유동상 멤브레인 여과기술의 적용가능성 평가에 관한 연구)

  • Chang, Soomin;Kwon, Deaeun;Kim, Jeonghwan
    • Membrane Journal
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    • v.28 no.4
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    • pp.252-259
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    • 2018
  • An acidic, real metal-plating wastewater was treated by a fluidized bed membrane reactor introduced with granular activated carbon (GAC) as fluidized media. With GAC fluidization, there was no increase in suction pressure with time at each flux set-point applied. At neutral solution pH, much less fouling rate was observed than acidic pH under GAC fluidization. Higher solution pH resulted in the increase in particle size in metal-finishing wastewater, thus producing a less dense cake structure on membrane. More than 95% of chemical oxygen demand was observed from the fluidized bed membrane reactor under GAC fluidization. Total suspended solid concentration in membrane permeate was near zero. At the raw wastewater pH, no removal of copper and chromium by the fluidized bed membrane reactor was observed. As the pH was increased to 7.0, removal efficiency of copper and chromium was increased considerably to 99 and 94%, respectively. Regardless of solution pH tested, more than 95% of cyanide was removed possibly due to the strong adsorption of organic-cyanide complex on GAC in fluidized bed membrane reactor.

Influence of Transgenic Corn on the In vitro Rumen Microbial Fermentation

  • Sung, Ha Guyn;Min, Dong Myung;Kim, Dong Kyun;Li, De Yun;Kim, Hyun Jin;Upadhaya, Santi Devi;Ha, J.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.12
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    • pp.1761-1768
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    • 2006
  • In this study, the comparative effects of transgenic corn (Mon 810 and Event 176) and isogenic corn (DK729) were investigated for their influence on in vitro rumen fermentation. This study consisted of three treatments with 0.25 g rice straw, 0.25 g of corn (Mon810/Event176/DK 729) mixed with 30 ml rumen fluid-basal medium in a serum bottle. They were prepared in oxygen free conditions and incubated at $39^{\circ}C$ in a shaking incubator. The influence of transgenic corn on the number of bacterial population, F. succinogenes (cellulolytic) and S. bovis (amylolytic), was quantified using RT-PCR. Fermentative parameters were measured at 0, 2, 4, 8, 12 and 24 h and substrate digestibility was measured at 12 and 24 h. No significant differences were observed in digestibility of dry matter, NDF, ADF at 12 and 24 h for both transgenic and isogenic form of corns (p>0.05) as well as in fermentative parameters. Fluid pH remained unaffected by hybrid trait and decreased with VFA accumulation as incubation time progressed. No influence of corn trait itself was seen on concentration of total VFA, acetic, propionic, butyric and valeric acids. There were no significant differences (p<0.05) in total gas production, composition of gas (methane and hydrogen) at all times of sampling, as well as in NH3-N production. Bacterial quantification using RT-PCR showed that the population number was not affected by transgenic corn. From this study it is concluded that transgenic corn (Mon810 and Event 176) had no adverse effects on rumen fermentation and digestibility compared to isogenic corn. However, regular monitoring of these transgenic feeds is needed by present day researchers to enable consumers with the option to select their preferred food source for animal or human consumption.

Spermatogenic and Antioxidant Potential of Mucuna prureins (L.) in Epididymal Spermatozoa: A Dose Dependent Effect

  • Suresh, Sekar;Prithiviraj, Ealumali;Venkatalakshmi, Nagella;Ganesh, Mohanraj Karthik;Ganesh, Lakshmanan;Lee, Hyun-Jeong;Prakash, Seppan
    • Reproductive and Developmental Biology
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    • v.35 no.4
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    • pp.441-447
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    • 2011
  • The study aim is to investigate the free radicals scavenging and spermatogenic potentials, as well as to analyze any reproductive toxicity of ethanolic extract of Mucuna prureins (M. pruriens) Linn. in spermatozoa, under different dosages in normal male rat. Normal rats were randomly selected and suspension of the extract was administered orally at the dosages of 150, 200 and 250 mg/kg body weight of the different groups of male rats (n=6) once in a day for 60 days and grouped as group II, III and IV respectively. Saline treated rats served as control -group I. On the $60^{th}$ day the animals were sacrificed and the epididymal sperm were subjected to various analyses like level of ROS production, LPO, enzymatic and non enzymatic antioxidant, morphology, morphometry, chromosomal integrity and DNA damage. Results showed significant reduction in ROS production and peroxidation and significant increase in both enzymic and non-enzymic antioxidants in all concentration treated groups when compared with control. Results from all the drug treated groups showed good sperm morphology, increased sperm count and motility. There was no DNA damage and showed normal chromosomal integrity even in 250 mg/kg dose. When compared with control all the three extract treated groups showed increased ROS scavenging activity. However, group II (200 mg/kg) showed significant changes in all the parameters. From the present study it was confirmed that the M. pruriens has potential to improve the sperm qualitatively and quantitatively through scavenging the excess ROS with any adverse side effects. These observations suggest that ethanolic seed extract of M. pruriens may serve as anti-oxidant that can exploit to treat the oxidative stress mediated male factor infertility.

The Distributions of Nutrients, Chlorophyll-a, and Primary Productivity in the South Pacific Ocean (남태평양의 영양염, 엽록소, 일차생산성 분포)

  • Kim, Dong-Yup;Shim, Jung-Hee;Song, Hwan-Seok;Kang, Young-Chul;Kim, Dong-Seon
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.6 no.1
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    • pp.40-48
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    • 2001
  • The vertical distributions of temperature, salinity, dissolved oxygen, nutrients, chlorophyll, and primary production were investigated within the top 200m water depth in the south Pacific Ocean in February,2000. The study area ($24^{\circ}-41^{\circ}S,\;81^{\circ}-168^{\circ}W$) can be hydrologically divided into two regions. Upwelling was actively occurring in the eastern region of the $110^{\circ}S$ line, meanwhile it was not active in the western region. Accordingly, chemical properties in the surface waters were different between the two regions; nitrate+nitrite and phosphate concentrations were much higher in the eastern region than in the western region due to the active upwelling, but silicate concentration was higher in the western region. Among the nutrients, the major element influencing primary production was also different between the two regions; silicon would be a major element influencing primary production in the eastern region, but nitrogen may act as a major element for primary production in the western region. Primary production showed similar values in the two regions in spite of the large differences of nutrient concentrations in the surface waters, but the total chlorophyll integrated within the 200 m water depth was almost twice as much as in the western region than that in the eastern legion.

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Eutrophication and Seasonal Variation of Water Quality in Masan-Jinhae Bay (마산-진해만의 수질 부영양화 및 계절 변동)

  • Cho, Kyung-Je;Choi, Man-Young;Kwak, Seung-Kook;Im, Sung-Ho;Kim, Dae-Yun;Park, Jong-Gyu;Kim, Young-Eui
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.3 no.4
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    • pp.193-202
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    • 1998
  • Water quality of Masan-Jinhae Bay was monitored from January 1996 to August 1997. The monitoring focused on the spatial and vertical gradients and seasonal changes of eutrophication parameters such as nutrients, DO and water transparency. Flagellate phytoplanktons persistently bloomed from April to October with monospecific or mixed algal blooms and dynamic algal successions were observed in this area. Algal blooms were highly correlated with salinity drops and made the water less transparent. Stratification of oxygen content was persistent through summer and oligo-oxygenation was developed in the bottom waters. Nutrient gradients were consistently maintained through the depth in summer and through spatial distribution from inner Masan Bay to outer Jinhae Bay in winter. Except the rainfall seasons, water quality was under the influence of the waste waters discharged from watershed around the Masan Bay. The waste waters would act as the primary factor for the water quality deterioration of the bay. Literature data for eutrophication were gathered and analyzed to review the water quality trends of the Masan and Jinhae bays since 1970. Annual mean COD and phosphate concentration consistently increased from 1975 to 1990 and decreased or dropped after 1991. The sediment of inner part of Masan Bay was dredged from 1991 to 1994 as a decontamination process and it is assumed that the dredging has weakened more or less the deterioration trend of the water quality of the bay.

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Molecular Mechanism of Tetrabromobisphenol A (TBBPA)-induced Target Organ Toxicity in Sprague-Dawley Male Rats

  • Choi, Jae-Seok;Lee, Young-Jun;Kim, Tae-Hyung;Lim, Hyun-Jung;Ahn, Mee-Young;Kwack, Seung-Jun;Kang, Tae-Seok;Park, Kui-Lea;Lee, Jae-Won;Kim, Nam-Deuk;Jeong, Tae-Cheon;Kim, Sang-Geum;Jeong, Hye-Gwang;Lee, Byung-Mu;Kim, Hyung-Sik
    • Toxicological Research
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    • v.27 no.2
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    • pp.61-70
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    • 2011
  • Brominated flame retardants (BFRs) are present in many consumer products ranging from fabrics to plastics and electronics. Wide use of flame retardants can pose an environmental hazard, which makes it important to determine the mechanism of their toxicity. In the present study, dose-dependent toxicity of tetrabromobisphenol A (TBBPA), a flame retardant, was examined in male prepubertal rats (postnatal day 18) treated orally with TBBPA at 0, 125, 250 or 500 mg/kg for 30 days. There were no differences in body weight gain between the control and TBBPA-treated groups. However, absolute and relative liver weights were significantly increased in high dose of TBBPA-treated groups. TBBPA treatment led to significant induction of CYP2B1 and constitutive androstane receptor (CAR) expression in the liver. In addition, serum thyroxin (T4) concentration was significantly reduced in the TBBPA treated group. These results indicate that repeated exposure to TBBPA induces drug-metabolising enzymes in rats through the CAR signaling pathway. In particular, TBBPA efficiently produced reactive oxygen species (ROS) through CYP2B1 induction in rats. We measured 8-hydroxy-2'-deoxyguanosine (8-OHdG), a biomarker of DNA oxidative damage, in the kidney, liver and testes of rats following TBBPA treatment. As expected, TBBPA strongly induced the production of 8-OHdG in the testis and kidney. These observations suggest that TBBPA-induced target organ toxicity may be due to ROS produced by metabolism of TBBPA in Sprague-Dawley rats.

Comparative Hepatotoxicity Assessment of Cadmium and Nickel with Isolated Perfused Rat Liver(IPRL) (적출간 관류법을 이용한 카드뮴과 니켈의 간독성 비교)

  • Cha, Bong-Suk;Chang, Sei-Jin;Lee, Jung-Woo;Wang, Seung-Jun
    • Journal of Preventive Medicine and Public Health
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    • v.33 no.1
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    • pp.117-124
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    • 2000
  • Objectives : It is the objective of this study to compare hepatotoxicity of nickel chloride and cadmium chloride with each other through IPRL(Isolated Perfused Rat Liver) method. Methods : Biochemical indicator of hepatic function such as AST(aspartate aminotransferase), ALT(alanine aminotransferase), LDH(lactate dehydrogenase) and perfusion flow rate were used as the indicator of hepatotoxicity. Oxygen consumption rate were used as vability indicator. $300({\pm}50)g$ - weighted rats were allocated randomly to each group($0{\mu}M,\;50{\mu}M,\;200{\mu}M\;NiCl_2\;and\;CdCl_2$ exposure) by 5, totally 25. After Krebs-Ringer bicarbonate butler solution flowed into the penal vein and passed the liver cell, it flowed out of vena cava. Liver was administered with each $NiCl_2\;and\;CdCl_2$ of each concentration and observed with buffer solution sampling time. Butler which got out of liver was sampled and then biochemical indicator of hepatotoxicity was measured. Results : AST, ALT, and LDH in buffer increased with sampling time much more in $CdCl_2$ exposure group than $NiCl_2$ exposure group in both 50 and $200{\mu}M$ and statistical significance w3s verified with 2-way repeated ANOVA. Viability was decreased more and more in all substances during passed time. Conclusions : It is inferred that $CdCl_2$ has stronger hepatotoxicity than $NiCl_2$. IPRL method would be used widely for acute hepatotoxicity when considerating the benefit of it.

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