• Title/Summary/Keyword: oxygen ambient

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Characteristics of NiCr Thin Films Prepared by rf Magnetron Sputtering as Absorption Layer for Infrared Sensors (적외선 센서를 위해 흡수층으로서 rf Magnetron Sputtering에 의해 제조된 NiCr 박막의 특성)

  • Hur, Sung-Gi;Choi, Eun-Suck;Yoon, Soon-Gil
    • Korean Journal of Materials Research
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    • v.13 no.10
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    • pp.640-644
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    • 2003
  • NiCr thin films were fabricated by rf magnetron sputtering for applying to both the top electrode and absorption layer on Pb(Zr, Ti)O$_3$(PZT) thin films for infrared sensors. The rms roughness and resistivity of NiCr films prepared with Ni power of 80 W and Cr power of 50 W showed the most stable oxidation resistance after annealing at $600^{\circ}C$ for 5 min in oxygen ambient. The rms roughness and resistivity of NiCr films annealed at $V^{\circ}C$ in oxygen ambient were about 2$0\AA$ and $70 \mu$Ω-cm, respectively. As-deposited Ni/PZT/Pt and NiCr (Ni 80 W, Cr 50 W)/PZT/Pt structures showed well saturated hysteresis loops. However, in case of the samples annealed at $500^{\circ}C$ in oxygen ambient, only NiCr/PZT/Pt showed saturated loops having a remanent polarization of 20$\mu$C/$\textrm{cm}^2$. Ultra-thin NiCr films showed a possibility as a top electrode for infrared sensors.

Electrical and structural characteristics of AZO thin films deposited by reactive sputtering (Reactive sputtering 법으로 증착된 AZO 박막의 전기적 및 구조적 특성)

  • Heo, Ju-Hee;Lee, Yu-Lim;Lee, Kyu-Mann
    • Journal of the Semiconductor & Display Technology
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    • v.8 no.1
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    • pp.33-38
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    • 2009
  • We have investigated the effect of the ambient gases on the characteristics of AZO thin films for the OLED (organic light emitting diodes) devices. These AZO thin films are deposited by rf-magnetron sputtering under different ambient gases (Ar, Ar+$O_2$, and Ar+$H_2$) at 300. In order to investigate the influences of the oxygen and hydrogen, the flow rate of oxygen and hydrogen in argon mixing gas has been changed from 0.2sccm to 1sccm and from 0.5sccm to 5sccm, respectively. The AZO thin films were preferred oriented to (002) direction regardless of ambient gases. The electrical resistivity of AZO film increased with increasing flow rate of $O_2$ under Ar+$O_2$ while under Ar+$H_2$ atmosphere the electrical resistivity showed minimum value near 1sccm of $H_2$. All the films showed the average transmittance over 80% in the visible range. The OLED device was fabricated with different AZO substrates made by configuration of AZO/$\acute{a}$-NPD/DPVB/$Alq_3$/LiF/Al to elucidate the performance of AZO substrate.

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Effects of Post-Annealing Treatment of ZnO Thin Films by Pulsed Laser (PLD를 이용한 ZnO 박막의 후열처리에 관한 연구)

  • Lee Cheon;Kim Jae-Hong
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.3
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    • pp.103-108
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    • 2005
  • ZnO thin films on (001) sapphire substrates have been deposited by pulsed laser deposition(PLD) technique using an Nd:YAG laser with a wavelength of 266nm. Before post-annealing treatment in the oxygen ambient, the experiment of the deposition of ZnO thin films has been performed for substrate temperatures in the range of $300\~450^{\circ}C$ and oxygen gas flow rate of $100\~700\;sccm$. In order to investigate the effect of post-annealing treatment of ZnO thin films, films have been annealed at various temperatures after deposition. After post-annealing treatment in the oxygen ambient, the structural properties of ZnO thin films were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM) and the optical properties of the ZnO were characterized by photoluminescence(PL).

$MgB_2$ Superconducting Properties under Different Annealing Condition (열처리 분위기에 따른 $MgB_2$ 초전도의 특성 변화)

  • Chung, K.C.;Kim, Y.K.;Zhou, S.;Dou, S.X.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.362-362
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    • 2009
  • $MgB_2$ bulk samples were sintered at different ambient. In this work, high purity Ar gas was added with oxygen and hydrogen gas, which can be regarded as impurity in a sense, as a possible dopant in the $MgB_2$. It was found that oxygen in the sintering ambient leads to a decrease in the critical current density $J_c$ at self field and lower fields. However, we can obtained higher $J_c$ at higher fields. It was also noted that $MgB_2$ samples sintered with 5% hydrogen in Ar revealed the increased $J_c$ at all fields compared to those processed in pure Ar ambient. From the XRD and FESEM analysis, the impurity gas in Ar can refine the $MgB_2$ grain size and result in increased grain. boundary, which can act as a strong flux pinning sites in $MgB_2$ samples. Also discussed are the effects of sintering ambient on irreversibility field, $H_{irr}$ and the upper critical field, $H_{C2}$.

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Effect of annealing pressure on the growth and electrical properties of $YMnO_3$ thin films deposited by MOCVD

  • Shin, Woong-Chul;Park, Kyu-Jeong;Yoon, Soon-Gil
    • Journal of Korean Vacuum Science & Technology
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    • v.4 no.1
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    • pp.6-10
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    • 2000
  • Ferroelectric YMnO$_3$ thin films were deposited on $Y_2$O$_3$/si(100) substrates by metalorganic chemical vapor deposition. The YMnO$_3$ thin films annealed in vacuum ambient (100 mTorr) above 75$0^{\circ}C$ show hexagonal structured YMnO$_3$. However, the film annealed in oxygen ambient shows poor crystallinity, and the second phase as $Y_2$O$_3$ and orthorhombic-YMnO$_3$ were shown. The annealing ambient and pressure on the crystallinity of YMnO$_3$ thin films is very important. The C-V characteristics have a hysteresis curve with a clockwise rotation, which indicates ferroelectric polarization switching behavior. When the gate voltage sweeps from +5 to 5 V, the memory window of the Pt/YMnO$_3$/Y$_2$O$_3$/Si gate capacitor annealed at 85$0^{\circ}C$ is 1.8 V. The typical leakage current densities of the films annealed in oxygen and vacuum ambient are about 10$^{-3}$ and 10$^{-7}$ A/cm$^2$ at applied voltage of 5 V.

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An Experimental Study on the Combustion Behavior of Single Coal-Water Slurry Droplet (석탄-물 혼합물 단일액적의 연소 특성에 관한 실험적 연구)

  • 채재우;조용철;전영남;한영수
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.11
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    • pp.2159-2168
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    • 1992
  • Coal-water slurry is considered to have the potential for displacing petroleum used in the existing oil-fired industrial and utility boilers. The combustion of coal-water slurry(CWS) is a complex process and little is known about the detailed mechanism. In this paper the combustion behavior of a single suspended droplet of CWS in hot gas stream was investigated. The effect of coal particle size, water content in droplet, initial droplet size, ambient temperature and oxygen fraction in ambient gas were studied. The results are as follows; (1) Increasing the oxygen fraction in ambient gas considerably reduced the char combustion time. (2) The variation of water content and coal particle size in droplet showed little effect on the combustion behavior. (3) In the relatively high temperature ambient gas, the water evaporation time became shorter and the combustion process was stable.

Effect of Initial Diameter on the Soot Generation of Toluene Fuel Droplet (초기 직경 변화가 Toluene 액적의 Soot 생성에 미치는 영향)

  • Lim, Young Chan;Suh, Hyun Kyu
    • Journal of ILASS-Korea
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    • v.20 no.4
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    • pp.261-267
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    • 2015
  • The main purpose of this study is to provide the information of soot generation of toluene fuel droplet. To achieve this, this paper provides the experimental results on the different initial diameter of toluene droplet combustion characteristics conducted under equivalent ambient pressure ($P_{amb}$) and oxygen concentration ($O_2$) conditions. Visualization of single fuel droplet was performed with high resolution CCD camera and visualization system. At the same time, ambient pressure ($P_{amb}$) and oxygen concentration ($O_2$) were maintained by ambient condition control system. Soot volume fraction ($f_v$) was analyzed and compared on the basis of intensity ratio ($I/I_0$) of background image. The result of soot generation was almost the same regardless of initial droplet diameter since thermophoretic flux is not much changed under the same ambient conditions. Soot standoff ratio (SSR) of 2 mm diameter showed unstable variation characteristics due to the short available measuring time.

Experimental Study on the Soot Formation Characteristics of Alkane-based Single Fuel Droplet (알케인계 단일 연료 액적의 Soot 생성 특성에 관한 실험적 연구)

  • Lim, Young Chan;Suh, Hyun Kyu
    • Journal of ILASS-Korea
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    • v.22 no.2
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    • pp.80-86
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    • 2017
  • The soot formation characteristics of various alkane-based single fuel droplets were studied in this work. Also, This study was performed to provide the database of the soot behavior and formation of alkane-based single fuel droplet. The experimental conditions were set to 1.0 atm of ambient pressure ($P_{amb}$), 21% of oxygen concentration ($O_2$) and 79% of nitrogen concentration ($N_2$). Combustion and soot formation of single fuel droplet was visualized by visualization system with high speed camera. At the same time, ambient pressure, oxygen concentration and nitrogen concentration were maintained by ambient condition control system. Soot formation characteristics was analyzed and compared on the basis of intensity ratio ($I/I_0$) of background image. The results of toluene fuel droplet showed the largest soot generation. Soot volume fraction ($f_v$) was almost the same under the identical fuel types regardless of various initial droplet diameter ($d_0$) since thermophoretic flux was not much changed under the same ambient conditions.

A Study on the Degradation Mechanism of ZnO Ceramic Varistor Manufactured by Ambient Sintering-Process (분위기 소결공정에 의해 제조된 ZnO 세라믹 바리스터의 열화기구 연구)

  • 소순진;김영진;박춘배
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.5
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    • pp.383-389
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    • 2000
  • The relationship between the DC degradation characteristics of the ZnO varistor and the ambient sintering-process is investigated in this study. ZnO varistors made o matsuoka’s composition were fabricated by standard ceramic techniques. The ambient sintering-process is performed at the extraordinary electrical-furnace which is equipped with the vacuum system. Gases used in sintering process were oxygen nitrogen argon and air. Using XRD and SEM the phase and microstructure of samples were analyzed respectively. The conditions of DC degradation tests were conducted at 115$\pm$2$^{\circ}C$ for 13 h. Current-voltage analysis is used to determine nonlinear coefficients($\alpha$). Frequency analysis are performed to understand electrical properties as DC degradation test. From above analysis it is found that the ZnO varistor sintered in oxygen atmosphere showed superior properties at the DC degradation test and degradation phenomenon of ZnO varistor is caused by the change of electrical properties in grain boundary. These results are in accordance with Gupta’s degradation model.

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Effect of Ambient Air Temperature on the Pattern of Clothing Ventilation through Openings (환경 온도가 개구부를 통한 의복의 환기 양상에 미치는 영향)

  • 추미선
    • The Research Journal of the Costume Culture
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    • v.10 no.6
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    • pp.793-801
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    • 2002
  • The effects of ambient air temperature on the clothing ventilation were investigated numerically by a finite difference method. Numerical analysis using a 2-dimensional model comprising the air space between the skin and the clothing was conducted under the assumption that the clothing ventilation occurred only through the openings not through the fabric. The larger the temperature difference between the skin and the surroundings, the more apparent the thermal boundary layer As the ambient air temperature decreased, the air flow and the rate of the return of oxygen concentration to the atmosphere level in the clothing increased. Convection was dominant under low ambient air temperature, whereas conduction was dominant under high ambient air temperature. The ventilation rate was faster in the clothing microenvironment of the body part than that of the arm part.

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