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The Research on the Oxidative Stress by Free Oxygen Radicals in Sasang Constitution (활성산소(活性酸素)에 의한 산화스트레스환자의 사상체질별(四象體質別) 특성(特性)에 관한 연구(硏究))

  • Han, Kyoung-Su;Ahn, Taek-Won;Bae, Na-Young
    • Journal of Sasang Constitutional Medicine
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    • v.18 no.3
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    • pp.155-165
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    • 2006
  • 1. Objectives The purpose of this research is to find out the Constitutional difference of Oxidative stress by Free oxygen radicals. 2. Methods We enrolled 55 patients who visited our hospital for medical examination from February 1, 2006 to May 31, 2006. This research investigated the Constitutional difference of Oxidative stress by Free oxygen radicals. 3. Results and Conclusions l) The Sasang Constitutional distribution of patients have oxidatative stress by Free oxygen radicals was Taeunmin 30%(8persons of total 27persons), Soeumin 56%(9persons of total 16persons), Soyangin 33%(4persons of total 12persons). The rate of patients have oxidatate stress was high in Soeumin. The Sasang Constitution had significance relation with oxidatative stress by Free oxygen radicals. 2) Triglyceride on the average of Taeumin patients have oxidatative stress by Free oxygen radicals is ststistical significantly higher than Triglyceride on the average of controlled normal persons in Taeumin(p-value=0.010) and Soyangin(p-value=0.015). Blood uric acid level on the average of patients have oxidatate stress by Free oxygen radicals is ststistical significantly lower than Blood uric acid level on the average of controlled normal persons in Taeumin(p-value=0.004) and Soyangin(p-value=0.037). This research has shown that there is a statistical significance between the Triglyceride level, Blood uric acid level and oxidatate stress by Free oxygen radicals.

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Inhibition of Aldehyde Dehydrogenase by the Active Oxygen Species (활성산소종에 의한 알데히드 탈수소 효소의 불활성화)

  • 문전옥;김태완;백기주;김기헌
    • YAKHAK HOEJI
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    • v.37 no.6
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    • pp.647-658
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    • 1993
  • The susceptibilities of aldehyde dehydrogenase (AldDH) and alcohol dehydrogenase (ADH) to active oxygen generated by xanthine-xanthine oxidase (XOD) system were studied. Incubation of AldDH with 2$\times$10$^{-3}$ units of XOD for 30 min at $25^{\circ}C$ resulted in the decrease of enzyme activity to 30% and it was inactivated completely when incubated with 5$\times$10$^{-3}$ units of XOD. Whereas 70% of ADH activity was retained after exposure to 5$\times$10$^{-3}$ units of XOD for 30 min, 40% of ADH activity was retained after exposure to 5$\times$10$^{-2}$ unit of XOD for 30 min. This inhibition effect by the active oxygen was preventable by catalase and glutathione, but not by SOD. The rates of the NADPH-dependent oxygen consumption by the liver S-9 mixture and microsomes were also determined in this study. Rate of oxygen consumption is increased in the liver S-9 mix and microsomes from phenobarbital-treated rat, and it was consistent with increased lipid peroxidation. In the presense of ethanol as a substrate, the oxygen consumption rates were increased. It is reported that hepatic AldDH activity is depressed in alcoholic liver diseases, however there is few report that explains the reason of depressed AldDH activity. These results are supportive of the theory that the increase in hepatic ethanol oxidation through the induced ME activity after chronic ethanol feeding generate oxygen radical at elevated rates and it leads to the depression of AldDH activity.

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Cultivation of Sprout by Highly Concentrated Oxygen Water Soaking (고농도 산소수 침지를 통한 새싹 재배)

  • Cha, Jin-Myeong;Hong, Seung-Ho;Kim, Sun-Yil;Park, Ju-Young;Kim, Maeng-Su;Lee, In-Hwa
    • KSBB Journal
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    • v.23 no.6
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    • pp.525-528
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    • 2008
  • In order to compare the germination and growth rate of the sprouts soaked in highly concentrated oxygen water, it with specific amounts of oxygen dissolved was produced in a high pressure reactor by pressuring oxygen. The sprouts were observed after being soaked in $20^{\circ}C$ oxygen water with 20, 30, 40, 50 ppm of oxygen dissolved each. Results of ten days later indicate that the final germination rate of the sprout soaked in 50 ppm oxygen water was $24.6{\sim}28.6%$ higher than that of the sprout soaked in distilled water. The final growth length also measured 6-7 mm higher than the sprout soaked in distilled water, demonstrating that enough supply of oxygen to the sprout induces stability and efficiency in its growth.

The Effect of Chemical Pretreatment on Steam Explosion and Oxygen-alkali Pulping of Oak Wood (참나무재의 약액함침 처리가 폭쇄 및 산소-알칼리펄프화에 미치는 영향)

  • 박승영;최태호;조남석
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.3
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    • pp.75-83
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    • 2001
  • The potential of oxygen delignification is a powerful tool to reduce detrimental environmental effects. This study was performed to investigate the effect of steam explosion treatment of chemically treated oak wood on oxygen-alkali pulping. Pulp yield during steam explosion treatment by ${Na_2}{O_3}$-NaOH impregnation was higher than the other impregnation chemicals. Also, NaOH extraction at room temperature after steam explosion treatment improved the kappa number from 140~116 to 90~64. Oxygen-alkali pulping of chemical steam explosion treated woods affected to pulp yields. ${Na_2}{O_3}$-NaOH impregnation was very effective to higher carbohydrate yields at same delignification level. Its carbohydrate yield seemed to be highly related to the effluent pH. Oxygen-alkali pulping after steam explosion treatment of ${Na_2}{O_3}$-NaOH impregnated wood was shown that carbohydrate yield was very high because its effluent pH was increase from natural to mild alkali. Even if oxygen bleaching limit the delignification to 50% in order to avoid unacceptable yield and viscosity losses, oxygen-alkali pulping after steam explosion by ${Na_2}{O_3}$-NaOH impregnation was possible to extend the delignification more than 80%. Considering high pulp yield with lower lignin content from steam explosion treated wood, it might be profitable to end the cook at a high kappa number instead of a low kappa number, and continuously apply the oxygen delignification, in order to better quality pulp.

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Urban Streams' Water Quality and Odor Control Using Pure Oxygen and Vortex Aerator (순산소와 Vortex Aerator를 이용한 도심하천의 수질 및 악취 관리)

  • Yoon, Dain;Choi, Mijeong;Park, Sunghyuk
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.41 no.5
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    • pp.493-504
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    • 2021
  • The target site, Goejeongcheon flows through downtown of Saha-gu, Busan and it connects to the Nakdong-gang estuary. But non-point pollutants and sewage sludge are partially flowing into the stream and deposited. As a result, dissolved oxygen concentrations of the stream were observed close to the anaerobic condition. Multistage Vortex Aerator was applied for restoring this urban stream. It dissolves oxygen by repeatedly causing collisions between water and oxygen by vortex flow. The changes in water quality and odor were monitored for 2 months while circulating 1 m3/min of water with 22 ppm dissolved oxygen. As a result of the operation, the dissolved oxygen was improved from slightly Bad (4)~Bad (5) to Good (1b)~Normal (3) grade, and the total phosphorus concentration was decreased by 76 % on average. In the case of complex odor, a maximum reduction of 84.5 % was observed on the day the entire river was anaerobic. Through this study, we evaluated the feasibility of applying pure oxygen and Vortex Aerator for the the stream restoration. It is expected that the results of this study can be used for full-scale design.

A Study on the Stability Improvement of Oxygen Handling Equipment to Prevent Fire and Explosion Accidents in High-Pressure Oxygen Transport Piping (고압산소 이송배관시 화재·폭발 사고 방지를 위한 산소 취급 설비 안정성 향상에 관한 연구)

  • Sang Kyu Oh;Sang Ryung Kim
    • Journal of the Korean Institute of Gas
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    • v.27 no.3
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    • pp.84-90
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    • 2023
  • Oxygen, which is always present in the atmosphere among the three elements of combustion, can cause fires and explosions with only a very small amount of combustibles under high-pressure oxygen conditions. The burning rate is also significant, and can rise to temperatures that can have a direct impact, such as melting process equipment and piping in an instant. Therefore, accidents that occur under high pressure oxygen often cause more damage than other accidents. Recently, while operating a valve installed in an oxygen supply pipe, rapid combustion and rupture occurred inside, resulting in human casualties due to an explosion. In the case of an old carbon steel pipe, particles generated during operation become combustible and can cause accidents. . In particular, since oxygen facilities are facilities licensed under the High Pressure Gas Safety Management Actand there are no restrictions under the Occupational Safety and Health Act, accumulating these standards is of utmost importance. Therefore, in this study, based on accident cases and overseas standards, methods for improving safety when handling hyperbaric oxygen are reviewed.

Oxygen Removal Performance of M/γ-Al2O3 Catalyst through H2-O2 Recombination Reaction and the Effect of Oxygen Vacancies on the Catalyst (H2-O2 재결합 반응을 통한 M/γ-Al2O3 촉매의 산소 제거 성능과 산소 결손이 촉매에 미치는 영향)

  • TAEJUN KIM;PUTRAKUMAR BALLA;DAESEOB SHIN;YOUJUNG SONG;SUNGTAK KIM
    • Journal of Hydrogen and New Energy
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    • v.34 no.5
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    • pp.535-548
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    • 2023
  • The intermittent nature of renewable energy is a challenge to overcome for safety and stable performance in water electrolysis systems linked to renewable energy. Oxygen removal using the catalyst is suitable for maintaining the oxygen concentration in hydrogen below the explosive level (4%) even in intermittent power supply. Metals such as Pd, Pt, and Ni are expected to be effective materials due to their hydrogen affinity. The oxygen removal performance was compared under high hydrogen concentration conditions by loading on γ-Al2O3 with high reactivity and large surface area. The characteristics of the catalyst before and after the reaction were analyzed through X-ray diffraction, transmission electron microscope, H2-temperature programmed reduction, X-ray photoelectron spectroscope, etc. The Pd catalyst that showed the best performance was able to lower 2% oxygen to less than 5 ppm. Changes in catalyst characteristics after the reaction indicate that oxygen vacancies are related to oxygen removal performance and catalyst deactivation.

Variation of Oxygen Nonstoichiometry of Porous $La_{0.6}Ca_{0.4}MnO_{3-{\delta}}$ SOFC-Cathode under Polarization

  • Mizusaki, Junichiro;Harita, Hideki;Mori, Naoya;Dokiya, Masayuki;Tagawa, Hiroaki
    • The Korean Journal of Ceramics
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    • v.6 no.2
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    • pp.177-182
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    • 2000
  • At the porous $La_{0.6}Ca_{0.4}MnO_{3-{\delta}}$(LCM)/YSZ electrodes of solid oxide fuel cells (SOFC), the electrochemical redox reaction of oxygen proceeds via the triple boundary (TPB) of gas/LCM/YSZ. The surface diffusion of adsorbed oxygen on LCM has been proposed as the rate determining process, assuming the gradient of oxygen chemical potential from the outer surface of porous layer to TPB. Along with the formation of this gradient, oxygen nonstoichiometry in the bulk of LCM may varies. In this paper, an electrochemical technique was described precisely to determine the variation of oxygen content in LCM of porous LCM/YSZ under polarization. It was shown that the oxygen potential in LCM layer under large cathodic polarization is much lower than that in the gas phase, being determined from the electrode potential and Nernst equation.

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Gas Separation Membranes Containing $Re_6Se_8(MeCN)_6^{2+}$ Cluster-Supported Cobalt-Porphyrin Complexes

  • Park Su Mi;Won Jongok;Lee Myung-Jin;Kang Yong Soo;Kim Se-Hye;Kim Youngmee;Kim Sung-Jin
    • Macromolecular Research
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    • v.12 no.6
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    • pp.598-603
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    • 2004
  • Cellulose nitrate (CN) composite membranes, containing cobalt porphyrin (CoP) complexes self-assembled within nanometer-sized rhenium clusters (ReCoP), have been prepared and their oxygen and nitrogen gas perme­abilities were analyzed. The solubility of ReCoP and the characteristics of the corresponding composite membranes were analyzed using a Cahn microbalance, FT-IR spectroscopy, wide-angle X-ray scattering, and differential scanning calorimetry. The nitrogen permeability through the CN composite membranes decreased upon addition of ReCoP and CoP, which implies that the presence of these oxygen carrier complexes affects the structure of the polymer matrix. The oxygen permeability through the composite membranes containing small quantities of ReCoP decreased, but it increased upon increasing the concentration. The oxygen gas transport was affected by the matrix at low ReCoP concentrations, but higher concentrations of ReCoP increased the oxygen permeability as a result of its reversible and specific interactions with oxygen, effectively realizing ReCoP carrier-mediated oxygen transport.

Quantification of Oxygen Production from Carbon Dioxide Using Potassium Superoxide for Oxygen Generating Closed-Circuit SCBA (산소 발생 폐쇄식 SCBA를 위한 이산화칼륨과 이산화탄소의 반응 정량화)

  • Yang, Won-Ho;Song, Young-Woong
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.20 no.4
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    • pp.236-240
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    • 2010
  • This study demonstrates the use of a chemical containing potassium superoxide (KO2) to convert carbon dioxide (CO$_2$) in air to oxygen (O$_2$). A oxygen generating closed-circuit SCBA (self contained breathing apparatus) removes carbon dioxide by a chemical reaction with potassium dioxide that consumes the carbon dioxide and produces oxygen. Considering the disasters, there is a need to develop strategies to enable the introduction of self-contained self rescuers (SCSR). The potassium superoxide reacts with the wears breath to produce oxygen and absorb carbon dioxide. If the respiration rate of a person is 5 MET (metabolic equivalent), to say 30 L/min, at disaster such as fire, mass of potassium superoxide was evaluated as 33.3 g with yield and safety factor. Four researchers tested on a laboratory treadmill breathing through SCSRs in a closed circuit, it appears useable for 9 minutes.