• 제목/요약/키워드: oxidizing agent

검색결과 141건 처리시간 0.027초

서리태 발효추출물이 탈색을 통해 손상된 모발에 미치는 영향 (Effect of Extract from Fermented Black Soybean (Glycine max var. Seoritae) on the Hair Damaged by Decolorization)

  • 정희훈;신민규;이수열;이상린;김무성
    • 대한화장품학회지
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    • 제43권2호
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    • pp.149-155
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    • 2017
  • 본 연구에서는 서리태 발효추출물의 모발보호효과를 확인하기 위한 연구를 수행하였다. 화학적 산화를 통해 손상된 모발을 준비한 뒤 서리태 발효추출물을 처리하였을 때 모발의 형태학적 특성, 인장강도, 구성성분의 변화를 분석하여 비교하였다. 그 결과 모발에 산화제를 처리하였을 때, 표피의 큐티클 층이 손상되고 모발의 인장강도가 $14.32{\pm}0.83g/cm^2$에서 $12.32{\pm}0.79g/cm^2$로 감소되었음을 확인하였다. FT-IR 분석결과 산화제를 처리한 모발은 버진 헤어에 비하여 1,077, 1,041, $801cm^{-1}$에 해당하는 피크가 증가하였으며, 이를 통해 케라틴 단백질 간의 이황화 결합에 필수적인 시스테인이 산화되는 것을 확인하였다. 반면, 손상된 모발에 서리태 발효추출물을 처리한 경우에는 표피의 큐티클 층의 틈이 메워지고, 인장강도가 $14.27{\pm}0.96g/cm^2$로 회복되었으며, 모발의 성분 중 시스테인의 산화물 비율이 감소하는 것으로 분석되었다. 이러한 결과들을 통해 발효 서리태 추출물은 산화제에 의해 손상된 모발의 보호 소재로 연구될 가치가 있는 것으로 기대된다.

묽은 산 전기분해에 의한 복합 산화제 생성 (Composite Oxidizing Agents Generation Using Electrolysis of Dilute Hydrochloric Acid)

  • 강신영;박종훈;김상현
    • 대한환경공학회지
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    • 제38권6호
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    • pp.329-333
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    • 2016
  • 전기분해에 의한 소독은 소규모 하수처리장, 강우월류수, 선박평형수, 수영장, 양식장 등 염소의 운송, 보관, 사용에 어려움이 있는 곳에 활용될 가능성이 높다. 본 연구에서는 전압(2-5 V), 반응시간(1-10 min), 전해질농도(HCl 0.4-2.2% (w/v), NaCl 5-20 g/L)가 전기분해 산화제(HOCl, $O_3$, $H_2O_2$) 생성 효율에 미치는 영향을 고찰하였다. 회분식 실험 시 투입 전자 대비산화제 전환율(전류 효율)이 가장 높은 최적 조건은 HCl 2.2%, 3 V, 반응 시간 5분이었으며, 이 때의 전류 효율은 99.3%였다. HCl 2.2%, 3 V에서 수행한 연속식 전기분해실험에서는 전류 효율이 97.4% 이상이었으며, NaCl 농도(0-20 g/L) 증가에 따라 주요 산화제인 HOCl의 농도가 비례하여 증가하여 최대 99.8%의 결과를 보였다. 연속식 실험에서 얻은 전기분해수를 이용한 살균실험 결과 5분 안에 92.2% 이상의 총대장균군이 제거되어, 전기분해가 병원성 미생물 소독에 유효하게 사용될 수 있을 것으로 확인되었다.

급성 댑손 중독 환자에서 메틸렌블루 치료중 유발된 메트헤모글로빈혈증과 중증 용혈성 빈혈 1례 (A Case of Acute Dapsone Poisoning Complicated with Methylene Blue-induced Hemolytic Anemia)

  • 이미진;박규남
    • 대한임상독성학회지
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    • 제4권2호
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    • pp.170-174
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    • 2006
  • Methylene blue is a basic thiazine dye frequently used for histologic staining. In clinical toxicology settings, it is also used to treat clinically significant methemoglobinemia. It has dose-dependent oxidation or reduction properties, acting as a reducing agent at lower doses and as an oxidizing agent at higher doses. Hemolytic anemia and hyperbilirubinemia are known toxic effects of methylene blue treatment that have been reported clinically. A 42-year-old woman developed significant methemoglobinemia after acute dapsone overdose; she was treated appropriately with intravenous methylene blue in the therapeutic range. The patient's methemoglobin levels returned to normal. However, 2-4 days later she was noted to have rebound methemoglobinemia, hemolytic anemia, and hyperbilirubinemia. A repeat of Coomb's test and other anemia workups were negative. For management of methylene blue-induced hemolytic anemia, she was administered steroid therapy, N-acetylcysteine, and a blood transfusion. She ultimately recovered, and there were no long-term sequelae from the methylene blue poisoning.

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전처리 공정에 따른 폐 신문지의 효소 가수분해 특성

  • 문남규;이재환;김성배
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2000년도 춘계학술발표대회
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    • pp.459-462
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    • 2000
  • The pretreatment of used newspaper for the enzymatic digestion preprocess was performed on a percolation reactor and a batch reactor. The test condition of percolation process was $170^{circ}C$, 60min, 1 mL/min, and 400psi, that of batch was $40^{circ}C$, 3hr. and latm Reaction solutions used in pretreatment process were aqueous ammonia, sulfuric acid, water, and hydrogen-peroxide as an oxidizing agent. As a result, the effect of pretreatment was similar to batch and percolation process, but the yield of enzymatic hydrolysis was higher in batch than percolation. This batch pretreatment enhanced enzymatic hydrolysis rate and increased glucose yield from about 15 to 20%. The inhibition factors influenced the rate of enzymatic hydrolysis was investigated, and the ink contented newspaper was the major factor.

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AC 스트리머 코로나 방전으로 생성된 O 라디칼과 매연 입자의 산화반응 (Oxidation of Soot Particles with O Radicals Generated in a AC Streamer Corona Discharge)

  • 김필승;이교승;황정호
    • 한국연소학회지
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    • 제8권1호
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    • pp.9-16
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    • 2003
  • Carbon soot emission from combustion processes, especially from diesel engines, is a subject of growing concern since soot is known to seriously affect human health. Efforts have been made to oxidize soot particles utilizing Non-Thermal Plasma(NTP) techniques. When oxygen is carried into a plasma device, electrons generated by the plasma dissociate the oxygen, resulting in the formation of oxygen atoms. These highly activated atoms, called O radicals, are known as strong oxidizing agent. This paper presents concentration variations of CO and $CO_2$ at the exit of the plasma device, resulting from the soot oxidation by O radicals, with variations of inlet oxygen concentration, gas temperature, and gas flow rate. Based on the data, Arrehenious rate constants of reactions between C(s)+O and C(s)+O+O were proposed.

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Fouling and cleaning of a tubular ultrafiltration ceramic membrane

  • Siddiqui, Farrukh Arsalan;Field, Robert W.
    • Membrane and Water Treatment
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    • 제7권5호
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    • pp.433-449
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    • 2016
  • The successful application of cleaning protocols is vital for optimized filtration processes. A series of experiments with an ultrafiltration ceramic tubular membrane were carried out for the foulants dextran and carboxymethyl cellulose. Firstly, the impact on fouling of concentration changes was investigated with the increase in resistance being used as the key parameter. In the second phase, removal of reversible fouling was also investigated by employing intermittent rinsing consisting of a cold water rinse followed by a hot one. A comparative analysis for both foulants is reported. Across a range of concentrations and for both foulants, the reduction in resistance due to rinsing was found to depend upon concentration (C); it changed as $C^n$ where n was found to be 0.3. A plausible semi-theoretical explanation is given. Thirdly, for both foulants, the application of a combination of strong alkaline solutions with oxidizing agent (mainly sodium hypochlorite) followed by acid was found to be appropriate for cleaning of the ceramic membrane. The effect of increased temperature for cleaning agents followed by a warm water rinse contributed positively to the cleaning capability.

캐스팅법으로 제작한 Poly(3-hexylthiophene)의 흡수스펙트럼에 따른 형광 특성 (Characteristics of Electronic Absorption Spectrum and Photoluminescence in Cast-Poly(3-hexylthiophene) Films)

  • 김주승;구할본;조재철
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 추계학술대회 논문집
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    • pp.57-60
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    • 1998
  • Poly(3-hexylthiophene)(P3HT) was synthesized by use of FeCl$_3$ as a oxidizing agent at $25^{\circ}C$. The infrared spectrum of our polymer gave good evidence for the conjugation of 3-hexylthiophene monomer unit. P3HT contains the HT(head-to-tail) linkage larger than 64% based on NMR analysis. Electronic absorption and photoluminescence studies show that cast films of P3HT have three exciting state. Absorption spectrum was separated with three maximum peaks by Giese-French method and shifted to the shorter wavelength with increasing temperature. Separated absorption spectrum of P3HT is well adapted to PL peak appeared at longer wavelength. Low temperature PL spectrum is well separated at 669nm, 733nm and 812nm.

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Toluene-o-monooxygenase와 Fluoresceinamine을 이용한 Trichloroethene와 Tetrachloroethene 감지용 광섬유 바이오센서의 특성 (Characteristics of Trichloroethene and Tetrachloroethene Sensing Optical Fiber Biosensor Using Toluene-o-monooxygenase and Fluoresceinamine)

  • 류두현
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제23권4호
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    • pp.42-47
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    • 2018
  • E. coli TG1 pBS TOM Green was cultured to produce toluene-o-monooxygenase (TOM). A biosensor system was successfully constructed using purified TOM to effectively detect trichloroethene (TCE) and tetrachloroethene (PCE), which represent some of the major contaminants in groundwater and soil. In order to utilize TOM as a sensor, NADH, a biological oxidizer, was replaced with hydrogen peroxide which is a chemical oxidizing agent. A three-layered sandwich-type sensing tip was fabricated on the outside of the hydrophilic polyvinylidene fluoride membrane. TCE and PCE were applied to the sensor and the hydrogen ions were measured by a fiber optic fluorometer using fluoresceinamine. Calibration curves were obtained for TCE and PCE in the concentration range of 0.2-100 mg/l, and the detection limit of the system was $10{\mu}g/l$ for TCE and PCE.

질산은 처리된 실크의 환원 발색 (Cathodic Coloration of Silk Fabric Treated with Silver Nitrate)

  • 정문화;이문철
    • 한국염색가공학회지
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    • 제21권2호
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    • pp.14-21
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    • 2009
  • In this article, silk fabric was treated with silver nitrate ($AgNO_3$) as oxidizing agent, with conditions such as concentration, and treating time, and subsequently treated with reducing agents such as sodium boron hydride ($NaBH_4$) and sodium sulfide ($Na_2S$) to obtain cathodic coloration. After coloration of silk fabric, dyeing properties (K/S value), colorfastnesses such as wash, rubbing and light, and antibacterial activity property were examined. $AgNO_3$ treating time and reducing time did not influence K/S value, whereas the pH value at alkaline region showed a high K/S value of silk fabric. The cathodic colorations of silk fabric with both of reducing agents at $30^{\circ}C$ have excellent color fastnesses. Also the high antibacterial activities were obtained by the treatment with silver nitrate even at 1% of lower concentration.

냉간 가공용 인산염 피막처리의 저온화에 관한 연구 (A Study on Low Temperature Phosphating for Cold Forming)

  • 이만식;정충택;이광호;김준호;이근대;홍성수
    • 한국표면공학회지
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    • 제35권5호
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    • pp.279-288
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    • 2002
  • Zinc phosphating for cold forming of steel was studied with emphasis on decreasing phosphating temperature. To lower phosphating temperature, some techniques, such as adding Cu ion into bath, using activator in the form of pre-dip, and aeration in bath, instead of using conventional accelerator, namely oxidizing agent, have been tried. It was revealed that phosphating, leading to coatings of Improved uniformity and fine crystal size, can be carried out using above techniques at lower temperature ($55^{\circ}C$) compared to conventional phosphating temperature ($80 ~ 90^{\circ}C$ ). Under present condition, it was seen that optimum concentrations of Cu ion in phosphating bath and activator in pre-dip are 0.015% (w/w) and 2.0 g/1, respectively. The coating weight was within the range of 15 ~ 20 g/$\m^2$. When lubricant was applied into phosphating coatings, the amount of lubricating component (total soap) was found to be 6 ~ 10 g/$\m^2$ and the lubricated panel revealed excellent lubricating properties.