• 펄프종이기술
• /
• 제34권1호
• /
• pp.7-11
• /
• 2002

The print quality of a ink jet printer is generally affected by three major components of the printing process: printer, ink formulation, and paper. The result of this study indicated that the surface sized paper with oxidized starch and cationic starch differed ink jet print quality in terms of ink spread and black optical density of the print image. Paper properties, like air permeability and siting degree, which may influence the ink jet printing were also measured. It was found that black print quality was controlled by starch level and ionic charge on the paper surface. Cationic surface sizing starch improved black ink jet print quality.

• 한국식품과학회지
• /
• 제32권1호
• /
• pp.147-153
• /
• 2000

구조와 용해도가 다른 4종류의 다당류(옥수수전분, 쌀전분, 고구마전분 및 셀룰로오스) 내의 1차 alcohol기를 특이적으로 산화시켜 제조된 polyglucuronic acid를 polyglucuronic acid C5-epimerase와 반응시켜 algin 유사 물질을 값싸게 대량으로 구득하고자 하였는 바, 신선한 소의 간을 마쇄한 후 $100,000{\times}g$에서 1시간 원심분리한 상등액에서 조효소 용액을 구득하여 개선된 Dische carbazole 방법으로 효소활성도를 측정하였다. 이때 효소 활성 측정을 위한 반응식을 다음과 같이 확립하여 활성도를 계산하였다. Abs. at $530nm=-(5.3958{\times}10^{-3})$(Concentration of epimerized product) +0.8090. 또한 polyglucuronic acid C5-epimerase 효소반응을 위한 최적 기질은 산화된 고구마전분이었으며, 최적 pH 및 온도는 각각 7.0과 $30^{\circ}C$이었다. 따라서 특이적으로 산화된 고구마전분과 소의 간으로부터 추출된 polyglucuronic acid C5-epimerase를 이용하여 polyglucuronic acid가 polyiduronic acid로 전환된 algin 유사 물질의 효소적 생산이 가능한 것으로 판단되었다.

• 펄프종이기술
• /
• 제35권3호
• /
• pp.21-28
• /
• 2003

It is essential to use base papers having proper surface characteristics in coating operation for improving coated paper quality and coater runnability. To fulfill these purposes surface sizing of coating base stock with anionic oxidized starch is commonly practiced. It is suggested that use of cationic starch for surface sizing rather than conventional oxidized starch will improve coated paper quality since cationic starch penetrates less into paper structure because of its strong electrostatic interaction with anionically charged paper surface. Strong interaction of cationic surface sizing starch with anionic coating color is expected to promote rapid immobilization of the coating color and improve coating holdout and optical property. The immediate objective of this study was to examine the influence of surface sizing starches on the properties of coated papers. Structural characteristics of the coatings formed on the substrate surface sized with cationic and anionic starches were examined. To enhance the efficiency of cationic surface sizing starch on coated paper properties, strongly charged cationic polymers were added to the surface sizing starch and its effect on coated paper properties was evaluated. Results showed that opacity and light scattering coefficient of coated paper were higher when base paper surface sized with cationic starch was used. Addition of less than 1% of cationic poly-DADMAC to the cationic surface sizing starch improved the opacity of coated paper significantly.

• 한국식품영양학회지
• /
• 제12권3호
• /
• pp.265-270
• /
• 1999

The stabilization of Aspergillus sp. $\alpha$-amylase was attained by modification with periodate-oxidized sol-uble starch. The pH stability of modified enzyme was increased at pH 3~4 and 9~11 in the presence of $\alpha$-cyclodextrin($\alpha$-CD) compared with that of native enzyme. Thermal stability of the modified enzyme was increased. After treatment at 6$0^{\circ}C$ for 30min the activity remained 20% for the enzyme modified at pH 9.7 in the presence of $\alpha$-CD and tested in the presence of $\alpha$-CD 10% for the enzyme modified at pH 9.7 in the presence of $\alpha$-CD 0% for the native enzyme. The native enzyme and modified enzyme showed one peak in HPLC. The substrate specificity of the modified enzyme was not changed in HPLC analysis of reaction product.

• Preventive Nutrition and Food Science
• /
• 제3권1호
• /
• pp.27-35
• /
• 1998

Starch-polyethylene films containing high molecular weight(NW) oxidized-polyethylene and prooxidant were prepared , and thermal -and bio-degradability of the films were determined. Increased levels of starch resulted in a corresponding reduction in mechanical strength of the films. However, the addition of high MW oxidized-polyethylene did not significantly reduce the percent elongation of the films. Thefilms containing high MW oxidized-polyethylene andproosicant were degreaded faster than those containing no aadditive during the heat treatment. The films lost their measureable mechanical properties when their weight-average MW(Mw) fell below 50,000. Biodegradability of the films was determined by a pure culture assay with either Streptomyces badius 252.S. setonii 75Vi2 or S. viridosporous T7A, and by an extracellulr enzyme assay using S. setonii 75vi2. The results from pure culture assay indicated that biomass accumulation on the film surface inhibited chemical and biological degradation of the films. The extracellular enzyme assay demonstrated decrease of percent elongation and increase of carbonyl index of the films. Therefore, extracellular enzyme assay could be used as a good method to evaluate biodegradability of the films.

• 펄프종이기술
• /
• 제46권4호
• /
• pp.44-53
• /
• 2014

This research were aimed at developing starches which have high preservability and high bonding strength from corn starch, modified cationic and oxidized corn starches, as compared to the fermented wheat starch. On the lining that attaching the base paper on the back of the work with paste, the coating weight was determined by the solid contents of the paste rather than the viscosity of paste. Adhesive strength and stiffness were also determined by the solid contents of the paste. Corn starch had lower solid contents, higher viscosity, and higher adhesive strength than other starches. In the iodine stain to the surface of peeled base paper off, paste deeply penetrated into the traditional Hanji than modern Hanji. And oxidized starch paste deeply penetrated into the paper layer than the cationic starch.

• 펄프종이기술
• /
• 제34권2호
• /
• pp.1-12
• /
• 2002

Starch dissolved in paper-mill wastes, either as a result of poor retention on the paper web or recycling of surface-treated broke, was a major pollutant Laboratory tests were performed by using different kinds of starch as a surface treatment. It was concluded that the use of cationic starch can positively affect the level of starch dissolved in liquid effluents. When cationically modified starches were used for surface sizing, the starch was tightly bound to the paper fibers, it was not removed during the repulping of broke. The result of mill trial in fine paper manufacture for the application of low-viscosity cationic starches used in size press reduced COD load in the effluents and increased One Pass Retention. It had been found that when cationic starch used as a surface sizing agent, more starch was retained on or near the surface of the sheet than with conventional oxidized starches. Thus surface strengths and quality were improved. In addition it is possible to maintain the desired level of starch penetration into the fiber net and improve porosity, opacity and brightness. In contrast, in most cases, dusting problems are notably eliminated. Cationic surface sized starch improved black and color ink-jet print quality in terms of feathering and optical density of the print image. These improved properties were believed to be due to a combination of fiber bonding and surface orientation more uniform starch concentration on the paper surface was resulted. Moreover cationic charges in the paper surface lend themselves excellently to fix ink jet ink anionic in nature.

• 한국펄프종이공학회:학술대회논문집
• /
• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
• /
• pp.245-250
• /
• 2006

This study was focused on the use of cationic PAM (Polyacrylamide) as a surface sizing additive to improve the surface sizing properties of paper. Effects of the ionic property, viscosity and charge density of PAM on bending stiffness of surface sized papers were investigated. Use of cationic PAM as a surface sizing additive improved bending stiffness while addition of anionic PAM did not show any effect. Increase of starch holdout with the addition of cationic PAM was attributed as a prime reason of stiffness increase. Viscosity of PAM was one of the most important factors affecting surface sizing due to its influence on the interaction between cationic PAM and oxidized starch solution. Greater improvement of bending stiffness of paper was obtained when high charged PAM was used as an additive. The order of addition was found to have significant influence on the effect of additives since it influences the formation of network structure among starch, cationic PAM, and SA (styrene acrylic acid copolymer). Investigation on the penetration of starch solution was carried out with CLSM (Confocal Laser Scanning Microscopy), and it was shown that the addition of cationic PAM to oxidized starch solution made starch molecules stay on the paper surface rather than penetrating into the paper structure because of the electrostatic interaction between negatively charged fibers and positively charged cationic PAM.

• 한국식품영양학회지
• /
• 제11권5호
• /
• pp.561-564
• /
• 1998

The stabilizatio of amaylolytic enzyme such as $\beta$-amylase of barley, $\beta$-amylase of wheat, $\beta$-amylase of sweet potato, $\alpha$-amylase of Bacillus licheniformis, $\alpha$-amylase of Aspergillus sp. and $\alpha$-glucosidase of Aspergillus awamori was attained by modification with periodate-oxidized soluble starch. The pH stability of modified enzyme was increased at pH 9 for $\beta$-amylase of sweet potato, pH 3~5 and 8~11 for $\beta$-amylase of barley, pH 2~3 and 7~12 for $\beta$-amylase of wheat and pH 6 for $\alpha$-glucosidase of Aspergillus awamori. Thermal stability increased 17.6% for $\alpha$-amylase of Aspergillus sp. at 6$0^{\circ}C$ for 10min, 30% for $\alpha$-amylase of Bacillus licheniformis at 10$0^{\circ}C$ for 5min and 4.5% for $\alpha$-amylase of sweet potato at 6$0^{\circ}C$ for 10min compared with those of native enzymes.

• 펄프종이기술
• /
• 제31권3호
• /
• pp.47-53
• /
• 1999

The effect of coating of liner components with oxidized starch on the properties of corrugated box was examined . Coating was carried out on liner components of B flute, single-wall corrugated board(SK180/S120/K200) , and corrugated box was made from the treated corrugated board. Box was made in a regular slotted container (RSC) style, and box compression strength was determined in the direction of top-to-bottom compression. The compression strength of box coated on outside liner component showed 15.4% improvement for 1.58g㎡ coating. On the other hand, the strength of box coated on outside liner component showed only 1.45% improvement for 1.41g/㎡ coating and 3.46% improvement for 2.32g/㎡ coating. Coating on inside liner component with oxidized starch at low coating weight more significantly improved box compression strength than coating on outside liner component, and the improvement was marked at the coating weight of 1.5-2.5g/㎡. In estimating top-to-bottom box compression strength, the experimental values were closer to the calculated values from McKee's equation suing edgewise compression strength of the combined board measured by column crush test than those from Kellicutt's equation using compression strength of component paperboards measured by ring crush test.