• 제목/요약/키워드: oxidized mixture

검색결과 92건 처리시간 0.026초

Cartridge에 의한 지질과 폐놀물질 혼합산화물의 분리 (Separation in Oxdized Mixture of Lipids and Phenolics by Cartridge)

  • 김정숙
    • 동아시아식생활학회지
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    • 제5권1호
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    • pp.87-93
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    • 1995
  • The oxidized mixture of lipid(methyl linoleate) and phenolics(phloroglucinol) at 37$^{\circ}C$, 82$m\ell$ O/min., for 9 days were separated each by C cartridge and silica cartridge making use of different eluting solvent. And the oxidation products were analyzed by HPLC. In conclusion, the oxidized mixture were separated into methyl linoleate and phloroglucinol by cartridge on HPLC. and also in this experiment, separated methyl linoleate and phloroglucinol could be analyzed in the common eluant, water and acetonitrile on HPLC. SEP-PAK cartridges were used almost sample purification until now, but under the various eluting solvents and conditions, cartridge will be expected to mini columns which can separate different polarity materials.

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물-에탄올 기반 이성분 산화탄소나노유체의 특성 비교 연구 (A Comparative Study on the Characteristics of Binary Oxidized Carbon Nanofluids Based DI Water and Ethanol)

  • 박성식;김남진
    • 한국태양에너지학회 논문집
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    • 제32권6호
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    • pp.85-92
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    • 2012
  • A nanofluid is a fluid containing suspended solid particles, with sizes on the order of nanometers. Normally, nanofluids have higher thermal conductivitiest han their base fluids. Therefore, we measured the thermal conductivity and viscosity of oxidized carbon nanofluids based the mixture of distilled water and ethanol (ethanol concentration is 0.2) oxidized carbon nanofluids were made by ultrasonic dispersing oxidized multi-walled carbon nanotubes in the mixture of distilled water and ethanol at the rates of 0.001~ 0.1 vol%. The thermal conductivity and viscosity of oxidized carbon nanofluids were measured by using transient hot-wire method and rotational digital viscometer, respectively. And all of experiments were carried out at the same temperature conditions($10^{\circ}C$, $25^{\circ}C$ and $70^{\circ}C$). As a result, when volume fraction of nanofluids is 0.1 vol%, thermal conductivity was improved 13.6% ($10^{\circ}C$), 15.1% ($25^{\circ}C$), and 17.0% ($70^{\circ}C$), and its viscosity was increased by 36.0% ($10^{\circ}C$), 32.9% ($25^{\circ}C$) and 19.5% ($70^{\circ}C$) than the base fluids.

마이크로파 에너지를 이용한 저수축 반응소결 알루미나의 제조에 관한 연구 (The Study on the Production of Reaction Bonded Aluminum Oxide by Using Microwave Energy)

  • 박정현;안주삼
    • 한국세라믹학회지
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    • 제32권2호
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    • pp.227-233
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    • 1995
  • By using homestyle microwave oven, Al-Al2O3 powder mixture could be oxidized and sintered into Al2O3 body. The differences in powder characteristics among the differently processed raw materials affect the oxidation and sintering behaviours, and these effects were more pronounced in case of microwave oven than of conventional furnace. Al-Al2O3 powder mixture was oxidized and sintered within 2hrs, which could save both processing time and energy.

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삼성분 전분혼합에 의한 이겹지의 층간결합강도 개선 (The Effects of Blending Starches on the Development of Plybond Strength of Two-ply Linerboard)

  • 이학래;류정용
    • 펄프종이기술
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    • 제39권4호
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    • pp.14-20
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    • 2007
  • The effects of blending starches with different gelatinization temperatures on the development of ply-bond strength were systematically investigated using a three component mixture design technique. Oxidized corn starches with different gelatinization temperatures were blended with natural corn starch and sprayed for plybonding. Optimum blend ratio for maximizing plybond strength improvement for the starch blends was 40% of natural starch, 27% of oxidized starch with low gelatinization temperature and 33% of oxidized starch with high gelatinization temperature. Starch granules with the lowest gelatinization temperature gelatinizes at the lowest temperature, while the natural corn starch gelatinizes at later stage of drying. The improvement of plybond strength with starch blends were verified on machine trial as well. Plybond strength improvement obtained from the machine trial was lower than that achievable with handsheets, which was attributed to the lower internal bond strength of the linerboards made from recycled fibers.

산화(酸化)된 pellet에 의(依)한 틸라피아의 Ceroid증(症)과 비타민 E, C의 예방효과(豫防效果) (Ceroidosis of Tilapia, Oreochromis niloticus, due to the Oxidized Pellet and the Preventive Effect of Vitamin E and C addition)

  • 조문규;전세규
    • 한국어병학회지
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    • 제3권2호
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    • pp.69-77
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    • 1990
  • 시판(市販)되는 배합사료(配合飼料)를 장기간(長期間) 보관(保管)하거나 직사광선(直射光線)을 쪼이면 산화(酸化)되어 과산화물질(過酸化物質)을 많이 함유(含有)하게 되는데, 이와 같이 산화(酸化)된 pellet을 틸라피아에 먹이면 내장(內臟)에 ceroid가 침착(沈着)되므로 대사장해(代謝障害)를 일으켜 어류(魚類)의 성장(成長)이 나빠지고 체색(體色)이 검어지면서 서서히 폐사(斃死)한다. 본(本) 논문(論文)은 산화사료(酸化飼料)를 먹임으로 인하여 양식(養殖) 틸라피아에서 발생(發生)하는 ceroid증(症)의 예방(豫防) 효과(效果)를 밝히기 위(爲)하여 비타민 C와 E를 첨가(添加)한 산화사료(酸化飼料)와 비첨가사료(非添加飼料)를 투여(投與)한 다음 그 결과(結果)를 병리조직학적(病理組織學的)으로 관찰(觀察)할 것이다. 실험(實驗)에는 1990년(年) 9월(月)부터 동년(同年) 11월(月) 27일(日)까지 67일가(日間) 실험실(實驗室)에서 체중(體重)이 100g인 80마리의 실험어(實驗魚)를 사용(使用)하였으며, 각각 농도(濃度)를 다르게 비타민 C, E를 산화사료(酸化飼料)에 첨가하여 사육(飼育)했다. 각(各) 장기(臟器)의 병리조직학적(病理組織學的) 차이(差異)를 알기 위(爲)해 장기별(臟器別)로 조직(組織) 표본(標本)을 제작(製作)하여 관찰(觀察)해 본 결과(結果), 비타민 C와 E를 각각 1.0mg/g diet, 2.01U/g diet 이상(以上) 첨가(添加)한 산화사료(酸化飼料) 투여(投與) 실험구(實驗區)는 비타민 비첨가(非添加) 산화사료(酸化飼料) 투여(投與) 실험구(實驗區)에 비(比)하여 간장(肝臟), 비장(脾臟), 신장(腎臟) 등(等)의 내장(內臟)에 심착(沈着)된 ceroid의 양(量)이 현저(顯著)하게 적은 것으로 나타났을 뿐만 아니라 macrophage의 출현율(出現率)도 적었다. 이상(以上)의 결과(結果)로부터, 틸라피아의 사육시(飼育時) 먹이로 주는 pellet은 산화(酸化) 정도(程度)에 따라서 비타민 C와 E의 양(量)을 적절(適切)히 혼합첨가(混合添加)하여 투여(投與)하면 산화사료(酸化飼料)의 섭취(攝取)로 인한 ceroid증(症)의 예방(豫防) 효과(效果)가 있을 것으로 생각된다.

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Methyl Linoleate에 대한 Phenol성 물질의 항산화성과 산화 생성물 (Antioxidative Effectiveness and Oxidized Products in Mixture of Methyl Linoleate and Phenolic Compounds)

  • 김정숙;이기동;권중호;윤형식
    • 한국식품과학회지
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    • 제25권4호
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    • pp.379-385
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    • 1993
  • Phenol성 물질로서 hydroxyl기가 두개인 caffeic acid와 세개인 phloroglucinol을 methyl linoleate에 첨가하여 산화시키면서 활성화 효과와 산화생성물을 분석하였다. Methyl linoleate에 대한 $37^{\circ}C,\;3{\sim}9$일간의 산화반응에서 caffeic acid 및 phloroglucinol 첨가군은 ${\alpha}-tocopherol$ 첨가군에 비해 높은 항산화성을 나타내었다. 이 때 산화생성물로서는 methyl linoleate(ML)군은 methyl-8-(2-furyl)-octanoate, 9,13-trans, cis hydroperoxide isomer 9,13-trans, trans hydroperoxide isomer 및 9-TMSO-12, 13-epoxy-10-octadecenoate로 나타났으며, 기간이 경과함에 따라 9,13-trans, trans isomer에 대한 9,13-trans, cis isomer의 비율이 낮아졌다. Caffeic acid 첨가군(CML)에서는 methyl-8-(2-furyl)-octanoate, 9-trans, cis hydroperoxide isomer 및 9-trans, trans hydroperoxide isomer였으며, 13-hydroxy isomer는 검출되지 않았다. Caffeic acid의 농도를 높일수록 9-trans, trans isomer에 대한 9-trans, cis isomer의 비율이 높아지는 것으로 나타났으며, 이 때 가장 주된 산화물인 caffeic quinone이 생성되는 것으로 보아 caffeic acid와 같은 o-dihydroxy cinnamate들은 lipid media에서 산화가 쉽게 일어나는 것으로 나타났다. 또한 phloroglucinol 첨가군(PML)의 산화 생성물들은 methyl-8-(2-furyl)-octanoate, 9-trans, cis hydroperoxide isomer, 9-trans, trans hydroperoxide isomer 및 9-hydroxy-12,13-epoxy-10-octadecenoate로서 CML군과 유사한 경향을 보였으나 phloroglucinol은 반응 9일째에도 산화되지 않았다.

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반응소결에 의하여 제조된 $SiC/MoSi_2$ 복합체의 산화 거동 (Oxidation Behavior of $SiC/MoSi_2$ Composites Prepared by Reaction Sintering Method)

  • 양준환;한인섭;우상국;서동수
    • 한국세라믹학회지
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    • 제31권12호
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    • pp.1588-1598
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    • 1994
  • The SiC/MoSi2 composite materials were fabricated by infiltrating the mixture of molybdenum disilicide and metal silicon(MoSi2+Si=100) to a porous compact of silicon carbide and graphite under the vacuum atmosphere of 10-1 torr. The specimen were oxidized in dry air under 1 atm at 130$0^{\circ}C$~150$0^{\circ}C$ for 240 hours. The oxidation behavior was evaluated by the weight gain and loss per unit area of the oxidized samples. Also, SEM and XRD analysis of the oxidized surface of the samples were carried out. With increasing the MoSi2 content and oxidation temperature, the passive oxidation was found. The trend of weight gain of all samples was followed the parabolic rate law with the formation of a protective layer of cristobalite on the surface.

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분쇄된 초경합금 분말의 산화에 미치는 진공열처리 효과 (EffEct of vacuum annealing on an oxidation of milled WC-Co powder)

  • 김소나
    • 한국분말재료학회지
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    • 제3권2호
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    • pp.91-96
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    • 1996
  • The effect of vacuum annealing on the oxidation behavior of milled WC-15%Co powder mixture has been studied. A cobalt component in the milled powder mixture was oxidized preferentially above 175$^{\circ}C$ in air. The specimens showed a steady increase in weight at 175$^{\circ}C$ but did constant weight followed by rapid increase in specimen weight at the beginning above 20$0^{\circ}C$. Oxidation of the milled powder mixture was significantly suppressed by vacuum annealing at 30$0^{\circ}C$ for 10 h. Suppression of oxidation by vacuum annealing and different oxidation behaviors of the milled powder mixture between 175$^{\circ}C$ and 20$0^{\circ}C$, were attributed to removal of strain energy stored in the cobalt powder during vacuum annealing or oxidation treatment above 20$0^{\circ}C$. The role of stored strain energy on oxidation of milled WC-15%Co powder mixture was proved by X-ray diffraction method and differential thermal analysis.

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펄프몰드용 새로운 고기능 코팅제 제조기술개발(제2보) -혼합코팅제 제조- (Development of Higher Functional Coating Agents for Pulp Mold (II) -Manufacture of mixed coating agents-)

  • 강진하;임현아
    • 펄프종이기술
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    • 제35권1호
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    • pp.19-26
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    • 2003
  • In recent years, numerous studies have been carried out to find out the possible substitution of PE-coated paperboards used in packaging of watery or oily foods. Accordingly, this study was carried out to obtain the basic data for producing higher functional coating agents for pulp mold by evaluating various kinds of mixed coating agents. At that time, two kinds of synthetic coating agents(AKD, PYA) and three kinds of natural coating agent(CMC, corn starch, oxidized starch) were used for making the mixed coating agents respectively. Physical properties of coated paperboards were tested. Conclusions obtained from this study were as follows. Based on concentrations, the proper mixture ratios were 10:90(AKD:CMC), 10:90(AKD:corn starch), 10:90(AKD:oxidized starch), 40:60(PVA:CMC), 20:80(PVA:corn starch) and 20:80(PYA:oxidized starch). The mixed coating agent of PYA:corn starch(20:80) was the most efficient coating agent. Consequently, water and oil resistance were improved even with much addition of natural coating agents. We consider that they can be suitable for the packaging used in the storage of higher moisture vegetables and other food, and also can be suitable for oily fried food.

산화된 사료에 첨가한 비타민과 Glycyrrhizin이 나일틸라피아의 성장 및 Edwardsiella 감염시 저항력에 미치는 영향 (Effects of Vitamins and Glycyrrhizin Added to Oxidized Diets on the Growth and on the Resistance to Edwardsiella Infection of Nile Tilapia, Oreochromis niloticus)

  • 장선일;조재윤;이주석
    • 한국양식학회지
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    • 제5권2호
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    • pp.143-155
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    • 1992
  • 산화된 사료에 첨가한 비타민 E, C 와 glycyrrhizin이 나일 틸라피아의 성장 및 Edwardsiella tarda 감염 시 저항력에 미치는 영향을 알아 보기 위해 thiobarbitric acid (TBA) 값이 $80\~88$ mg/kg 사료만을 단독으로 또는 이 사료 100 g 당 비타민 E (50 mg), C (60 mg)과 glycyrrhizin ($25\~200$ mg) 등을 각기 또는 상호 혼합하여 7 주간 사육하였다. 사육후 성장을 조사한 결과 비타민 E, C 및 glycyrrhizin 등을 각기 또는 혼합한 실험군이 산화된 사료만을 투여한 대조군에 비해 성장율이 좋았으며, 혈청 내의 glutamic oxaloacetic transaminase (GOT)와 glutamic pyruvic transaminase (GPT) 값은 산화된 사료를 투여한 실험군에서만 매우 높게 나타났다. 질병원인 E. tarda를 인위적으로 감염시켰을 때 저항력에 있어서도 glycyrrhizin 25 mg 투여군을 제외한 비타민 E, C 및 glycyrrhizin 등을 투여한 실험군이 산화된 사료만을 투여한 대조군에 비해 생존율이 현저히 높았다. 이상의 결과를 종합해 볼 때 산화된 사료만을 나일 틸라피아에 투여했을 때 성장 및 간의 활성도가 떨어지는 반면, 비타민 E, C 및 glycyrrhizin 등을 섞어서 투여했을때 성장 및 간의 활성도가 증가되었을 뿐만 아니라 E. tarda에 대한 저항력도 증가되었음을 알 수 있었다.

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