• 한국재료학회지
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• 제17권3호
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• pp.147-151
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• 2007

Cu-free multi-component sol, of which final oxide composition becomes $Bi_{1.9}Pb{0.35}SrCaO,\;Bi_{1.8}Pb_{0.2}SrCaO\;and\;Bi_{1.5}SrCaO$, respectively, was prepared through sol-gel route and coated on a bare Cu substrate. Starting materials were metal-alkoxides as follows.; [$Bi(OC_{2}H_{5})_{3}\;Pb(O^{1}C_{3}H_{7})_{2},\;Sr(O^{i}C_{3}H_{7})_{2},\;Ca(OC_{2}H_{5})_{2}$] as a reagent grade. Transparent light yellowish sol was obtained in the case of $Bi_{1.9}Pb_{0.35}SrCaO\;and\;Bi_{1.8}Pb_{0.2}SrCaO$ composition and $Bi_{1.5}SrCaO$ composition's sol was light greenish. Each sol was repeatedly dip-coated on Cu substrate four times and pre-heated at $400^{\circ}C$ and finally heat-treated in the range of $740{\sim}900^{\circ}C$. In the results, crystalline phases confirmed by XRD were (2201) orthorhombic and monoclinic phases. However, only $Bi_{1.9}Pb_{0.35}SrCaO_{x}$ composition showed pseudo-superconductive behavior after heat-treatment at $900^{\circ}C$ for 12 seconds and then onset temperature was 77 K, even though it did not exhibit zero resistance below Tc.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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• pp.235-235
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• 2003

The development of a buffer layer is an important issue for the second -generation wire, YBCO coated metal wire. The buffer layer demands not only on the prohibition of the reaction between YBCO and metal substrate, but also the proper lattice match and conductivity for high critical current density (Jc) of YBCO superconductor, In order to satisfy these demands, we suggested CaRuO3 as a useful candidate having that the lattice mismatches with Ni (200) and with YBCO are 8.2% and 8.0%, respectively. The CaRuO3 thin films were deposited on Ni substrates using various methods, such as e-beam evaporation and DC and RF magnetron sputtering. These films were investigated using SEM, XRD, pole-figure and AES. In e-beam evaporation, the deposition temperature of CaRuO3 was the most important since both hi-axial texturing and NiO formation between Ni and CaRuO3 depended on it. Also, the oxygen flow rate had i[n effect on the growth of CaRuO3 on Ni substrates. The optimal conditions of crystal growth and film uniformity were 400$^{\circ}C$, 50 ㎃ and 7 ㎸ when oxygen flow rate was 70∼100sccm In RF magnetron sputtering, CaRuO3 was deposited on Ni substrates with various conditions and annealing temperatures. As a result, the conductivity of CaRuO3 thin films was dependent on CaRuO3 layer thickness and fabrication temperature. We suggested the multi-step deposition, such as two-step deposition with different temperature, to prohibit the NiO formation and to control the hi-axial texture.

• 한국전자파학회지:전자파기술
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• 제14권3호
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• pp.20-40
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• 2003

고온초전도 필터의 무부하 양호도 값(unloaded Q-value)이 매우 높기 때문에, 삽입손실의 증가없이 극수(pole number)를 크게 증가시킨 대역통과 및 저역통과 필터를 제작할 수 있다(현재, 70-pole 대역통과 필터가 개발). 초전도 필터는 급준한 스컷 특성과 차단대역에 대한 양호한 감쇠수준을 얻을 수 있고, 집중상수형 공진기(lumped element resonators)를 사용하거나 지연파(slow wave) 특성을 활용하면 소형화가 가능하다. 다성분계인 산화물(oxide) 고온초전체를 에피택셜 박막 및 대면적(4-인치급) 박막으로 제조함으로서 다양한 구조의 평면형(planar type) 필터 개발뿐만 아니라, 전력처리력(power handling capability)도 향상시킬 수 있게 되었다. 최근에 고온초전도 평면형 필터는 반도체 저잡음 증폭기(GaAs-based LNA), 초소형 냉각기(mini-cooler)와 집적되어 서브-시스템화되었다. 그리고 이동통신 기지국용 수신전치부(receiver front-end) 서브-시스템으로 발전하여 통신시스템의 잡음수준과 인접한 주파수 대역에 의한 전파간섭을 현저히 줄일 수 있고, 동시에 주파수 이용효율의 향상과 통신시스템의 용량증대도 가능케 하고 있다. 본고에서는 고온초전도체 필터의 원리, 종류 및 설계법, 그리고 초전도 필터의 특징과 상품화의 요구사항에 대해 알아보고, 이동통신 기지국 수신 전치부용으로 사용되고 있는 고온초전도 필터 시스템개발과 관련된 연구 및 시장 동향의 특징들을 살펴보고자 한다.