• 제목/요약/키워드: oxidation speed

검색결과 141건 처리시간 0.027초

전기화학적 처리에 의한 배추 절임염수 재이용 가능성 평가 (Evaluation of brine reuse on salting of chinese cabbage using electrochemical process)

  • 정희숙;이은실;한성국;한응수
    • 상하수도학회지
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    • 제28권5호
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    • pp.541-548
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    • 2014
  • The pickling brine generated from the salting process of kimchi production is difficult to treat biologically due to very high content of salt. When pickling brine is treated and discharged, it cannot satisfy the criteria for effluent water quality in clean areas, while resources such as the salt to be recycled and the industrial water are wasted. However, sterilization by ozone, UV and photocatalyst is expensive installation costs and operating costs when considering the small kimchi manufacturers. Therefore there is a need to develop economical process. The study was conducted on the sterilization efficiency of the pickling brine using electrochemical processing. The electrochemical treatment of organic matters has advantages over conventional methods such as active carbon absorption process, chemical oxidation, and biological treatment because the response speed is faster and it does not require expensive, harmful oxidizing agents. This study were performed to examine the possibility of electrochemical treatment for the efficient processing of pickling brine and evaluated the performance of residual chlorine for the microbial sterilization.

Characterization of Al2O3 Thin Film Encasulation by Plasma Assisted Spatial ALD Process for Organic Light Emitting Diodes

  • Yong, Sang Heon;Cho, Sung Min;Chung, Ho Kyoon;Chae, Heeyeop
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.234.2-234.2
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    • 2014
  • Organic light emitting diode (OLED) is considered as the next generation flat panel displays due to its advantages of low power consumption, fast response time, broad viewing angle and flexibility. For the flexible application, it is essential to develop thin film encapsulation (TFE) to protect oxidation of organic materials from oxidative species such as oxygen and water vapor [1]. In many TFE research, the inorganic film by atomic layer deposition (ALD) process demonstrated a good barrier property. However, extremely low throughput of ALD process is considered as a major weakness for industrial application. Recently, there has been developed a high throughput ALD, called 'spatial ALD' [2]. In spatial ALD, the precursors and reactant gases are supplied continuously in same chamber, but they are separated physically using a purge gas streams to prevent mixing of the precursors and reactant gases. In this study, the $Al_2O_3$ thin film was deposited by spatial ALD process. We characterized various process variables in the spatial ALD such as temperature, scanning speed, and chemical compositions. Water vapor transmission rate (WVTR) was determined by calcium resistance test and less than $10-^3g/m^2{\cdot}day$ was achieved. The samples were analyzed by x-ray photoelectron spectroscopy (XPS) and field emission scanning electron microscope (FE-SEM).

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상대재와 분위기에 따른 순철의 미끄럼 마멸 기구 분석 (Analysis of the Sliding Wear Mechanism of Pure Iron Tested Against Different Counterparts in Various Atmospheres)

  • 구본우;권혁우;김용석
    • 소성∙가공
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    • 제26권6호
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    • pp.365-371
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    • 2017
  • During sling wear of a ferrous metal, a surface layer is formed. Its microstructure, constituting phases, and mechanical property are different from those of the original wearing material. Since wear occurs at the layer, it is important to characterize the layer and understand how wear rate changes with different layers. Various layers are formed depending on external wear conditions such as load, sliding speed, counterpart material, and environmental conditions. In this research, sliding wear tests of pure iron were carried out against two different counterparts (AISI 52100 bearing steel and $Al_2O_3$) in the air and in an inert Ar gas atmosphere. Pure iron was employed to exclude other effects from secondary phases in steel on the wear. Wear tests were performed at room temperature. Worn surfaces, wear debris, and cross-sections were analyzed after the test. It was found that these two different counterparts and environments produced diverse layers, resulting in significant changes in wear rate. Against the bearing steel, pure iron showed higher wear rate in an Ar atmosphere due to severe adhesion than that in the air. On the contrary, the iron showed much higher wear rate in the air against $Al_2O_3$. Different layers and wear rates were analyzed and discussed by oxidation, severe plastic deformation, and adhesion at wearing surfaces.

The effect of dynamic operating conditions on nano-particle emissions from a light-duty diesel engine applicable to prime and auxiliary machines on marine vessels

  • Lee, Hyungmin;Jeong, Yeonhwan
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제4권4호
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    • pp.403-411
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    • 2012
  • This study presents the nano-sized particle emission characteristics from a small turbocharged common rail diesel engine applicable to prime and auxiliary machines on marine vessels. The experiments were conducted under dynamic engine operating conditions, such as steady-state, cold start, and transient conditions. The particle number and size distributions were analyzed with a high resolution PM analyzer. The diesel oxidation catalyst (DOC) had an insignificant effect on the reduction in particle number, but particle number emissions were drastically reduced by 3 to 4 orders of magnitude downstream of the diesel particulate filter (DPF) at various steady conditions. Under high speed and load conditions, the particle filtering efficiency was decreased by the partial combustion of trapped particles inside the DPF because of the high exhaust temperature caused by the increased particle number concentration. Retarded fuel injection timing and higher EGR rates led to increased particle number emissions. As the temperature inside the DPF increased from $25^{\circ}C$ to $300^{\circ}C$, the peak particle number level was reduced by 70% compared to cold start conditions. High levels of nucleation mode particle generation were found in the deceleration phases during the transient tests.

Characteristics of GMR-SV Sensor for Measurement of Mineral Contents in Edible Water

  • Kim, Da-Woon;Lee, Ju-Hee;Kim, Min-Ji;Lee, Sang-Suk
    • Journal of Magnetics
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    • 제14권2호
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    • pp.80-85
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    • 2009
  • The mineral dissolution sensor system using GMR-SV and glass/Mg(200 nm) was prepared and characterized. The magnetic field sensitivity of GMR-SV to microscopic magnetic variation was about 0.8%/Oe. The change that occurs when Mg-film dissolves in water, the solubility of water, which is one of the basic properties of mineral water, was sensed by measuring the subtle variation of an electric current. In the case of edible water with Mg mineral added, bubbles were generated on the surface of the Mg film in the first 45 minutes, and the number of drops that were dissolved more rapidly than with the tap and DI waters later reduced to zero. For the edible water samples that each had different mineral Mg concentrations, the Mg solubility speed significantly differed. After injecting Mg film into the edible water, the magnetoresistance of the output GMR-SV signal decreased from a maximum of $45.4\;{\Omega}$ to a minimum of $43.6\;{\Omega}$. The measurement time was within 1 min, giving the rate of change ${\Delta}R/{\Delta}t=0.18\;{\Omega}/s$. This measurement system can be applied to develop a mineral Mg solubility GMR-SV sensor that can be used to sense the change from edible water to reduced alkali.

Comparison of HVOF Thermal Spray Coatings of T800 and WC-Co Powders

  • Cho, T.Y.;Yoon, J.H.;Kim, K.S.;Baek, N.K.;Song, K.O.;Youn, S.J.;Hwang, S.Y.;Chun, H.G.
    • 한국표면공학회지
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    • 제39권6호
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    • pp.295-301
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    • 2006
  • Hard chrome plating has been used in surface hard coating over 50 years both for applying hard coating and re-building of worn components. Hard chrome plating solution and mist pollute environment with very toxic $Cr^{6+}$(hex-Cr) known as carcinogen which causes lung cancer, High velocity oxy-fuel (HVOF) thermal spray coatings of WC base cermet and Co-alloy powders are the most promising candidates for the replacement of the traditional hard chrome plating. Surface properties, wear, and friction behaviors of micron size Co-alloy (T800) and micron size WC-l2Co (WC-Co) have been studied for the application as hard coatings. The temperature dependence of wear and friction behaviors of T800 and WC-Co have been investigated at the temperature of $25^{\circ}C$ and $538^{\circ}C$ for the application to high speed spindle.

대량 생산용 SiC CVD 리엑터에의 전산유체역학 시뮬레이션의 적용 (Application of Computational Fluid Dynamic Simulation to SiC CVD Reactor for Mass Production)

  • 서진원;최균
    • 한국세라믹학회지
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    • 제50권6호
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    • pp.533-538
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    • 2013
  • Silicon carbide (SiC) materials are typical ceramic materials with a wide range of uses due to their high hardness and strength and oxidation resistance. In particular, due to the corrosion resistance of the material against acids and bases including the chemical resistance against ionic gases such as plasma, the application of SiC has been expanded to extreme environments. In the SiC deposition process, where chemical vapor deposition (CVD) technology is used, the reactions between the raw gases containing Si and C sources occur from gas phase to solid phases; thus, the merit of the CVD technology is that it can provide high purity SiC in relatively low temperatures in comparison with other fabrication methods. However, the product yield rarely reaches 50% due to the difficulty in performing uniform and dense deposition. In this study, using a computational fluid dynamics (CFD) simulation, the gas velocity inside the reactor and the concentration change in the gas phase during the SiC CVD manufacturing process are calculated with respect to the gas velocity and rotational speed of the stage where the deposition articles are located.

딥러닝을 이용한 육불화텅스텐(WF6) 제조 공정의 지능형 영상 감지 시스템 구현 (Implementation of an Intelligent Video Detection System using Deep Learning in the Manufacturing Process of Tungsten Hexafluoride)

  • 손승용;김영목;최두현
    • 한국재료학회지
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    • 제31권12호
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    • pp.719-726
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    • 2021
  • Through the process of chemical vapor deposition, Tungsten Hexafluoride (WF6) is widely used by the semiconductor industry to form tungsten films. Tungsten Hexafluoride (WF6) is produced through manufacturing processes such as pulverization, wet smelting, calcination and reduction of tungsten ores. The manufacturing process of Tungsten Hexafluoride (WF6) is required thorough quality control to improve productivity. In this paper, a real-time detection system for oxidation defects that occur in the manufacturing process of Tungsten Hexafluoride (WF6) is proposed. The proposed system is implemented by applying YOLOv5 based on Convolutional Neural Network (CNN); it is expected to enable more stable management than existing management, which relies on skilled workers. The implementation method of the proposed system and the results of performance comparison are presented to prove the feasibility of the method for improving the efficiency of the WF6 manufacturing process in this paper. The proposed system applying YOLOv5s, which is the most suitable material in the actual production environment, demonstrates high accuracy (mAP@0.5 99.4 %) and real-time detection speed (FPS 46).

Development of Water Treatment Device By Fluidization Electrolysis Using Granular Ceramics

  • Ishikawa, Katsumi;Tamura, Rokurou;Shuto, Rika;Miyawaki, Jinuchi;Tanabe, Kimiko
    • 한국농업기계학회:학술대회논문집
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    • 한국농업기계학회 1996년도 International Conference on Agricultural Machinery Engineering Proceedings
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    • pp.737-745
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    • 1996
  • In recent years, with the increase in the consumption of natural resources and energy, global environmental problems have appeared. This is a very serious environmental load on worldwide food production. For this reason, innovative techniques for production of low entropy by using effectively the energy for the ecosystemic agriculture have been expected. In this study, granular ceramics of 2 to 3mm in diameter having electrical charges at the surface were produced, using the natural raw materials of silicate minerals haing excellent moldabilities and sintering properties . Production of water having functions was attempted by effective use of the electrochemical energy of the ceramics with an efficient water treatment apparatus in which the ceramics were fluidized in water, differently from conventional systems. In the experimental results, the EC of water treated with the ceramics was not changed, but the ORP and also the pH and the DO were changed. The speed of oxidation -re uction reaction was high, and the ceramics -treated water enhanced the vigor of seeds. It can be expected that this treatment system, by which the ORP of water can be moderately controlled, is advantageous in controlling the growth of plants.

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초미립 WC-Graphene-Al2O3 복합재료 소결 및 기계적 성질 (Mechanical Properties and Sintering of Ultra Fine WC-Graphene-Al Composites)

  • 손인진
    • 열처리공학회지
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    • 제36권4호
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    • pp.206-214
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    • 2023
  • Tungsten carbide has many industrial applications due to its high electrical and thermal conductivity, high melting temperature, high hardness and good chemical stability. Because tungsten carbide is difficult to sinter, it is sintered with nickel or cobalt as a binder and is currently used in nozzles, cutting tools, and molds. Alumina is reported to be a viable binder for tungsten carbide due to its higher oxidation resistance and lower cost than nickel and cobalt. The ultrafine tungsten carbide-graphene-alumina composites were rapidly sintered in a high frequency induction heating active sintering unit. The microstructure and mechanical properties (fracture toughness and hardness) of the composites were investigated and analyzed by Vickers hardness tester and electron microscope. Since the high-frequency induction heating sintering method enables high-speed sintering, ultrafine composites can be prepared by preventing grain growth. In the tungsten carbide-graphene-alumina composites, the grain size of tungsten carbide increased with the amount of alumina participation. The hardness and fracture toughness of the tungsten carbide-5% graphene- x% alumina (x = 0, 5, 10,15) composites were 5.1, 8.6, 8.6, and 8.4 MPa-m1/2 and 2384, 2168, 2165, and 2102 kg/mm2, respectively. The fracture toughness increased without a significant decrease in hardness. Sinterability was improved by adding alumina to tungsten carbide-graphene.