• 제목/요약/키워드: oxidation resistance

검색결과 825건 처리시간 0.022초

표면개질을 달리한 자동차 변속기어의 마멸특성 비교 (Comparision of Wear Characteristics of Automobile Transmission Gear on Surface Modification)

  • 류을현;조연상;김영희;박흥식
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2003년도 학술대회지
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    • pp.299-306
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    • 2003
  • The SCM420 used mainly to automobile transmission gear has problems that it costs transmission gear maker much money in carburizing treatment. For this, it needs to alternate the existing material and heat treatment to new gear material and surface modification. For this, friction and wear experiment according to sliding speed and applied load was carried out to evaluate the wear resistance of two transmission gear materials with oxidation nitrocarburising and non-oxidation nitrocarburising NT100, The presumed wear volume was calculated with the image processing for evaluation of wear resistance of two transmission gear materials. The results show that the oxidation nitrocarburising has a distinguished wear resistance than non-oxidation nitrocarburising.

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수소 첨가 열처리에 따른 Ti-6Al-4V 합금 분말의 격자 변형 및 내산화성 향상 (Lattice Deformation and Improvement Oxidation Resistance of Ti-6Al-4V Alloy Powders Prepared by Hydrogen Added Argon Heat Treatment)

  • 조계훈;오정민;임재원
    • 한국분말재료학회지
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    • 제26권2호
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    • pp.126-131
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    • 2019
  • In the present work, a new hydrogen added argon heat treatment process that prevents the formation of hydrides and eliminates the dehydrogenation step, is developed. Dissolved hydrogen has a good effect on sintering properties such as oxidation resistance and density of greens. This process can also reduce costs and processing time. In the experiment, commercially available Ti-6Al-4V powders are used. The powders are annealed using tube furnace in an argon atmosphere at $700^{\circ}C$ and $900^{\circ}C$ for 120 min. Hydrogen was injected temporarily during argon annealing to dissolve hydrogen, and a dehydrogenation process was performed simultaneously under an argon-only atmosphere. Without hydride formation, hydrogen was dissolved in the Ti-6Al-4V powder by X-ray diffraction and gas analysis. Hydrogen is first solubilized on the beta phase and expanded the beta phases' cell volume. TGA analysis was carried out to evaluate the oxidation resistance, and it is confirmed that hydrogen-dissolved Ti-6Al-4V powders improves oxidation resistance more than raw materials.

Characteristics of Solid Fuel Oxidation in a Molten Carbonate Fuel Cell

  • Lee, Choong-Gon;Kim, Yu-Jeong;Kim, Tae-Kyun;Lee, Sang-Woo
    • Journal of Electrochemical Science and Technology
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    • 제7권2호
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    • pp.91-96
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    • 2016
  • Oxidation behaviours of ash free coal (AFC), carbon, and H2 fuels were investigated with a coin type molten carbonate fuel cell. Because AFC has no electrical conductivity, its oxidation occurs via gasification to H2 and CO. An interesting behaviour of mass transfer resistance reduction at higher current density was observed. Since the anode reaction has the positive reaction order of H2, CO2 and H2O, the lack of CO2 and H2O from AFC results in a significant mass transfer resistance. However, the anode products of CO2 and H2O at higher current densities raise their partial pressure and mitigate the resistance. The addition of CO2 to AFC reduced the resistance sufficiently, thus the resistance reduction at higher current densities did not appear. Electrochemical impedance results also indicate that the addition of CO2 reduces mass transfer resistance. Carbon and H2 fuels without CO2 and H2O also show similar behaviour to AFC: mass transfer resistance is diminished by raising current density and adding CO2.

다상 금속간 화합물의 내마모 및 내산화 특성 (Wear and Oxidation Charateristics of Two Phase Intermetallic Compounds)

  • 이종훈;배종욱;이상율
    • 연구논문집
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    • 통권28호
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    • pp.183-192
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    • 1998
  • The wear and oxidation resistance of two phase nickel aluminides was investigated. Wear tests of various heat-treated specimens at room temperature and at $500^{\circ}C$ were performed under no lubricant condition in air by using a ball-on-disk type tribotester. Isothermal oxidation tests were made at $1100^{\circ}C$ in air flowing at the rate of 70cc/min and at $1000^{\circ}C$ in air by using TGA. Experimental results from wear tests showed that nickel aluminide with a higher content of Al had an improved wear resistance at both temperatures. Also the examination of the wear tracks after wear test at both room temperature and $500^{\circ}C$ indicated that regardless of the alloy compositions the wear tracks of the two phase nickel aluminides showed an abrasive type wear The improved oxidation resistance observed in the Ni-34at%Al alloy could to be attributed to the microstructural difference between the aluminides. An accelerated oxidation along the thin layer of $Ni_3AL$ along the grain boundary observed in the microstructure of the Ni-32at%Al aluminide could be attributed to the poor oxidation resistance.

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Inconel 738LC의 Pt Modified-pack Aluminizing 내산화 코팅의 산화저항성에 미치는 Palladium 완충층의 영향 (Effects of Palladium Buffer Layer on the Oxidation Resistance of Inconel 738LC Oxidation Resistant Coating Layer by Pt Modified-pack Aluminizing)

  • 한원규;최재웅;홍석준;황길호;강성군
    • 한국재료학회지
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    • 제15권4호
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    • pp.233-239
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    • 2005
  • In this study, the effects of Pd buffer layer on the oxidation resistance of Pt modified-pack aluminized Inconel 738LC, used for gas turbine, were investigated. Pd was electroplated on Inconel 738LC, and Pt was electroplated on the electroplated Pd surface. Thus, the thickness of electroplated Pt/Pd was $10\;{\mu}m$ and the atomic ratio of Pt : Pd was about 6 : 4. After Pt/Pd electroplating, Inconel 738LC was pack aluminized to form the oxidation resistant layer. To investigate the oxidation resistance of Pt/Pd modified-pack aluminized Inconel 738LC, iso-thermal oxidation and cyclic oxidation were performed. The iso-thermal oxdation and the cyclic oxidation data indicated that the Pt/Pd modified-pack aluminized Inconel 738LC was more oxidation resistant than the Pt modified-pack aluminized Inconel 738LC. It was thought that the difference of thermal expansion coefficient between Inconel 738LC and Pt was lowered by the Pd buffer layer.

B2-NiAl 금속간 화합물의 기계적 성질 및 내산화성에 미치는 Ni함량의 영향 (The Effects of Ni Content on Mechanical and Oxidation Resistance Properties of B2-NiAl Intermetallic Compounds)

  • 오창섭;한창석
    • 열처리공학회지
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    • 제26권1호
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    • pp.1-6
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    • 2013
  • The B2-ordered NiAl has attracted much attention as one of the candidates as a next generation high temperature material, because it has a high melting temperature, a low specific gravity and an excellent high temperature oxidation resistance. However, the application of NiAl to structural materials needs the improvement of its brittleness at room temperature. The study was carried out on the relation between several properties of NiAl and some variation of Ni content within NiAl phase, which means deviations from the stoichiometric composition. The main results were as follows; (i) Good ductility was obtained at the testing temperature more than 1073 K irrespective of Ni content. (ii) Increasing Ni content offered preferable tensile properties. (iii) Every NiAl with varying Ni contents showed the superior oxidation resistance.

TiAl합금의 Al 피복시 Al확산 피복층의 내고온산화성 (Oxidation Resistance of Al Diffusion Coating Layer on TiAl)

  • 이철형;최진일
    • 열처리공학회지
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    • 제10권2호
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    • pp.150-156
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    • 1997
  • The effect of variation of pack activators, compositions, temperature and time on the thickness and structure of aluminide coatings formed on the TiAl alloy was studied in one-step packs and two-step packs containing aluminum for the purpose of improvement of oxidation resistance. The thickness of coating layer was increased with increasing $NH_4Cl$ content up to 3wt% and then it was saturated. Oxidation resistance of coating layers carried out at one step pack was superior to that of ones through of two step pack. The improvement of high temperature oxidation resistance was due to the formation of a protective $Al_2O_3$ surface layers and coating the alloys with $TiAl_3$ phase.

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거품 제어에 의해 형성된 무정형 그물망 구조의 니켈이 코팅된 은나노와이어 유연 투명전극의 특성 분석 (Characterization of Nickel-coated Silver Nanowire Flexible Transparent Electrodes with a Random-mesh Structure Formed by Bubble Control)

  • 박종설;박태곤;박진석
    • 반도체디스플레이기술학회지
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    • 제19권3호
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    • pp.36-42
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    • 2020
  • Silver nanowire (AgNW) random-meshes with high transmittance, low sheet resistance, and high oxidation stability and flexibility were fabricated using solution-based processes. The random-mesh structure was obtained by forming bubbles whose sizes and densities were controlled using a corona treatment of polyethylene terephthalate (PET) substrates. To reduce the sheet resistance of the fabricated AgNW electrode, a washing process using ethanol solution was performed. In addition, nickel (Ni) was coated on AgNW to improve resistance to oxidation. The effects of corona treatment and Ni-coating on the transmittance, sheet resistance, oxidation stability, and flexibility of the AgNW electrodes were investigated.

방전플라즈마 소결법으로 제작한 β-FeSi2 소결체의 고온 내산화성 (Oxidation Resistance of SPS (Spark Plasma Sintering) Sintered β-FeSi2Bodies at High Temperature)

  • 장세훈;홍지민;오익현
    • 한국재료학회지
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    • 제17권3호
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    • pp.132-136
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    • 2007
  • Oxidation resistance of sintered ${\beta}-FeSi_{2}$ was investigated at intermediate temperature range in air atmosphere. Fully dense and porous bodies of ${\beta}-FeSi_{2}$ samples were fabricated by using the Spark Plasma Sintering (SPS). They were annealed at $900^{\circ}C$ for 5days to obtain ${\beta}-FeSi_{2}$ phase. The bulk samples were oxidized at $800,\;900\;and\;950^{\circ}C$ in air atmosphere. The high temperature oxidation tests reveal that amorphous $SiO_{2}$ layer, similar to Si was formed and grew parabolically on ${\beta}-FeSi_{2}$. Accelerated oxidation is not observed as well as cracks and grain boundary oxidation. Granular ${\varepsilon}-FeSi$ was developed below the oxide layer as a result of oxidation of ${\beta}-FeSi_{2}$. Oxidation resistance of sintered ${\beta}-FeSi_{2}$ was excellent for high-temperature thermoelectric application.

Preparation of Carbon Composite with High Oxidation Resistance by MoSi2 Dispersion

  • Goto, S.;Kodera, M.;Toda, S.;Fujimori, H.;Ioku, K.
    • The Korean Journal of Ceramics
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    • 제5권2호
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    • pp.115-118
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    • 1999
  • Carbon composites with $MoSi_2$ dispersion were prepared by hot-pressing at $1700^{\circ}C$ under 30 MPa for 1 h using polysilazance as binding material. The composites consisted of C, $Mo_{4.8}Si_3C_{0.6}$ and SiC. Bulk density and porosity of the carbon composites with 10 vol% $MoSi_2$ was 1.8g.$\textrm{cm}^{-3}$ and 34%, respectively. This composite was oxidized about 0.05mm from the surface of the carbon composite after oxidation test at $1500^{\circ}C$ for 10h in air. Formation of the $SiO_2$ glass layer was observed by SEM. When this composite suffered damage in the coating layer, it had hardly farther oxidation because of its self-repairing property. The composite prepared in this study indicated good oxidation resistance.

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