• Title/Summary/Keyword: oxa-Michael addition

Search Result 1, Processing Time 0.02 seconds

Highly Chemo- and Regioselective Reaction of Hydroxybenzenes in Acidic Ionic Liquid

  • Guo, Hui;Zhuang, Yu Wei;Cao, Jian;Zhang, Guo Bao
    • Bulletin of the Korean Chemical Society
    • /
    • v.34 no.9
    • /
    • pp.2594-2596
    • /
    • 2013
  • Highly chemo- and regioselective reaction of hydroxybenzenes with ${\alpha},{\beta}$-unsaturated compounds in acidic ionic liquid l-butyl-3-methylimidazolium hydrogen sulphate ([BMIM]HSO4) was reported for the first time. A series of oxa-Michael adducts and Friedel-Crafts alkylated products were synthesized with good yields. The acidic ionic liquid could be easily recycled for at least 5 times with only minor loss in activity.