Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Highly Chemo- and Regioselective Reaction of Hydroxybenzenes in Acidic Ionic Liquid

  • Guo, Hui (High New Technology Research Center of Henan Academy of Sciences) ;
  • Zhuang, Yu Wei (High New Technology Research Center of Henan Academy of Sciences) ;
  • Cao, Jian (High New Technology Research Center of Henan Academy of Sciences) ;
  • Zhang, Guo Bao (High New Technology Research Center of Henan Academy of Sciences)
  • Received : 2013.03.26
  • Accepted : 2013.06.04
  • Published : 2013.09.20
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Abstract

Highly chemo- and regioselective reaction of hydroxybenzenes with ${\alpha},{\beta}$-unsaturated compounds in acidic ionic liquid l-butyl-3-methylimidazolium hydrogen sulphate ([BMIM]HSO4) was reported for the first time. A series of oxa-Michael adducts and Friedel-Crafts alkylated products were synthesized with good yields. The acidic ionic liquid could be easily recycled for at least 5 times with only minor loss in activity.

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