• Title/Summary/Keyword: overtones

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THEORY AND PRINCIPLES OF NEAR INFRARED SPECTROSCOPY

  • Barton, Franklin E.
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1012-1012
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    • 2001
  • The elegant early experiments of Herschel demonstrated that there is light after the visible spectrum in a region we call the near infrared (NIR). This was followed by the work which showed that the spectrum went further into what we call the mid infrared (MIR). The MIR has been used for many years as a qualitative and quantitative region to measure constituent values. The MIR region contains the fundamental vibrations which can be theoretically calculated from symmetry rules and harmonic oscillator equations. The NIR is not as straight forward because the region from 400-2500 nm does not contain any of the fundamental vibrations only combination bands and overtones. Over the past fifty years efforts to understand the NIR have largely been ignored while the quantitative aspects of the region have been utilized. This presentation will focus on the efforts to define terms for NIR, examine the calculation of combination bands and overtones and ways to interpret the spectra. The interpretation of the NIR has been aided greatly in recent years by the use of two dimensional spectroscopy which allows the correlation of bands in one spectral region with that of the NIR.

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The Relationship Between Overtones And Diatonic (배음과 장음계와의 연관성)

  • Kim, Dae-Seung
    • Proceedings of the KAIS Fall Conference
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    • 2009.12a
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    • pp.115-117
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    • 2009
  • 대부분의 화성학 교재의 첫머리에 소개되는 배음은 그것이 가진 음악적 가치를 간과하고 과학적 수치에 근거한 자연적 현상으로 다루어지는 경향이 있다. 따라서 본 논문을 통해 배음이 가진 음악적인 중요성을 메이저 스케일의 Diatonic Chord와 Chord Scale을 중심으로 재조명 하고자 한다.

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수학과 음악의 상호작용적 관계에 대한 소고

  • Ma, Doc-Un;Lee, Byung-Soo
    • East Asian mathematical journal
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    • v.24 no.5
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    • pp.477-496
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    • 2008
  • In this paper, we consider the relations between mathematics and music, for examples rational numbers with musical scales, irrational numbers with musical scales, the golden ratio with musical compositions, the Fourier analysis with overtones. Our aim in this paper is to enhance the students' mathematical abilities by using musical materials.

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EXPERIMENTAL AND AB INITIO CHARACTERIZATION OF THE ANHARMONICITY OF $v_s(OH)$ VIBRATION IN PHENOL DERIVATIVES

  • Boguslawa, Czarnik-Matusewicz;Rospenk, Maria;Koll, Aleksandern
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1274-1274
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    • 2001
  • An anharmonicity is a fundamental quantity shaping the potential for stretching OH vibration in phenol and its derivatives. The phenomenon is examined both by experimental and theoretical methods. FT-IR and NIR spectra of series of phenols derivatives were measured in the range of fundamental and first two Overtones of $_{s}(OH)$ Vibrations in $CCl_4$ solutions. The electronic influence of substituents on the analyzed frequencies is discussed and correlated with $pK_{a}$ parameters. Ab initio MP2/6-31G(d,p) and B3LYP/6-31G(g,p) calculations of the potential for proton movement in OH group were performed. Equilibrium structures were also determined. The frequencies of fundamental and overtones were calculated by Numerov-type procedure. The results of calculations are compared with the experimental data. The best linear correlations were obtained for the results of MP2/6-31G(d,p) calculations. It was shown that some structural parameters are especially sensitive on substitution. The linear correlations were found between those parameters and spectroscopic data. The results of calculation are compared with available crystallographic data.

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Influence of Thermal Annealing on the Microstructural Properties of Indium Tin Oxide Nanoparticles

  • Kim, Sung-Nam;Kim, Seung-Bin;Choi, Hyun-Chul
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.194-198
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    • 2012
  • In this work, we studied the microstructural changes of ITO during the annealing process. ITO nanoparticles were prepared by the sol-gel method using indium tin hydroxide as the precursor. The prepared sample was investigated using TEM, powder XRD, XPS, DRIFT, and 2D correlation analysis. The O 1s XPS spectra suggested that the microstructural changes during the annealing process are closely correlated with the oxygen sites of the ITO nanoparticles. The temperature-dependent in situ DRIFT spectra suggested that In-OH in the terminal sites is firstly decomposed and, then, Sn-O-Sn is produced in the ITO nanoparticles during the thermal annealing process. Based on the 2D correlation analysis, we deduced the following sequence of events: 1483 (due to In-OH bending mode) ${\rightarrow}$ 2268, 2164 (due to In-OH stretching mode) ${\rightarrow}$ 1546 (due to overtones of Sn-O-Sn modes) ${\rightarrow}$ 1412 (due to overtones of Sn-O-Sn modes) $cm^{-1}$.

A study on the growth and electrical-optical characteristics of undoped-InSe and Sn-doped Inse single crystals by vertical bridgman method (수직 Bridgman법에 의한 InSe 단결정의 성장 및 Sn 도핑에 따른 전기.광학적 특성에 관한 연구)

  • 정희준;송필근;문동찬;김선태
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.481-484
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    • 1999
  • The undoped-InSe and Sn-doped InSe single crystals were grown by vertical Bridgman method and their properties were invesigated. These crystals were obtained by lowering the quartz ampoule for growth in the furnace and growth rate at optimum condition is 0.4mm/hr. The orientations and the crystallinites of these crystals were identified by X-ray diffraction(XRD), double crystal rocking curve(DCRC) and etch-pit density(EPD) measurements. From the Raman spectrum at room temperature, TO, LO modes together with their overtones and combinations were observed. Optical properties were investigated by photoluminescence at 12K and direct band gap of these crystals obtained from optical absorption spectrum. Compared with undoped-lnSe, electrical properties of Sn-doped InSe were increased and the electrical conductivity type were n-type. But electrical properties along growth direction of crystals and radial direction of wafer showed nearly uniform distribution.

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A study on the growth of undoped-lnSe single crystal by vertical Bridgman method and Zn diffusion in Sn-doped InSe (수직 Bridgman법에 의한 InSe 단결정의 성장 및 Sn이 첨가된 InSe에서 Zn의 확산에 잔한 연구)

  • 정회준;문동찬;김선태
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.464-467
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    • 1999
  • The undoped-InSe and Sn-doped InSe single crystals were grown by vertical Bridgman method and their properties were invesigated. The orientations and the crystallinites of these crystals were identified by X-ray diffraction(XRD), double crystal rocking curve(DCRC) and etch-pit density(EPD) measurements. From the Raman spectrum at room temperature, TO, LO modes and together with their overtones and combinations were observed. Optical properties were inves ated by PL at 12K and direct band gap of these crystals obtained from optical absorption spectrum. Compared with undo&-InSe, electrical properties of Sn-doped InSe were increased and the electrical conductivity type were n-type. But electrical properties along growth direction of crystals and radial direction of wafer showed nearly uniform distribution. The Zn diffusion mechanism in InSe could be explained by interstitial-substitutional and vacancy complex models and the activation energy of 1.15-3.01eV were needed for diffusion.fusion.

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Investigation of the Reaction Coordinate for Dissociation in $Cr(CO)_6$ Using Resonance Raman Spectroscopy

  • 유수창;고석범;J. B. Hopkins
    • Bulletin of the Korean Chemical Society
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    • v.16 no.11
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    • pp.1043-1045
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    • 1995
  • The overtone of the ν2 vibrational mode in Cr(CO)6 are observed for the first time in cyclohexane and methanol at both the 266 and 213 nm excitations. The appearance of the overtones due to the displacement of the electronic excited state with respect to the ground state along the ν2 vibrational mode is interpreted in terms of wavepacket concept and molecular orbital (MO) theory. Our Raman results suggest a new interpretation for the excited state potential.

A Study of Analysis about Virtual Musical Instruments' Timbre - Focused on Violin, Erhu, Haegeum - (가상악기의 음색 분석 연구 - 바이올린, 얼후, 해금을 중심으로 -)

  • Sung, Ki-Young;Lee, You-Jung
    • Journal of Korea Entertainment Industry Association
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    • v.13 no.7
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    • pp.219-227
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    • 2019
  • In this paper, we proactively looked at the structure and characteristics of each instrument in order to compare and analyze the sound colors of the western violin, chinese erhu and korean haegeum, which are representative bow string instruments. Also, many performers have simply been unable to fully explain how the violin is rich in pitch and the haegeum has a unique tone. Also, many performers thinks that violin sounds rich just because it has many overtones and have been unable to fully explain how haegeum makes unique tone. While previous research data show that most instruments are studied and published by analyzing their own frequencies or related cases of acoustic studies, this study provides a visual look how the harmonics composition, which determines musical instruments' timbres, consists of and suggests data specifically by analyzing each sound pressure of integer multiple overtones so that the structure of instruments' unique timbre can be understood. Based on this, we hope that it will be of considerable help to the development of virtual musical instruments of korean traditional instruments, which are relatively small compared to western virtual instruments, by reproducing instrument sounds through the synthesizers in the future.