• Journal of the Korean Ceramic Society
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• v.36 no.5
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• pp.459-464
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• 1999

A carbon-containing silica glass was prepared from orgaincally modified silicate(Ormosil) by heat treatment in N2 atmosphere after the ormosil was synthesized using sol-gel method. The Ormosil was fabricated from the TEOS as the inorganic component and the PDMS as the organic component. The Ormosil changed to balck-coloured glass by carbon decomposed from the PDMS when the Ormosil was heated to 450$^{\circ}C$ 20hrs. A dense silicon oxycarbide glass with 2.08 g/cm3 was obtained by heating the Ormosil at 1050$^{\circ}C$ 10hrs. The microstructure of the carbon-containing silica glass was observed by SEM and the SiOxC4-x structure was confirmed by XPS measurement. The densification of the glass was studied by measurements of specific surface area linear shrinkage and geometric density.

• Analytical Science and Technology
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• v.10 no.3
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• pp.225-229
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• 1997

The stability of Rhodamine 6G Perchlorate(Rh6GP) doped in organically modified silicate(Ormosil) was investigated after the Ormosil was synthesized by sol-gel process. The composition of the Ormosil which makes organic dye molecules stable and dimer-free was decided from comparing absorption peaks of dye molecules in sol state, in wet gel and in completely dried gel. The stable and dimer-free Rh6GP doped in the Ormosil was achieved in the 0.1 molar ratio of HCl/TEOS.

• Journal of the Korean Ceramic Society
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• v.33 no.12
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• pp.1365-1372
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• 1996

In order to obtain a transparent and dimer-free Ormosil embedded with orgainc dye variations of gel struc-ture and optical properties were studied as a functiion of the change of gel composition. The Ormosils which have good optical property were produced in the 90/10 ratio of TEOS/PDMS and the structural variations of the gel were achived by the change of ratio of HCl/TEOS. As the ratio of HCl/TEOS was increased pore size of the Ormosil enlarged and porosity increased. Increasing HCl concentration led to gradually lower trans-mittance values. In the xerogel doped with the organic dye Rhodamine 6G perchlorate a dimer peak near 500nm was observed with the increase of the ratio of HCl/TEOS

• Analytical Science and Technology
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• v.7 no.1
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• pp.17-23
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• 1994

Through sol-gel process, inorganic/organic composite as a dye host was made. It was observed that this composite has about 90% of trnasmittance by UV/VIS spectrophotometer. The transmittance is the most important requirement to decide whether the composite could apply or not as the dye host. The transmittance was increased with decreasing HCl as a catalyst, aging time, and amount of PDMS. Also, fluorescent and transmittant charateristics of Rhodamine 6G Perchlorate that was doped into ORMOSIL were measured. The fluorescent intensity was increased and the trnasmittance was decreased with rising gelling temperature.

• Journal of the Korean Ceramic Society
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• v.30 no.1
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• pp.34-40
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• 1993

ORMOSIL was synthesized with inorganic precursor, TEOS and organic precursor, PDMS, and the variation of composite properties according to the concentration of HCl, solvent content and reaction time were studied. As the concentration of HCl increased, condensation reaction was well proceeded and more regularly distributed network was observed. Increase in reactivity was found with the amount of solvent, and composite had a tendency of forming more porous microstructure as reaction time was increased, which had no influence on the bonding degree.

• Proceedings of the Korean Ceranic Society Conference
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• 2003.04a
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• pp.157.1-157
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• 2003

• Proceedings of the Korean Ceranic Society Conference
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• 2002.10a
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• pp.146.1-146
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• 2002

• Proceedings of the Korean Ceranic Society Conference
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• 2003.10a
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• pp.175.2-175
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• 2003

• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.204-206
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• 2009

Luminescent films were prepared by infiltration of tris(dibenzoylmethane) mono(1, 10-phenanthroline) europium incorporated ormosil into colloidal $SiO_2$ photonic crystal templates. The PL intensity of the infiltrated film into the template was about 13 times higher than that of the plane film prepared without the template.

• Journal of the Korean Ceramic Society
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• v.29 no.8
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• pp.593-600
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• 1992

Through sol-gel processing, Inorganic-organic composite was obtained. The influence of water content used in hydrolysis on the bonding state, microstructure, strength, and elongation into IR, NMR, Tg, etc. As the water content was increased, the bonds between inorganic Si-(OH) and organic Si-(OH) increased, and relatively denser microstructure was formed. Tensile strength and elongation decreased with amount of water content.