• Title/Summary/Keyword: organization absorption

Search Result 46, Processing Time 0.026 seconds

Solvent-vapor surface treatment induced performance improvement of organic solar cells

  • Kim, Chang-Su;Kang, Jae-Wook;Kim, Do-Geun;Kim, Jong-Kuk
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2011.05a
    • /
    • pp.42-43
    • /
    • 2011
  • Improvement of the photovoltaic efficiency via exposure of organic solar cells to solvent-vapor at room temperature is reported. Carbon disulfide ($CS_2$) vapor treatment can induce Poly(3-hexylthiophene) (P3HT) self-organization into ordered structure leading to enhanced hole transport and light absorption. The power conversion efficiency (PCE) of the organic solar cells can be increased from 0.89 to 1.67% by solvent-vapor treatment.

  • PDF

A Case Analysis on the Catch-up Strategy of Late-Comer Firms in the Social-Media Service Industry (소셜 미디어 서비스 산업 후발기업의 Catch-up 전략 사례분석)

  • Ham, Yeon-Joo;Jo, Hyung-Rae
    • Journal of Information Technology Services
    • /
    • v.11 no.4
    • /
    • pp.309-333
    • /
    • 2012
  • Recently, emergence of smart-phones and Social Networking Service(SNS) would offer the market environment changes and the opportunities for new business. For the case analysis comprehensive survey were implemented. And those data were analyzed along the research framework. The late-comer firms offered differential services, maintained creative and opened corporate culture, shoed learning capabilities which means absorption and organization of external knowledge, innovative efforts to control the insurgents than early-mover firms. When we analyze these phenomena along the developmental stages of late-comer, we can perceive that the stage of late-comers firms were moving from the "tracing the path" stage to "jumping the path" stage which means the creating capabilities were more or less enhanced and the firms become more stable in terms of business operation. In business model, early-mover firms showed clear definition for each business element, especially the revenue structure, while late-mover firms seemed unstable or unclear revenue structure.

Measurement of Sulfur Dioxide Concentration Using Wavelength Modulation Spectroscopy With Optical Multi-Absorption Signals at 7.6 µm Wavelength Region (7.6 µm 파장 영역의 다중 광 흡수 신호 파장 변조 분광법을 이용한 이산화황 농도 측정)

  • Song, Aran;Jeong, Nakwon;Bae, Sungwoo;Hwang, Jungho;Lee, Changyeop;Kim, Daehae
    • Clean Technology
    • /
    • v.26 no.4
    • /
    • pp.293-303
    • /
    • 2020
  • According to the World Health Organization (WHO), air pollution is a typical health hazard, resulting in about 7 million premature deaths each year. Sulfur dioxide (SO2) is one of the major air pollutants, and the combustion process with sulfur-containing fuels generates it. Measuring SO2 generation in large combustion environments in real time and optimizing reduction facilities based on measured values are necessary to reduce the compound's presence. This paper describes the concentration measurement for SO2, a particulate matter precursor, using a wavelength modulation spectroscopy (WMS) of tunable diode laser absorption spectroscopy (TDLAS). This study employed a quantum cascade laser operating at 7.6 ㎛ as a light source. It demonstrated concentration measurement possibility using 64 multi-absorption lines between 7623.7 and 7626.0 nm. The experiments were conducted in a multi-pass cell with a total path length of 28 and 76 m at 1 atm, 296 K. The SO2 concentration was tested in two types: high concentration (1000 to 5000 ppm) and low concentration (10 ppm or less). Additionally, the effect of H2O interference in the atmosphere on the measurement of SO2 was confirmed by N2 purging the laser's path. The detection limit for SO2 was 3 ppm, and results were compared with the electronic chemical sensor and nondispersive infrared (NDIR) sensor.

Development of Multiwire Proportional Counter for Measurement of Environmental-level Alpha Particles (환경준위 알파입자측정을 위한 다중선 비례계수기 개발(I))

  • Oh, Pil Jae;Park, Tae Soon;Lee, Min Kie;Kim, Kyung Hwa
    • Analytical Science and Technology
    • /
    • v.9 no.3
    • /
    • pp.262-269
    • /
    • 1996
  • The muiltiwire proportional counter for the measurement of low-level and environmental $\alpha$ particles emitting nuclides was developed. External dimension of the devloped multiwire proportional counter is $350{\times}290{\times}30mm$ and the sensitivity area is $250{\times}200mm$. The wall material of the detector was selected the stainless steel to prevent the deformation by external impact and to obtain minimum background. The anode and cathode wires were used the stainless steel material of diameter $50{\mu}m$. The spacing of each wires are 10.0mm, 5.0mm and the numbers of total wire are 21, 42 lines, respectively. The multiwire proportional counter was designed that the measurement source is placed within the detector to prevent the wall absorption effect and the efficiency variation by various source heights. The characteristics of the developed detector have been investigated to obtain the plateau, operating voltage, background, counting efficiency, position sensitivity and energy resolution etc. For the $^{241}Am$ nuclide, the calculated LLD(Lower Limit of Detection) is 5.0mBq/L which is lower than 40mBq/L of recommended LLD value by ISO(International Organization for Standardization).

  • PDF

Gold Nanoparticles Enhance the Anticancer Activity of Gallic Acid against Cholangiocarcinoma Cell Lines

  • Rattanata, Narintorn;Daduang, Sakda;Wongwattanakul, Molin;Leelayuwat, Chanvit;Limpaiboon, Temduang;Lekphrom, Ratsami;Sandee, Alisa;Boonsiri, Patcharee;Chio-Srichan, Sirinart;Daduang, Jureerut
    • Asian Pacific Journal of Cancer Prevention
    • /
    • v.16 no.16
    • /
    • pp.7143-7147
    • /
    • 2015
  • Gold nanoparticles (GNPs) were conjugated with gallic acid (GA) at various concentrations between 30 and $150{\mu}M$ and characterized using transmission electron microscopy (TEM) and UV-Vis spectroscopy (UV-VIS). The anticancer activities of the gallic acid-stabilized gold nanoparticles against well-differentiated (M213) and moderately differentiated (M214) adenocarcinomas were then determined using a neutral red assay. The GA mechanism of action was evaluated using Fourier transform infrared (FTIR) microspectroscopy. Distinctive features of the FTIR spectra between the control and GA-treated cells were confirmed by principal component analysis (PCA). The surface plasmon resonance spectra of the GNPs had a maximum absorption at 520 nm, whereas GNPs-GA shifted the maximum absorption values. In an in vitro study, the complexed GNPs-GA had an increased ability to inhibit the proliferation of cancer cells that was statistically significant (P<0.0001) in both M213 and M214 cells compared to GA alone, indicating that the anticancer activity of GA can be improved by conjugation with GNPs. Moreover, PCA revealed that exposure of the tested cells to GA resulted in significant changes in their cell membrane lipids and fatty acids, which may enhance the efficacy of this anticancer activity regarding apoptosis pathways.

A Monochromatic X-Ray CT Using a CdTe Array Detector with Variable Spatial Resolution

  • Tokumori, Kenji;Toyofuku, Fukai;Kanda, Shigenobu;Ohki, Masafumi;Higashida, Yoshiharu;Hyodo, Kazuyuki;Ando, Masami;Uyama, Chikao
    • Proceedings of the Korean Society of Medical Physics Conference
    • /
    • 2002.09a
    • /
    • pp.411-414
    • /
    • 2002
  • The CdTe semiconductor detector has a higher detection efficiency for x-rays and $\square$amma rays and a wider energy band gap compared with Si and Ge semiconductor detectors. Therefore, the size of the detector element can be made small, and can be operated at room temperature. The interaction between a CdTe detector and incident x-rays is mainly photoelectric absorption in the photon energy range of up to 100 keV. In this energy range, Compton effects are almost negligible. We have developed a 256 channel CdTe array detector system for monochromatic x-ray CT using synchrotron radiation. The CdTe array detector system, the element size of which is 1.98 mm (h) x 1.98 mm (w) x 0.5 mm (t), was operated in photon counting mode. In order to improve the spatial resolution, we tilted the CdTe array detector against the incident parallel monochromatic x-ray beam. The experiments were performed at the BL20B2 experimental hutch in SPring-8. The energy of incident monochromatic x-rays was set at 55 keV. Phantom measurements were performed at the detector angle of 0, 30 and 45 degrees against the incident parallel monochromatic x-rays. The linear attenuation coefficients were calculated from the reconstructed CT images. By increasing the detector angle, the spatial resolutions were improved. There was no significant difference between the linear attenuation coefficients which were corrected by the detector angle. It was found that this method was useful for improving the spatial resolution in a parallel monochromatic x-ray CT system.

  • PDF

Design and analysis of low velocity impact on thermoplastic hat section with curvilinear profile

  • Gaur, Kumresh K;Dwivedi, Mayank;Bhatnagar, Naresh
    • Advances in materials Research
    • /
    • v.6 no.1
    • /
    • pp.65-78
    • /
    • 2017
  • A hat section was designed and developed for maximum impact energy absorption and/or transmission under low velocity impact. Towards this, different hat sections, having material properties of thermoplastic, were modeled and investigated numerically using finite element analysis (FEA) in the range of 20-50 J impact energy. In the study it was experienced that the design configuration of hat section with curvilinear profile (HSCP) was excellent in energy attenuation capacity and for even distribution of maximum impact force around and along the hat section under low velocity impact loading. To validate the numerical findings, polypropylene copolymer (Co-PP) HSCP and low density polyethylene (LDPE) HSCP were developed and evaluated experimentally in the said impact energy range. A correlation was established between FEA and experimental test results, thereby, validating a numerical model to predict results for other thermoplastic materials under given range of impact energy. The LDPE HSCP exhibited better performance as compared to Co-PP HSCP in the said range of impact energy. The findings of this study will enable the engineers and technologists to design and develop low velocity impact resistance devices for various applications including devices to protect bone joints.

Development of a Candidate Equipment for Ozone SRP and its Uncertainty Evaluation (오존 SRP의 제작과 측정 불확도 평가)

  • 정규백;우진춘;이진홍
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.17 no.4
    • /
    • pp.313-319
    • /
    • 2001
  • The development of ozone SRP (Standard Reference Photometer) designated as a G-7 project by the Korean Ministry of Environment began 1997 and is now nearly completed. With the completion of the ozone SRP we will not only acquire a qualification to participate in the international ozone calibration system but also enhance calibration credibility of ozone similarly to that of other ambient air pollution monitors. As the ozone SRP uses highly cleaned blank air that can be distinguished from general ozone analyzer, it is possible to reduce errors associated with the determination of ozone via elongation of the absorption length as long as 1 meter In addition, gas chopping method hat been adopted to cut down interference of other substances and time drift. Furthermore, the system has also been modified to minimize the strayed ultra-violet noise along the light path. In this paper, a new method for uncertainty evaluation has been introduced, which is guided by the ISO (International Standard Organization) GUM (Guide to the Expression of Uncertainty in Measurement) through assessments of the uncertainty type B (that was impossible to estimate before) as well as the uncertainty type A (based on statistics).

  • PDF

Conjugated Oligomers Combining Fluorene and Thiophene Units : Towards Supramolecular Electronics

  • Leclere, Ph.;Surin, M.;Sonar, P.;Grimsdale, A.C.;Mllen, K.;Cavallini, M.;Biscarini, F.;Lazzaroni, R.
    • Proceedings of the Polymer Society of Korea Conference
    • /
    • 2006.10a
    • /
    • pp.228-228
    • /
    • 2006
  • Conjugated oligomers, used as models for fluorene-thiophene copolymers, are compared in terms of the microscopic morphology of thin deposits and the optical properties. The AFM images and the solid-state absorption and emission spectra are interpreted in line with the structural data, in terms of the assembly of the conjugated molecules. The compound with a terthiophene central unit and fluorene end-groups shows well-defined monolayer-by-monolayer assembly into micrometer-long strip-like structures, with a crystalline herringbone-type organization within the monolayers. Polarized confocal microscopy indicates a strong orientation of the crystalline domains within the stripes. In contrast, the compound with a terfluorene central unit and thiophene end groups forms no textured aggregates. The difference in behavior between the two compounds most probably originates from their different capability of forming densely-packed assemblies of ${\pi-pi}$ interacting molecules. These assemblies are used as active elements in organic field effect transistors designed by using soft lithography technique.

  • PDF

Classification of Biological Effect of 1,763 MHz Radiofrequency Radiation Based on Gene Expression Profiles

  • Im, Chang-Nim;Kim, Eun-Hye;Park, Ae-Kyung;Park, Woong-Yang
    • Genomics & Informatics
    • /
    • v.8 no.1
    • /
    • pp.34-40
    • /
    • 2010
  • Radiofrequency (RF) radiation might induce the transcription of a certain set of genes as other physical stresses like ionizing radiation and UV. To observe transcriptional changes upon RF radiation, we exposed WI-38, human lung fibroblast cell to 1763 MHz of mobile phone RF radiation at 60 W/kg of specific absorption rate (SAR) for 24h with or without heat control. There were no significant changes in cell numbers and morphology after exposure to RF radiation. Using quantitative RT-PCR, we checked the expression of three heat shock protein (HSP) (HSPA1A, HSPA6 and HSP105) and seven stress-related genes (TNFRSF11B, FGF2, TGFB2, ITGA2, BRIP1, EXO1, and MCM10) in RF only and RF/HS groups of RF-exposed cells. The expressions of three heat shock proteins and seven stress-related genes were selectively changed only in RF/HS groups. Based on the expression of ten genes, we could classify thermal and non-thermal effect of RF-exposure, which genes can be used as biomarkers for RF radiation exposure.