• Title/Summary/Keyword: organic zinc

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The Luminance characteristics of Red OELD based on Znq$_2$ and dye (Znq2와 dye에 의한 적색 OELD의 발광특성)

  • 조민정;최완지;박철현;임기조;박수길;김현후
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.358-360
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    • 2001
  • In this study, the bis(8-oxyquinolino)zinc II (Znq$_2$) were synthesized successfully from zinc chloride (ZnC1$_2$) as a initial material. Then, we fabricated red organic electroluminescent device with a dye (DCJTB)-doped and inserted Znq$_2$ between emission layer and cathode layer for increasing EL efficiency. The hole transfer layer is a N,N'-diphenyl-N,N'-bis-(3-methyl phenyl) -1,1'-diphenyl-4,4'- diamine(TPD), and the host material of emission layer is Znq$_2$. And we study the electrical and optical properties of devices. We found that the device using Znq$_2$ inserting layer result in the increased efficiency.

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Development of Anti-Fingers Printed EGI Steel Sheet With High Corrosion Resistance (고내식성 내지문 EGI 강판 개발)

  • 김형준
    • Journal of Surface Science and Engineering
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    • v.26 no.6
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    • pp.307-315
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    • 1993
  • A study on a new anti-finger printed EGI steel sheet with high corrosion resistance has been carried out to meet the recent requirement of high quality and performance of the pure zinc electrogalvanized steel sheet. The substrate was the pure zinc electrogalvanized sheet with the metallic coating of 20g/$\m^2$. The two differ-ent processes for inorganic(chromating) and organic(resin) coating were applied. One was a two coat/two bake type to separately treat chromating and resin coating which is now widely used. The other was a one coat/one bake type to simultaneously treat them which is newly developed in this study. The solution for the one coat/one bake type was an aqua-base coating agents which was composed of inorganic and organic components. The new anti-finger printed EGI steel sheet with the Cr and resin coating weight of 13mg/$\m^2$ and 800mg/$\m^2$, respectively shows the superior corrosion resistance besides the good paintability, formability fingerprint resistance and earth characteristics properties.

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A Study on the Synthesis of Organic/Inorganic Flame Retardant and Its Application (유ㆍ무기계 난연제의 합성 및 그 응용에 관한 연구)

  • 조승현;하진욱
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.4 no.3
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    • pp.218-222
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    • 2003
  • 본 연구의 목표는 난연화를 위한 기존 공법의 단점 보완과 환경 친화적인 난연제를 사용한 비 난연 XLPE 케이블의 난연화 방법과 최적의 난연 코팅액 배합에 있다. 전력용, 통신용 둥과 같이 고난연성이 요구되는 경우 기존 컴파운드 방법으로는 난연제를 다량으로 첨가하여 사용하며, base polymer와의 혼합성, 기계적인 물성에도 영향을 끼쳐서는 안 되는 등 여러 가지 요구 조건을 만족시켜야 하는 문제점을 가지고 있다. 각 난연 코팅액에 따른 코팅 표면을 고찰한 결과 모든 코팅의 표면은 깨끗하였으며, 코팅층의 두께는 약 10-20㎛로 일정하게 코팅이 되었다. TBBA/Sb₂O₃, TBBA/Zinc Borate의 무게비(wt%)가 1:0.7 이상부터 난연 효과를 보였다. 또한 Mg(OH)₂/Zinc Borate의 경우는 무게비(wt%)가 1:0.5, 1:0.6에서 난연효과를 보였으나, 1:0.7 이상에서는 난연 효과가 떨어지는 현상을 보였다. Mg(OH)₂/AF100 S/Zinc Borate의 경우는 AF100 S의 첨가량이 증가할수록 난연성이 향상되었다. 난연 코팅액의 열 분해 거동을 비교한 결과, Mg(OH)₂/Zinc Borate의 경우 초기 분해 온도가 유기계 난연제를 사용하였을 경우보다 늦어졌으며, 최종 잔류 탄화물 양도 많이 생성되었다. Mg(OH)₂/AF100 S/Zinc Borate의 경우 난연 효과를 상승을 위해 인계 난연제(AF100 S)를 첨가하였으나. 오히려 초기 분해온도가 빨라졌으며 잔류 탄화물의 양도 적게 나타났다. 그러나 연소 테스트 결과 가장 우수한 난연 효과를 보였다.

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Effects of Salmonella typhymurium Lipopolysaccharide Challenge on the Performance, Immune Responses and Zinc Metabolism of Laying Hens Supplemented with Two Zinc Sources

  • Cheng, Tingshui;Guo, Yuming
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.12
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    • pp.1717-1724
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    • 2004
  • The study was conducted to determine the effect of Salmonella typhymurium lipopolysaccharide (LPS) challenge on egg-laying performance, inflammatory response, zinc metabolism in layer fed diets supplemented with organic or inorganic zinc since 3-wk-old. The three dietary treatments were corn-soybean meal basal diet without supplemental zinc or with supplemental zinc at 60 mg/kg zinc from $ZnSO_4$ or zinc amino acid complex (ZnAA). At the age of 58 wk-old, twelve hens from each dietary treatment were allotted into two sub-groups. On day 1, 3, 5, 7 of the $58^{th}$ week of age, six birds of one sub-group were injected intraperitoneally (i.p.) with 2 ml LPS (1.0 $\ell$/ml) or sterile saline. Neither zinc source ${\times}$ immune challenge interaction nor zinc source effect on egg production performance was observed (p>0.05), LPS-challenge decreased egg production (p<0.04) and increased percentage of cracked eggs (p <0.01). With LPS challenged, the fever response of hens fed ZnAA peaked and subsided earlier than in hens fed $ZnSO_4$ or basal diet. Serum IL-1$\beta$ at 3 h was higher (p<0.01), but lower (p<0.001) at 12 h post-challenge with LPS in hens fed ZnAA than $ZnSO_4$. In salinetreated groups, serum IL 1$\beta$ was higher in hens fed ZnAA than the basal diet at 3 h post-injection (p<0.01). LPS-challenged birds had lower serum zinc and higher zinc sequestered in liver and spleen (p<0.001). In saline-treated birds, there was no difference in zinc concentration of serum, liver and spleen among different dietary treatments (p>0.05). Supplementation of 60 mg/kg zinc from either ZnAA or $ZnSO_4$ significantly (p<0.05) elevated metallothionein (MT) concentration in liver and spleen. MT concentration in liver of birds fed ZnAA diet was higher than in those fed $ZnSO_4$ diet (p<0.05). The magnitude of increase of hepatic and splenic MT due to LPS challenge was higher by supplementation of ZnAA than $ZnSO_4$. The results suggest that zinc amino acid complex enhanceed MT synthesis and zinc sequestered in liver and spleen and increased the sensitivity to immune response due to LPS challenge.

Partially Dry-Transferred Graphene Electrode with Zinc Oxide Nanopowder and Its Application on Organic Solar Cells (ZnO 나노 분말 코팅 기반 건식전사 그래핀 전극 제작 및 유기태양전지 응용)

  • Jo, Yeongsu;Woo, Chae Young;Hong, Soon Kyu;Lee, Hyung Woo
    • Journal of Powder Materials
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    • v.27 no.4
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    • pp.305-310
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    • 2020
  • In this study, partially dry transfer is investigated to solve the problem of fully dry transfer. Partially dry transfer is a method in which multiple layers of graphene are dry-transferred over a wet-transferred graphene layer. At a wavelength of 550 nm, the transmittance of the partially dry-transferred graphene is seen to be about 3% higher for each layer than that of the fully dry-transferred graphene. Furthermore, the sheet resistance of the partially dry-transferred graphene is relatively lower than that of the fully dry-transferred graphene, with the minimum sheet resistance being 179 Ω/sq. In addition, the fully dry-transferred graphene is easily damaged during the solution process, so that the performance of the organic photovoltaics (OPV) does not occur. In contrast, the best efficiency achievable for OPV using the partially dry-transferred graphene is 2.37% for 4 layers.

Influence of Various Levels of Organic Zinc on the Live Performance, Meat Quality Attributes, and Sensory Properties of Broiler Chickens

  • Salim, Hossan Md.;Lee, Hak-Rim;Jo, Cheo-Run;Lee, Soo-Kee;Lee, Bong-Duk
    • Food Science of Animal Resources
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    • v.31 no.2
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    • pp.207-214
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    • 2011
  • The influence of supplementing diets with various levels of organic zinc (OZ) on the performance, meat quality attributes, and sensory properties of broiler chickens was investigated. A total of 3,200 1-d-old female broiler chicks were randomly allotted to 16 floor pens (replicates) with 200 birds per pen. A corn-wheat-soybean meal basal diet (control) was formulated and 20 ppm OZ (20 OZ), 40 ppm OZ (40 OZ), or 80 ppm OZ (80 OZ) was added to the basal diet to form four dietary treatments with four replicates per treatment. Live performance of broiler chickens, meat quality, and sensory properties were evaluated. The results showed no significant difference among the treatments for live performance of broiler chickens. Significant increases (p<0.05) in thigh skin epidermis and dermis thickness were shown in the OZ supplementation groups; however, no effect of OZ on the thickness of back skin epidermis or dermis was found. Dietary OZ levels did not affect the pH of breast and thigh meat or the water holding capacity (WHC) of thigh meat, but the WHC of breast meat increased significantly (p<0.05) when birds were fed 40 OZ and 80 OZ. Results of a sensory analysis showed no differences among the dietary treatments. In conclusion, dietary OZ did not affect live performance or sensory properties of broiler chickens but did increase the WHC of breast meat and thickness of skin layers; thus, improving carcass quality in broiler chickens.

Reaction of Organic Halogen Compounds with Metals (Part Ⅰ) A Formation of Organometallic Complex in Dimethyl Formamide Solvent (有機할로겐 化合物과 金屬과의 反應 (第1報) 디메칠호름아마이드 溶媒存在下에서의 有機金屬콤프렉스 生成에 關한 硏究)

  • Yon Sun Kim
    • Journal of the Korean Chemical Society
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    • v.7 no.3
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    • pp.216-224
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    • 1963
  • Reaction of organic chlorine containing ester, alcohol, and acids with metallic tin and zinc in dimethyl formamide solvent gave a good yield of organo metallic complex. The same reaction under a mixed U.V. irradiation could not give an appreciable yield of the complex except in the case of an elevated reaction temperature. The solvation effect of dimethyl formamide of the metallic complex formation was markedetly increased as compared to the reaction in toluene and cyclohexane. In case of chlorine containing carboxylic acid, the formation of organo chloro zinc complex of the salt was observed. The reaction of organo zinc complex with a carbonyl precursor gave the addition product together with a dimerized product. Especially the aldehyde species enhanced the formation of zinc complex. The addition reaction was simple and convenient, but the yield was not high.(30-40% for the acid, 73% for the ester, 14.6% for alcohol). The result was discussed on basis of solvent effect and the procedures were described.

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