• Title/Summary/Keyword: organic sulfur

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Kiwi-persimmon wine produced using wild Saccharomyces cerevisiae strains with sugar, acid, and alcohol tolerance

  • Hee Yul Lee;Kye Man Cho;Ok Soo Joo
    • Food Science and Preservation
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    • v.30 no.1
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    • pp.52-64
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    • 2023
  • 100 different yeast colonies were isolated from spontaneously fermented kiwis, persimmons, apples, pears, watermelons, grapes, grape fruits, peachs, and plums, and selected yeast strains were used to produce kiwi-persimmon mixed wine (KPMW). Among the isolates, five representative strains exhibited tolerance to sucrose, alcohol, pH, and potassium metabisulfite when compared with the control yeast strain (Saccharomyces cerevisiae KCCM 12615). All five yeast strains (Y4, Y10, Y28, Y78, and Y81) exhibited 99% 26S rDNA sequence similarity to S. cerevisiae. The pH, acidity, Brix, reducing sugar, alcohol, and organic acid contents were consistent in KPMW prepared from the S. cerevisiae KCCM 12615 and Y28 strains. KPMW made from the Y4, Y10, and Y28 strains exhibited lower quantities of free sugars than those of the KPMW made from the other yeast strains. The level of ethyl esters in KPMW prepared from the Y28 was higher than that in the other KPMWs. All strains, except for Y28, produced lower concentrations of sulfur and ketone compounds. Furthermore, the KPMW produced by the Y28 strains had total phenolic contents with 1.1 g/L, with DPPH and ABTS radical scavenging activities of 57.06% and 55.62%, respectively, and a FRAP assay value of 0.72. Our results suggest that Y28 is a promising yeast strain for producing high-quality wines.

Evaluation of Indoor Air Quality in a Hospital Operating Room During Laparoscopic Surgery (병원 수술실에서의 복강경 수술 중 실내공기질 평가)

  • Choi, Dong Hee;Kang, Dong Hwa
    • Journal of The Korea Institute of Healthcare Architecture
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    • v.30 no.3
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    • pp.67-74
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    • 2024
  • Purpose: The identification and quantification of indoor airborne contaminants, including bio-aerosols, particulates, and gaseous contaminants, are crucial for maintaining acceptable indoor air quality for hospital operating rooms (ORs). Laparoscopic surgery has become widely accepted for various surgical procedures due to its rapid recovery rate and the low risk associated with small incisions compared to conventional open surgery. The objective of this study is to investigate the indoor air quality in hospital ORs and to identify indoor airborne contaminants generated during laparoscopic surgery. Methods: Measurements of an indoor environment, including temperature, humidity and air quality, were performed in an OR before and during a laparoscopic surgery. Indoor airborne contaminants, including volatile organic compounds (VOCs), formaldehyde, carbon monoxide (CO), carbon dioxide (CO2), sulfur dioxide (SO2), nitrogen dioxide (NO2), suspended indoor particles, and airborne bacteria, were measured simultaneously. Results: The study determined that the concentrations of indoor air particles and airborne bacteria increased during the surgery but were within acceptable levels. However, the concentration of CO2, reached a high level of 1,791 ppm due to the CO2 gas required for maintaining the pneumoperitoneum during the surgery. Implications: The results emphasized the use of ventilation and filtration in a laparoscopic surgery room to lower the concentration of filterable and non-filterable contaminants.

Effects of Nitrogen Fertilizers on Growth and Nutrient Uptake of Rice Plants and Chemical Properties of Paddy Soil (질소질(窒素質) 비종(肥種)이 수도(水稻)의 생육(生育)과 양분흡수(養分吸收) 및 토양(土壤)의 화학적(化學的) 성질(性質)에 미치는 영향(影響))

  • Lim, Sun-Uk;Kim, You-Hak
    • Korean Journal of Soil Science and Fertilizer
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    • v.17 no.3
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    • pp.232-241
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    • 1984
  • For the purpose of investigating the effect of chemical composition of nitrogenous fertilizers such as urea, ammonium sulfate, ammonium phosphate(dibasic) and aqua-ammonia on growth, yield, efficiency and chemical properties of paddy soil this study was carried out at the same nitrogen concentration through field experiment. The results obtained was summarized as follows. 1. Nitrogenous fertilizers had an effect on plant height at heading stage, plant weight at harvest and No. of spikelet per panicle of rice plants in decreasing order: Ammonium sulfate > Diammonium phosphate > Urea > Ammonia water. But they didn't effect on culm length, spike length, dry matter weight, No. of grain per spike, ripening ratio and weight of 1000 grains of rice plants. 2. The absorbed amount of nitrogen and that of sulfur and nitrogen availability were highest in ammonium sulfate application and lowest in ammonia water application and these were positively correlated with yield. 3. The influence of nitrogenous fertilizers on nitrogen and sulfur efficiency and translocation efficiency was insignificant but that of ammonium sulfate on nitrogen efficiency was higher than that of the others. 4. The effect of nitrogenous fertilizers on a basic chemical properties of paddy soil experimented such as pH, C.E.C, exchangeable cation and organic matter was insignificant. But the sulfur content of ammonium sulfate application and phosphorous content of diammonium phosphate application were higher than that of the others.

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Emission characteristics of odor from salted food materials using Spam (염처리 음식물의 냄새성분 배출특성에 대한 연구: 스팸을 중심으로)

  • Lee, Min-Hee;Kim, Ki-Hyun;Kim, Yong-Hyun;Jo, Sang-Hee
    • Analytical Science and Technology
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    • v.25 no.6
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    • pp.447-459
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    • 2012
  • In this study, the emission characteristics of volatile and odorant species released from salted meat product (Spam) was investigated as a function of time. Gas samples released from Spam samples were analyzed for volatile organic compounds (VOC) and sulfur compounds (RSC) at five different times for the elapsed (E) days of 0, 1, 3, 6, and 9 (E-0 to E-9) by GC/MS and GC/PFPD system, respectively. Results indicated that reduced sulfur, aldehyde, and ketone groups were the dominant odorants. Especially, hydrogen sulfide was the predominant in concentration and odor activity value (OAV) during the fresh stage. Its concentration was 1465 ${\mu}g/m^3$ (60.0% of the total mass) in E-0 and 455 ${\mu}g/m^3$ (28.0%) in E-1, while its OAV was 19.4 (78.3%: E-0) and 6.02 (41.7%: E-1). On the other hand, the concentration of acetone showed the maximum values in the decaying stage (E-3: 451 (43.2%), E-6: 369 (64.2%), and E-9: 1150 ${\mu}g/m^3$ (70.2%)). Furthermore, the concentration of 2,3-butanedione was also detected considerably from decaying sample (E-3: 17.6 (1.68%), E-6: 16.1 (2.80%), and E-9: 179 ${\mu}g/m^3$ (10.9%)). However, OAV of acetone was insignificant (<0.01%) in the decaying stage, while that of 2,3-butanedione was relatively high in the range of 1.14-11.6 (14.5-76.2% of ${\Sigma}OAV$). It thus confirmed that the major odorant groups generated from Spam samples changed with the progress of decay such as sulfur (fresh stage), aldehyde (intermediate stage), and ketone compounds (decaying stage).

Characteristic evaluation of anaerobic co-digestion using desulfurization sludge and primary sludge (탈황슬러지 및 생슬러지를 이용한 혐기성 병합소화 특성평가)

  • Seulki Koo;Woojin Chung;Soonwoong Chang;Myoungsoo Park
    • Journal of the Korea Organic Resources Recycling Association
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    • v.31 no.4
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    • pp.51-58
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    • 2023
  • In this study, anaerobic co-digestion was carried out using desulfurization sludge and sewage sludge (primary sludge) to evaluate the effects of sulfur compounds in anaerobic digestion. The experiment was carried out in the form of a batch test using 500 mL duran bottle, and the mixing ratio of the feedstock was selected based on the ratio of COD/SO4. As a result of the experiment, it was confirmed that the amount of biogas generated and the yield decreased at the mixing ratio of COD/SO4 20 or less. In particular, below COD/SO4 10, it was lower than seed (283.5 mL) which was set without feedstock to correct biogas generated by itself from seed sludge. Methane yield tended to decrease from a ratio of COD/SO4 20 or less to 0.135 m3/kg VS compared to 0.396 m3/kg VS of COD/SO4 50. In addition, compared to 0.0097 m3/kg VS of hydrogen sulfide yield from COD/SO4 50, the ratio of COD/SO4 20 increased sharply to 0.0223 m3/kg VS, and in particular, the highest result was 0.0855 m3/kg VS in COD/SO4 10. Based on these results, it is judged that the effect of sulfide in anaerobic digestion can have an adverse effect if the COD/SO4 ratio decreases to less than 20.

Characteristics of Oil Shale as Unconventional Oil Resources (비재내형(非在來型) 원유(原油) 자원(資源)으로서의 오일셰일 특성(特性) 고찰(考察))

  • Na, Jeong-Geol;Chung, Soo-Hyun
    • Resources Recycling
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    • v.17 no.6
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    • pp.62-67
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    • 2008
  • Oil shale is a sedimentary rock that contains organic compounds called kerogen that are released as petroleum-like liquids by retorting. In order to evalute oil shale as alternative oil resources, the physical properties of oil shale samples from US and Russia were investigated and Fischer assays were carried out. Thermogravimetric analysis shows that thermal degradation of oil shale consisted of two stage processes, with hydrocarbon release from kerogen followed by $CO_2$ release by carbonate decomposition. Organic compounds in oil shale have an high hydrogen/carbon ratio, and therefore liquid hydrocarbons could be obtained easily. Shale oil yields from Russian and US oil shales by Fischer assay were 12.7% and 18.5%, respectively. The density and boiling point of shale oils are higher than that of Middle East crude oil, indicating that further upgrading processes are necessary for refinery. On the other hands, sulfur contents are relatively low, and the amounts of Vanadium and Nickel are extremely small in shale oil. It was found that paraffins were rich in US shale oil while main components of Russian shale oil were oxygenated hydrocarbons.

Analysis of Volatile Organosulfur Compounds in Korean Allium Species (국내산 Allium속(마늘, 양파, 대파)의 휘발성 함유황 유기화합물 분석)

  • Song, Hyun-Pa;Shim, Sung-Lye;Jung, In-Sun;Kim, Jun-Hyeong;No, Gi-Mi;Seo, Hye-Yeong;Kim, Dong-Ho;Kim, Kyong-Su
    • Food Science and Preservation
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    • v.16 no.6
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    • pp.929-937
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    • 2009
  • We identified volatile organic compounds in Korean Allium species. Volatile organic components in three Korean Allium species, dried garlic, dried onion, and dried Welsh onion, were extracted using a simultaneous distillation and extraction (SDE) method and identified by GC/MS analysis. The numbers of volatile compounds were 48, 32, and 33 in the three species, respectively. In dried onion, the major compounds were dipropyl trisulfide, methyl propyl trisulfide, and propanethiol. (Z), (E)-propenyl propyl trisulfide, methyl propyl trisulfide, and dipropyl trisulfide were detected at high levels in Welsh onion. In dried garlic, presence of the allyl group identified characteristic volatile organosulfur compounds including diallyl disulfide and diallyl trisulfide. Qualitative and quantitative analysis of volatile compounds in three Korean Allium species showed that sulfur-containing compounds were dominant, and allyl groups derived from (+)-S-(2-propenyl)-L-cysteine sulfoxide (ALLYL CSO, alliin) were more abundant in dried garlic, than in other materials.

The Study on the Odor Removal of Digested sludge using BIO-CLOD (BIO-CLOD를 이용한 소화슬러지의 악취저감에 대한 연구)

  • Sung, Il-Wha
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.12
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    • pp.8665-8672
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    • 2015
  • In this study, to investigate the feasibility of malodorous substance and organic matter removal by digest sludge in sewage treatment plants, ammonia, methyl mercaptan(MMC), and hydrogen sulfide($H_2S$) in a reactor submerged with BIO-CLOD(BIO-CLOD) and a reactor not submerged with BIO-CLOD(Non BIO-CLOD) were measured at 24 hours, 48 hours, and 72 hours after the submergence of BIO-CLOD. Whereas the reactor in which BIO-CLOD was submerged showed an ammonia removal rate of 48% and high $H_2S$ and MMC removal rates exceeding 98% in 24 hours, the reactor in which BIO-CLOD was not submerged showed an ammonia removal rate of 45%, an $H_2S$ removal rate of 71%, and an MMC removal rate of 84% in 24 hours indicating the possibility of removal of malodor using BIO-CLOD. A nitrification was shown in which ammonia concentrations decreased over time while nitrate nitrogen concentrations increased and sulfur based malodor components were oxidation decomposed indicating that BIO-CLOD had effects to increase sulfate concentrations in the solution and that sulfate concentration increases and atmospheric $H_2S$ removal rates were correlated with each other. With regard to decreases in organic matter in reactor effluents, BIO-CLOD did not affect in a short period of time and when reactors were operated with HRT 12 hours and HRT 24 hours, HRT 12 hours was considered desirable in terms of economy.

A Study on the Degradation Mechanism of Diazinon and the Acute Toxicity Assessment in Photolysis and Photocatalysis (광반응과 광촉매 반응을 이용한 Diazinon 농약의 분해 기전과 독성 평가에 관한 연구)

  • Oh, Ji-Yoon;Kim, Moon-Kyung;Son, Hyun-Seok;Zoh, Kyung-Duk
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.11
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    • pp.1087-1094
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    • 2008
  • Diazinon is a phosphorothiate insecticide widely used in the world including Korea. This study investigates the feasibility of photolysis and photocatalysis processes for the degradation of diazinon in water. Both photolysis and photocatalysis reactiosn were effective in degrdading diazinon, however lower TOC removals were achieved. In case of photocatalysis, approximately 40% of nitrogen from diazinon was recovered as NO$_3^-$, and less than 5% of phosphorus as PO$_4{^{3-}}$. However, the sulfur in diazinon molecule was completely recovered to SO$_4{^{2-}}$ from photocatalysis reaction, and the recovery from photolysis was 50%, indicating that P=S bond easily breaks first during photolysis and photocatalysis. The poor recoveries of ionic byproducts and TOC from photolysis and photocatalysis indicate the presence of other organic intermediates during reactions. The formation of organic intermediates were identified during reactions using GC/MS and LC/MS/MS, and the main degradation products were diazoxon, and 2-isopropyl-4-methyl-6-hydroxypyrimidine (IMP), respectively. Finally, the acute 48-hr toxicity test using Daphnia magna were employed to measure the toxicity reduction during photocatalysis of degradation. The results showed that the toxicity increased until 180 min of the photocatalysis reaction (from EC$_{50}$ (%) of 69.6 to 13.2%), however, acute toxicity completely disappeared (>100%) after 360 min. The toxicity results showed that the intermediates from photocatalysis such as diazoxon were more toxic than diazinon itself, however these intermediates can be degraded or mineralized with further reaction.

SRF Conversion Potential of Biomass and Mixed Plastic Waste Generated in D City (D시 내에서 발생하는 바이오매스 및 폐플라스틱 혼합 폐기물의 SRF 전환 포텐셜 분석)

  • Yang, Han-Sol;Kim, Ki-Kwang;Lim, Chae-Wook;Hyun, Jae-Hyuk
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.3
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    • pp.55-61
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    • 2018
  • This study evaluated if the selected samples meets the Solid Refuse Fuel quality criteria in Korea. Biomass and plastic wastes generated in D City were mixed in diverse ratio. When the biomass content was about 40%, the moisture content was close to the SRF criteria and was measured to be 9.8%. The ash contents were analyzed up to 4.19%, and the lower calorific values based on Steuer, Dulong Equation and Bomb Calorimeter were at least 4,851, 4,181 and 3,847 kcal/kg, respectively. As a result of the elemental analysis, sulfur and chloride content were measured up to 0.05%. Those values satisfied the SRF criteria. Also, heavy metals(Hg, Cd, Pb, As) were analyzed to be below the SRF criteria. This makes it possible to use efficiently the wood byproducts abandoned in the woods, and the physical properties of wood being weak to moisture can be supplemented with plastics. Consequently, if plastic and biomass were well mixed and made into SRF, it would overcome the problem of shortening the life span of incineration facilities due to the high temperature of plastic wastes in the incinerator.