• 제목/요약/키워드: organic structure

검색결과 2,401건 처리시간 0.029초

Synthesis of a Series of Long Chain Lamellar Inorganic/Organic Iron(II) Alkylsulfonate Hydrates

  • Park, Seong-Hun
    • 통합자연과학논문집
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    • 제1권2호
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    • pp.76-78
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    • 2008
  • A series of the long-chain iron(II) alkylsulfonate hydrates were synthesized via self-assembly of surfactant alkyl chains in aqueous medium. Reaction of iron(II) salts with n-alkylsulfonate yields lamellar $Fe(CnH2n+1SO3)2{\cdot}4H_2O$. These compounds show a layered structure, as determined by XRD, consisting of alternating organic alkylsulfonate layers and inorganic iron(II) hydrate layers, with interlayer distances of upto 3.2 nm. This lamellar structure may be attributed to the amphiphilic nature of the surfactants, mediating the coordination and H-bionding interactions, and the hydrophobic alkyl chains. An alkyl chain packing of present system are differ from those of similar Cu(II) series, which are attributed from the size of hydrated metal(II) ions.

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Preparation of SAN/Silicate Nanocomposites Using PMMA as a Compatibilizer

  • Kim, Ki-Hong;Jo, Won-Ho;Jho, Jae-Young;Lee, Moo-Sung;Lim, Gyun-Taek
    • Fibers and Polymers
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    • 제4권3호
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    • pp.97-101
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    • 2003
  • Polymer/silicate nanocomposites were prepared via two-step manufacturing process: a master batch preparation and then mixing with matrix polymer. A hybrid of PMMA and Na-MMT with exfoliated structure was first prepared by emulsion polymerization of MMA in the presence of Na-MMT. For the case that SAN24, miscible with PMMA, is used as matrix, we could prepare a nanocomposite with exfoliated structure. However, SAN31 nanocomposite shows the aggregation and/or reordering of the silicate layers due to the immiscibility between SAN31 and PMMA.

MEH-PPV를 이용한 유기전계발황소자의 열적 특성 분석 (Thermal Characteristics Analysis of Organic Electroluminescence Device using MEH-PPV)

  • 박재영;박승욱;신무환
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.112-116
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    • 2001
  • Organic Electroluminescence device, which have the single-layer structure of ITO(indium-tin-oxide)/MEH-PPV (Poly [2-(2'-ethylhexyloxy)-5-methoxy-1, 4-phenylenevinylene])/Al(aluminium) and ITO/MEH-PPV/Alq$_3$(tris-8-hydroxyquinolinato aluminium)/Al were fabricated and electrical properties were investigated. Experimental results, in single-layer structure, shown that alum on voltage is about 12 V, and current density increases as a function of increasing temperature. It was explained by thermionic emission. In double-layer structure, thickness 200 $\AA$ of Alq$_3$ is shown electrical properties that turn on voltage is about 11V, and current density decreases as a function of increasing temperature.

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A Molecular Dynamics Simulation on the Self-assembly of ABC Triblock Copolymers.3. Effects of Block Composition in Asymmetric Triblock Copolymers

  • Ko, Min-Jae;Kim, Seung-Hyun;Jo, Won-Ho
    • Fibers and Polymers
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    • 제4권1호
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    • pp.15-19
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    • 2003
  • The self-assembly of asymmetric ABC triblock copolymers in the ordered structure is investigated using an isothermal-isobaric molecular dynamics simulation. Unlike symmetric A BC triblock copolymers, more fascinating mophologies are observed in asymmetric ones because of a larger difference of incompatibility between the components. Various modes of self-assembly in assymmetric ABC triblock copolymers are also observed depending on the block composition. When the composition of block A Is changed from 0.125: to 0.25 at the same $f_B$ : 0.25, the morphological transition from the “cylinder in cylinder” to “cylinders at cylinder” structure is observed in the simulation. In the case of ABC triblocks with $f_B$=0.5, a lamellar-type structure is changed to a cylinder-type structure with increasing the length of block A. When the midblock length increases further to $f_B$=0.625, the “spheres on cylinder” structure is observed in both the $A_{10}$$B_{50}$$C_{20}$ and $A_{20}$$B_{50}$$C_{10}$ triblocks. From these results, the phase diagram of ABC triblock copolymers can be constructed.

Electrical Properties of Organic Materials as Low Dielectric Constant Materials

  • Oh Teresa;Kim Hong Bae;Kwon Hak Yong;Son Jae Gu
    • 반도체디스플레이기술학회지
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    • 제4권3호
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    • pp.5-9
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    • 2005
  • The bonding structure of organic materials such as fluorinated amorphous carbon films was classified into two types due to the chemical shifts. The electrical properties of fluorinated amorphous carbon films also showed very different effect of two types notwithstanding a very little difference. Fluorinated amorphous carbon films with the cross-link break-age structure existed large leakage current resulting from effect of the electron tunneling. Increasing the cation due to the electron-deficient group increased the barrier height of the films with the cross-link amorphous structure, therefore the electric characteristic of the final materials with low dielectric constant was also improved. The lowest dielectric constant is 2.3 at the sample with the cross-link amorphous structure.

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습식 이온 도핑 p-i-n 구조 유기 발광 소자 (Solution Processable Ionic p-i-n OLEDs)

  • 한미영;오승석;박병주
    • 한국전기전자재료학회논문지
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    • 제22권11호
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    • pp.974-979
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    • 2009
  • We studied solution-processed single-layered phosphorescent organic light-emitting diodes (PHOLEDs), doped with ionic salt and treated with simultaneous electrical and thermal annealing. Because the simultaneous annealing causes the accumulation of salt ions at the electrode surfaces, the energy levels of the organic molecules are bent by the electric fields due to the adsorbed ions, i.e., the simultaneous annealing can induce the proper formation of an ionic p-i-n structure. As a result, an ionic p-i-n PHOLED with a peak luminescence of over ${\sim}35,000\;cd/m^2$ and efficiency of 27 cd/A was achieved through increased and balanced carrier-injections.

건축적 패션 디자인의 구조적 전략 (Tectonic Strategies in Architectonic Fashion Design)

  • 임은혁
    • 패션비즈니스
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    • 제18권1호
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    • pp.164-181
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    • 2014
  • As the boundary between fashion and architecture is getting blurred, the interactions of the two fields are turning out abundant as well as essential. This study investigates the tectonic strategies in architectural fashion design as a novel aesthetic in the 21st century by combining literary survey and case analysis on architecture and contemporary fashion. The tectonic strategies in the works of architectural fashion designers were categorized as follows: organic geometry, technological garment construction, and independent space. Organic geometry transforms basic geometric shapes into subtle organic forms after being thrown on the body. Technological garment construction explores the garment structure and volume by applying the structural principle of suspension and fractal geometry. Independent space refers to maintaining the firm three-dimensionality of garment structure which keeps the distance from the body, assuming the similarity to architecture.

유기 가스 검지를 위한 다공질 실리콘층의 전기 저항 의존성 (Dependence of Electrical Resistance in Porous Silicon Layer for Detecting Organic Vapors)

  • 박광열;김성진;이상훈;최복길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.792-796
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    • 2002
  • In this work, porous silicon(PS) layer is used as a sensing material to detect organic gases. To do this, PS sensors with membrane structure are fabricated. The sensors were made by applying the technologies of membrane formation by anisotropic etching of silicon, and PS layer formation by anodization in HF solution. From fabricated sensors, current-voltage (I-V) curves were measured against ethanol (called alcohol), methanol and acetone gases evaporated from 0.1 to 0.5% solution concentrations at $36^{\circ}C$. As the result, all curves showed rectifying behavior due to a diode structure between Si and PS, and the conductance of sensor devices increased largely with the organic solution concentration at high voltage of 5V.

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유기절연체를 사용한 ZnO 박막트랜지스터 (ZnO TFT with Organic Dielectric)

  • 최운섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.56-56
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    • 2008
  • ZnO Oxide TFT with organic dielectric was prepared. ZnO thin film as active channel was prepared by plasma enhanced atomic deposition technique. Organic dielectric was spin coated on the gate metal. The structure of prepared TFT is bottom gate type and top contact structure. The characterization of oxide TFT was performed. We obtained the mobility of $0.7cm^2$/Vs, the threshold voltage of -14V, and the on-off ratio of $10^4$. We also obtained good output characterization with solid saturation.

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전극 구조에 따른 유기 트랜지스터 특성 (Organic Transistor Characteristics with Electrode Structures)

  • 이붕주
    • 한국전자통신학회논문지
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    • 제8권1호
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    • pp.93-98
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    • 2013
  • 본 논문에서는 유기박막트랜지스터용 절연막에 활용코자 플라즈마 중합방법을 이용하여 PMMA 절연막을 제작하였다. 유기트랜지스터 성능향상을 위해 전극구조에 따른 특성을 파악하고자 트랜지스터의 이동도 및 출력특성을 본결과, 상부전극구조의 경우 최대 이동도는 $8{\times}10^{-3}[cm^2V^{-1}s^{-1}]$을 보이고 하부전극구조의 경우 $2{\times}10^{-4}[cm^2V^{-1}s^{-1}]$의 낮은 이동도 값을 얻었으며, 하부전극구조의 경우 off current값이 증가되는 특성을 볼 수 있다. 그러므로 유기트랜지스터의 전극구조는 상부전극 방식이 좋은 것 알 수 있었다.